Patent Application
20190115164
The present invention relates to a method for manufacturing a stack of graphene and carbon nanotube, an electrode material including a stack of graphene and carbon nanotube, and an electric double-layer capacitor using the same.
Power storage devices typified by an electric double-layer capacitor and a lithium ion battery have attracted attention for their large capacitance. The performance of such power storage devices largely depends on an electrode material, and electrode materials that can increase the electrostatic capacitance, the energy density, and the power density have been developed.
It has been known that graphene is used as an electrode material of an electric double-layer capacitor. For example, a sheet-shaped electrode including a porous graphene layer through which electrolyte solution ions can pass has been developed (see, for example, Non-Patent Literature 1). According to Non-Patent Literature 1, graphene is integrated into layers to achieve an energy density of 35 Wh/kg. Another example is a porous graphene sheet in which graphene is grown by CVD using MgO as a template (see, for example, Non-Patent Literature 2). According to Non-Patent Literature 2, the electrolyte solution ions move easily to a vertical direction of the graphene sheet to achieve an electrostatic capacitance of 303 F/g.
Still another known example is a graphene sheet film having carbon nanotube held between graphene sheets (see, for example, Patent Literature 1). According to Patent Literature 1, by using the conductivity of carbon nanotube in addition to the characteristics of the graphene sheet, an electrostatic capacitance of 290.6 F/g and an energy density of 62.8 Wh/kg are achieved.
An electrode material including graphene with nanopores has also been developed (for example, see Non-Patent Literatures 3 and 4, and Patent Literature 2). According to Non-Patent Literature 3, an electrode material in which nanopores are introduced to graphene by KOH using microwaves achieves an energy density of 100 Wh/kg. According to Non-Patent Literature 4, graphene oxide is separated by microwaves, activation is performed using KOH, and then, heating is performed, so that nanopores are introduced to graphene. Such graphene includes nanopores each having a size of 0.6 nm to 5 nm, and has a specific surface area of 3100 m2/g. According to Patent Literature 2, nanopores are introduced to graphene by a continuous electrolytic peeling method. In addition, Patent Literature 2 discloses that the electrode material includes a stack of carbon nanotube and graphene having nanopores introduced by a continuous electrolytic peeling method. Such an electrode material achieves an energy density of 90.3 Wh/kg.
On the other hand, it has been known that graphene is used for other purposes than the electrode material (for example, see Patent Literature 3 and Non-Patent Literature 5). Patent Literature 3 discloses that macromolecules are analyzed using a nanopore device based on graphene. Non-Patent Literature 5 discloses a sensor in which nanopores are introduced to a graphene stack and DNA is caused to pass the nanopores by an electric field.
As described above, it has been examined to utilize the characteristics of graphene by various perspectives and attempts of means for those perspectives. However, the examinations for the utilization of graphene are still in the unexplored territory, and it has been strongly expected to develop an electrode material including graphene that further improves capacitor characteristics such as the electrostatic capacitance, the energy density, and the power density. It would be preferable if other applications of such an electrode material were developed.
Patent Literature 1: International Publication No. WO 2012/073998
Patent Literature 2: International Publication No. WO 2014/065241
Patent Literature 3: U.S. Patent Application Publication No. 2013/0309776
Non-Patent Literature 1: Y. Xu, et al., Nature Communication, 2014, 5554
Non-Patent Literature 2: H. Wang, et al., Nanoscale, 2014, 6, 6577
Non-Patent Literature 3: T-Y. Kim, et al., ACSNANO, 2013, 7, 6899
Non-Patent Literature 4: Y. Zhu, et al., Science, 2011, 332, 1537
Non-Patent Literature 5: S. M. Avdoshrnko, et al., Nano Letters, 2013, 13, 1969
An object of the present invention is to provide a novel method for manufacturing a graphene stack that can further improve a capacitor characteristic using graphene, an electrode material including the graphene stack, and an electric double-layer capacitor including the graphene stack.
The present invention provides a novel method for manufacturing a stack of graphene and carbon nanotube. That is to say, the manufacturing method according to the present invention includes a step of dispersing the graphene in an aqueous MOH solution (M represents an element selected from a group consisting of Li, Na, and K) to adsorb MOH on the graphene, a step of heating the graphene with MOH adsorbed thereon that is obtained in the adsorption step in vacuum or in an inert atmosphere in a temperature range of 400° C. or more and 900° C. or less to form pores in the graphene, and a step of dispersing the carbon nanotube and the graphene with the pores that are obtained in the step of forming the pores in a dispersion medium to stack the carbon nanotube and the graphene with the pores.
In the step of forming the pores, the graphene with MOH adsorbed thereon may be heated in a temperature range of 650° C. or more and 800° C. or less for 10 minutes or more and 3 hours or less.
In the step of forming the pores, the graphene with MOH adsorbed thereon may be heated in a temperature range of 650° C. or more and 750° C. or less.
In the step of forming the pores, the graphene with MOH adsorbed thereon may be heated in a temperature range of 675° C. or more and 725° C. or less.
The method may further include prior to the adsorption step: a step of freeze-drying an oxidized graphene dispersion liquid in which oxidized graphene is dispersed in water; and a step of thermally reducing the oxidized graphene dispersion liquid that is freeze-dried in a temperature range of 300° C. or more and 700° C. or less for 1 second or more and 10 minutes or less to prepare graphene including a graphene sheet of one or more and three or less layers.
In the adsorption step, the aqueous MOH solution may have a molarity of 5 M or more and 10 M or less.
In the adsorption step, the graphene may be dispersed so that the graphene in the aqueous MOH solution has a concentration of 5 g/L or more and 20 g/L or less.
In the adsorption step, the aqueous MOH solution with the graphene dispersed therein may be stirred at room temperature for 12 hours or more and 30 hours or less.
In the stacking step, the graphene and the carbon nanotube may be dispersed so that a mass ratio of the graphene to the carbon nanotube (graphene/carbon nanotube) is in a range of 1 or more and 50 or less.
In the stacking step, the graphene and the carbon nanotube may be dispersed so that the mass ratio of the graphene to the carbon nanotube (graphene/carbon nanotube) is in a range of 5 or more and 15 or less.
In the stacking step, the dispersion medium may be selected from the group consisting of water, N-methylpyrrolidone (NMP), N,N-dimethylformamide (DMF), and dimethyl sulfoxide (DMSO).
In an electrode material including a stack of graphene and carbon nanotube according to the present invention, the graphene includes pores through which electrolyte solution ions pass; and layers of the graphene are stacked with the carbon nanotube interposed therebetween at intervals that enable the electrolyte solution ions to pass. Thus, the above problem is solved.
The graphene may include a graphene sheet of one or more and three or less layers, and include pores with a pore diameter of 0.4 nm or more and 10 nm or less.
The stack may have a specific capacity in a range of 200 F/g or more and 400 F/g or less.
The graphene may include a carboxylic group and/or a hydroxyl group.
The stack may be manufactured by any of the above methods.
In an electric double-layer capacitor according to the present invention including an electrode and an electrolyte, the electrode includes the electrode material described above. Thus, the above problem is solved.
The electrolyte may be M′OH (M′ is an alkali metal) or an ionic liquid selected from the group consisting of EMI-TFSI, EMI-BF4, and MPPp-TFSI.
The electrolyte may be EMI-TFSI and an application voltage may be 4 V or less.
The electrolyte may be MPPp-TFSI and an application voltage may be 4.5 V or more.
In the manufacturing method according to the present invention, graphene with MOH (M is an element selected from the group consisting of Li, Na, and K) adsorbed thereon is heated in the temperature range of 400° C. or more and 900° C. or less; thus, MOH reacts with C in graphene to become M2CO3. The resulting M2CO3 is burned away by the heating, and thus, graphene with pores through which electrolyte solution ions can pass is obtained. When such graphene and carbon nanotube are dispersed in the dispersion medium, the stack in which the carbon nanotube and the graphene are stacked in a self-organizing manner can be provided. In this graphene, the electrolyte solution ions can pass, and between the layers of graphene, the electrolyte solution ions can pass.
The stack allows the electrolyte solution ions to penetrate not just a surface of graphene but also the inside of the stack through the pores and moreover, the electrolyte solution ions that have penetrated can move between the layers of graphene easily. Thus, graphene and the electrolyte solution ions can exchange electrons also inside the stack. As a result, the electrostatic capacitance can be increased drastically and the energy density and the power density can be improved. Thus, when a capacitor is formed using an electrode material including the stack according to the present invention, an electric double-layer capacitor with high capacitor performance having the energy density and the power density increased can be provided.
Embodiments of the present invention will hereinafter be described with reference to the drawings. Note that the similar components are denoted by the same reference sign and the description of such components is not repeated.
In a first embodiment, it will be described a stack according to the present invention and a method for manufacturing the stack.
A stack 100 according to the present invention is a stack of graphene 110 and a carbon nanotube 120. The graphene 110 includes pores 130 through which electrolyte solution ions pass. Layers of the graphene 110 are stacked with the carbon nanotube 120 interposed therebetween, and the layers of the graphene 110 are spaced apart from each other so that the electrolyte solution ions can pass. For simplification,
The inventors of the present application have discovered that, by such a design using the graphene and the carbon nanotube, the electrode material that can drastically improve the capacitor performance is obtained. When the stack according to the present invention is used in the electrode material of the capacitor, the electrolyte solution ions can penetrate not just a surface of the graphene 110 but also the inside of the stack 100 through the pores 130 (that is, the electrolyte solution ions move in a vertical direction relative to a plane direction of the graphene 110). Furthermore, the electrolyte solution ions that have penetrated can move easily between the layers of the graphene 110 (that is, the electrolyte solution ions move in a horizontal direction that is the same as the plane direction of the graphene 110). Thus, the graphene 110 and the electrolyte solution ions can exchange electrons also inside the stack 100. As a result, the electrostatic capacitance can be drastically increased and the energy density and the power density can be increased.
The graphene 110 preferably includes a graphene sheet of one or more and three or less layers. The graphene 110 serves as walls that form the space between the layers of the graphene 110 and the walls are very thin and flexible. Therefore, by using the flexibility of the graphene 110, the size of the space between the layers of the graphene 110 can be expanded easily on the basis of the application voltage.
The pore 130 has a diameter of, preferably, 0.4 nm or more and 10 nm or less. Thus, the electrolyte solution ions can pass through the pores 130. More preferably, the pore 130 has a diameter of 2 nm or more and 4 nm or less, and in this case, more electrolyte solution ions can pass through the pores 130.
The graphene 110 may have a functional group 140 such as a carboxyl group or a hydroxyl group. Such a functional group 140 remains on a surface of the graphene 110 in the manufacture, and even if the capacitor includes the functional group 140, the capacitor performance can be maintained.
The stack 100 has a specific capacity of 200 F/g or more and 400 F/g or less; therefore, by using such an electrode material for the capacitor, the energy density and the power density can be improved.
The carbon nanotube 120 may be an aggregation of a plurality of carbon nanotubes, or single nanotube; how the carbon nanotube exists is not limited to a particular mode. The carbon nanotube 120 may independently exist or may exist in a bundle shape, an entangled shape, or a mixed state of these shapes. Alternatively, the carbon nanotube 120 may have various numbers of layers or may include various outer diameters.
The carbon nanotube 120 is single-walled carbon nanotube (SWNT), double-walled carbon nanotube (DWNT), or multi-walled nanotube (MWNT), and is preferably single-walled carbon nanotube. The single-walled carbon nanotube has conductivity as high as 104 S/cm or more, and since the stack 100 has the higher conductivity, the capacitor performance can be improved.
The carbon nanotube 120 is controlled so that the distance between the layers of the graphene 110 in the stack 100 corresponds to the electrolyte solution ions. From this perspective, the diameter of the carbon nanotube 120 is preferably 0.4 nm or more and 10 nm or less. Since the graphene 110 is highly flexible as described above, the distance between the layers can be controlled on the basis of the application voltage so that the electrolyte solution ions can pass. More preferably, the diameter of the carbon nanotube 120 is 1 nm or more and 3 nm or less.
In the stack 100, the mass ratio of the graphene to the carbon nanotube is in the range of 1 or more and 50 or less. If the mass ratio is less than 1, the graphene is not contained enough to achieve the function as the electrode material. If the mass ratio is more than 50, the carbon nanotube does not function as a spacer. Preferably, the mass ratio is in the range of 5 or more and 15 or less. Within this range, the stack 100 can have the specific surface area and the specific capacity that are described above.
In the present specification, the carbon nanotube 120 is used between the layers of the graphene 110; however, other fibrous materials than the carbon nanotube 120 may be used for the perspective of the spacer.
The average of the outer diameters of the fibrous materials is not limited to a particular value; however, it is preferable that the average of the outer diameters is in the range of 0.4 to 5.0 nm, more preferably 1.0 to 3.0 nm, from the viewpoint of efficiently forming a composition with a two-dimensional material. The average of the outer diameters of the fibrous materials can be calculated in the following manner: the fibrous materials are observed with a transmission type electronic microscope at an arbitrary magnification, a plurality of parts of the fibrous materials is extracted arbitrarily from a viewing field whose certain proportion in a viewing field area is the fibrous materials, and an arithmetic average value is obtained from the outer diameters of the extracted parts of the fibrous materials.
In the stack 100, it is preferable that the carbon nanotube 120 is not aggregated in a bundle shape but dispersed between the layers of the graphene 110. Thus, the electrolyte solution ions can easily move between the layers of the graphene 110. Such a dispersed state of the carbon nanotube 120 is achieved by a manufacturing method according to the present invention that will be described below.
As described with reference to
The pores 130 are formed in the graphene 110 including a graphene sheet of one or more and three or less layers. The size of the pore 130 is controlled by adjusting a heating condition to be described below. On the other hand, since the space is formed between the graphene 110 including the graphene sheet of one or more and three or less layers, the walls that form the space are thin and flexible. The size of the space can have a relatively wide distribution ranging from the space between the layers of the graphene 110 to the carbon nanotube 120.
As illustrated in
The stack 100 according to the present invention having the structure as described above is manufactured by a manufacturing method according to the present invention, which is to be described next. The method for manufacturing the stack 100 according to the present invention will be described with reference to
Step S310: graphene is dispersed in an aqueous MOH solution (M is an element selected from the group consisting of Li, Na, and K) and MOH is adsorbed on graphene. The molarity of the aqueous MOH solution is preferably in the range of 0.1 M or more and 10 M or less. If the molarity is less than 0.1 M, MOH is not sufficiently adsorbed on graphene; therefore, the formation of the pores may fail. If the molarity is more than 10 M, MOH is excessively adsorbed on graphene and it may be difficult to control the pore diameter. The molarity of the aqueous MOH solution is preferably in the range of 5 M or more and 10 M or less. Thus, graphene can adsorb MOH more certainly. The aqueous MOH solution is preferably an aqueous KOH solution. KOH is easily adsorbed on graphene.
The graphene is dispersed so that the graphene concentration in the aqueous MOH solution is 1 g/L or more and 50 g/L or less. If the graphene concentration in the aqueous solution is less than 1 g/L, graphene is deficient; therefore, MOH is adsorbed excessively on graphene and it may be difficult to control the pore diameter. If the graphene concentration in the aqueous solution is more than 50 g/L, graphene is excessive; therefore, MOH is not sufficiently adsorbed on graphene and the formation of the pores may fail. It is more preferable that graphene is dispersed so that the graphene concentration in the aqueous MOH solution is 5 g/L or more and 20 g/L or less. Thus, MOH is adsorbed on graphene and graphene with the above pore diameter can be obtained. It is much more preferable that the graphene is dispersed so that the graphene concentration in the aqueous MOH solution is 15 g/L or less. Thus, it is possible to control so that MOH is adsorbed to graphene certainly and the graphene with the pore diameter in the above range can be obtained.
In a specific procedure of the adsorption, the aqueous MOH solution with the graphene dispersed therein may be held at room temperature for 12 hours or more and 30 hours or less. If the solution is held for less than 12 hours, the adsorption occurs but may be insufficient. If the solution is held over 30 hours, the amount of adsorption remains the same. After the solution is held, the aqueous MOH solution with the graphene dispersed therein is filtered. In the present specification, the room temperature refers to the temperatures in the range of 15° C. or more and 30° C. or less.
Step S320: the graphene with MOH adsorbed thereon obtained in step S310 is heated in vacuum or an inert atmosphere in the temperature range of 400° C. or more and 900° C. or less. Between MOH and the carbon of graphene, the following reaction occurs and finally, pores are formed in the graphene with high density. The inert atmosphere may be nitrogen, or rare gas such as argon.
First, MOH adsorbed on graphene and the carbon of graphene react with each other to generate a carbonate of M (Formula (1)):
6MOH+2C→2M+3H2+2M2CO3 (1)
Next, as heat is applied, the carbonate of M and the carbon of graphene react further as expressed by the following Formula (2), and through the decomposition and burning, the pores 130 (
M2CO3+2C→2K+3CO (2)
Alternatively, as heat is applied, the carbonate of M is decomposed and burned as expressed by Formulae (3) and (4) and thus, the pores 130 are formed:
M2CO3→K2O+CO2 (3)
CO2+C→2CO (4)
When the heating temperature is less than 400° C., the reaction does not progress sufficiently and the pores are not formed. When the heating temperature is more than 900° C., it may be difficult to control the pore diameter. Preferably, the heating temperature is 650° C. or more and 800° C. or less, and the heating time is 10 minutes or more and 3 hours or less. Thus, the graphene including the pores with a pore diameter of 0.4 nm or more and 10 nm or less and having a specific surface area (BET method) of 700 m2/g or more and 4000 m2/g or less can be obtained. More preferably, the heating temperature is 650° C. or more and 750° C. or less. Thus, the graphene including the pores with a pore diameter of 0.4 nm or more and 10 nm or less and having a specific surface area of 700 m2/g or more and 4000 m2/g or less can be obtained for sure. More preferably, the heating temperature is 675° C. or more and 725° C. or less. Thus, the graphene including the pores with a pore diameter of 0.4 nm or more and 10 nm or less and having a specific surface area as large as 2000 m2/g or more and 4000 m2/g or less can be obtained.
Step S330: the carbon nanotube and the graphene with the pores obtained in step S320 are dispersed in a dispersion medium and the carbon nanotube and the graphene with the pores are stacked.
The dispersion medium is preferably selected from the group consisting of water, N-methylpyrrolidone (NMP), N,N-dimethylformamide (DMF), and dimethyl sulfoxide (DMSO). NMP, DMF, and DMSO can disperse the graphene and the carbon nanotube well. Water can also disperse the graphene and the carbon nanotube, and in the case of using water, a surfactant is preferably used together. Examples of the surfactant include dodecylbenzene sodium sulfonate, dodecyl sodium sulfate, sodium cholate, and sodium deoxycholate.
The carbon nanotube is single-walled carbon nanotube (SWNT), double-walled carbon nanotube (DWNT), or multi-walled nanotube (MWNT), and is preferably single-walled carbon nanotube. The single-walled carbon nanotube has conductivity as high as 104 S/cm or more, and can provide a stack with the higher conductivity.
In step S330, it is preferable to disperse in the dispersion medium the carbon nanotube and the graphene with the pores so that the mass ratio of the graphene to the carbon nanotube (graphene/carbon nanotube) is in the range of 1 or more and 50 or less. If the mass ratio is less than 1, the graphene is not contained enough to achieve the function as the electrode material. If the mass ratio is more than 50, the carbon nanotube does not function as the spacer and the formation of the stack may fail. Preferably, the mass ratio is in the range of 5 or more and 15 or less. Within this range, the graphene and the carbon nanotube are stacked in the excellent manner.
In a specific procedure of stacking the layers, for example, the graphene with the pores may be dispersed in the dispersion medium and the carbon nanotube may be added thereto, and the mixture may be stirred at room temperature. Thus, the stack including the carbon nanotube between the layers of the graphene can be obtained in a self-organizing manner.
Note that the graphene used in step S310 is preferably graphene manufactured by a thermal reduction method. The graphene manufactured by the thermal reduction method is formed of a graphene sheet including one or more and three or less layers and is excellent in dispersibility. In addition, since the graphene manufactured by the thermal reduction method includes functional groups such as a carboxyl group and a hydroxyl group abundantly in its manufacturing process, using the graphene with such functional groups as a starting material can promote the adsorption of MOH on the graphene in step S310 and thus, the pores can be formed with high density.
The thermal reduction method that is performed prior to step S310 is described with reference to
Step S410: oxidized graphene is dispersed in water to form an oxidized graphene dispersion liquid, and the oxidized graphene dispersion liquid is freeze-dried. Thus, oxidized graphene in a foamed state is obtained. Oxidized graphene may be commercial oxidized graphene, or may be manufactured from graphite particles by, for example, Brodie method, Staudenmaier method, Hummer method, or improved Hummers method. To a surface of oxidized graphene, functional groups such as a carbonyl group, a carboxyl group, and a hydroxyl group are added. Oxidized graphene is also referred to as graphene oxide (GO).
Oxidized graphene is dispersed in water so that the concentration of oxidized graphene in the dispersion liquid becomes 0.5 mg/mL or more and 50 mg/mL or less. More preferably, the oxidized graphene is dispersed in water so that the concentration becomes 1 mg/mL or more and 5 mg/mL or less. This dispersion promotes freeze-drying, and thus, oxidized graphene in a foamed state having a density of 1 g/L or more and 50 g/L or less can be obtained.
In a specific procedure of the freeze-drying, the oxidized graphene dispersion liquid with the concentration controlled as above may be kept in a dry-freezer maintained at −5° C. or less for 5 hours or more and 100 hours or less, or immersed in liquid nitrogen for 1 minute or more and 10 minutes or less.
Step S420: the oxidized graphene dispersion liquid that is freeze-dried in step S410 is thermally reduced in the temperature range of 300° C. or more and 700° C. or less for 1 second or more and 10 minutes or less. Thus, the carbonyl group added to the oxidized graphene dispersion liquid that is freeze-dried is removed and the oxidized graphene is reduced to graphene. The reduced graphene includes a graphene sheet of one or more and three or less layers. Since the functional groups such as the carboxyl group and the hydroxyl group added in step S410 remain, the graphene keeps the hydrophilicity and the adsorption of MOH can be promoted in step S310 as described above. The atmosphere of the thermal reduction may be air, or an inert atmosphere of argon, nitrogen, or the like.
In a second embodiment, it will be described the application of the electrode material including the stack according to the present invention that is obtained in the first embodiment.
The electric double-layer capacitor according to the present invention includes at least an electrode and an electrolyte. An electric double-layer capacitor 500 illustrated in
As described with reference to
The electric double-layer capacitor 500 further includes a separator 540 between the positive electrode 510 and the negative electrode 520 so as to separate these positive electrode 510 and negative electrode 520 from each other.
Examples of the material of the separator 540 include fluorine polymer, polyether such as polyethylene oxide and polypropylene oxide, polyolefin such as polyethylene and polypropylene, polyacrylonitrile, polyvinylidene chloride, polymethyl methacrylate, polymethyl acrylate, polyvinyl alcohol, polymethacrylonitrile, polyvinyl acetate, polyvinyl pyrrolidone, polyethylene imine, polybutadiene, polystyrene, polyisoprene, polyurethane polymer, a derivative of any one of those above, cellulose, paper, and non-woven fabric.
In the electric double-layer capacitor 500, the positive electrode 510, the negative electrode 520, the electrolyte 530, and the separator 540 described above are housed in a cell 550. Each of the positive electrode 510 and the negative electrode 520 may include the existing current collector.
The electric double-layer capacitor 500 may be a capacitor of a chip type, a coin type, a mold type, a pouch type, a laminate type, a cylindrical type, or a rectangular type, and may be a module in which these are connected.
Next, description is made of the operation of the electric double-layer capacitor 500 in
When voltage is applied to the electric double-layer capacitor 500, ions (anions) of the electrolyte 530 are adsorbed on the positive electrode 510 and ions (cations) of the electrolyte 530 are adsorbed on the negative electrode 520. As a result, an electric double layer is formed in each of the positive electrode 510 and the negative electrode 520 and charging is performed. Here, since the positive electrode 510 and the negative electrode 520 are formed using the stack described in the first embodiment, the adsorption and diffusion of the cations and anions become easy and the high rate characteristic can be achieved. In addition, since the positive electrode 510 and the negative electrode 520 are formed using the stack described in the first embodiment, many electrolyte solution ions are adsorbed not just on the surface of the stack but also inside the stack, and the electric double layer is formed. As a result, more electrons are exchanged between the graphene and the electrolyte solution ions, and the higher energy density can be achieved.
When the electric double-layer capacitor 500 that is charged is connected to a circuit such as a resistor, the anions and the cations adsorbed respectively on the positive electrode 510 and the negative electrode 520 are desorbed and discharged. Here, the positive electrode 510 and the negative electrode 520 are formed using the stack described in the first embodiment, and therefore the desorption and the diffusion of the electrolyte solution ions become easy and the high rate characteristic and the high power density can be achieved. Furthermore, since the conductivity is excellent, the power density can also be improved as the desorption and the diffusion become easier.
The stack according to the present invention in the electric double-layer capacitor 500 according to the present invention functions as the electrode material with the high energy density (100 Wh/kg or more) and the high power density (500 kW/kg or more) as described above. Therefore, quick charging becomes possible and the high energy density and the high power density can be achieved. Moreover, since the charging and discharging use the formation of the electric double-layer, the charging and discharging can be performed repeatedly. The electric double-layer capacitor 500 according to the present invention can be used for wind power generation, electric vehicles, or the like.
The stack according to the present invention is effective for the use in the electrode material. If a functional biomolecule such as DNA, enzyme, or antibody is held in the pores of graphene through which the electrolyte solution ions pass or in the space between the layers of graphene through which the electrolyte solution ions pass, a sensor using the functional biomolecule as a sensing element can be formed.
Next, the present invention will be described in detail with reference to specific examples; however, the present invention is not limited to these examples.
In Example 1, by using the graphene manufactured by a thermal reduction method, a stack in which carbon nanotube (CNT) and graphene with pores formed by heating at 650° C. were stacked was manufactured.
Before the graphene was manufactured by the thermal reduction method, oxidized graphene was prepared from natural graphite powder by improved Hummers method. Graphite powder (2 g) and sodium nitrate (1 g) were mixed and sulfate (50 mL) was added to the mixture, and the solution was stirred in an ice bath. Sodium permanganate (12 g) was slowly added to the solution so that the temperature would not exceed 20° C. The mixture of these was subjected to reaction for an hour in a bath with a temperature of 35° C. Thus, the mixture in a paste form was obtained.
To this paste-form mixture, deionized water was slowly added, and the resulting mixture was further stirred for an hour. Next, water was added to this mixture and after 30-minute stirring, hydrogen peroxide was added. Thus, the dark brown mixture became a yellow suspension.
The yellow suspension was subjected to centrifugal separation, and the obtained solid was washed six times with 5 mass % of chloric acid and deionized water to remove metal ions and acid; then, the solid was dried in vacuum. Thus, oxidized graphene was obtained.
An oxidized graphene dispersion liquid (2 mg/mL) in which oxidized graphene was dispersed in water was freeze-dried at −10° C. for 72 hours (step S410 in
The oxidized graphene dispersion liquid with the dark yellow color in the foamed state is reduced thermally for 1 minute in the air at 400° C. (step S420 in
Next, the obtained graphene (0.4 g) was dispersed in an aqueous KOH solution (7 M), and held for 24 hours at room temperature (step S310 in
The graphene after the filtering was heated for 0.5 hours at 650° C. in an Ar atmosphere (step S320 in
Here, the heated graphene was examined in detail. The graphene was observed using the atomic resolution analytical electron microscope (JEM-ARM200F) and evaluated using the Raman microscope based on the Raman spectroscopy (RAMAN-11, Nanophoton). The specific surface area and the pore diameter distribution of the graphene were measured by the BET method. In the measurement, Autosorb-iQ analyzer manufactured by Quantachrome Corporation was used. The specific surface area was calculated based on the amount of adsorption when the relative pressure (P/P0) is in the range of 0.08 to 0.4. These results are shown in
Next, in order to evaluate the electric characteristics of the heated graphene, an electric double-layer capacitor using the heated graphene in an electrode was manufactured. The specific manufacturing procedure was as below. In ethanol, a product (90 wt %) and polytetrafluoroethylene (PTFE, 10 wt %) were dispersed, and the mixture was subjected to an ultrasonic process, so that a suspension was obtained. The suspension was filtered through a porous film by vacuum filtration. This porous film was dried in vacuum for 24 hours, and the film including PTFE and graphene obtained by the vacuum filtration was cut into a circular shape and this circular film was used as the electrode. This electrode had a circular shape with a diameter of 15 mm and a weight of approximately 1 mg. Next, in the cell of stainless steel (550 in
In the electro-chemical measurement of the electric double-layer capacitor, a multi-channel potentiostat galvanostat (VMP-300, Bio-Logic) was used. The specific capacity-voltage measurement (CV measurement) and the galvanostat charging-discharging measurement were performed at room temperature in the potential range of 0 V to 3.5 V.
The specific capacity Cs (F/g) was calculated in accordance with Cs=4 I/(mdV/dt). Here, I (A) represents constant current, m (g) represents the total mass of the two electrodes, dV/dt (V/s) represents an inclination obtained by performing linear fitting on a discharging curve between Vmax (voltage at a start of discharging) and 1/2 Vmax. The energy density Ecell (Wh/kg) was calculated in accordance with Ecell=CsV2/8. The power density Pcell (W/kg) was calculated in accordance with Pcell=Ecell/t (where t represents discharging time). The results are shown in Table 2.
Subsequently, the stack was formed using the graphene with the pores that corresponds to the heated graphene. That is to say, the graphene with the pores was dispersed in N-methylpyrrolidone (NMP, 500 mL) as the dispersion medium and then, single-walled CNT (Cheap Tube Inc., purity of 90% or more) was added and the mixture was stirred for two hours at room temperature (step S330 in
The single-walled CNT that was used contained 3 wt % of amorphous carbon. The single-walled CNT had a specific surface area of 407 m2/g, conductivity of 104 S/m, a length of 5 μm or more and 30 μm or less, and a diameter of 4 nm or more and 10 nm or less.
The stirring was performed by an ultrasonic process. It has been confirmed that the graphene and the CNT were uniformly dispersed in the dispersion medium. This dispersion liquid was filtered in vacuum and dried. The obtained stack was examined in detail. A structure of the stack was observed using the SEM and the TEM.
In order to evaluate the electric characteristics of the stack, the electric double-layer capacitor using the stack in the electrode was manufactured. The specific procedure is not described because it is the same as the procedure for the electric double-layer capacitor manufactured to evaluate the electric characteristics of the graphene after step S320.
In regard to the electric double-layer capacitor, the CV measurement and the galvanostat charging-discharging measurement were similarly performed at room temperature in the potential range of 0 V to 3.5 V; thus, the specific capacity, the energy density, and the power density were calculated.
In Example 2, a stack in which CNT and graphene manufactured by the thermal reduction method and provided with the pores by heating at 700° C. were stacked was manufactured. Since Example 2 is the same as Example 1 except that the heating temperature in step S320 is set to 700° C., the description is omitted.
In a manner similar to Example 1, the morphology of the graphene after the heating in step S320 and before the stacking in step S330 was observed by an atomic resolution TEM, and thus the Raman spectrum was measured. The nitrogen adsorption-desorption isotherm by the BET method was measured, and the specific surface area and the pore diameter distribution were obtained. The results are shown in
In a manner similar to Example 1, the electric double-layer capacitor in which the graphene after the heating in step S320 and before the stacking in step S330 was used in the electrode was manufactured, and similarly, the CV measurement and the galvanostat charging-discharging measurement were performed at room temperature in the potential range of 0 V to 3.5 V, and thus, the specific capacity, the energy density, and the power density were calculated. These results are shown in
In a manner similar to Example 1, the structure of the stack after step S330 was observed by the SEM and the TEM. The results are shown in
In a manner similar to Example 1, the electric double-layer capacitor in which the stack after step S330 was used in the electrode was manufactured, and the CV measurement and the galvanostat charging-discharging measurement were performed at room temperature in the potential range of 0 V to 3.5 V, and thus, the specific capacity, the energy density, and the power density were calculated. The results are shown in
In Example 3, the stack in which CNT and graphene manufactured by the thermal reduction method and provided with the pores by the heating at 800° C. were stacked was manufactured. Since Example 3 is similar to Example 1 except that the heating temperature in step S320 is set to 800° C., the description is omitted.
In a manner similar to Example 1, the morphology of the graphene after the heating in step S320 and before the stacking in step S330 was observed by the atomic resolution TEM, and thus the Raman spectrum was measured. The nitrogen adsorption-desorption isotherm by the BET method was measured, and the specific surface area and the pore diameter distribution were obtained. The results are shown in
In a manner similar to Example 1, the electric double-layer capacitor in which the graphene after the heating in step S320 and before the stacking in step S330 was used in the electrode was manufactured, and similarly, the CV measurement and the galvanostat charging-discharging measurement were performed at room temperature in the potential range of 0 V to 3.5 V, and thus, the specific capacity, the energy density, and the power density were calculated. The results are shown in Table 2.
In a manner similar to Example 1, the structure of the stack after step S330 was observed using the SEM and the TEM. The electric double-layer capacitor in which the stack after step S330 was used in the electrode was manufactured, and the CV measurement and the galvanostat charging-discharging measurement were performed at room temperature in the potential range of 0 V to 3.5 V, and thus, the specific capacity, the energy density, and the power density were calculated.
In Comparative example 4, the stack of CNT and graphene without the pores was manufactured. In Comparative example 4, graphene manufactured by the thermal reduction method in a manner similar to Example 1 was heated in an Ar atmosphere at 650° C. for 0.5 hours. The heated graphene was dispersed in NMP, and the single-walled CNT was added and the mixture was stirred at room temperature for two hours. Here, the graphene and the CNT were dispersed so that the mass ratio of the graphene to the CNT became 10. That is to say, Comparative example 4 was similar to Example 2 except that step S310 was not carried out in Comparative example 4.
In a manner similar to Example 1, the morphology of the graphene after the heating and before the stacking was observed by the atomic resolution TEM, and thus the Raman spectrum was measured. The nitrogen adsorption-desorption isotherm by the BET method was measured, and the specific surface area and the pore diameter distribution were obtained. The results are shown in
In a manner similar to Example 1, the electric double-layer capacitor in which the graphene after the heating and before the stacking was used in the electrode was manufactured, and similarly, the CV measurement and the galvanostat charging-discharging measurement were performed at room temperature in the potential range of 0 V to 3.5 V, and thus, the specific capacity, the energy density, and the power density were calculated. The results are shown in
In a manner similar to Example 1, the structure of the stack was observed using the SEM and the TEM. The electric double-layer capacitor in which the stack after step S330 was used in the electrode was manufactured, and the CV measurement and the galvanostat charging-discharging measurement were performed at room temperature in the potential range of 0 V to 3.5 V, and thus, the specific capacity, the energy density, and the power density were calculated. The results are shown in
In Comparative example 5, a capacitor was manufactured in accordance with the procedure according to Example 3 described in Patent Literature 2. The capacitor was subjected to the CV measurement and the galvanostat charging-discharging measurement at room temperature in the potential range of 0 V to 3.5 V, and thus, the specific capacity, the energy density, and the power density were calculated. The results are shown in
In Reference example 6, a stack of CNT and graphene in which the pores are not formed intentionally was manufactured. The graphene used in this stack was prepared as below. Into 30 mL of distilled water, oxidized graphene (100 g) manufactured by improved Hummers method in a manner similar to Example 1 was added and dispersed for 30 minutes through an ultrasonic process. This mixture was heated on a hot plate until the temperature reached 100° C., and then, hydrazine hydrate (3 mL) was added thereto and the mixture was kept at 98° C. for 24 hours so as to be reduced. Thus, black graphene was obtained. This black graphene was washed with distilled water to remove excessive hydrazine.
In a manner similar to Example 1, the graphene was dispersed in NMP and then, the single-walled CNT was added. The mixture was stirred at room temperature for two hours. Here, the graphene and the CNT were dispersed so that the mass ratio of the graphene to the CNT became 10. Thus, the stack was obtained.
In a manner similar to Example 1, the structure of the stack was observed using the SEM and the TEM. As the electrolyte, various ionic liquids (EMI-TFSI, EMI-BF4, and MPPp-TFSI) were used and thus, the electric double-layer capacitors using the stack in the electrode were manufactured. The electric double-layer capacitors were subjected to the CV measurement and the galvanostat charging-discharging measurement at room temperature in the potential range of 0 V to 3.5 V, and thus, the specific capacity, the energy density, and the power density were calculated. The results are shown in
A list of manufacturing conditions for the stacks according to Examples/Comparative examples/Reference example 1 to 6 are shown in Table 1, and the results are described in detail.
In
In the CV curves in
On the basis of the CV curve (electrolyte solution: EMI-BF4, voltage: 3.7 V), the specific capacity (F/g) in Examples and Comparative example 1 to 4 was calculated, and the results were 135, 195, 154, and 120, respectively. For example, the comparison between Example 2 and Comparative example 4 indicates that the specific capacity is improved by 63% when the electrolyte solution is EMI-BF4, and improved by 44% when the electrolyte solution is KOH.
In
The above results indicate that the electric characteristics of graphene are remarkably improved by using the graphene with the pores formed by steps S310 and S320 according to the present invention. This indicates that the graphene has the large specific surface area due to the pores and the electrolyte solution ions pass the graphene because of the diffused pores.
In each of the CV curves in
On the basis of the CV curve (electrolyte solution: EMI-BF4, voltage: 3.7 V, 4 V), the specific capacity (F/g) of the stack according to Example 2 was calculated and the result was 221 (@3.7 V) and 292 (@4 V). On the other hand, the specific capacity of the stack according to Comparative example 4 was calculated and the result was 134 (@3.7 V) and 156 (@4 V). The comparison between Example 2 and Comparative example 4 indicates that the specific capacity of the stack according to Example 2 was remarkably higher than that of Comparative example 4 when the electrolyte solution was EMI-BF4.
Each charging-discharging curve in
The above results have shown that the stack including the CNT and the graphene with the pores formed by steps S310 to S330 according to the present invention functions as the electrode material that largely improves the electric characteristics and that has an energy density as high as 100 Wh/kg or more and a power density as high as 500 kW/kg or more. Thus, this stack can provide the electric double-layer capacitor with the high energy density and the high power density. This is because the graphene has the large specific surface area due to the pores, and the electrolyte solution ions pass the pores to penetrate the stack and diffuse therein.
The comparison between the CV curve at a sweeping speed of 50 mV/s in
The above results show that employing the thermal reduction method in steps S410 to S420 in the manufacturing method by steps S310 to S330 according to the present invention is very preferable to manufacture the stack of the CNT and the graphene with the pores.
In
According to
In addition, Table 4 shows the results of calculating the energy density and the specific capacity at each voltage from
Thus, it is understood that although the stack of the CNT and the graphene either with or without the pores is used as the electrode in Reference example 6, the similar effect can be obtained also when the stack of the CNT and the graphene with the pores is used as the electrode.
By the manufacturing method according to the present invention, the stack of the CNT and the graphene with the pores having the excellent capacitor characteristic can be obtained. The electric double-layer capacitor including the stack in the electrode is advantageous in wind power generation, electric vehicles, and the like. If a functional biomolecule such as DNA, enzyme, or antibody is held in the pores of graphene or in the space between the layers of graphene, the stack can form a sensor using the functional biomolecule as a sensing element.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2016-057675 | Mar 2016 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2016/077866 | 9/21/2016 | WO | 00 |
