Patent Application
20170138326
The invention relates to a method for nitriding a component of a fuel injection system, said component being subject to high pressure and being composed of an alloyed steel.
German Laid-Open Application DE 102 56 590 A1 discloses that an injection nozzle of a fuel injection system is very robust if the injection nozzle is in a nitrided state. In this case, corrosion resistance and wear resistance, in particular, are enhanced. However, no details are given of the nitriding method per se in this publication.
WO publication WO 2001/042528 A1 has furthermore disclosed a method for nitriding an injection nozzle. The known nitriding method comprises a nitrocarburizing process in a salt bath in a first step, followed, in a second step, by a gas nitriding process at a temperature between 520° C. and 580° C. with a low nitriding index or low nitriding potential (in a range between 0.08 and 0.5), i.e. in the “α range” of the Lehrer diagram.
The stresses on the components of a fuel injection system carrying fuel under very high pressure—especially in the region of restrictions—can lead to very high cavitation stresses on these components. Even in the case of the components treated by the nitriding methods described above, this can lead to relatively severe cavitation damage.
In contrast, the nitriding method according to the invention minimizes the cavitation damage caused by the high pressures by further increasing ductility (toughness) below the surface of the material of the components by means of the nitriding method. In addition, the nitriding has a positive effect on pulsating fatigue strength. The life and endurance of the components is thereby increased.
For this purpose, the method for nitriding a component of a fuel injection system, said component being subject to high pressure and being composed of an alloyed steel, has the following method steps:
By means of activation, the resistance of the component to penetration by nitrogen diffusion is reduced. This step therefore increases the capacity of the component for nitriding. The subsequent pre-oxidization process leads to the component having a higher corrosion resistance during operation.
The actual nitriding is divided into two steps, in which gas containing ammonia is preferably used:
The nitriding method according to the invention not only reduces the thickness of the brittle white layer but, in particular, reduces the nitride inclusions along the grain boundaries in the diffusion layer as compared with the known nitriding methods. As a result, the grain boundaries are less susceptible to fracture, increasing toughness and hence robustness with respect to cavitation and enhancing the pulsating fatigue strength of the component.
It is advantageous if the first nitriding potential KN,1 is between 1 and 10, preferably between 2 and 8. The first nitriding potential KN,1 is therefore relatively high. As a result, the range in the Lehrer diagram at temperatures between 520° C. and 570° C. is substantially the ε nitride range, which ensures high nitrogen absorption by the activated component around which nitriding gas flows.
It is furthermore advantageous if the second nitriding potential KN,2 is between 0.2 and 0.4. The second nitriding potential KN,2 is therefore relatively low. As a result, deep diffusion of a high nitrogen content into the component is prevented. The nitrogen content is increased predominantly in the white layer; in the base material, the percentage of nitrogen by mass increases to no more than about 6%. The toughness of the material is thus very largely maintained.
In an advantageous embodiment, a component that has been nitrided by the method according to the invention has a percentage of nitrogen by mass at the surface thereof between 11% and 25%. This ensures a very hard, cavitation-resistant, wear-resistant and corrosion-resistant surface of the component.
In another advantageous embodiment, a component which has been nitrided by the method according to the invention has a percentage of nitrogen by mass of between 3% and 8% at a first depth t1 of 10 μm from the surface of the component. The comparatively large fall in the percentage of nitrogen by mass at a depth of just 10 μm leads to a relatively high toughness of the component, despite the high surface hardness. The transition from the white layer to the diffusion layer is also situated approximately at this depth in the component.
In another advantageous embodiment, a component which has been nitrided by the method according to the invention has a percentage of nitrogen by mass of between 2% and 7% at a second depth t2 of 15 μm from the surface of the component. This leads to a further increase in the toughness of the component in comparison with known nitriding methods.
In another advantageous embodiment, a component which has been nitrided by the method according to the invention has a percentage of nitrogen by mass of between 2% and 6% at a third depth t3 of 20 μm from the surface of the component. This leads to a further increase in the toughness of the component in comparison with known nitriding methods.
From this depth in the component, the percentage of nitrogen changes asymptotically as far as the end of the diffusion zone and then falls relatively abruptly at the end of the diffusion zone to the percentage of nitrogen already contained in the base material. In this case, the diffusion zone usually extends up to about 500 μm into the interior of the component. From the third depth t3 onward, the percentage of nitrogen has fallen to such an extent that there is only a small number of nitride inclusions. Thus, the material has the necessary toughness from this depth in the component.
In an advantageous embodiment, the component is a nozzle body of a fuel injector for injecting fuel into a combustion chamber of an internal combustion engine, wherein the fuel injector has a nozzle needle, which is guided for longitudinal movement in the nozzle body. Precisely because of the high pressure and the high speed of flow of the fuel in the fuel injector and, more specifically, in the nozzle body there, the nozzle body is suitable for a nitriding method according to the invention. There may be very high cavitation stress at the nozzle body injection openings leading into the combustion chamber of the internal combustion engine, for example. Owing to the increased pulsating fatigue strength of the nozzle body due to the nitriding method according to the invention, cavitation damage caused thereby can be minimized or even entirely avoided.
The nitriding potential KN is defined as
Here, p(NH3) is the partial pressure of the ammonia and p(H2) is the partial pressure of the hydrogen. The partial pressure is in each case the pressure in an ideal gas mixture, which is associated with an individual gas component. This means that the partial pressure corresponds to the pressure which the individual gas component would exert in the relevant volume if it were present in isolation. The partial pressure is generally used instead of the mass concentration when the diffusion behavior of the dissolved gas is being considered.
The state phases of the iron-nitrogen system are divided into an ε nitride range, a γ nitride range, a γ′ nitride range and an a nitride range. ε nitrides have very high percentages of nitrogen by mass and are generally found at the surface of the nitrided component, the “white layer” or the diffusion layer situated below the latter. The γ′ nitride range likewise has a high percentage of nitrogen, but the nitrogen atoms are more ordered than in the ε nitride range. The γ′ nitride range is likewise found in the white layer and diffusion layer. Both the ε nitride range and the γ′ nitride range are relatively hard and brittle. At temperatures which are very high but outside the nitriding method according to the invention, γ nitrides also occur, and these have very high nitrogen concentrations. The α nitride range has a relatively low nitrogen concentration and is relatively tough. α nitride ranges are generally found in the diffusion layer and in the base material.
In
The method according to the invention for nitriding a fuel injection system component, e.g. the nozzle body 4, subject to high pressure and composed of an alloyed steel, comprises the following method steps:
1) activating the component in inorganic acid.
2) pre-oxidizing the component in an oxygen-containing atmosphere between 380° C. and 420° C.
3) nitriding the component between 520° C. and 570° C. at a high first nitriding potential KN,1 in the ε nitride range, preferably where 1≦KN,1≦10.
4) nitriding the component between 520° C. and 570° C. at a low second nitriding potential KN,2 in the γ′ nitride range, preferably where 0.2≦KN,2≦0.4.
A percentage of nitrogen by mass as a function of the depth t in the component as shown in
| Number | Date | Country | Kind |
|---|---|---|---|
| 10 2014 213 510.9 | Jul 2014 | DE | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2015/059781 | 5/5/2015 | WO | 00 |
