The present invention is based on a method for operating an internal combustion engine, particularly of a motor vehicle, in which a lean air/fuel mixture is burned in a combustion chamber; in which nitrogen oxides contained in the exhaust gas are stored in an accumulator-type catalytic converter; in which a storage efficiency, with which the accumulator-type catalytic converter stores the nitrogen oxides contained in the exhaust gas, is ascertained; and in which the storage efficiency is ascertained as a function of an instantaneous space velocity of the exhaust gases in the accumulator-type catalytic converter. The present invention also relates to a computer program, a control device and an internal combustion engine of the corresponding type.
Such a method is known from German Patent No. 199 26 305. There, an internal combustion engine is operated with a lean fuel/air mixture, which means nitrogen oxides are stored temporarily in an accumulator-type catalytic converter. In a regeneration phase, the internal combustion engine is operated with a rich fuel/air mixture, which means the stored nitrogen oxides are catalytically converted.
During the storage of nitrogen oxides, a storage efficiency is calculated, with which the accumulator-type catalytic converter stores nitrogen oxides contained in the exhaust gas of the internal combustion engine. This storage efficiency is dependent, inter alia, on an air-mass flow which, however, only represents a substitute for the space velocity of the exhaust gas in the accumulator-type catalytic converter. In column 3, lines 47 through 49 of German Patent No. 199 26 305, it is assumed that this substitution can be made, since the catalytic converter volume is constant.
However, ascertainment of the storage efficiency according to German Patent No. 199 26 305 has proven to be inaccurate.
An object of the present invention is to provide a method which supplies the most optimal storage efficiency possible, without greater expenditure. This objective is achieved according to the present invention in a method of the type indicated at the outset, in that two efficiencies are ascertained at least as a function of the temperature of the accumulator-type catalytic converter and a space velocity; one of the two efficiencies is ascertained for a great space velocity and the other efficiency is ascertained for a small space velocity; and the storage efficiency is ascertained as a function of the instantaneous space velocity from the two efficiencies.
Thus, according to the present invention, the instantaneous space velocity of the exhaust gas in the accumulator-type catalytic converter is taken into account. Therefore, there is no replacement by other variables. This measure alone substantially improves the precision of the method according to the present invention compared to the related art.
At the same time, however, it is not necessary that corresponding efficiencies be available for all possible instantaneous space velocities. Instead, this is only necessary for two space velocities, based on which the storage efficiency is then ascertained. It is thereby ensured that the method of the present invention entails only a small expenditure, accompanied by nevertheless optimal results.
In one advantageous further development of the invention, the two efficiencies are ascertained as a function of the NOx mass already stored in the accumulator-type catalytic converter. It is thereby possible, in addition to the temperature of the accumulator-type catalytic converter, to also take into account the aforementioned NOx mass already stored when determining the storage efficiency. In this manner, the accuracy of the ascertained storage efficiency is further optimized.
It is particularly useful if the two efficiencies are interpolated. It is thereby possible, in simple manner, to achieve optimal linkage of the two efficiencies.
In one advantageous embodiment of the invention, the two efficiencies for the two space velocities are measured in advance on a reference accumulator-type catalytic converter of the same type. The efficiencies may then advantageously be stored in the form of two characteristics maps.
In another advantageous development of the invention, the storage efficiency is influenced by further factors, e.g., by the storage of sulphur oxides in the accumulator-type catalytic converter and/or by the ageing of the accumulator-type catalytic converter over time. The accuracy of the storage efficiency may thereby be further increased.
Further features, uses and advantages of the present invention come to light from the following description of exemplary embodiments of the invention which are shown in the figures of the drawing. In this context, all described or depicted features, alone or in any desired combination, form the subject matter of the present invention, and irrespective of their wording or illustration in the description and in the drawing, respectively.
a and 2b show two schematic, three-dimensional characteristics maps of performance quantities of the internal combustion engine in
Internal combustion engine 10 has a cylinder 11 in which a piston 12 is movable back and forth. Cylinder 11 and piston 12 delimit a combustion chamber 13. Connected to combustion chamber 13 is an intake manifold 14, via which air may be conveyed to combustion chamber 13. Also connected to combustion chamber 13 is an exhaust pipe 15 via which exhaust gas is able to be discharged from combustion chamber 13. Valves 16 are provided to control the air supply and the exhaust flow. Furthermore, a fuel injector 17 and a spark plug 18 are assigned to combustion chamber 13. Fuel may be injected into combustion chamber 13 via fuel injector 17, and the injected fuel in combustion chamber 13 is able to be ignited with the aid of spark plug 18 and thus combusted.
Connected to exhaust pipe 15 is a three-way catalytic converter 19 which is provided to convert the pollutant components HC, CO and NOx, into the components H2O, CO2 and N2. Three-way catalytic converter 19 is not absolutely necessary for a diesel engine. The three-way catalytic converter is connected to an accumulator-type catalytic converter 21 via a pipe 20. In pipe 20, a temperature sensor 22 may be provided which ascertains the temperature of the exhaust gas flowing into accumulator-type catalytic converter 21. Alternatively, temperature sensor 22 may also be assigned to accumulator-type catalytic converter 21 or to another location in the exhaust branch, in order to measure or ascertain the temperature of the exhaust gas directly and/or with the aid of a modeling. A further pipe 23 is connected to accumulator-type catalytic converter 21.
If internal combustion engine 10 is operated with a stochiometric air/fuel mixture, thus where Lambda=1, then the pollutant components formed in this case are converted by three-way catalytic converter 19. However, to save on fuel, internal combustion engine 10 is also operated with a lean air/fuel mixture, thus where Lambda>1. The result is that, because of the excess air, the nitrogen oxides NOx contained in the exhaust gas can no longer be reduced in three-way catalytic converter 19.
For this purpose, accumulator-type catalytic converter 21 is provided, which is capable of storing the nitrogen oxides NOx temporarily. The storage capacity of accumulator-type catalytic converter 21 is limited. Thus, the storage capability decreases as the filling ratio of accumulator-type catalytic converter 21 increases. Moreover, the storage-capability limit is a function of performance quantities of internal combustion engine 10. Accumulator-type catalytic converter 21 must always be discharged again and regenerated. To that end, internal combustion engine 10 is operated for a short period with a rich air/fuel mixture, thus where Lambda<1. The nitrogen oxides NOx stored in accumulator-type catalytic converter 21 are thereby converted into the components N2 and CO2. After such a regeneration of accumulator-type catalytic converter 21, it is again able to temporarily store nitrogen oxides NOx.
The point of time for regenerating accumulator-type catalytic converter 21 may be determined, for example, with the aid of an NOx sensor downstream of accumulator-type catalytic converter 21. Often, however, it is also necessary to control the regeneration of accumulator-type catalytic converter 21 without the aforesaid NOx sensor. The method of the present invention described below may be used for that purpose.
a and 2b show two characteristics maps having state variables of accumulator-type catalytic converter 21, which in each case are spanned over three axes. In both characteristics maps, they are a temperature T of accumulator-type catalytic converter 21, an NOx mass M already stored in accumulator-type catalytic converter 21 and an efficiency η1 and η2, respectively. The characteristics map of
For example, from the characteristics map in
Space velocity R1 of the exhaust gas in accumulator-type catalytic converter 21 is greater in the characteristics map of
The two characteristics maps of
According to
According to
In a following block 33, the NOx mass M is compared to a predefined threshold value. If NOx mass M exceeds this threshold value, a signal S is generated which is supplied to a regeneration control (not shown), that uses this information within the framework of a decision process with respect to initiating a regeneration of accumulator-type catalytic converter 21.
Moreover, the NOx mass M already temporarily stored in accumulator-type catalytic converter 21 is supplied to the two characteristics maps in
Temperature T of accumulator-type catalytic converter 21 is also supplied to both characteristics maps 34, 35. Temperature T may be ascertained with the aid of a model, if temperature sensor 22—as shown in
In each case an efficiency η1 and η2 are now read out from the two characteristics maps 34, 35 as a function of NOx mass M and temperature T. The two efficiencies η1, η2 are supplied to an interpolation, represented in
The two efficiencies η1, η2 are thereupon linked as a function of space velocity R by interpolation 36 to form a storage efficiency η. Familiar interpolation methods may be used for this purpose. In the simplist case, from known space velocities R1, R2, which form the basis of both characteristics maps 34, 35, and from instantaneous space velocity R, a factor may be ascertained with which the two efficiencies η1, η2 enter into the calculation of storage efficiency η.
Achieved by interpolation 36 is that neither space velocity R, which forms the basis of characteristics map 34, nor space velocity R2, which forms the basis for characteristics map 35, is solely decisive in each instance, but rather that actual space velocity R in accumulator-type catalytic converter 21 is taken into account. Overall, therefore, storage efficiency η is a function of actual space velocity R of accumulator-type catalytic converter 21, as well as—via the two characteristics maps 34, 35—temperature T of accumulator-type catalytic converter 21 and the NOx mass M already stored therein.
As was already mentioned, storage efficiency η is linked with untreated NOx mass N in block 31. In the simplist case, this may be accomplished by multiplying untreated NOxmass N by storage efficiency η. In this case, block 31 is a multiplier. However, other linkages may also be provided and carried out with the aid of block 31.
Due to the linkage of untreated NOx mass N with storage efficiency η, it is not the entire untreated NOx mass N flowing into accumulator-type catalytic converter 21 which is considered as though it would be completely stored in accumulator-type catalytic converter 21, but rather only that portion of untreated NOx mass N is considered which accumulator-type catalytic converter 21 is presently able to store at all based on the instantaneous operating conditions.
During operation of internal combustion engine 10 with a lean air/fuel mixture, not only nitrogen oxides NOx but also sulphur oxides, in particular sulphur dioxide SO2, are formed. Accumulator-type catalytic converter 21 stores this sulphur dioxide SO2 as well, so that accumulator-type catalytic converter 21 is also loaded to the extent that the loading is comparable to the loading of accumulator-type catalytic converter 21 with nitrogen oxides NOx. As a result of the loading with sulphur dioxide SO2, the storage capability, and therefore the storage efficiency η for the loading of accumulator-type catalytic converter 21 with nitrogen oxides NOx is reduced. One difference is that the loading with sulphur dioxide SO2 takes place substantially more slowly than the loading with nitrogen oxides NOx. Furthermore, regeneration of accumulator-type catalytic converter 21 is not possible under normal operating conditions, but rather requires an elevated temperature of accumulator-type catalytic converter 21.
Likewise, it is possible to ascertain the loading of accumulator-type catalytic converter 21 with sulphur dioxide SO2 as a function of the total amount of burned fuel on the basis of the known content of sulphur dioxide SO2 in the fuel. In this case, it may be assumed that approximately the total sulphur dioxide SO2 is stored in accumulator-type catalytic converter 21. Plausibility analyses may be carried out in the event of changing fuel, and therefore changing content of sulphur dioxide SO2. In this context, the loading of accumulator-type catalytic converter 21 must be carried out starting from the regeneration of the latter last implemented, with respect to sulphur dioxide SO2. On this basis, it is then possible to again derive the factor, already mentioned, which thereupon alters storage efficiency η.
Quite generally, therefore, from the quantity of sulphur dioxide SO2 already stored, determined in any way desired and optionally checked for plausibility, it is possible to infer the indicated factor, which ultimately then represents a deterioration of the storage efficiency of accumulator-type catalytic converter 21.
If the factor generated by block 37 reaches a predefined threshold value, then accumulator-type catalytic converter 21 may be regenerated with regard to sulphur dioxide SO2. To that end, given, for instance, a rich air/fuel mixture, thus where Lambda<1, accumulator-type catalytic converter 21 is heated to an elevated temperature. Thereupon, the indicated factor may be reset to an initial value determined in advance.
In corresponding manner, as the storage of sulphur dioxide SO2 in accumulator-type catalytic converter 21 can be taken into account by block 37, it is likewise possible to utilize block 37 for taking into account further changes in accumulator-type catalytic converter 21 dependent on the operating conditions. Thus, for example, a further factor may be provided, which takes into account the ageing over time and/or, e.g., damage to accumulator-type catalytic converter 21 caused by temperature, and which influences storage efficiency η in corresponding manner.
Number | Date | Country | Kind |
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103 19 224.7 | Apr 2003 | DE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP04/50451 | 4/6/2004 | WO | 9/7/2006 |