Patent Application
20190280164
The present invention relates to methods for manufacturing wavelength conversion members, wavelength conversion members, and light-emitting devices.
Recently, attention has been increasingly focused on light-emitting devices and the like using LEDs or LDs, as next-generation light sources to replace fluorescence lamps and incandescent lamps. As an example of such a next-generation light source, there is a disclosure of a light-emitting device in which an LED for emitting a blue light is combined with a wavelength conversion member capable of absorbing part of the light from the LED to convert it to a yellow light. This light-emitting device emits a white light which is a synthesized light of the blue light emitted from the LED and having passed through the wavelength conversion member and the yellow light emitted from the wavelength conversion member. Patent Literature 1 proposes, as an example of a wavelength conversion member, a wavelength conversion member in which phosphor powder is dispersed in a glass matrix.
Patent Literature 2 discloses a method for manufacturing wavelength conversion members by dividing a base material for the wavelength conversion members by dicing.
The inventors found that division of a base material by dicing as in Patent Literature 2 presents a problem that chipping occurs in the surfaces of wavelength conversion members, so that the light extraction efficiency of the wavelength conversion members decreases. Furthermore, there is also a problem that dicing causes material loss.
An object of the present invention is to provide a method for manufacturing wavelength conversion members that enables manufacturing of wavelength conversion members having a high light extraction efficiency and suppression of material loss, a wavelength conversion member obtained by the method, and a light-emitting device.
A manufacturing method according to the present invention is a method for manufacturing a plurality of wavelength conversion members by breaking into parts a base material for the wavelength conversion members and includes the steps of: preparing the base material having a first principal surface and a second principal surface opposed to each other; forming a breaking groove in the first principal surface; bonding a support to the second principal surface of the base material having the breaking groove formed in the first principal surface; pressing through the support a region of the base material where the breaking groove is formed, thus breaking the base material into the plurality of wavelength conversion members along the breaking groove; expanding the support to form a gap between the plurality of wavelength conversion members lying on the support; and removing the plurality of wavelength conversion members from the support after forming the gap.
The breaking groove is preferably formed by scribing.
The support is preferably expanded by pressing from a side of the support opposite to the base material.
It is preferred that an adhesive layer made of an ultraviolet curable resin be formed on a surface of the support and the second principal surface be bonded to the adhesive layer. In this case, it is preferred that after the adhesive layer is irradiated with ultraviolet rays to decrease adhesiveness of the adhesive layer, the plurality of wavelength conversion members be removed from the support.
The base material is preferably broken into parts by using a pressing member with a blade to press the blade against a portion of the support opposed to the breaking groove.
The base material is preferably formed to have phosphor particles dispersed in an inorganic matrix. In this case, the inorganic matrix is preferably a glass.
A wavelength conversion member according to the present invention is a wavelength conversion member having a first principal surface and a second principal surface opposed to each other and has a scribe line formed on a periphery of the first principal surface.
A wavelength conversion member according to the present invention is a wavelength conversion member having a first principal surface and a second principal surface opposed to each other, wherein a missing portion in a periphery of the first principal surface makes up 10% or less of the entire periphery.
The wavelength conversion member is preferably a wavelength conversion member in which phosphor particles are dispersed in an inorganic matrix.
A wavelength conversion member according to the present invention is a wavelength conversion member that has a first principal surface and a second principal surface opposed to each other and contains phosphor particles dispersed in an inorganic matrix, wherein a convex portion is formed by the phosphor particle on a side surface of the wavelength conversion member connecting between the first principal surface and the second principal surface.
The inorganic matrix is preferably a glass.
A light-emitting device according to the present invention includes: the wavelength conversion member according to the present invention; a light source provided toward the second principal surface of the wavelength conversion member and capable of irradiating the wavelength conversion member with excitation light; and a reflective member provided around a side surface of the wavelength conversion member connecting between the first principal surface and the second principal surface.
The reflective member is preferably made of a resin composition containing a white pigment.
The manufacturing method according to the present invention enables manufacturing of wavelength conversion members having a high light extraction efficiency and enables suppression of material loss.
The wavelength conversion member and light-emitting device according to the present invention have a high light extraction efficiency.
Hereinafter, a description will be given of preferred embodiments. However, the following embodiments are merely illustrative and the present invention is not limited to the following embodiments. Throughout the drawings, members having substantially the same functions may be referred to by the same reference characters.
(Embodiment of Manufacturing Method)
No particular limitation is placed on the type of the phosphor particles 3 so long as they emit fluorescence upon entry of excitation light. A specific example of the type of the phosphor particles 3 is one or more selected from the group consisting of oxide phosphor, nitride phosphor, oxynitride phosphor, chloride phosphor, oxychloride phosphor, sulfide phosphor, oxysulfide phosphor, halide phosphor, chalcogenide phosphor, aluminate phosphor, halophosphoric acid chloride phosphor, and garnet-based compound phosphor. In using a blue light as the excitation light, for example, a phosphor emitting a green light, a yellow light or a red light as fluorescence can be used. The average particle diameter of the phosphor particles 3 is preferably 1 μm to 50 μm and more preferably 5 μm to 25 μm. If the average particle diameter of the phosphor particles 3 is too small, the luminescence intensity may decrease. On the other hand, if the average particle diameter of the phosphor particles 3 is too large, the luminescent color may be uneven.
The content of the phosphor particles 3 in the base material 10 is preferably not less than 1% by volume, more preferably not less than 1.5% by volume, particularly preferably not less than 2% by volume, preferably not more than 70% by volume, more preferably not more than 50% by volume, and particularly preferably not more than 30% by volume. If the content of the phosphor particles 3 is too small, it is necessary to increase the thickness of the base material 10 in order to obtain a desired luminescent color. This results in increased internal scattering of the resultant wavelength conversion members, which may decrease the light extraction efficiency. On the other hand, if the content of the phosphor particles 3 is too large, it is necessary to decrease the thickness of the base material 10 in order to obtain the desired luminescent color, which may decrease the mechanical strength of the resultant wavelength conversion members.
An example of the inorganic matrix 2 is a glass. No particular limitation is placed on the type of the glass so long as it can be used as a dispersion medium for the phosphor particles 3. For example, a borosilicate-based glass, a phosphate-based glass, a tin-phosphate-based glass or a bismuthate-based glass can be used. Examples of the borosilicate-based glass include those containing, in % by mass, 30 to 85% SiO2, 0 to 30% Al2O3, 0 to 50% B2O3, 0 to 10% Li2O+Na2O+K2O, and 0 to 50% MgO+CaO+SrO+BaO. Examples of the tin-phosphate-based glass include those containing, in % by mole, 30 to 90% SnO and 1 to 70% P2O5.
The base material 10 may be made of, aside from the above composition, a ceramic, such as a YAG ceramic.
Referring to
The width w of the breaking grooves 13 is preferably not less than 0.001 mm, more preferably not less than 0.002 mm, preferably not more than 0.010 mm, and more preferably 0.005 mm. If the width w is too large, missing portions occur during the breaking. If the width w is too small, breaking along the breaking grooves 13 may be difficult to achieve.
The breaking grooves 13 are preferably formed by scribing. A specific method for forming the breaking grooves 13 (scribe lines) can be appropriately selected depending upon the material of the inorganic matrix 2. If the inorganic matrix 2 is a glass, the breaking grooves 13 are preferably formed by a scriber or the like using diamond particles or the like. Alternatively, the breaking grooves 13 may be formed by laser depending upon the material of the inorganic matrix 2.
In a state shown in
When in the above manner the pressing member 30 is moved laterally (in the x direction) from below one breaking groove 13 to below another to place it below each breaking groove 13 and then moved up and down, the base material 10 is broken into parts along a row of breaking grooves 13 arranged side by side in the x direction. Referring to
Next, as shown in
By breaking the base material 10 into parts along the breaking grooves 13 in the above manner, a plurality of wavelength conversion members 1 can be manufactured. The method according to this embodiment enables accurate breaking of the base material 10 along the breaking grooves 13. Therefore, the resultant wavelength conversion members 1 tend to have a higher dimensional accuracy in the first principal surfaces than in the second principal surfaces. Hence, in producing a light-emitting device by combining the wavelength conversion member 1 with a light source, it is preferred to produce it so that the first principal surface of the wavelength conversion member 1 serves as a light outgoing surface.
Although in this embodiment breaking grooves having a grid-like pattern are formed and a plurality of wavelength conversion members having a rectangular plan shape are manufactured, the present invention is not limited to this. For example, the plan shape of the wavelength conversion members may be triangular or polygonal, such as pentagonal or hexagonal. Alternatively, the plan shape may be circular, oval or like shapes. Still alternatively, the plan shape may be a shape partly including an arc.
Although in this embodiment breaking grooves are formed only in the first principal surface of the base material, breaking grooves may also be formed in the second principal surface. Although in this embodiment the support is expanded by pressing the support from below to make it bulge upward, the present invention is not limited to this. Other means for expanding the support laterally may be used. Although the support used is a support on which an adhesive layer made of an ultraviolet curable resin is formed, the present invention is not limited to this.
(Wavelength Conversion Member and Light-Emitting Device of First Embodiment)
Since the wavelength conversion member 1 according to this embodiment is a wavelength conversion member manufactured by the method according to the above embodiment, the scribe lines are formed along the periphery 6 of the first principal surface 4. The wavelength conversion member 1 according to this embodiment has less missing portions in the periphery 6 of the first principal surface 4 as compared to a conventional wavelength conversion member produced by dicing. Since as described previously the width w of the breaking grooves 13 is smaller than a missing portion in the present invention to be described below, the effect exerted on the light extraction efficiency of the wavelength conversion member 1 by the breaking grooves 13 is small.
A description will be given below of the effect exerted on the light extraction efficiency of the wavelength conversion member 1 by a missing portion in the periphery 6 of the first principal surface 4.
In the present invention, portions of the periphery 6 located inwardly of the second imaginary line(s) B are assumed as missing portions 6b. The present invention has a feature that the missing portions 6b make up 10% or less of the entire periphery 6. This means that the sum of the lengths L of the missing portions 6b along the second imaginary line(s) B throughout the entire periphery 6 is 10% or less of the total length of the first imaginary line(s) A along the periphery 6. To be specific about the wavelength conversion member 1 according to this embodiment, the plan shape of the wavelength conversion member 1 is rectangular and formed of four sides. The length of the first imaginary line A and the lengths L of missing portions 6b are measured for each side of the rectangular shape, the sum of the lengths of the first imaginary lines A of the four sides and the sum of the lengths L of the missing portions 6b of the four sides are determined, and determination is made of whether or not the sum of the lengths L is 10% or less of the sum of the lengths of the first imaginary lines A.
So long as the plan shape of the wavelength conversion member 1 is composed of linear line segments, the lengths L of the missing portions 6 can be measured in the same manner as described above. If the plan shape of the wavelength conversion member 1 includes any arcuate portion, an arcuate first imaginary line A is assumed and an arcuate second imaginary line B located concentrically inwardly of the first imaginary line A is assumed. Thus, the lengths L of missing portions 6b can be measured in the same manner as described above. In this case, the second imaginary line B is set a distance D radially inwardly of the first imaginary line A.
Since, according to the present invention, the missing portions 6b make up 10% or less of the entire periphery 6, the light extraction efficiency of the wavelength conversion member 1 can be increased. This will be described below.
Examples of the reflective member 41 that can be used include a resin composition containing a resin and a ceramic powder and a glass ceramic. Examples of a material for the glass ceramic that can be used include a mixed powder of glass powder and ceramic powder and a crystallizable glass powder.
Examples of the glass powder that can be used include SiO2—B2O3-based glasses, SiO2-RO-based glasses (where R represents an alkaline earth metal), SiO2-Al2O3-based glasses, SiO2-ZnO-based glasses, SiO2-R2O-based glasses (where R represents an alkali metal), and SiO2-TiO2-based glasses. These glass powders may be used alone or in a combination of two or more of them.
Examples of the ceramic powder that can be used include silica, alumina, zirconia, and titania. These ceramic powders may be used alone or in a combination of two or more of them.
The reflective member 41 is particularly preferably made of a white resin composition containing a white pigment. Examples of the white pigment include ceramic powders of silica, alumina, zirconia, and titania as described above.
Examples of the light source 51 that can be used include an LED (light emitting diode) and an LD (laser diode).
Examples of the substrate 61 that can be used include white LTCCs (low temperature co-fired ceramics) capable of efficiently reflecting light emitted from the light source 51. A specific example of the white LTCC is a sintered body of an inorganic powder, such as aluminum oxide, titanium oxide or niobium oxide, and a glass powder. Alternatively, ceramics, including aluminum oxide and aluminum nitride, can also be used as the substrate 61.
Excitation light emitted from the light source 51 excites phosphor particles in the wavelength conversion member 1, so that fluorescence is emitted from the phosphor particles. A synthesized light of this fluorescence and excitation light having passed through the wavelength conversion member 1 is emitted from the light-emitting device 50.
Respective wavelength conversion members having a plan shape of a 1.4 mm×1.4 mm rectangle and a thickness of 0.2 mm were produced by a method for manufacturing wavelength conversion members by breaking a base material into parts in the breaking manner according to the present invention (Example 1) and a method for manufacturing wavelength conversion members by breaking a base material into parts using a dicing saw (Comparative Example 1). YAG:Ce was used as phosphor particles, an alkaline earth silicate glass was used as an inorganic matrix, and the content of phosphor particles in a base material was 10% by volume.
Breaking grooves were formed in the first principal surface of the base material to a depth d of 0.004 mm and a width w of 0.004 mm and the base material was then broken into parts by the method according to the present invention, thus obtaining wavelength conversion members. Missing portions in the periphery of the first principal surface of the obtained wavelength conversion member made up 3% of the entire periphery.
The obtained wavelength conversion member and a light source was adhesively bonded with a transparent silicone resin by curing the resin and a reflective member was then provided on the side surfaces of the wavelength conversion member and the light source, thus producing a light-emitting device. The reflective member was produced using a white resin composition made of silicone resin and titania powder. A flip-chip LED having a wavelength of 445 nm was used as the light source. The obtained light-emitting device was irradiated with excitation light (having a current value of 0.3 A) from the light source and the luminous flux of light emitted from the light-emitting device was measured. The luminous flux was 105 a.u.
Wavelength conversion members were obtained in the same manner as in Example 1 except that the base material was broken into parts by cutting with a dicing saw. The dicing saw used was a dicing saw having a blade width of 0.1 mm. When cutting the base material, portions of the base material corresponding the blade width of the dicing saw were chipped away, resulting in a material loss of about 14%. Missing portions in the periphery of the first principal surface of the obtained wavelength conversion member made up 20% of the entire periphery.
In the same manner as in Example 1, a light-emitting device was produced and the luminous flux of light emitted from the light-emitting device was measured. The luminous flux was 100 a.u.
Comparison between Example 1 and Comparative Example 1 shows that by suppressing the occurrence of missing portions in the periphery to 10% or less of the entire periphery according to the present invention, the light extraction efficiency of the wavelength conversion member can be improved.
Although the wavelength conversion member shown in
(Wavelength Conversion Member and Light-Emitting Device of Second Embodiment)
The side surfaces 7 of the wavelength conversion member 1 according to this embodiment are surfaces formed by breaking the base material in the manner described above. When the base material is broken, the inorganic matrix 2 is broken, but phosphor particles 3 present in the broken surfaces are not broken. Therefore, as shown in
| Number | Date | Country | Kind |
|---|---|---|---|
| 2016-239326 | Dec 2016 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2017/041765 | 11/21/2017 | WO | 00 |
