The present invention relates to a method for operating a blast furnace with which the combustion temperature is increased by blowing pulverized coal from a tuyere of a blast furnace, thereby achieving an improvement of productivity and a reduction in CO2 emissions.
In recent years, global warming due to an increase in carbon dioxide emissions has become a problem, and controlling CO2 emissions is an important issue also in the steel industry. In response to this, the operation with a low reduction agent ratio (abbreviated as low RAR, total amount of a reducing agent blown from a tuyere and coke charged from a top of a furnace per manufacture of a ton of pig iron) has been promoted strongly in the recent blast furnace operations. Since coke charged from a top of a furnace and pulverized coal blown from a tuyere are mainly used as a reducing agent in a blast furnace, and in order to achieve a low reduction agent ratio, and eventually, control carbon dioxide emissions, a measure to replace coke or the like with a reducing agent having a high hydrogen content ratio, such as LNG (Liquefied Natural Gas) and heavy oil, is effective. In PTL 1 described below, a lance from which a fuel is blown through a tuyere is configured by a triple tube, pulverized coal is blown from an inner tube of the triple tube lance, LNG is blown from a gap between the inner tube and an intermediate tube, oxygen is blown from a gap between the intermediate tube and an outer tube, and LNG is combusted on ahead, so that the temperature of the pulverized coal is increased, and the combustion efficiency of the pulverized coal is improved. In addition, in PTL 2 described below, oxygen is blown from a single tube lance arranged in a blast pipe (blowpipe) to the central part of high-temperature air flowing in the blast pipe, and the temperature of oxygen is increased to several hundred degrees C., and moreover, pulverized coal is blown from a lance arranged so as to penetrate a tuyere, and the pulverized coal is brought into contact with heat oxygen of several hundred degrees C., so that the temperature increase of the pulverized coal is improved, and the combustion efficiency of the pulverized coal is improved.
PTL 1: JP 2011-174171 A
PTL 2: JP 2013-531732 A
However, as described in PTL 1, when the pulverized coal, LNG, and oxygen are blown from the triple tube lance, LNG is combusted ahead of the pulverized coal because LNG is easy to be combusted, as it is called, flammable, oxygen blown from the lance is used by the combustion of LNG, the contacting property between oxygen and the pulverized coal is deteriorated, and the combustion efficiency may be decreased. Moreover, since the outside diameter of the triple tube lance is large, the triple tube lance sometimes cannot be inserted into the existing lance insertion through hole, and in such a case, the inside diameter of the lance insertion through hole needs to be made larger. Furthermore, since LNG is flammable and is rapidly combusted, when LNG is rapidly combusted at an end of the lance, the temperature of the end of the lance is increased, and wear damage, such as a crack and erosion, may be generated in the end of the lance. When such wear damage is generated in the end of the lance, backfire, clogging of the lance, or the like may be induced. In addition, as described in PTL 2, when the pulverized coal is blown from an end of the tuyere, and the pulverized coal is brought into contact with heat oxygen, the temperature increase of the pulverized coal is improved, but the pulverized coal is blown into a raceway quickly, and thus, there is no time for the pulverized coal to be combusted in the blast pipe and the tuyere, and the combustion efficiency of the pulverized coal may not be improved as the result.
The present invention was made in view of the problems as described above, and an object of the present invention is to provide a method for operating a blast furnace with which the combustion efficiency of a solid fuel, such as pulverized coal, is improved, thereby making it possible to improve productivity and reduce CO2 emissions.
In order to solve the above-described problems, according to one mode of the present invention, a method for operating a blast furnace including: when hot air is blown into a blast furnace from a blast pipe through a tuyere, using a double tube as an upstream lance for blowing a solid fuel into the blast pipe; blowing one of the solid fuel and combustion-supporting gas from one of an inner tube of the upstream lance and a gap between the inner tube and an outer tube, and blowing the other of the solid fuel and the combustion-supporting gas from the other of the inner tube and the gap between the inner tube and the outer tube; disposing a downstream lance on a downstream side in a blast direction of the hot air from a blowing end part of the upstream lance; and blowing flammable gas from the downstream lance is provided.
Examples of the solid fuel of the present invention include pulverized coal.
In addition, the combustion-supporting gas of the present invention is defined as gas having an oxygen concentration of at least 50 vol % or more.
In addition, the flammable gas used in the present invention is gas having combustibility higher than pulverized coal literally, and, in addition to hydrogen, city gas, LNG, and propane gas containing hydrogen as a main component, converter gas, blast furnace gas, coke-oven gas, and the like generated in a steel mill can be applied. Moreover, shale gas equivalent to LNG can also be used. The shale gas is natural gas obtained from a shale stratum, and is called an unconventional natural gas resource because of being produced in a place that is not a conventional gas field. Flammable gas, such as city gas, is ignited/combusted very rapidly, flammable gas having high hydrogen content has high combustion calorie, and furthermore, flammable gas is advantageous in air permeability and heat balance of a blast furnace because of not containing ash unlike pulverized coal.
In a method for operating a blast furnace of the present invention, a solid fuel and combustion-supporting gas are blown from an upstream lance configured by a double tube, and flammable gas is blown from a downstream lance on a downstream side in a hot air blast direction, so that oxygen to be used for combustion of the flammable gas is supplied from the upstream lance, and the solid fuel whose temperature has been increased by the combustion of the flammable gas is combusted along with the supplied oxygen or oxygen in an air blast. Therefore, the combustion efficiency of the solid fuel is improved, and accordingly, it makes possible to efficiently improve productivity and reduce CO2 emissions.
Next, one embodiment of a method for operating a blast furnace of the present invention will be described with reference to the drawings.
For example, when pulverized coal as a solid fuel is blown from the lance 4, the pulverized coal is blown along with carrier gas, such as N2. When only the pulverized coal as a solid fuel is blown from the lance 4, a volatile matter and fixed carbon of the pulverized coal which has passed through the tuyere 3 from the lance 4 and has been blown into the raceway 5 are combusted along with coke, and an aggregate of carbon and ash generally called char, which has not combusted and is left, is discharged from the raceway 5 as incombusted char. Since the incombusted char is accumulated in the furnace, thereby deteriorating the air permeability in the furnace, it is required that the pulverized coal is combusted in the raceway 5 as much as possible, that is, the combustibility of the pulverized coal is improved. Since the hot air speed in front of the tuyere 3 in the hot air blast direction is approximately 200 m/sec and the existence region of oxygen in the raceway 5 from an end of the lance 4 is approximately 0.3 to 0.5 m, it is necessary to increase the temperature and improve contact efficiency with oxygen (diffusibility) of pulverized coal particles virtually at a level of 1/1000 sec.
The pulverized coal that has been blown into the raceway 5 from the tuyere 3 is first heated by heat transfer by convection from an air blast, and furthermore, the particle temperature is drastically increased by heat transfer by radiation and conductive heat transfer from a flame in the raceway 5, heat decomposition is started from the time when the temperature has been increased to 300° C. or more, the volatile matter is ignited to generate a flame, and the combustion temperature reaches 1400 to 1700° C. When the volatile matter is discharged, the pulverized coal becomes the above-described char. The char is primarily fixed carbon, and thus, a reaction called a carbon dissolution reaction also occurs along with a combustion reaction. At this time, an increase in the volatile matter of the pulverized coal to be blown into the blast pipe 2 from the lance 4 facilitates ignition of the pulverized coal, an increase in the combustion amount of the volatile matter increases the temperature increase speed and the maximum temperature of the pulverized coal, and an increase in the diffusibility and the temperature of the pulverized coal increases the reaction speed of the char. More specifically, it is considered that, as the volatile matter expands by gasification, the pulverized coal diffuses and the volatile matter is combusted, and the pulverized coal is rapidly heated and its temperature is rapidly increased by combustion heat thereof. In contrast, when, for example, LNG as flammable gas is blown into the blast pipe 2 from the lance 4 along with the pulverized coal, it is considered that LNG is in contact with oxygen in the air blast, LNG is combusted, and the pulverized coal is rapidly heated and its temperature is rapidly increased by combustion heat thereof, thereby facilitating ignition of the pulverized coal.
In the present embodiment, pulverized coal as a solid fuel and oxygen (pure oxygen) as combustion-supporting gas were used. In addition, a double tube lance is used for the upstream lance 4, one of the pulverized coal and oxygen is blown from an inner tube of the upstream lance 4 configured by the double tube lance, and the other of the pulverized coal and oxygen is blown from a gap between the inner tube and an outer tube. Regarding the blowing from the double tube lance, the pulverized coal may be blown from the inner tube and oxygen may be blown from the gap between the inner tube and the outer tube, or oxygen may be blown from the inner tube and the pulverized coal may be blown from the gap between the inner tube and the outer tube. Here, the pulverized coal was blown from the inner tube of the upstream lance 4 configured by the double tube lance, and oxygen was blown from the gap between the inner tube and the outer tube.
In the present embodiment, as illustrated in
Here, the density of the pulverized coal used was 1400 kg/m3, N2 was used as carrier gas, and the pulverized coal blowing condition was 1100 kg/h. In addition, the oxygen blowing condition was 100 Nm3/h, and, regarding the blast condition from the blast pipe 2, the blast temperature was 1200° C., the flow volume was 12000 Nm3/h, the flow speed was 150 m/s, and air was used. Regarding the LNG blowing condition, the flow volume was 350 Nm3/h and the flow speed was 146 m/s.
The main stream of the pulverized coal (including oxygen and carrier gas) blown from the upstream lance 4 flows by the hot air blast, as indicated by the solid line in
In order to prove this, the LNG molar fraction around the pulverized coal was evaluated by variously changing the blast pipe circumferential direction angle of the downstream lance 6 relative to the upstream lance 4 and performing a fluid analysis in the raceway 5 with a computer using general-purpose fluid analysis software. As illustrated in
In addition, it is considered that the blowing direction of the LNG blown from the downstream lance 6 with respect to the blast direction also affects the LNG molar fraction in gas in contact with the pulverized coal particles, i.e. the combustibility of the pulverized coal in the raceway 5. For example, when the blowing direction of the LNG blown from the downstream lance 6 with respect to the hot air blast direction, which is perpendicular to the hot air blast direction, is designated as 0°, and the blowing directions of the LNG (angle γ in
In order to prove this, the LNG molar fraction around the pulverized coal was evaluated by variously changing the blowing direction of the LNG blown from the downstream lance 6 with respect to the hot air blast direction and performing, in the same manner as the above, a fluid analysis in the raceway 5 with a computer using general-purpose fluid analysis software. Similarly, the evaluation position of the LNG molar fraction was set to be a position of 300 mm from the center position of the blowing end part of the upstream lance 4 in the hot air blast direction, i.e. a position in the raceway 5 of 200 mm from the end part of the tuyere 3 in the blast direction. In addition, also in the fluid analysis with the computer, in the same manner as the above, the molar fraction of LNG in gas of a mesh in which pulverized coal particles exist was defined as the molar fraction of the LNG in contact with the pulverized coal particles, and the evaluation was performed by an average value of the LNG molar fraction in gas in contact with all pulverized coal particles at the evaluation point of 300 mm from the center position of the blowing end part of the upstream lance 4 in the blast direction.
Next, in order to confirm the mixability of the pulverized coal flow and the LNG flow, which was considered in
In the same manner, the LNG molar fraction around the pulverized coal was evaluated by variously changing a blowing speed of the flammable gas from the downstream lance 6 and performing, in the same manner as the above, a fluid analysis in the raceway 5 with a computer using general-purpose fluid analysis software. The evaluation of the LNG molar fraction is the same as the above, the position of the downstream lance 6 relative to the upstream lance 4 is 180° in terms of the blast pipe circumferential direction angle, the blowing direction of the LNG blown from the downstream lance 6 with respect to the hot air blast direction is perpendicular to the blast direction, i.e. 0°, and other conditions are the same as the above.
Therefore, by satisfying these conditions, the pulverized coal is in contact with oxygen at the end of the lance, so that the combustion proceeds to some extent, furthermore, the pulverized coal is in contact with LNG by the LNG blowing from the downstream lance 6, so that the temperature increase of the pulverized coal becomes fast, and the combustibility of the pulverized coal can be improved. In addition, the rapid combustion of the pulverized coal at the end of the lance is controlled, and thus, a crack and erosion of the end of the lance due to heat can be prevented.
In order to confirm the effect of the method for operating a blast furnace, in a blast furnace having 38 tuyeres and an inner volume of 5000 m3, under the conditions that a desired production volume of hot metal was 11500 t/day, a pulverized coal ratio was 150 kg/t-hot metal, the distance of the downstream lance 6 from the upstream lance 4 was 80 mm, and the blowing speed of the flammable gas from the downstream lance 6 was 146 m/s and the above-described blast condition, pulverized coal blowing condition, and oxygen blowing condition were set, the operation was performed for three days in two ways, the case where LNG was blown from the downstream lance 6 and the case where a downstream lance was not used (LNG was added to air to be blasted), respectively, and the effect was confirmed by recording changes in average coke ratios (kg/t-hot metal). It is to be noted that the blowing direction of the LNG blown from the downstream lance 6 with respect to the hot air blast direction was perpendicular to the hot air blast direction, and the position of the downstream lance 6 relative to the upstream lance 4 was 180° in terms of the blast pipe circumferential direction angle. As a result, the coke ratio when a downstream lance was not used was 370 kg/t-hot metal, whereas the coke ratio when LNG was blown from the downstream lance 6 was 368 kg/t-hot metal. Accordingly, by blowing LNG from the downstream lance 6, the combustion efficiency of the pulverized coal was improved, and the coke ratio could be reduced. In addition, it was confirmed that there was not wear damage, such as a crack and erosion, in the end part of the upstream lance 4 configured by the double tube lance.
As just described, in the method for operating a blast furnace of the present embodiment, the pulverized coal as a solid fuel and oxygen as combustion-supporting gas are blown from the upstream lance 4 configured by a double tube, and LNG as flammable gas is blown from the downstream lance 6 on the downstream side in the hot air blast direction, so that oxygen to be used for the combustion of the LNG is supplied from the upstream lance 4, and the pulverized coal whose temperature has been increased by the combustion of the LNG is combusted along with the supplied oxygen or oxygen in the air blast. Therefore, the combustion efficiency of the pulverized coal is improved, and accordingly, it makes possible to efficiently improve productivity and reduce CO2 emissions.
In addition, when a direction perpendicular to the hot air blast direction is designated as 0°, and the downstream direction and the upstream direction therefrom in the hot air blast direction are designated as positive and negative, respectively, the blowing direction of the LNG from the downstream lance 6 with respect to the blast direction ranges from −30° to +45°. Accordingly, the combustion efficiency of the pulverized coal is surely improved.
In addition, a blowing position of the LNG from the downstream lance 6 with reference to a position at which the upstream lance 4 is inserted into the blast pipe 2 ranges from 160° to 200° in terms of the blast pipe circumferential direction angle. Accordingly, the combustion efficiency of the pulverized coal is surely improved.
In addition, the distance of the downstream lance from the upstream lance is set to be 27 mm to 80 mm, so that the combustion efficiency of the pulverized coal is surely improved.
In addition, the blowing speed of the flammable gas from the downstream lance is set to be 50 m/s to 146 m/s, so that the combustion efficiency of the pulverized coal is surely improved.
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