The present invention relates to a method for manufacturing a three-dimensional shaped object, and also relates to the three-dimensional shaped object obtained thereby. More particularly, the present invention relates to a method for manufacturing a three-dimensional shaped object with a plurality of solidified layers stacked integrally by repeating the step of forming a solidified layer by irradiating a predetermined portion of a powder layer with a light beam, and also relates to the three-dimensional shaped object obtained by such manufacturing method.
Heretofore, a method for manufacturing a three-dimensional shaped object by irradiating a powder with a light beam has been known (such method can be generally referred to as “selective laser sintering method”). Such method can produce a three-dimensional shaped object with a plurality of solidified layers stacked integrally by repeating the step (i) of forming a solidified layer by irradiating a predetermined portion of a powder layer with a light beam, thereby allowing sintering of the predetermined portion of the powder or melting and subsequent solidification thereof, and the step (ii) of forming another solidified layer by newly forming a powder layer on the resulting solidified layer, followed by similarly irradiating the powder layer with the light beam (see JP-T-01-502890 or JP-A-2000-73108). The three-dimensional shaped object thus obtained can be used as a metal mold in a case where inorganic powder materials such as a metal powder and a ceramic powder are used as the powder material. While on the other hand, the three-dimensional shaped object can be used as a model or replica in a case where organic powder materials such as a resin powder and a plastic powder are used as the powder material. This kind of technology makes it possible to produce the three-dimensional shaped object with a complicated contour shape in a short period of time.
In most cases regarding the selective laser sintering method, the manufacturing of the three-dimensional shaped object is performed under an inert atmosphere in a chamber to prevent an oxidation of the shaped object. Within the chamber, a base plate is disposed on a forming table, and the base plate is secured to the table by means of a bolt. Thereafter, the three-dimensional shaped object is manufactured on the bolted base plate. By way of the case of using a metal powder as a powder material and using the resulting three-dimensional shaped object as metal mold, as shown in
Due to the fact that the three-dimensional shaped object is manufactured by irradiation of the light beam, not only the three-dimensional shaped object but also the base plate serving as supporting it is more or less affected by a heat of the light beam. Specifically, the irradiated portion of the powder layer is once melted and subsequently the molten powder is solidified to form the solidified layer. In such formation of the solidified layer, a shrinkage phenomenon can occur (see
The present invention has been created in order to address the above problem. That is, an object of the present invention is to provide a “method for manufacturing a three-dimensional shaped object” wherein the warping of the base plate is suitably coped with.
In order to achieve the above object, the present invention provides a method for manufacturing a three-dimensional shaped object, comprising the steps of:
(i) forming a solidified layer by irradiating a predetermined portion of a powder layer on a base plate with a light beam, thereby allowing a sintering of the powder of the predetermined portion or a melting and subsequent solidification thereof; and
(ii) forming another solidified layer by newly forming a powder layer on the resulting solidified layer, and then irradiating another predetermined portion of the new powder layer with the light beam, the steps (i) and (ii) being repeatedly performed;
wherein, prior to or upon the manufacturing of the three-dimensional shaped object, (a) the base plate is subjected to a heat treatment, thereby causing the base plate to be warped, and (b) at least a lower surface of the warped base plate is subjected to a flattening process.
One of features of the manufacturing method according to the present invention is that a “plate in which a deformed portion thereof due to a heat treatment has been subjected to a flattening process” is used as the base plate for the shaped object. In other words, the present invention is characterized in that the “base plate with a residual stress attributed to the heat treatment remaining therein” is positively used in spite of such residual stress.
The meaning of the term “heat treatment” as used in the present description and claims includes not only a direct heat treatment wherein the base plate is directly heated, but also an indirect heat treatment wherein the base plate is indirectly heated (for example, a powder layer formed on the base plate is heated). As for the former case (i.e., “direct” heat treatment), a warp deformation of the base plate is caused largely by “thermal stress”. While on the other hand, as for the latter case (i.e., “indirect” heat treatment), the warp deformation of the base plate is caused not only by “thermal stress”, but also by “tensile stress generated upon the formation of the solidified layer” or the like. The term “base plate” as used in the present description and claims substantially means a member which serves as a platform for the three-dimensional shaped object to be manufactured. In a preferred embodiment, the term “base plate” means a plate-like member disposed on a forming table. In this regard, the term “lower surface” of the base plate, which is also used in the present description and claims, substantially means a surface opposed to an “upper surface”, provided that a surface in contact with the shaped object is the “upper surface”.
The term “warp” or “warping” as used in the present description and claims substantially means a “deformation of the base plate” which can be attributed to a heat treatment of the base plate. Therefore, the meaning of the term “warp” or “warping” includes not only a typical deformation wherein an outer edge of the base plate transforms largely as illustrated in
The term “flattening process” as used in the present description and claims substantially means that a machining process of the base plate wherein a surface portion thereof is partially removed to provide a flat surface.
Describing just for confirmation, the term “powder layer” as used in this description and claims means “metal powder layer made of a metal powder” or “resin powder layer made of a resin powder”, for example. Also, the term “predetermined portion of a powder layer” substantially means a portion of a three-dimensional shaped object to be manufactured. Therefore, a powder existing in such predetermined portion is irradiated with a light beam, whereby, the powder undergoes a sintering or a melting and subsequent solidification thereof to form a shape of the three-dimensional shaped object. Furthermore, the term “solidified layer” substantially means “sintered layer” in a case where the powder layer is a metal powder layer, whereas it substantially means “cured layer” in a case where the powder layer is a resin powder layer.
In the manufacturing method of the present invention, an irradiation source for the light beam of the steps (i) and (ii) is used as a heat source for the warp deformation of the base plate. Alternatively, any other suitable heat sources, which are different from the irradiation source of the selective laser sintering, may also be used. In this regard, an arc discharge source or a thermal spray source may be used, for example.
In one preferred embodiment, one or more layers of the powder layer and/or solidified layer formed on the base plate is subjected to the heat treatment to cause the warping of the base plate. This means that the warping of the base plate may be caused during the manufacturing of the three-dimensional shaped object.
In another preferred embodiment, the base plate is subjected to the heat treatment such that the upper surface of the base plate (especially, the whole upper surface of the base plate) is heated. This can cause a possible residual stress to occur as much as possible in advance in the base plate. As a result, the further warp deformation of the base plate, which may occur in subsequent formation of the solidified layer, can be suitably prevented. The heating area of the base plate may be limited according to the three-dimensional shaped object to be manufactured. For example, “heating area of the base plate” or “heating area of one or more layers of the powder layer and/or solidified layer formed on the base plate” may be determined in accordance with the weight, volume, position and/or “contact shape and/or contact area between the three-dimensional shaped object and the base plate”. In this case, the heat treatment is performed with respect to such limited area of the base plate or the layer.
In still another preferred embodiment, the flattening process is performed after the formation of 50 to 100 layers of the solidified layers (in some cases, 10 to 200 layers of the solidified layers) on the base plate is completed. This makes it possible to inhibit the too large warp deformation after the flattening process.
The present invention also provides a three-dimensional shaped object obtained by the aforementioned manufacturing method. In particularly preferred embodiment, a bottom surface of such three-dimensional shaped object is provided with a base plate wherein the bottom surface of the shaped object and the base plate are jointed with each other, and a lower surface of the base plate is a flattened surface.
The manufacturing method of the present invention utilizes the base plate which has been subjected to the flattening process after causing it to be warped (particularly, it utilizes the base plate obtained by flattening the warped portion thereof attributed to a thermal stress or a tensile stress). This utilization of the warped and subsequent flattened base plate makes it possible to reduce an accumulation of the further stress after a point in time of the flattering during the manufacturing process of the shaped object. In other words, in accordance with the present invention, the possible stress which may occur upon the manufacturing of the three-dimensional shaped object is caused in advance in the base plate, and the resulting deformation of the base plate due to such stress is removed in advance, and thereby a suppression of the further warping of the base plate after that can be effectively achieved.
The suppression of the warping of the base plate can enhance a shape accuracy of the three-dimensional shaped object. In this regard, it was inevitably required in the prior art to design on preliminary assumption of the extent of the warping in order to achieve the shape accuracy of the three-dimensional shaped object. However, it is possible according to the present invention to achieve the shape accuracy only in advance by subjecting the base plate for supporting the shaped object to the heat treatment and the subsequent flattening process. In other words, the present invention is very useful in that it can eliminate the difficulty of such unpredictable “extent of the warping of the plate” by introducing the simple steps (i.e., by introducing the heating and flattening steps) to the manufacturing of the shaped object.
The present invention will be hereinafter described in more detail with reference to the accompanying drawings.
[Selective Laser Sintering Method]
First, a selective laser sintering method, on which the manufacturing method of the present invention is based, will be described. For convenience, the selective laser sintering method, which will be described, is one where powder material is supplied from a storage tank therefor, followed by being flattened by means of a squeegee blade to form a powder layer therefrom. Moreover, by way of example, the selective laser sintering method wherein a machining process is additionally carried out with respect to the shaped object (i.e., the process embodiment shown in
Operations of the laser-sintering/machining hybrid machine 1 will be described in detail with reference to
The operations of the laser-sintering/machining hybrid machine are mainly composed of a powder layer forming step (S1) of forming the powder layer 22; a solidified layer forming step (S2) of irradiating the powder layer 22 with the light beam L to form a solidified layer 24; and a machining step (S3) of milling a surface of the shaped object. In the powder layer forming step (S1), first, the forming table 20 is descended by Δt1 (S11). Subsequently, a powder table 25 is elevated by Δt1, and thereafter the squeegee blade 23 is driven to move in the direction of arrow “A” as shown in
The powder layer forming step (S1) and the solidified layer forming step (S2) are repeatedly performed until the thickness of the stacked layers 24 reaches such a predetermined value that is obtained based on a tool length of the milling head 40 (see
When the thickness of the stacked solidified layers 24 reaches the predetermined thickness, the machining step (S3) is initiated. In the embodiments as shown in
An irradiation path of the light beam L in the solidified layer forming step (S2) and a milling path in the machining step (S3) are determined in advance using 3-D CAD data. In this case, the machining path is determined by applying contour line processing. For example, in the solidified layer forming step (S2), the contour shape data of each of sliced sections, which are regularly-pitched (e.g., 0.05 mm pitch in the case of Δt1 being 0.05 mm) sliced sections of STL data produced from a 3-D CAD model, are used.
[Manufacturing Method of the Present Invention]
With respect to the selective laser sintering method, the present invention particularly takes account of a stress which may occur in the base plate. More specifically, as shown in
In the following description, the present invention will be described by way of an embodiment using a “metal powder” as the powder. The “embodiment using a metal powder” corresponds to an “embodiment using a metal powder layer as a powder layer”. In this regard, the metal powder used in the present invention may be a powder containing an iron based powder as a main component, and may be a powder which further contains at least one kind powder selected from the group consisting of a nickel powder, a nickel based alloy powder, a copper powder, a copper based alloy powder and a graphite powder in some cases. Examples of the metal powder include a metal powder in which the proportion of an iron based powder having a mean particle diameter of about 20 μm is 60 to 90% by weight, the proportion of both or either of a nickel powder and a nickel based alloy powder is 5 to 35% by weight, the proportion of both or either of a copper powder and/or a copper based alloy powder is 5 to 15% by weight, and the proportion of a graphite powder is 0.2 to 0.8% by weight.
The heat treatment performed in the present invention may be any one as long as it causes the warp deformation of the base plate. In other words, any heat treatment can be performed in the manufacturing method of the three dimensional shaped object as long as a warping stress occurs in the base plate by the heat treatment. Therefore, examples of the heat treatment include a direct heating of the base plate, and also an indirect heating of the base plate wherein a powder layer and/or a solidified layer formed on the base plate is heated for example.
For performing the heat treatment, the base plate may be irradiated with a light beam used in the selective laser sintering method, for example. Alternatively, the base plate may be irradiated with another light beam, not that of the selective laser sintering method. The term “light beam” as used herein means a directional energy beam like a laser light, for example. In other words, an irradiation source of the light beam for the laser sintering, or another irradiation source which is different therefrom may be used as a heat source for the warp deformation of the base plate. The former has an advantage not only in terms of an improved facility cost since the laser sintering device (i.e., a device for performing the selective laser sintering method) can be utilized even for the heat treatment of the base plate, but also in terms of a wholly facilitated manufacturing process since the same device is used throughout the whole processes. While on the other hand, the latter has an advantage in that a plurality of the operations can be performed in parallel when a plurality of the shaped objects are manufactured. More specifically, the latter makes it possible to execute the “laser sintering” and the “warp deformation of the base plate (and subsequent flattening thereof)” in parallel when a plurality of the shaped objects are manufactured, which leads to a shorten manufacturing time of the shaped objects as a whole.
In a case of the heat treatment of the base plate by the irradiation of the light beam, an adjustment of an output energy of the light beam makes it possible to suitably cause the “warp deformation” attributed to the heat treatment. For example, it is preferred that the irradiation energy density E of the light beam is in the range of about 4 J/mm2 to about 15 J/mm2. The “warp deformation” can be suitably caused by, in addition to (a) adjusting an output energy of a light beam, (b) adjusting a scanning rate of the light beam, (c) adjusting a scanning pitch of the light beam, and (d) adjusting a condensing diameter of the light beam. The above operations (a) to (d) may be performed alone, or performed in combination. It should be noted that Energy density E=Laser output power [W]/(Scanning rate [mm/s]×Scanning pitch [mm]) wherein the manufacturing condition is as follows: Powder layer thickness: 0.05 mm, Laser: CO2 Laser (Carbon dioxide laser), Spot diameter: 0.5 mm).
In addition to the heating by the light beam irradiation, examples of the heat treatment of the base plate according to the manufacturing method of the present invention include a heating by using an arch discharge, a heating by means of a gas burner, and a heating by an introduction of the base plate into a heating chamber.
More detailed explanation about the base plate used in the manufacturing method of the present invention is as follows: The form of the base plate is not particularly limited as long as the base plate has a surface serving as a platform for the shaped object (i.e., as long as the base plate has a main surface which serves to support the shaped object). For example, the form of the base plate 21 is not limited to a cuboid form as illustrated in
The material of the base plate is not particularly limited. For example in a case where a metal powder is used as the powder so as to form a sintered layer as the solidified layer (i.e., sintered layer made of an iron-based material), the base plate is preferably made of at least one material selected from the group consisting of a steel, a hardmetal (cemented carbide), a high-speed tool steel, an alloy tool steel, a stainless steel, and a carbon steel for machine construction. According to the present invention, the flattening process of the warped base plate is performed, such warping being attributed to the heat treatment. In this regard, a flat machining means or a machining means may be used for such flattening process. The machining means may be any suitable one as long as it can perform a surface machining treatment. For example, the machining means may be a numerical control (NC: Numerical Control) machine tool or those analogous thereto. Specifically, it is preferred that the machining means is a machining center (MC) whose milling tool (end mill) is automatically exchangeable. As the end mill, for example, a twin bladed ball end mill made of a superhard material is mainly used. A square end mill, a radius end mill or the like may also be used in some cases.
As shown in
The flattening process according to the present invention enables the warped face of the base plate to be flattened. Thus, the flattening process can form a flat surface in the base plate. In this regard, it is particularly preferred that the flattening process is performed such that the base plate has the flat surface whose surface roughness Rz is preferably 10 μm or less and more preferably 5 μm or less. The term “surface roughness Rz” used herein substantially means a roughness measure which is obtained by adding up “height up to the uppermost mountain peak” and “depth down to the valley portion” from an average line in a roughness profile (i.e., in “cross-sectional profile of the surface of the base plate”).
Now, with reference to
As illustrated in
The three-dimensional shaped object is obtained such that the shaped object and the base plate are mutually integrated. The three-dimensional shaped object thus manufactured can be used as a metal mold. In this case, the flattened portion can be used as a later-machining reference. The term “later-machining reference” as used herein substantially means an indication used at the later time of another processing. More specifically, considering a case where the three-dimensional shaped object and the base plate integrated therewith are afterward subjected to a machining process in accordance with an intended end-usage, an indicating part therefor can correspond to the later-machining reference. There are various other embodiments with respect to the characterizing feature “the base plate is subjected to the heat treatment, thereby causing the base plate to be warped, and then the lower surface of the warped base plate is subjected to the flattening process”. More detailed explanations about that will be described below.
(Heat Input Through Whole Surface of Base Plate)
Considering that the warp deformation of the base plate is sufficiently caused, it is preferred that the whole upper surface and/or the whole lower of the base plate are/is heated. For example, in a case where the base plate is heated by the irradiation of the light beam, the whole upper surface and/or the whole lower of the base plate can be heated by scanning the light beam as illustrated in
Upon the laser sintering, a stress tends to occur and accumulate at a boundary area between the base plate and the shaped object (more detailed explanation about this will be described with reference to
(Heat Treatment of Powder Layer and/or Solidified Layer)
The heat treatment according to the present invention may be performed upon the manufacturing of the three-dimensional shaped object. More specifically, “one or more layers of the powder layer and/or solidified layer formed on the base plate” may be subjected to the heat treatment to cause the warping of the base plate. For example, as illustrated in
The heat treatment of the powder layer and/or the solidified layer is described below in detail. The residual stress, which may occur in the base plate, tends to accumulate mainly at a boundary portion between the base plate and the solidified layer (i.e., sintered layer) as well as the uppermost surface of the stacked layers (i.e., the vicinity of the last layer which has been lastly molten and subsequently solidified). This means that the residual stress tends to hardly accumulate at a middle portion of the stacked layers. See
With respect to the result shown in
●Graph of
The graph of
The heat treatment of the base plate may be suitably performed in accordance with the three-dimensional shaped object to be manufactured. More specifically, a heat input area or a heat input amount regarding the base plate may be determined according to at least one of the following parameters, for example:
The term “heat input area” as used herein corresponds to the “heating area of the base plate” in a case where the base plate is heated prior to the manufacturing of the three-dimensional shaped object, whereas it corresponds to the “heating area of the one or more layers of the powder layer and/or solidified layer formed on the base plate” in a case where the base plate is heated upon the manufacturing of the three-dimensional shaped object. As illustrated in
[Three-Dimensional Shaped Object of the Present Invention]
The three-dimensional shaped object of the present invention which can be obtained according to the above manufacturing method will be now described. The three-dimensional shaped object of the present invention has the base plate wherein the bottom surface of the three-dimensional shaped object and the base plate are jointed with each other. In this regard, the three-dimensional shaped object of the present invention is configured to have the base plate whose bottom surface is a flattened surface due to the above manufacturing method. It is preferred that a surface roughness Rz of the flattened surface may be preferably 10 μm or less (Rz=0 to 10 μm), and more preferably 5 μm or less (Rz=0 to 5 μm). Since the other configurations of the three-dimensional shaped object is described in the above [Manufacturing Method of the Present Invention], the description thereof is omitted here in order to avoid the duplicated explanation.
Although a few embodiments of the present invention have been hereinbefore described, the present invention is not limited to these embodiments. It will be readily appreciated by those skilled in the art that various modifications are possible without departing from the scope of the present invention. As an additional remark, the invention of JP 2007-270227 will be briefly explained, while the technical idea thereof being essentially different from that of the present invention. Japanese Unexamined Publication No. 2007-270227 discloses a “method for manufacturing an optically shaped article”. In the manufacturing method disclosed therein, the residual stress is eliminated by the heating treatment of the sintered layer. Specifically, the disclosed method of JP 2007-270227 is characterized in that the elimination of the residual stress is performed particularly by a heat annealing treatment. Therefore, JP 2007-270227 neither discloses nor suggests the idea of the present invention wherein the base plate with the stress remaining therein is positively used.
It should be noted that the present invention as described above includes the following aspects:
(i) forming a solidified layer by irradiating a predetermined portion of a powder layer on a base plate with a light beam, thereby allowing sintering of the powder of the predetermined portion or melting and subsequent solidification thereof; and
(ii) forming another solidified layer by newly forming a powder layer on the resulting solidified layer, and then irradiating another predetermined portion of the new powder layer with the light beam, the steps (i) and (ii) being repeatedly performed;
wherein, prior to or during the manufacturing of the three-dimensional shaped object, (a) the base plate is subjected to a heat treatment, and thereby causing the base plate to be warped, and then (b) at least a lower surface of the base plate thus warped is subjected to a flat machining process.
the determined heating area is subjected to the heat treatment in the (a).
a lower surface of the base plate is a flat machined surface.
The method for manufacturing a three-dimensional shaped object according to present invention can produce various kinds of objects. For example in a case where the powder layer is a metal powder layer (i.e., inorganic powder layer) and thus the solidified layer corresponds to a sintered layer, the produced three-dimensional shaped object can be used as a metal mold for a plastic injection molding, a press molding, a die casting, a casting or a forging. While on the other hand in a case where the powder layer is a resin powder layer (i.e., organic powder layer) and thus the solidified layer corresponds to a cured layer, the produced three-dimensional shaped object can be used as a resin molded article.
The present application claims the right of priority of Japanese Patent Application No. 2010-32684 (filed on Feb. 17, 2010, the title of the invention: “METHOD FOR MANUFACTURING THREE-DIMENSIONAL SHAPED OBJECT AND THREE-DIMENSIONAL SHAPED OBJECT”), the disclosure of which is incorporated herein by reference.
Number | Date | Country | Kind |
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2010-032684 | Feb 2010 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2011/053276 | 2/16/2011 | WO | 00 | 8/9/2012 |
Publishing Document | Publishing Date | Country | Kind |
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WO2011/102382 | 8/25/2011 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
4863538 | Deckard | Sep 1989 | A |
4938816 | Beaman et al. | Jul 1990 | A |
4944817 | Bourell et al. | Jul 1990 | A |
5017753 | Deckard | May 1991 | A |
5053090 | Beaman et al. | Oct 1991 | A |
5076869 | Bourell et al. | Dec 1991 | A |
5132143 | Deckard | Jul 1992 | A |
5147587 | Marcus et al. | Sep 1992 | A |
5155324 | Deckard et al. | Oct 1992 | A |
5156697 | Bourell et al. | Oct 1992 | A |
5182170 | Marcus et al. | Jan 1993 | A |
5284695 | Barlow et al. | Feb 1994 | A |
5296062 | Bourell et al. | Mar 1994 | A |
5316580 | Deckard | May 1994 | A |
5382308 | Bourell et al. | Jan 1995 | A |
5431967 | Manthiram et al. | Jul 1995 | A |
5597589 | Deckard | Jan 1997 | A |
5616294 | Deckard | Apr 1997 | A |
5639070 | Deckard | Jun 1997 | A |
6163961 | McMeekin | Dec 2000 | A |
6391251 | Keicher et al. | May 2002 | B1 |
6501997 | Kakino | Dec 2002 | B1 |
6657155 | Abe et al. | Dec 2003 | B2 |
7255830 | Abe et al. | Aug 2007 | B2 |
7323132 | Abe et al. | Jan 2008 | B2 |
7754135 | Abe et al. | Jul 2010 | B2 |
7867431 | Higashi et al. | Jan 2011 | B2 |
8062020 | Abe et al. | Nov 2011 | B2 |
8163224 | Higashi et al. | Apr 2012 | B2 |
20040021256 | DeGrange et al. | Feb 2004 | A1 |
20040056022 | Meiners et al. | Mar 2004 | A1 |
20060208396 | Abe et al. | Sep 2006 | A1 |
20070023977 | Braun et al. | Feb 2007 | A1 |
20100034983 | Fuwa | Feb 2010 | A1 |
20110123383 | Fuwa et al. | May 2011 | A1 |
20120041586 | Abe et al. | Feb 2012 | A1 |
20120093674 | Abe et al. | Apr 2012 | A1 |
20120126457 | Abe et al. | May 2012 | A1 |
20120139166 | Abe et al. | Jun 2012 | A1 |
20120251378 | Abe et al. | Oct 2012 | A1 |
Number | Date | Country |
---|---|---|
1753747 | Mar 2006 | CN |
101511509 | Aug 2009 | CN |
102009036648 | Feb 2010 | DE |
1-502890 | Oct 1989 | JP |
06-155587 | Jun 1994 | JP |
2000-073108 | Mar 2000 | JP |
2006-124732 | May 2006 | JP |
2007-077443 | Mar 2007 | JP |
2007-270227 | Oct 2007 | JP |
2008-101256 | May 2008 | JP |
2008-291315 | Dec 2008 | JP |
2010-042524 | Feb 2010 | JP |
8802677 | Apr 1988 | WO |
Entry |
---|
German to English machine translation of DE 102009036648. |
German to English machine translation of DE 102009036648 A1. |
China Office action, dated Feb. 8, 2014 along with an english translation thereof. |
Office Action issued in Germany Counterpart Patent Appl. No. 112011100572.5, dated Feb. 8, 2018, along with an English translation thereof. |
Office Action issued in India Counterpart Patent Appl. No. 7933/CHENP/2012, dated Mar. 13, 2018. |
Number | Date | Country | |
---|---|---|---|
20120308781 A1 | Dec 2012 | US |