The present invention relates to packaging systems generally, and more particularly to packaging systems which are configured to efficiently package and deliver a tack product, such as a conformable thermal interface material, to installation facilities. In particular, the packaging systems of the present invention enable removal of the tacky product from the package without damage or destruction to the product.
Electronic components of the various type require heat transfer systems in order to remove excess heat generated in the operation thereof. Excess heat can reduce performance of the electronic components, and, in some cases, can lead to damage or shut down of the electronic components. A common electronic component in need of heat transfer systems is an integrated circuit, such as a microprocessor, which typically generates significant amounts of excess thermal energy.
One mechanism for transferring excess heat from, for example, integrated circuits, utilizes a thermal interface material (TIM) placed between the integrated circuit and a thermal diffusion structure, which typically has high surface area for efficient heat transfer to a cooling medium such as air. The thermal interface material is typically one that is highly thermally conductive, and is preferably “conformable” so as to conform to the uneven surfaces of the electronic component and the thermal diffusion structure without substantial gaps, which create barriers to heat transfer. The thermal interface material may posses a relatively low bulk modulus value in order to provide the conformability characteristic described above, and to therefore most efficiently transfer thermal energy away from the operating electronic component. Some thermal interface materials are “phase-changing”, in that their native viscosities decrease in elevated temperature environments, such as in proximity to an operating electronic component. In most installations, however, thermal interface materials have relatively low modulus values even at room temperature. Typical TIM modulus values at 20° C. may be less than about 50 Shore 00, and may be between about 5-50 Shore 00. This modulus range often results in a relatively “tacky” surface characteristic of the TIM.
Conventional thermal interface materials include various types of pastes, gels, and metals, and may be executed in a variety of formats. An increasingly popular format for thermal interface materials is a “pad” or a defined body with substantially defined surfaces and dimensions. Such thermal interface pads have proven useful and efficient in packaging and installation, and particularly in connection with “pick and place” installation operations.
The attachment of TIMs to electronic devices typically involves a number of process steps. The increasing prevalence of “pick and place” installation systems for thermal interface pads has reduced the number of process steps required in the attachment of thermal interface materials to electronic components. However, pick and place systems are most effective when used in connection with rigid, non-tacky structures, and efforts to implement the installation of relatively low-modulus TIM with pick and place equipment has therefore been challenging. A primary problem encountered in this scenario is the TIM becoming wholly or partially adhered to the pick and place equipment and/or the TIM packaging. Such adherence can damage the TIM, and can also require installation equipment shut down for cleaning.
In some cases, releasable surface liners have been employed in relatively low-modulus thermal interface pads so that the pad may be readily disengaged from the installation equipment. Addition of release liners, however, increases the cost of the thermal interface pads, and requires a further process step to remove the release liner prior to attachment of a thermal diffusion structure to the electronic apparatus. Other efforts have focused on an integrated, relatively high cross-linked integrated surface layer for interfacing with the pick and place installation equipment. Neither of such solutions, however, address the tackiness of the thermal interface pad where the pad is stored in packaging. Consequently, delivery of thermal interface pads to installation facilities through conventional packaging has resulted in unsatisfactory rates of TIM damage due to undesired adherence of the thermal interface pad to the packaging. The tackiness of the relatively low modulus thermal interface pads adheres to conventional packaging systems, and inhibits efficient and damage-free removal of the thermal interface pads therefrom.
Therefore it is an object of the present invention to provide packaging which facilitates delivery and removal of a tacky product, such as a thermal interface pad, by thermal interface installation equipment.
It is another object of the present invention to provide packaging that is compatible with conventional tape and reel packaging systems, which packaging facilitates efficient and non-destructive removal of tacky products from respective receptacles in the packaging.
It is a still further object of the present invention to provide methods for facilitating installation of tacky products, such as thermal interface pads, to heat-generating components.
By means of the present invention, tacky products such as relatively low modulus thermal interface materials may be packaged and delivered to an installation location, and may be removed from the packaging with a significantly reduced risk of damage. The package of the present invention minimizes the surface area which operably comes into contact with the tacky product. By minimizing such contact surface area, adhesion force between the tacky product and the packaging is significantly reduced, thereby enabling efficient and non-damaging removal of the product from the packaging.
In one embodiment, the package may be adapted for delivery of the tacky product having a base contact modulus of less than about 50 Shore 00, and includes a carrier tape having an upper surface and a plurality of cavities separately disposed in the upper surface along a length thereof. Each of the cavities includes a base that is sized to operably receive and support the product, and has a base surface area and a surface profile defining an elevated contact surface area that is less than about 50% of the base surface area. The surface profile includes a ridge extending at least partially about a central portion of the base, wherein the central portion makes up at least about 1-15% of the base surface area.
In some embodiments, the package of the present invention may be configured for use in tape and reel packaging systems. In addition, the contact surface area may be less than 20% of the base surface area, or may be less than about 10% of the base surface area.
In another embodiment, the package includes a carrier tape having an upper surface and a plurality of cavities separately disposed in the upper surface along a length thereof, wherein each of the cavities includes a base that is sized to operably receive and support the product. The base has a base surface area and a surface profile which defines a delineated first contact surface area that is less than about 50% of the base surface area. The package further includes a cover tape which has a first side that is removably securable to the upper surface of the carrier tape. At least a contact portion of the first side of the cover tape has a surface texture which defines a second contact surface area that is less than about 50% of the contact portion of the cover tape. Such cover tape may be adhesively securable to the upper surface of the carrier tape.
In a still further embodiment, a package system of the present invention includes a product having a base contact modulus of less than about 50 Shore 00, and a carrier tape having an upper surface and a plurality of cavities separately disposed in the upper surface along a length thereof. Each of the cavities includes a base that is sized to operably receive and support the product, and a base surface area and a surface profile defining an elevated first contact surface area that is less than about 50% of the base surface area. The package system described above may further include a cover tape having a first side that is removably securable to the upper surface of the carrier tape. At least a contact portion of the first side has a surface texture defining a second contact surface area that is less than about 50% of the contact portion of the cover tape.
A method for packaging a product having a base contact portion with a modulus of less than about 50 Shore 00 includes providing a carrier tape having an upper surface and plurality of cavities separately disposed in the upper surface along a length thereof. Each of the cavities includes a base that is sized to operably receive and support the product. The base has a base surface area and a surface profile which defines an elevated first surface contact area that is less than about 50% of the base surface area. The method further includes positioning the product in a respective one of said cavities such that the base contact portion of the product is in contact only with the contact surface area of the base. A cover tape is then secured to the upper surface the carrier tape, wherein the cover tape includes a first side that is removably securable to the upper surface of the carrier tape. At least a contact portion of the first side of the cover tape has a surface texture defining a second contact surface area that is less than about 50% of the contact portion of the cover tape.
The objects and advantages enumerated above together with other objects, features, and advances represented by the present invention will now be presented in terms of detailed embodiments described with reference to the attached drawing figures which are intended to be representative of various possible embodiments of the invention. Other embodiments and aspects of the invention are recognized as being within the grasp of those having ordinary skill in the art.
With reference now to the drawing figures, and first to
Package 10 may be manufactured from materials having properties which enable compliance with conventional tape and reel packaging systems. In other embodiments, however, package 10 may not be used in tape and reel packaging systems, and may therefore be sized and configured as desired. Moreover, package 10 need not include sprocket holes 12 for all embodiments, and particularly for non-tape and reel embodiments. Moreover, package 10 may be fabricated from relatively inflexible materials not suited for tape and reel packaging applications.
As illustrated in
Base surface area 22 may be defined as the two-dimensional surface area of base 20. In the example embodiment illustrated in
Base 20 of cavity 18 includes a surface profile defining a first contact surface area 24 that is delineated from a remainder of base surface area 22. In some embodiments, contact surface area 24 is elevated from the remainder of base surface area 22, such that product 50 comes into contact with contact surface area 24, and not with the remainder of base surface area 22. Accordingly, contact surface area 24 may be defined as a surface area of base 20 against which product 50 comes into contact when operably positioned in cavity 18. In the illustrated embodiment, contact surface area 24 substantially includes the respective upper surfaces of the elevated portions of the surface profile of base 20.
In one embodiment, the surface profile of base 20 includes a ridge 26 extending about a central portion 30 of base 20. Ridge 26 may take on the overall configuration of an oval about central portion 30, though a variety of other configurations for ridge 26 are contemplated by the present invention, and ridge 26 may be configured to not completely enclose central portion 30 of base 20. In one embodiment, a contact surface 27 of ridge 26 may be elevated by a dimension “HR” appropriate to support product 50 above a major surface 21 of base 20. In some embodiments, dimension “HR” may be between about 1-5 mm, and is configured to enable product 50 to be operably positioned in cavity 18 with an upper surface 52 of product 50 remaining below upper surface 16 of carrier tape 14. The overall configuration for ridge 26 may be designed to provide adequate support to product 50, so that base contact portion 52 remains suspended above major surface 21 of base 20, while minimizing the total contact surface area 24 required to so support product 50.
In some embodiments, the surface profile of base 20 may further include one or more pedestals 28 having respective upper surfaces 29 forming a portion of contact surface area 24. Pedestals 28 may be provided at various locations of base 20 for further supporting product 50 operably positioned in cavity 18. Upper surfaces 29 of respective pedestals 28 may be elevated similarly to contact surface 27 of ridge 26. In other embodiments, however, upper surface 29 of pedestals 28 may be elevated to a greater or lesser extent than contact surface 27 of ridge 26. In the illustrated embodiment, one or more upper surfaces 29 of pedestals 28 may be elevated by a dimension HP that is slightly less than dimension “HR” of ridge 26. For example, one or more upper surfaces 29 of pedestals 28 may be between 0.1 and 1 mm less elevated than contact surfaces 27 of ridge 26. Such a relationship ensures primary contact between product 50 and contact surface area 24 take place at ridge 26, so that operable contact between product 50 and upper surfaces 29 of pedestals 28 occurs only in the event that the contact surface area provided by ridge 26, alone, is insufficient to fully support product 50 above major surface 21 of base 20. In other embodiments, however, such a differential elevation between ridge 26 and pedestals 28 may be provided generally to facilitate removal of product 50 from cavity 18. In still further embodiments, upper surfaces 29 of pedestals 28 are equally elevated with respect to contact surface 27 of ridge 26.
The surface profile arrangement of base 20 may take on a variety of configurations, sizes, and elevations, as desired per application. Moreover, the surface profile of base 20 may take on a variety of forms other than ridge 26 and pedestals 28, with the overarching goal of the surface profile of base 20 being to provide a minimum contact surface area 24 that is nonetheless sufficient and appropriate for facilitating storage of product 50 at cavity 18, as well as for facilitating removal of product 50 from cavity 18. Thus, contact surface area 24 is preferably of appropriate magnitude to adequately support product 50 in storage and transit without damage to product 50, and to also facilitate removal of a potentially tacky product 50 from cavity 18 without damage thereto.
In one embodiment, contact surface area 24 is less than about 50% of base surface area 22. In another embodiment, contact surface area 24 is between about 20% and about 50% of base surface area 22. In a still further embodiment, contact surface area 24 is less than about 20% of base surface area 22. In a yet further embodiment, contact surface area 24 is less than about 10% of base surface area 22. In a still further embodiment, contact surface area 24 is between about 2% and about 10% of base surface area 22.
With reference back to
As described herein above, package 10 may be adapted for storing and delivering a plurality of products 50, which may be “tacky”. In some embodiments, the tackiness of products 50 may be the result of a relatively low modulus value, such as a bulk modulus of less than about 70 Shore 00. Such low modulus values result in a relatively soft material, which can therefore adhere to surfaces against which product 50 may come into contact. Example relatively low modulus products which may be used in connection with package 10 of the present invention include thermal interface materials, such as conformable thermal interface pads. A particular product 50 contemplated by the present invention is a thermal interface pad sold under the tradename “Gap Pad” by the Bergquist Company of Chanhassen, Minn. Such a product has a bulk modulus value of about 20-50 Shore 00.
Other products 50 may also be used in connection with package 10, and may have modulus values of between 5-70 Shore 00, and in some cases even less.
In some embodiments, product 50 may include a top contact layer 56 having a modulus of greater than about 50 Shore 00. Top contact layer 56 may be integrally formed with the remainder of product 50, or may instead by separately applied thereto. Contact layer 56 may be a highly cross-linked version of the material of the remainder of product 50, with an example product 50 with a top contact layer 56 being described in U.S. Pat. No. 6,657,297, assigned to the applicant, the content of which being incorporated herein by reference. The relatively high modulus of top contact layer 56 of product 50 facilitates compatibility with pick and place equipment, wherein product 50 may be easily engaged to, and disengaged from, vacuum heads of such pick and place equipment. In some embodiments, the lack of a top contact layer 56 may result in inadequate disengagement of product 50 from the pick and place equipment and/or damage to product 50 during installation process. The relatively high modulus of top contact layer 56 reduces the “tackiness” of product 50 for the portion of product 50 interfacing with the pick and place equipment.
While product 50 is illustrated in
In some embodiments of the present invention, package 10 may include a cover tape 42 that is removably securable to upper surface 16 of carrier tape 14. Cover tape 42 may be utilized to enclose product 50 in respective cavities 18 of carrier tape 14. In the embodiment illustrated in
As illustrated in
Contact portion 49 of first side 44 may include a surface texture which defines a second contact surface area 62 that is less than about 50% of the area of contact portion 49. An enlarged view of
The surface texture of contact portion 49 may be achieved by construction of a cover tape consisting of a strip of textured polyolefin film laminated to the center of an adhesive tape. A textured polyolefin film may be created by a cold embossing operation whereby a smooth polyolefin film is passed between a die with an embossed pattern and a flat or mating anvil, in a rotary embossing machine. It may also be achieved through a textured-mold hot casting process as the film is being fabricated. Typical textured embossing patterns include diamond pattern embossments, variously sized (i.e., with various diamond surface densities), with an embossed depth 65 of, for example, 8.5-11.5 mil (0.0085-0.0115 inch). Another common textured pattern is a taffeta pattern, which is a square embossed pattern, with a range of square sizes (i.e., square surface density) and embossing thicknesses available. A common taffeta pattern is 55 squares per square inch with an embossing thickness 65 of 8.5 mils (0.0085 inch). Typically there is a lower surface area side of a textured liner and a higher surface area side of the textured liner, which factors into the construction of a cover tape as described below.
While contact between cover tape 42 and product 50 is not desired, it is understood that such contact may result in the packaging and delivery process of product 50 in package 10. As a result, the surface texture of contact portion 49 described above may be provided to reduce the likelihood that product 50 undesirably adheres to cover tape 42. The surface texture of contact portion 49 reduces the total surface area which may come into contact with product 50, thereby reducing the likelihood of adherence of product 50 to cover tape 42. Second contact surface area 62 may be defined in a similar fashion as first contact surface area 24, in that second contact surface area 62 is the total surface area of first side 44 of cover tape 42 which operably comes into contact with product 50. In one embodiment, second contact surface area 62 may be defined by the sum of individual surface areas of facing surfaces 68 of each respective protrusion 64 making up the surface texture of contact portion 49.
In some embodiments, cover tape 42 may include one or more apertures 72, which may be operably aligned with cavities 18 of carrier tape 14 when cover tape 42 is removably secured to carrier tape 14. Apertures 72 may be so provided to facilitate removal of a product 50 from cover tape 42 in the unlikely event that a product 50 adheres to cover tape 42 when cover tape 42 is removed from carrier tape 14. Apertures 72 enable the direct application of a separation force to upper surface 54 of product 50 through aperture 72. Such separation force may be accomplished, for example, by a pin mechanism, air stream, or the like. Accordingly, apertures 72 have a relative spacing 74 that is consistent with the relative spacing of cavities 18 along length “L” of carrier tape 14.
The following example sets forth a particular embodiment of the invention. The dimensions, materials, and arrangements described in the following example, however, are exemplary only, and illustrate only one set of a variety of dimensions, materials, and arrangements contemplated by the present invention.
A carrier tape having a width dimension “WT” of about 24 mm was prepared from a polystyrene through a known molding process, such as a thermoforming molding process. A set of sprocket holes were punched through the carrier tape along its length and proximate to a first edge thereof. Sprocket hole spacing was set at 4 mm on center, according to an EIA standard for tape and reel package systems. A series of cavities having a spacing of 16 mm on center was provided, with each cavity having a base width dimension “WB” of 11.7 mm, and a base length dimension “LB” of 14.9 mm, wherein each base of each cavity assumed a substantially rectangular shape.
Base 20 was recessed from upper surface 16 by a cavity depth “D” of 3.6 mm, and the thickness of carrier tape 14 was about 0.3 mm. Each base was provided with a surface profile having a ridge 26 with a contact surface 27 being elevated by a height dimension “HR” of 2.3 mm, and a width dimension “WR” of 0.4 mm at contact surface 27. The surface profile further included four pedestals 28, as illustrated in
In addition to the above, aperture 34 has a diameter of 1.5 mm and is located at the center of base 22. The dimension “R1” measures to the “outer surface” of ridge 26 with respect to the origin of aperture 34.
The base surface area of each cavity is therefore about 174 mm2. The contact surface area is the sum of the ridge contact surface area and the pedestal upper surface areas. In this case, the contact surface area is about 10.5 mm2. Thus, the contact surface area is about 6% of the base surface area.
A gap pad “GP5000” from The Bergquist Company of Chanhassen, Minn. was die cut to a dimension of about 12 mm×10 mm (+/−0.5 mm), and was placed in the cavity of the carrier tape.
A cover tape was fabricated by laminating a strip of textured polyolefin film to the adhesive side of an adhesive tape, with the textured surface oriented to contact components in pockets. The strip of laminated film is narrower than the adhesive tape, and is laminated to the center of the adhesive tape, in order to leave a strip of exposed adhesive on either side of the constructed cover tape. The exposed strips of adhesive on either side of the cover tape ensure adherence of the two-piece cover tape to the carrier tape. The textured strip of film is wider than carrier tape pockets, ensuring that components inside the pocket can only come in contact with the textured film. One cover tape construction, for 24 mm wide carrier tape, consists of a clear precision adhesive tape 20 mm wide with a textured film strip (diamond or taffeta pattern as above) measuring 17 mm wide laminated to the center of the clear tape. This results in a cover tape with 85% textured liner coverage, and 15% exposed adhesive tape, per unit length. The exposed edges of adhesive, equal to 1.5 mm width on each side of cover tape, provides adherence of the cover tape to the top surface of the carrier tape. Typically, the adhesive tape used has a precise adhesion (peel) force specification (in addition to precision thickness and width ranges). This allows precise adjustment of exposed adhesive width by adjusting textured liner width, which allows precise adjustment of peel force of cover tape from carrier tape “seen” by the end user. This allows cover tape peel force to be adjusted to a designated target range within the whole peel force range as specified in the EIA-481 industry specification (10-130 grams for 24 mm carrier tape).
A cover tape was removably secured to the upper surface of the carrier tape for storage and delivery of the thermal interface pad product.
The invention has been described herein in considerable detail in order to comply with the patent statutes, and to provide those skilled in the art with the information needed to apply the novel principles and to construct and use embodiments of the invention as required. However, it is to be understood that various modifications to the described embodiments may be accomplished without departing from the scope of the invention itself.
Number | Name | Date | Kind |
---|---|---|---|
3858721 | Boyer | Jan 1975 | A |
4188438 | Burns | Feb 1980 | A |
4406367 | Bouwknegt | Sep 1983 | A |
4494902 | Kuppens | Jan 1985 | A |
4575995 | Tabuchi | Mar 1986 | A |
4702370 | Honda | Oct 1987 | A |
4716124 | Yerman | Dec 1987 | A |
4753061 | Braden | Jun 1988 | A |
4966282 | Kawanishi | Oct 1990 | A |
5076427 | Thomson et al. | Dec 1991 | A |
5101975 | Runyon | Apr 1992 | A |
5132160 | Bird | Jul 1992 | A |
5136827 | Sawaya | Aug 1992 | A |
5191693 | Umetsu | Mar 1993 | A |
5203143 | Gutentag | Apr 1993 | A |
5226226 | Fierkens | Jul 1993 | A |
5234104 | Schulte et al. | Aug 1993 | A |
5234105 | Sato | Aug 1993 | A |
5259911 | Ohnishi | Nov 1993 | A |
5325654 | Juntunen | Jul 1994 | A |
5361901 | Schenz et al. | Nov 1994 | A |
5472085 | Gelzer | Dec 1995 | A |
5499717 | Hayashi | Mar 1996 | A |
5524765 | Gutentag | Jun 1996 | A |
5526935 | Tidemann et al. | Jun 1996 | A |
5648136 | Bird | Jul 1997 | A |
5673795 | Clatanoff et al. | Oct 1997 | A |
5800772 | Kurasawa | Sep 1998 | A |
5810170 | Alvite | Sep 1998 | A |
5875897 | Duncan | Mar 1999 | A |
5908114 | Althouse et al. | Jun 1999 | A |
5931337 | Ando | Aug 1999 | A |
5960961 | Gutentag | Oct 1999 | A |
5964353 | Hamlin | Oct 1999 | A |
6003676 | Beyer | Dec 1999 | A |
6030692 | Auger | Feb 2000 | A |
6033933 | Hur | Mar 2000 | A |
6076681 | Chenoweth | Jun 2000 | A |
6105783 | Sato | Aug 2000 | A |
6149010 | Tanaka et al. | Nov 2000 | A |
6173750 | Davis et al. | Jan 2001 | B1 |
6176373 | Kato | Jan 2001 | B1 |
6182828 | Hiruta | Feb 2001 | B1 |
6206198 | Troxtell | Mar 2001 | B1 |
6216419 | Sakurai | Apr 2001 | B1 |
6250051 | Mori | Jun 2001 | B1 |
6297075 | Odajima | Oct 2001 | B1 |
6332268 | Imanishi | Dec 2001 | B1 |
6425484 | Sakurai | Jul 2002 | B1 |
6451623 | Kawada | Sep 2002 | B1 |
6469372 | Hayden | Oct 2002 | B2 |
6568535 | Pylant | May 2003 | B1 |
6657297 | Jewram et al. | Dec 2003 | B1 |
6694707 | Lehner | Feb 2004 | B2 |
6708816 | Schindler | Mar 2004 | B2 |
6740966 | Nakamura | May 2004 | B2 |
6820401 | Behnke | Nov 2004 | B2 |
6860391 | Kawada | Mar 2005 | B2 |
7005749 | Hsu | Feb 2006 | B2 |
7071026 | Fujimoto | Jul 2006 | B2 |
7096648 | Kawada | Aug 2006 | B2 |
7096914 | Kim | Aug 2006 | B2 |
7097040 | Gutentag | Aug 2006 | B1 |
7154166 | Ano | Dec 2006 | B2 |
7169643 | Hashimoto | Jan 2007 | B1 |
7288438 | Lu | Oct 2007 | B2 |
7318307 | Hoegerl | Jan 2008 | B2 |
7389877 | Dick | Jun 2008 | B2 |
7399657 | Bolken et al. | Jul 2008 | B2 |
20010039076 | Hashimoto | Nov 2001 | A1 |
20030129343 | Galkiewicz et al. | Jul 2003 | A1 |
20040188814 | Houle | Sep 2004 | A1 |
20050073037 | Wright | Apr 2005 | A1 |
20050151555 | Lewis | Jul 2005 | A1 |
20050176171 | Miyaki | Aug 2005 | A1 |
20060138019 | Yoshii et al. | Jun 2006 | A1 |
20060157381 | Adams | Jul 2006 | A1 |
20060157382 | Yasufuku et al. | Jul 2006 | A1 |
20060228542 | Cuzbarow | Oct 2006 | A1 |
20070023931 | Chew et al. | Feb 2007 | A1 |
20070210082 | English et al. | Sep 2007 | A1 |
20070216000 | Sasamura | Sep 2007 | A1 |
20070284144 | Too | Dec 2007 | A1 |
20070284737 | Too | Dec 2007 | A1 |
20080006922 | Gutentag | Jan 2008 | A1 |
20080096318 | Hariu | Apr 2008 | A1 |
20080124840 | Su | May 2008 | A1 |
Number | Date | Country |
---|---|---|
1073325 | Jan 2001 | EP |
3025947 | Feb 1991 | JP |
4016468 | Jan 1992 | JP |
4031260 | Feb 1992 | JP |
4069963 | Mar 1992 | JP |
6163617 | Jun 1994 | JP |
7122682 | May 1995 | JP |
9036135 | Feb 1997 | JP |
10116842 | May 1998 | JP |
10144735 | May 1998 | JP |
10258872 | Sep 1998 | JP |
11147507 | Jun 1999 | JP |
2001246666 | Sep 2001 | JP |
2003197715 | Jul 2003 | JP |
2003218165 | Jul 2003 | JP |
2003338526 | Nov 2003 | JP |
2004327550 | Nov 2004 | JP |
2005072626 | Mar 2005 | JP |
2005093958 | Apr 2005 | JP |
2006306403 | Nov 2006 | JP |
2007254079 | Oct 2007 | JP |
0207962 | Jan 2002 | WO |
0219354 | Mar 2002 | WO |
04001663 | Dec 2003 | WO |
Number | Date | Country | |
---|---|---|---|
20100294780 A1 | Nov 2010 | US |