Patent Grant
11944117
The present invention relates to a method of manufacturing a heat-not-burn smoking article.
A heat-not-burn smoking article, such as an electrically heated cigarette, has been under investigation. For example, Patent Literature (PTL) 1 discloses a heat-not-burn smoking article that includes a paper tube adjacent to a tobacco rod.
Different from a common combustion-type smoking article, a heat-not-burn smoking article includes members different in properties, such as stiffness. For this reason, when a heat-not-burn smoking article is manufactured by uniformly applying an adhesive to a tipping paper, failures, such as slipping off of part of the members and crease formation in a product, arise. In particular, slipping off of a heated tobacco rod poses a safety problem. In view of the above, an object of the present invention is to provide a method of manufacturing a heat-not-burn smoking article having reduced crease formation and slipping off of a member.
The inventors resolved the above-mentioned problems by optimizing the amount of an adhesive in a specific region of a tipping paper. In other words, the above-mentioned problems are resolved by the present invention below.
(Embodiment 1) A method of manufacturing a smoking article that contains, as members, at least a tobacco rod, a cooling segment, and a filter segment and in which a low-stiffness member 1, and a high-stiffness member H are adjacent to each other, the method including
(Embodiment 2) The method according to Embodiment 1, where an adhesive weight in the portion of a high adhesive weight is 1.5 to 3 times an adhesive weight in the portion of a low adhesive weight.
(Embodiment 3) The method according to Embodiment 1 or 2, where in a step of A, the portion of a high adhesive weight is provided in a region extending from a contact face between the member L and the member H to a 20 to 40% position of the member L in the longitudinal direction.
(Embodiment 4) The method according to any of Embodiments 1 to 3, where in a step of A, a non-adhesive portion is provided at the leading end of the tipping paper, which is defined as a tipping paper region positioned at the end on the side opposite to the mouth end when the tipping paper is wrapped around.
(Embodiment 5) The method according to any of Embodiments 1 to 4, where in a step of A, a non-adhesive portion is provided in a region of the tipping paper for wrapping the cooling segment or the filter segment.
(Embodiment 6) The method according to any of Embodiments 1 to 5, where the composite segment in a step of B is a double-length composite segment prepared by placing a pair of the composite segments such that filter segment end faces come into contact with each other.
(Embodiment 7) The method according to Embodiment 6, where a non-adhesive portion is provided near a region for wrapping a contact part between the filter segment end faces.
(Embodiment 8) The method according to Embodiment 5, further including providing a hole in the non-adhesive portion.
(Embodiment 9) The method according to Embodiment 5 or 8, further including performing printing in the non-adhesive portion.
(Embodiment 10) The method according to any of Embodiments 1 to 9, where the member L has a diameter larger than the member H.
(Embodiment 11) The method according to Embodiment 10, Where the member L has a diameter 0.05 to 0.15 mm larger than the member H.
(Embodiment 12) The method according to Embodiment 10, where the member L has a diameter 0.5 to 2.5% larger than the member H.
(Embodiment 13) A smoking article including, as members, at least a tobacco rod, a cooling segment in contact with the tobacco rod, a filter segment, and a tipping paper for wrapping the tobacco rod, the cooling segment, and the filter segment and including a low-stiffness member L adjacent to a high-stiffness member H, where
(Embodiment 14) The smoking article according to Embodiment 13, where an adhesive weight in the portion of a high adhesive weight is 1.5 to 3 times an adhesive weight in the portion of a low adhesive weight.
(Embodiment 15) The smoking article according to Embodiment 13 or 14, where the tipping paper has a non-adhesive portion in a region for wrapping the cooling segment.
(Embodiment 16) The smoking article according to any of Embodiments 13 to 15, where the tipping paper has a non-adhesive portion in a region for wrapping the filter segment.
(Embodiment 17) The method according to any of Embodiments 1 to 12, where the member L is the cooling segment.
(Embodiment 18) The method according to any of Embodiments 1 to 12 and 17, where the member H is the filter segment.
(Embodiment 19) A method of manufacturing a smoking article that contains, as members, at least a tobacco rod, a cooling segment, and a filter segment, including
(Embodiment 20) The method according to Embodiment 19, where an adhesive weight in the portion of a high adhesive weight is 1.5 to 3 times an adhesive weight in the portion of a low adhesive weight.
(Embodiment 21) The method according to Embodiment 19 or 20, where in a step of A′, the portion of a high adhesive weight is provided in a region extending from a contact face between the tobacco rod and a member neighboring the tobacco rod to a 20 to 40% position of the tobacco rod in the longitudinal direction.
(Embodiment 22) The method according to any of Embodiments 19 to 21, where
(Embodiment 23) The method according to any of Embodiments 19 to 22, where in a step of A′, a non-adhesive portion is provided in a region for wrapping the cooling segment.
(Embodiment 24) The method according to any of Embodiments 19 to 23, where the composite segment in a step of B′ is a double-length composite segment prepared by placing a pair of the composite segments such that filter segment end faces come into contact with each other.
(Embodiment 25) The method according to Embodiment 24, where a non-adhesive portion is provided near a region in the tipping paper for wrapping a contact part between the filter segment end faces.
(Embodiment 26) The method according to Embodiment 23, further including providing a hole in the non-adhesive portion.
(Embodiment 27) The method according to Embodiment 23 or 26, further including performing printing in the non-adhesive portion.
(Embodiment 28) The method according to any of Embodiments 19 to 27, where the tobacco rod has a diameter larger than a neighboring member.
(Embodiment 29) The method according to Embodiment 28, where the tobacco rod has a diameter 0.05 to 0.15 mm larger than the neighboring member.
(Embodiment 30) The method according to Embodiment 28, where the tobacco rod has a diameter 0.5 to 2.5% larger than the neighboring segment.
(Embodiment 31 The method according to any of Embodiments 19 to 30, where the member neighboring the tobacco rod has stiffness higher than the tobacco rod.
(Embodiment 32) The method according to any of Embodiments 19 to 31, where the member neighboring the tobacco rod is the cooling segment or a support segment.
(Embodiment 33) A smoking article including, as members, at least a tobacco rod, a cooling segment, a filter segment, and a tipping paper for wrapping the tobacco rod, the cooling segment, and the filter segment, where
(Embodiment 34) The smoking article according to Embodiment 33, where an adhesive weight in the portion of a high adhesive weight is 1.5 to 3 times an adhesive weight in the portion of a low adhesive weight.
(Embodiment 35) The smoking article according to Embodiment 33 or 34, where the tipping paper has a non-adhesive portion in a region for wrapping the cooling segment.
(Embodiment 36) The smoking article according to any of Embodiments 32 to 35, where the tipping paper has a non-adhesive portion in a region for wrapping the filter segment.
(Embodiment 37) The smoking article according to any of Embodiments 33 to 36, where a member neighboring the tobacco rod is the cooling segment or a support segment.
(Embodiment a1) A method of manufacturing a smoking article that contains, as members, at least a tobacco rod, a cooling segment, and a filter segment and in which a low-stiffness member L and a high-stiffness member H are adjacent to each other, the method including
(Embodiment a2) The method according to Embodiment a1, where an adhesive weight in the portion of a high adhesive weight is 1.5 to 3 times an adhesive weight in the portion of a low adhesive weight.
(Embodiment a3) The method according to Embodiment a1 or a2, where in a step of A″, the portion of a high adhesive weight is provided in a region extending from a contact face between the member L and the member H to a 20 to 40% position of the member L in the longitudinal direction.
(Embodiment a4) The method according to any of Embodiments a1 to a3, where
(Embodiment a5) The method according to any of Embodiments a1 to a4, where in a step of A″, a non-adhesive portion is provided in a region of the tipping paper for wrapping the cooling segment or the filter segment.
(Embodiment a6) The method according to any of Embodiments a1 to a5, where the composite segment in a step of B″ is a double-length composite segment prepared by placing a pair of the composite segments such that filter segment end faces come into contact with each other.
(Embodiment a7) The method according to Embodiment a6, where a non-adhesive portion is provided near a region for wrapping a contact part between the filter segment end faces.
(Embodiment a8) The method according to Embodiment a5, further including providing a hole in the non-adhesive portion.
(Embodiment a9) The method according to Embodiment a5 or a8, further including performing printing in the non-adhesive portion.
(Embodiment a10) The method according to any of Embodiments a1 to a9, where the member L has a diameter larger than the member H.
(Embodiment a11) The method according to Embodiment a10, where the member L has a diameter 0.05 to 0.15 mm larger than the member H.
(Embodiment a12) The method according to Embodiment a10, where the member L has a diameter 0.5 to 2.5% larger than the member H.
(Embodiment a13) A smoking article including, as members, at least a tobacco rod, a cooling segment, a filter segment, and a tipping paper for wrapping the tobacco rod, the cooling segment, and the filter segment and including a low-stiffness member L (excluding the tobacco rod) adjacent to a high-stiffness member H, where
(Embodiment a14) The smoking article according to Embodiment a13, where an adhesive weight in the portion of a high adhesive weight is 1.5 to 3 times an adhesive weight in the portion of a low adhesive weight.
(Embodiment a15) The smoking article according to Embodiment a13 or a14, where the tipping paper has a non-adhesive portion in a region for wrapping the cooling segment.
(Embodiment a16) The smoking article according to any of Embodiments a13 to a15, where the tipping paper has a non-adhesive portion in a region for wrapping the filter segment.
(Embodiment a17) The method according to any of Embodiments a1 to a12, where the member L is the cooling segment.
(Embodiment a18) The method according to any of Embodiments a1 to a12 and a17, where the member H is the filter segment.
According to the present invention, it is possible to provide a method of manufacturing a heat-not-burn smoking article having reduced crease formation and slipping off of a member.
In a smoking article having the sequence of a low-stiffness member adjacent to a high-stiffness member, the inventors found possible to suppress, for example, slipping off of the low-stiffness member by increasing the amount of an adhesive in a region of a tipping paper for Tapping the low-stiffness member. Meanwhile, in view of safety, it is necessary to reliably suppress slipping off of a tobacco rod. Fax this purpose, the inventors also found useful to increase the amount of an adhesive in a region of a tipping paper for wrapping a tobacco rod regardless of the stiffness value of the tobacco rod. Hereinafter, the present invention will be described in detail. In the present invention, the expression “X to Y” includes the lower and the upper limits of X and Y.
I. First Method
1. First Heat-not-Burn Smoking Article
A first heat-not-burn smoking article (hereinafter, also simply referred to as “first smoking article”) of the present invention includes, as members, at least a tobacco rod, a cooling segment, and a filter segment and has the sequence of a low-stiffness member L adjacent to a high-stiffness member H. The first heat-not-burn smoking article may or may not encompass an embodiment in which a tobacco rod as the low-stiffness member L is adjacent to another member (cooling segment, for example) as the high-stiffness member H. However, such an embodiment in which a tobacco rod as the member L is adjacent to the high-stiffness member H (cooling segment, for example) is encompassed in a second heat-not-burn smoking article of the present invention. Accordingly, the embodiment will be described in the next section and thus omitted in the description of the first heat-not-burn smoking article.
The member L preferably has a diameter larger than the member H. As a result, deformation of the member L can be suppressed. The member L preferably has a diameter 0.05 to 0.15 mm larger than the member H. Moreover, the member L has a diameter preferably 0.5 to 2.5% larger and more preferably 1.0 to 2.0% larger than the member H. The member L and the member H may be selected from a tobacco rod, a cooling segment, a filter segment, and other members. However, at least either of the member L and the member 14 is preferably selected from a tobacco rod, a cooling segment, and a filter segment.
(1) Tobacco Rod
A tobacco rod is an almost cylindrical member for generating smoking flavor components contained in tobacco raw materials and includes tobacco filler and a paper wrapper wrapped therearound, The tobacco filler is not limited, and tobacco shreds or tobacco sheets, for example, may be used therefor. Specifically, tobacco shreds prepared by cutting dry tobacco leaves into a width of 0.8 to 1.2 mm may be packed inside a paper wrapper. Alternatively, those prepared by uniformly pulverizing dry tobacco leaves into an average particle size of about 20 to 200 μm, forming into sheets, and cutting the sheets into a width of 0.8 to 1.2 mm may be packed inside a paper wrapper. Moreover, such sheets may be gathered, folded, or spirally rolled without cutting and packed inside a paper wrapper. Further, such sheets may be cut into strips and packed inside a paper wrapper concentrically or with the longitudinal direction of the strips aligned parallel to the longitudinal direction of a tobacco rod.
The tobacco rod may generate an aerosol upon heating. To promote the generation of an aerosol, it is preferable to add an aerosol source, such as glycerol, propylene glycol, 1,3-butanediol, or other polyols, to the tobacco tiller. The amount of an aerosol source to be added is preferably 5 to 50 weight % and more preferably 10 to 30 weight % based on the dry weight of the tobacco tiller. In addition, the tobacco rod may contain a flavor, such as menthol. The length of the tobacco rod is not limited but is preferably 15 to 25 mm. The diameter is also not limited but is preferably 6.5 to 7.5 mm. Meanwhile, when a neighboring member has stiffness higher than the tobacco rod, the tobacco rod preferably has a diameter larger than the neighboring member. As a result, deformation of the tobacco rod can be suppressed. Accordingly, in this case, the tobacco rod has a diameter preferably 0.5 to 2.5% larger and more preferably 1.0 to 2.0% larger than the neighboring member. In actual dimension, the tobacco rod preferably has a diameter about 0.05 to 0.15 mm larger than the neighboring member.
The term “stiffness” in the present invention means the resistance member to deformation as disclosed in paragraphs to of Japanese Unexamined Patent Application Publication (Translation of PCT Application) No. 2016-523565. Stiffness can be obtained, for example, from a change in diameter before and after applying a load F on the side surface of a tobacco rod. When the diameter of a tobacco rod before applying a load F is denoted by Ds and the diameter after applying the load is denoted by Dd as in
Stiffness(%)=Dd/Ds×100
(2) Cooling Segment
A cooling segment is a member for cooling an aerosol and smoking flavor components generated in the tobacco rod 1. The cooling segment 3 may be a hollow paper tube. The paper tube is preferably made of cardboard having stiffness higher than paper wrappers and tipping papers. The paper tube may be provided with a hole (ventilation holes). A plurality of holes are preferably formed along the circumference of the paper tube. In view of efficient operations, such holes are preferably formed by laser processing of a finished smoking article. Moreover, to enhance heat exchange efficiency, gathered sheets may be packed inside the cooling segment 3. Such sheets may be polymer sheets, such as polylactic acid. Although the dimensions of the cooling segment 3 are not limited, the length is preferably 15 to 25 rum and the diameter is preferably 5.5 to 7.5 mm. Meanwhile, when a member neighboring the cooling segment 3 has stiffness lower than the cooling segment 3, the cooling segment 3 has a diameter preferably 0.5 to 2.5% smaller and preferably 1.0 to 2.0% smaller than the neighboring member. When the cooling segment 3 includes a paper tube made of cardboard, the segment generally has stiffness higher than the tobacco rod 1. Meanwhile, as in the foregoing, when the cooling segment 3 is made of a polymer sheet or the like, such as polylactic acid, and wrapped in a common wrapper, the segment could have stiffness lower than the tobacco rod 1.
(3) Filter Segment
A filter segment is a member including a filter. As the filter, a publicly known filter member, such as an acetate filter or a paper filter, may be used. A paper filter is a paper-filled filter prepared by creasing paper through processing with a crepe roller or the like and by rolling the paper using a plug wrapper. An acetate filter is a filter filled with cellulose acetate fibers. The filter segment 5 is preferably composed of a plurality of members and more preferably includes a filter 51 and a center hole member 53 (
(4) Tipping Paper
The term “tipping paper” refers to a paper used for joining two or more members, such as a tobacco rod, a cooling segment, and a filter segment. Meanwhile, the term “paper wrapper” refers to a paper for wrapping individual members that constitute a tobacco rod, a cooling segment, or a filter segment. For example, when a filter segment includes a center hole member and an acetate filter as in the foregoing, a paper for wrapping the center hole member and a paper for wrapping the acetate filter are each paper wrapper.
Exemplary base paper for tipping papers and paper wrappers includes, but is not limited to, paper using cellulose fibers. Such cellulose fibers may be either derived from plants or chemically synthesized, or may be a mixture thereof. Exemplary plant-derived fibers include pulp of flax fibers, wood fibers, or seed fibers, for example. Such pulp may be colored unbleached pulp. However, from a viewpoint of obtaining white clean appearance, it is preferable to use bleached pulp, which is prepared using a bleaching agent, such as an oxidant or a reductant.
For a typical paper wrapper for cigarettes, a citric acid alkali metal salt or the like is used as a common burning chemical (combustion aid, for example) that can affect the spontaneous combustion rate of the paper wrapper. In the present invention, a heat-not-burn smoking article but not a combustion-type is preferable. In this case, since the combustion of a paper wrapper is unnecessary, the paper wrapper need not contain a burning chemical.
The lower limit of the basis weight of a paper wrapper is preferably 30 g/m2 or more, more preferably 35 g/m2 or more, and further preferably 40 g/m2 or more. The upper limit is preferably 65 g/m2 or less and more preferably 50 g/m2 or less. Meanwhile, the lower limit of the basis weight of a tipping paper is preferably 20 g/m2 or more, more preferably 25 g/m2 or more, and further preferably 30 g/m2 or more. The upper limit is preferably 50 g/m2 or less, more preferably 45 g/m2 or less, and further preferably 40 g/m2 or less. The basis weight can be measured by the method specified in JIS P 8124.
(5) Other Members
The smoking article of the present invention may include a member excluding the above-described members. Exemplary other members include a support segment. A support segment is a member that enhances the strength of the smoking article or a member that is disposed in the downstream side of a tobacco rod and that suppresses displacement of tobacco filler. Such a support segment may be the foregoing center hole member, for example. When a center hole member is used as a support segment, the dimensions are not limited but the length is preferably 5 to 10 mm and the diameter is preferably 5 to 8 mm.
2. First Manufacturing Method.
(1) Step A
In this step, an adhesive is placed on either surface of the tipping paper 7. A method of placing an adhesive is not limited, and a method of applying an adhesive to the tipping paper 7 or a method of preparing an adhesive sheet in advance and disposing the adhesive sheet on the tipping paper 7, for example, may be employed. Specific examples include a method of applying an adhesive to a roller surface and transferring the adhesive to the tipping paper 7 and a method of discharging an adhesive from nozzles onto the tipping paper 7.
As the adhesive, publicly known adhesives may be used but vinyl acetate-based adhesives are particularly preferable. The expression “after solidification” indicates a solidified state after removal of solvent in the case of a solvent-containing adhesive and a, crosslinked state in the case of a solvent-free crosslinkable adhesive. Moreover, the “adhesive weight per unit area after solidification” is also simply referred to as “adhesive weight.”
The adhesive portion b indicates a portion that has an adhesive and that excludes the increased adhesive portion 1b. An adhesive weight in the adhesive portion b can be adjusted appropriately but is preferably 0.005 to 0.015 mg/mm2. The adhesive layer thickness in the adhesive portion b is preferably set to about 0.01 to 0.03 mm in the unsolidified state. The unsolidified state means a state before solidification of the adhesive. In the present invention, the adhesive weight in the increased adhesive portion 1b is set larger than the adhesive weight in the adhesive portion b. In general, the adhesive strength increases as the adhesive weight increases. Consequently, however, creases tend to be formed in products. In the present invention, since the adhesive weight is increased only in the increased adhesive portion 1b, it is possible to prevent slipping off of the member L and prevent crease formation in the remaining portion. In this view, the ratio of the adhesive weight in the increased adhesive portion 1b (1b weight) to the adhesive weight in the adhesive portion b (b weight) is preferably 1.5 to 3.0 and more preferably 1.7 to 2.7. The “1b weight” is an average adhesive weight in the increased adhesive portion 1b. When a plurality of portions having different adhesive weights exist, the “1b weight” is defined as an average adhesive weight in a portion having the maximum adhesive weight and the “b weight” as an average adhesive weight in the adhesive portion b excluding the increased adhesive portion 1b.
As the area of the increased adhesive portion 1b increases, failures, such as slipping off of a member, becomes less likely to arise. However, in view of costs or the like, the increased adhesive portion 1b need not be placed on the entire surface of the member L, The increased adhesive portion 1b preferably exists in a region extending from a bonding face between the member L and the member H in
The tipping paper 7 preferably has a non-adhesive portion 1n at the leading end. The leading end indicates a tipping paper region positioned at the end on the side opposite to the mouth end when the tipping paper is wrapped around. As a result, bleeding of an adhesive from the leading end of the tipping paper 7 is prevented during wrapping. The length u of the non-adhesive portion 1n in the longitudinal direction of the tipping paper 7 is preferably 0.1 to 1.0 mm.
The tipping paper 7 preferably has a non-adhesive portion 3n in a region for wrapping the cooling segment 3 or the filter segment 5. When the non-adhesive portion 3n is provided, ventilation holes are easily formed in these segments of a smoking article 100 to be manufactured. Such ventilation holes can be formed, for example, by laser processing after manufacturing a smoking article 100. Moreover, printing may also be performed in the non-adhesive portion 3n. For example, when a code that represents the manufacturing machine is printed on the non-adhesive portion 3n, the code can be read after wrapping by peeling off the tipping paper 7.
The non-adhesive portion 3n may be provided in a region extending from a 40 to 50% position to a 70 to 90% position in the longitudinal direction of the filter segment 5 based on the contact face (point Y) between the cooling segment 3 and the filter segment 5. In other words, the non-adhesive portion 3n may be provided in a region from 0.4 to 0.5Y to to 0.9Y in the mouth end direction of
As illustrated in
The tipping paper 7 preferably has a non-adhesive portion 5n near the filter segment end. As illustrated in
(2) Step B
In this step, the composite segment 90 is wrapped in the tipping paper 7. As illustrated in
Wrapping can be performed by a publicly known method. As illustrated in
As in the foregoing, neighboring members have different diameters in some cases. For example,
II. Second Method
1. Second Heat-not-Burn Smoking Article
A second heat-not-burn smoking article of the present invention (hereinafter, also simply referred to as “second smoking article” includes, as members, at least a tobacco rod, a cooling segment, and a filter segment.
A member neighboring a tobacco rod is not limited. Exemplary combinations of a tobacco rod and its neighboring member include the following sequences.
Tobacco rod/cooling segment
The tobacco rod, the cooling segment, the filter segment, the support segment, and the tipping paper are as described for the first smoking article.
2. Second Manufacturing Method
The second manufacturing method includes (A′) placing an adhesive on either surface of a tipping paper to form each portion of a high adhesive weight and a low adhesive weight per unit area after solidification, where the portion of a high adhesive weight is provided in a region for wrapping the tobacco rod; and (B) preparing a composite segment that contains at least the tobacco rod, the cooling segment, and the filter segment and wrapping the composite segment in the tipping paper.
(1) Step A′
In this step, an adhesive is placed on either surface of the tipping paper 7. The method of placing an adhesive can be performed in the same manner as the first method as illustrated in
The increased adhesive portion 1b is preferably not wrapped around the cooling segment 3. When the cooling segment 3 having low stiffness is wrapped in the increased adhesive portion 1b, creases tend to be formed. Moreover, when the cooling segment 3 is a paper tube made of cardboard, an adhesive is less likely to permeate the cardboard, due to the high basis weight, compared with a paper wrapper for the tobacco rod 1. For these reasons, when the amount of an adhesive is smaller in a region for wrapping the paper tube than in a region for wrapping the tobacco rod 1, it is possible to suppress failures, such as bleeding of an adhesive, crease formation, and failed bonding.
The tipping paper 7 preferably has a non-adhesive portion in at the leading end.
The leading end in this embodiment indicates a tipping paper region positioned at the end on the tobacco rod side when the tipping paper is wrapped around. As a result, bleeding of an adhesive from the leading end of the tipping paper 7 is prevented during wrapping. The length u of the non-adhesive portion 1n in the longitudinal direction of the tipping paper 7 is preferably 0.1 to 1.0 mm. The non-adhesive portions 3n and 5n are as described for the first manufacturing method.
(2) Step B′
In this step, as described for the first manufacturing method, the composite segment 90 is wrapped in the tipping paper 7. As illustrated in
As in the foregoing, the tobacco rod 1 has a diameter larger than the neighboring member (cooling segment 3, for example) in some cases. In this case, as described for the first manufacturing method with reference to
The following members were prepared.
Tobacco rod of 7.0 mm in diameter and 20.0 mm in length (from Japan Tobacco Inc.)
Paper tube of 6.9 mm in diameter and 20.0 mm in length as a cooling segment
Double-length filter segment of 6.9 mm in diameter consisting of a center hole member (8.0 mm)/a double-length acetate filter (14.0 mm)/a center hole member (8.0 mm)
A tipping paper illustrated in
A double-length smoking article as illustrated in
| Number | Date | Country | Kind |
|---|---|---|---|
| PCT/JP2018/037340 | Oct 2018 | WO | international |
The present application is a continuation application of International Application No. PCT/JP2019/036045, filed on Sep. 13, 2019, which claims priority under 35 U.S.C. 119(a) to Patent Application No. PCT/JP2018/037340, filed in Japan on Oct. 5, 2018, all of which are hereby expressly incorporated by reference into the present application.
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| Number | Date | Country | |
|---|---|---|---|
| 20210212357 A1 | Jul 2021 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | PCT/JP2019/036045 | Sep 2019 | US |
| Child | 17219431 | US |
