Patent Application
20220220619
The present disclosure relates to a method for pickling a steel plate and a pickling apparatus.
In pickling of a steel plate, it is known that the pickling speed can be increased by adjusting the concentration of ferric ion (Fe3+) contained in the acid solution, and methods for adjusting the Fe3+ in the acid solution have been proposed.
For instance, Patent Document 1 discloses performing aeration of the acid solution to oxidize ferrous ion (Fe2+) which is generated in the acid solution during pickling and increase the concentration of Fe3+ contained in the acid solution, in order to maintain the concentration of Fe3+ in the acid solution within a predetermined range.
Patent Document 1: JP4186131B
Meanwhile, in a case where a gaseous oxidant (air or oxygen, for instance) is used to adjust the concentration of iron ion in the acid solution, the oxidation reaction of iron ion (Fe2+ to Fe3+) is relatively slow, as the rate of dissolution of the gaseous oxidant to the acid solution is limited. Thus, when the steel plate to be pickled is switched to a pickling-resistant member (steel plate that requires a longer time to be pickled), it is necessary to reduce the line speed compared to the previous speed. Furthermore, even when the concentration of Fe3+ in the acid solution is to be increased by adjusting the supply amount of the gaseous oxidant or the like, it takes a long time to increase the concentration of Fe3+, and thus it is not possible to increase the line speed much during a period after the line speed is reduced as described above and until the concentration of Fe3+ in the acid solution increases. Thus, the production efficiency of the steel plate may deteriorate.
In view of the above, an object of at least one embodiment of the present invention is to provide a method for pickling a steel plate capable of improving the production efficiency of the steel plate.
According to at least one embodiment of the present invention, a method for pickling a steel plate having a first steel plate portion and a second steel plate portion which is connected to a tail end of the first steel plate portion and which requires a longer time for pickling than the first steel plate portion when pickled under the same condition, includes: a step of pickling the steel plate by immersing the steel plate in an acid solution in at least one pickling tank while conveying the steel plate; a step of circulating the acid solution, through a circulation line connected to any of the at least one pickling tank, between the pickling tank and an oxidizing device disposed in the circulation line; a step of oxidizing Fe2+ in the acid solution to Fe3+ by the oxidizing device using a gaseous oxidant; and a feeding start step of, upon switching from pickling of the first steel plate portion to pickling of the second steel plate portion, starting feeding of a liquid oxidant for oxidizing Fe2+ in the acid solution to Fe3+ to any of the at least one pickling tank or to the circulation line.
According to at least one embodiment of the present invention, provided is a method of pickling a steel plate capable of improving the production efficiency of the steel plate.
Embodiments of the present invention will now be described in detail with reference to the accompanying drawings. It is intended, however, that unless particularly identified, dimensions, materials, shapes, relative positions and the like of components described in the embodiments shall be interpreted as illustrative only and not intended to limit the scope of the present invention.
(Configuration of Pickling Apparatus)
As depicted in
The pickling apparatus 1 depicted in
The plurality of pickling tanks 12 (12A to 12C) have respective conveyance rolls 16 (conveyance parts 10), and the conveyance rolls 16 convey the steel plate 2 while the steel plate 2 is immersed in the acid solution 3 in the plurality of pickling tanks 12.
In the pickling apparatus 1 depicted in
The pickling apparatus 1 includes a circulation line 21, connected to the pickling tank 12, for circulating the acid solution 3 in the pickling tank 12, and an oxidizing device 20 disposed in the circulation line 21. The circulation line 21 includes an extract line 22 for extracting the acid solution 3 from the pickling tank 12 and introducing the acid solution 3 to the oxidizing device 20, and a return line 24 for returning the acid solution 3 from the oxidizing device 20 to the pickling tank 12.
The oxidizing device 20 is configured to oxidize Fe2+ in the acid solution 3 to Fe3+ by using a gaseous oxidant. Although not illustrated, the oxidizing device 20 may include an airtight tank, and a gas supply part for supplying the gaseous oxidant to the airtight tank. The oxidizing device 20 may be configured such that the concentration of Fe3+ in the acid solution inside the oxidizing device 20 is adjustable by adjusting the partial pressure of the gaseous oxidant inside the oxidizing device 20.
In pickling of a steel plate, it is known that the pickling speed can be increased by adjusting the concentration of ferric ion (Fe3+) contained in the acid solution. That is, it is known that the concentration ratio of iron ion (Fe2+, Fe3+) in the acid solution and the pickling time has a predetermined relationship, and the pickling speed increases (that is, the pickling times becomes shorter) when the concentration of Fe3+ in the acid solution is increased to some extent. Accordingly, by adjusting the concentration of Fe3+ in the acid solution appropriately with the oxidizing device 20, it is possible to pickle a steel plate efficiently.
The gaseous oxidant used in the oxidizing device 20 may contain air, oxygen, or ozone, for instance.
In a pickling apparatus including the plurality of pickling tanks 12 (12A to 12C), a circulation line 21 connected to one of the plurality of pickling tanks 12 may be provided, and the oxidizing device 20 may be disposed in the circulation line 21. In the illustrative embodiment depicted in
Alternatively, in the pickling apparatus including the plurality of pickling tanks 12 (12A to 12C), circulation lines 21 respectively connected to two or more of the plurality of pickling tanks 12 may be provided, and the oxidizing device 20 may be disposed in each of the circulation lines 21. In the illustrative embodiment depicted in
Furthermore, in the illustrative embodiment depicted in
The pickling tank 12 at the downstream side may perform, in addition to dissolution of scale on the surface of the steel plate 2, dissolution of the base material surface of the steel plate 2. In a case where the base material of the steel plate 2 is dissolved by the acid solution as described above, Fe3+ in the acid solution is consumed. Thus, by supplying the acid solution 3 whose Fe3+ concentration is increased by the oxidizing device 20 to the downstream pickling tank of the plurality of pickling tanks 12 (e.g., the pickling tank 12C at the downstream side), it is possible to pickle the steel plate 2 effectively.
The pickling apparatus 1 further includes, in one of the at least one pickling tank 12 or in the circulation line 21, a liquid oxidant feeding part 30 capable of feeding a liquid oxidant for oxidizing the Fe2+ in the acid solution 3 to Fe3+. The liquid oxidant feeding part 30 includes a liquid oxidant tank 32 for storing a liquid oxidant, a liquid oxidant feeding line 34 for feeding the liquid oxidant from the liquid oxidant tank 32, and a liquid oxidant pump 33 disposed in the liquid oxidant feeding line 34 for pressurizing the liquid oxidant.
The liquid oxidant is not particularly limited, and any liquid having the capacity to oxidize iron ion (Fe2+) may be used as the liquid oxidant. The liquid oxidant may include, for instance, at least one of hydrogen peroxide solution, hypochlorous acid, ammonium peroxydisulfate (ammonium persulfate), or potassium permanganate solution.
The liquid oxidant feeding line 34 is connected to the pickling tank 12 or the circulation line 21 (including the oxidizing device 20 disposed in the circulation line 21), and is configured to feed the liquid oxidant from the liquid oxidant tank 32 to the pickling tank 12 or the circulation line 21 (including the oxidizing device 20 disposed in the circulation line 21).
In the illustrative embodiment depicted in
In the illustrative embodiment depicted in
In the illustrative embodiment depicted in
The pickling apparatus 1 may include a controller 100 for adjusting the concentration of Fe3+ in the acid solution inside the pickling tanks 12 (12A to 12C) or the conveyance speed (line speed) of the steel plate 2. The specific configuration of the controller 100 will be described later.
The controller 100 may include a processor, a memory (RAM), an auxiliary storage part, and an interface, for instance. The controller 100 is configured to receive signals from the above various measurement instruments via the interface. The processor is configured to process the accordingly received signals. Furthermore, the processor is configured to process programs expanded in the memory.
The content of process by the controller 100 may be implemented as programs to be executed by the processor, and stored in the auxiliary storage part. When the programs are executed, the programs are expanded in the memory. The processor is configured to read out the programs from the memory, and execute the orders contained in the programs.
(Steel Plate to be Pickled)
In the pickling apparatus 1 according to some embodiments, a pickling process is performed on a steel plate 2 including the first steel plate portion 2a and the second steel plate portion 2b (see
The steel plate 2 may include the third steel plate portion 2c in addition to the first steel plate portion 2a and the second steel plate portion 2b (see
Furthermore, a steel which has a relatively high content of Si requires a relatively longer time of pickling. The second steel plate portion 2b may be a steel (e.g., a high-strength steel material) having a relatively high content of Si.
(Pickling Method)
Next, a method of pickling the steel plate 2 according to some embodiments will be described.
First, with reference to
In some embodiments, the steel plate 2 is pickled while the steel plate 2 is conveyed by the conveyance part 10 and the steel plate 2 is immersed in the acid solution 3 inside the pickling tank 12. In the example illustrated in
While the first steel plate portion 2a is pickled in the pickling tank 12 (until time t0), the acid solution 3 is circulated between the pickling tank 12 and the oxidizing device 20 disposed in the circulation line 21, via the circulation line 21 connected to the pickling tank 12. Furthermore, the oxidizing device 20 oxidizes Fe2+ in the acid solution 3 to Fe3+ by using a gaseous oxidant. Accordingly, the concentration of Fe3+ in the acid solution 3 in the pickling tank 12 is maintained at the concentration suitable for pickling of the first steel plate portion 2a.
Upon switching from pickling of the first steel plate portion 2a to pickling of the second steel plate portion 2b , at time t0, the liquid oxidant feeding part 30 starts feeding the liquid oxidant to at least one of the pickling tank 12 or to the circulation line 21. The valve (valve 37, 39, or 41) disposed in the liquid oxidant feeding line 34 is opened, and the liquid oxidant stored in the liquid oxidant tank 32 is fed to the pickling tank 12 or to the circulation line 21 via the liquid oxidant feeding line 34. Accordingly, the concentration 201 (see
As depicted in
In a case where a gaseous oxidant (air or oxygen, for instance) is used instead of a liquid oxidant to adjust the concentration of iron ion in the acid solution, the oxidation reaction of iron ion (Fe2+ to Fe3+) is relatively slow, as the rate of dissolution of the gaseous oxidant to the air solution is limited. Thus, when the steel plate to be pickled is switched from the first steel plate portion 2a to the second steel plate portion 2b which requires a longer time to be pickled at time t0 shown in
In contrast, in a case where the liquid oxidant is used, the oxidant is dissolved in a solution, and thus the oxidation reaction of iron ion in the acid solution 3 proceeds more quickly compared to a case in which a gaseous oxidant is used. Thus, it is easier to increase the concentration of Fe3+ in the acid solution 3 quickly. In this regard, according to the above embodiment, upon switching from pickling of the first steel plate portion 2a to pickling of the second steel plate portion 2b (time t0 in
Next, with reference to
In the embodiment depicted in
Furthermore, similarly to the case illustrated in
Furthermore, similarly to the case illustrated in
In some embodiments, feeding of the liquid oxidant is started within a period in which the first connection portion 4 connecting the first steel plate portion 2a and the second steel plate portion 2b exists inside the pickling tank 12, for instance, as shown in
In the example shown in
In the illustrative embodiment depicted in
By feeding the liquid oxidant to the acid solution 3 at time t10 in
In the embodiment illustrated in
That is, upon switching from pickling of the first steel plate portion 2a to pickling of the second steel plate portion 2b , feeding of the liquid oxidant is started at time t10 and the conveyance speed of the steel plate is reduced, and then the conveyance speed of the steel plate is increased at time t11. Accordingly, it is possible to increase the conveyance speed of the steel plate 2 in accordance with an increase in Fe3+ during pickling, and thereby it is possible to maintain the conveyance speed of the steel plate 2 at a high speed during pickling of the second steel plate portion 2b (pickling-resistant member). Thus, it is possible to improve the production efficiency of the steel plate.
In the embodiment illustrated in
Furthermore, in the illustrative embodiment depicted in
As described above, upon switching from pickling of the first steel plate portion 2a to pickling of the second steel plate portion, Fe3+ derived from oxidation reaction using the gaseous oxidant by the oxidizing device 20 is increased (from time t10 to time t11), and the concentration of Fe3+ in the acid solution 3 in the pickling tank 12 is increased to raise the concentration of Fe3+ in the acid solution 3 in the pickling tank 12 sufficiently, and thereby it is possible to stop feeding of the liquid oxidant, which is relatively expensive (time t11). Accordingly, it is possible maintain the conveyance speed of the steel plate 2 and improve the production efficiency of the steel plate 2, while suppressing an increase in the cost for pickling the steel plate 2.
In some embodiments, supply of the liquid oxidant to the pickling tank 12 or to the circulation line 21 by the liquid oxidant feeding part 30 may be stopped when the concentration of Fe3+ in the acid solution 3 in the pickling tank 12 reaches the target value Ct. Alternatively, supply of the above described liquid oxidant may be stopped before the tail end of the second steel plate portion 2b is discharged from the pickling tank 12. As described above. supply of the liquid oxidant is stopped during pickling of the steel plate 2, and thus the liquid oxidant is supplied to the pickling tank 12 or the circulation line 21 for a relatively short period of time. Accordingly, it is possible maintain the conveyance speed of the steel plate 2 and improve the production efficiency of the steel plate 2, while suppressing an increase in the cost for pickling the steel plate 2 by suppressing the usage amount of the liquid oxidant, which is relatively expensive.
In the embodiment illustrated in
In some embodiments, as depicted in
As described above, upon switching from pickling of the second steel plate portion 2b to pickling of the third steel plate portion 2c , Fe3+ derived from the oxidizing device 20 is reduced to reduce the concentration of Fe3+ in the acid solution 3 in the pickling tank 12, and thereby it is possible to suppress excessive pickling of the third steel plate portion 2c which requires a shorter period of time to be pickled under the same condition. Thus, it is possible to reduce pickling loss of the steel plate 2 and improve the yield ratio, thereby improving the production efficiency of the steel plate 2.
In some embodiments, as depicted in
The third steel plate portion 2c requires a shorter period of time to be pickled than the second steel plate portion 2b under the same condition, and thus it is possible to pickle the third steel plate portion 2c sufficiently even when the conveyance speed of the steel plate 2 is increased upon switching to pickling of the third steel plate portion 2c . According to the embodiment described above, upon switching from pickling of the second steel plate portion 2b to the third steel plate portion 2c , the conveyance speed of the steel plate 2 is increased, and thereby it is possible to maintain the conveyance speed of the steel plate 2 at a high speed while pickling the third steel plate portion 2c sufficiently. Thus, it is possible to improve the production efficiency of the steel plate 2.
In the embodiment depicted in
At the timing (time t40, t41, t42) when the first connection portion 4 reaches the respective pickling tanks 12 (12A to 12C), feeding of the liquid oxidant to the respective pickling tanks 12 (12A to 12C) or to the circulation lines 21 (21A to 21C) connected to the pickling tanks 12 is started in series. This is illustrated in the graph of the supply flow rate of the liquid oxidant in
As shown in
In the illustrative embodiment depicted in
In some embodiments, the controller 100 is configured to control the line speed and the timing to change the line speed.
The pickling speed evaluation part 102 is configured to receive signals that indicate operation information, position of the welding portion (the first connection portion 4 or the second connection portion 5) in the conveyance direction, concentration of Fe ion (concentration of Fe2+ or concentration of Fe3+) in the acid solution 3 in the pickling tank 12, and sensing information of components of the acid solution 3 in the pickling tank 12 or the like. The operation information includes the kind of steel of the steel plate 2 to be pickled and the operation conditions of the pickling apparatus 1 (temperature, pressure, and the like). The pickling speed evaluation part 102 evaluates the pickling speed of the steel plate 2 on the basis of the received signals.
The target line speed calculation part 104 calculates the target line speed by the conveyance part 10, on the basis of the evaluation result of the pickling speed by the pickling speed evaluation part 102. The line speed control part 106 controls the conveyance part 10 to achieve the calculated target line speed. For instance, the line speed control part 106 calculates an electric current command value for a motor 17 (motor which drives the conveyance roll 16) for obtaining the calculated target line speed, and sends the electric current command value to the motor.
In some embodiments, the controller 100 may obtain information on the position of the first connection portion 4 in the conveyance direction, and determine the timing to reduce the line speed on the basis of the information.
In this case, the timing to reduce the conveyance speed of the steel plate 2 is determined on the basis of the information on the position of the first connection portion 4 in the conveyance direction, and thus, for instance, it is possible to reduce the conveyance speed of the steel plate 2 at an appropriate timing in accordance with the timing to start pickling of the second steel plate portion 2b (that is, the timing when the second steel plate portion 2b reaches the pickling tank 12). Accordingly, it is possible to pickle the second steel plate portion 2b appropriately, and suppress deterioration of the product quality.
In some embodiments, the timing to start supply of the liquid oxidant may be determined on the basis of the information of the position of the first connection portion 4 in the conveyance direction. The supply start timing of the liquid oxidant may be determined in relation to the timing to reduce the conveyance speed of the steel plate 2.
In the above described embodiment, the timing to start supplying the liquid oxidant is determined on the basis of the information on the position of the first connection portion 4 in the conveyance direction, and thus, for instance, it is possible to start feeding of the liquid oxidant at an appropriate timing in accordance with the timing to start pickling of the second steel plate portion 2b (that is, the timing when the second steel plate portion 2b reaches the pickling tank 12). Thus, upon switching to pickling of the second steel plate portion 12b , it is possible to increase Fe3+ in the acid solution 3 in the pickling tank 12 at an appropriately timing, and thus it is easier to maintain the conveyance speed of the steel plate 2 at a high speed. Thus, it is possible to improve the production efficiency of the steel plate 2.
In some embodiments, the controller 100 may be configured to adjust the concentration of Fe ion in the acid solution 3 in the pickling tank 12.
The concentration of Fe ion in the acid solution 3 in the pickling tank 12 may be adjusted according to the procedure shown in the flowchart of
As shown in the flow chart of
Next, on the basis of the mass balance calculated in step S1, the feeding flow rate of fresh acid solution (hydrochloric acid or the like) to the pickling tank 12, the circulation flow rate of the acid solution 3 between the oxidizing device 20 and the pickling tank 12, and the supply amount flow rate and the supply time of the liquid oxidant by the liquid oxidant feeding part 30 are set (step S40).
Next, the concentration of Fe3+ and the concentration of Fe2+ in the acid solution 3 in the pickling tank 12 are measured (detected) (step S6), and it is determined whether the concentrations match the target values (step S8). In a case where the measurement value and the target value of the concentration of Fe ion do not match in step S8 (No in step S8), the set values of the feeding flow rate of fresh acid solution (hydrochloric acid or the like) to the pickling tank 12, the circulation flow rate of the acid solution 3 between the oxidizing device 20 and the pickling tank 12, and the supply amount flow rate and the supply time of the liquid oxidant are changed (step S10), and the procedure returns to step S6. On the other hand, in a case where the measurement value and the target value of the concentration of Fe ion match in step S8 (Yes in step S8), the set values of the feeding flow rate of fresh acid solution (hydrochloric acid or the like) to the pickling tank 12, the circulation flow rate of the acid solution 3 between the oxidizing device 20 and the pickling tank 12, and the supply amount flow rate and the supply time of the liquid oxidant are maintained, and the procedure is completed.
In some embodiments, as described with reference to
In this case, the supply amount of the liquid oxidant is determined on the basis of the difference between the measurement value and the target concentration of Fe3+ in the acid solution in the pickling tank 12, and thus, by supplying the liquid oxidant on the basis of the supply amount determined accordingly, it is possible to increase Fe3+ in the acid solution 3 in the pickling tank 12, and maintain the conveyance speed of the steel plate 2 at a high speed. Thus, it is possible to improve the production efficiency of the steel plate 2.
Furthermore, in some embodiments, during pickling of the second steel plate portion 2b and after stopping supply of the liquid oxidant to the pickling tank 12 or the circulation line 21, at least one of the supply amount of the gaseous oxidant or the circulation flow rate of the acid solution 3 between the oxidizing device 20 and the pickling tank 12 may be adjusted to maintain the concentration of Fe3+ in the acid solution in the pickling tank 12 within a predetermined range including the target concentration of Fe3+ in the acid solution 3 in the pickling tank 12 for pickling of the second steel plate portion 2b.
In this case, by adjusting the supply amount of gaseous oxidant by the oxidizing device 20 or the circulation flow rate of the acid solution 3 between the oxidizing device 20 and the pickling tank 12 during pickling of the second steel plate portion 2b and after stopping supply of the liquid oxidant, the concentration of Fe3+ in the acid solution in the pickling tank 12 is maintained in the above described predetermined range. Thus, it is possible to maintain the Fe3+ in the acid solution 3 in the pickling tank 12 appropriately after stopping supply of the liquid oxidant to maintain the conveyance speed of the steel plate 2 at a high speed, and improve the production efficiency of the steel plate 2. Furthermore, a gaseous oxidant, which is relatively inexpensive, is used to adjust the concentration of Fe3+ in the acid solution 3 in the pickling tank 12, and thus it is possible to suppress a cost increase.
Hereinafter, a method for pickling a steel plate and a pickling facility according to some embodiments will be described briefly.
(1) According to at least one embodiment of the present invention, a method for pickling a steel plate having a first steel plate portion and a second steel plate portion which is connected to a tail end of the first steel plate portion and which requires a longer time for pickling than the first steel plate portion when pickled under the same condition, includes: a step of pickling the steel plate by immersing the steel plate in an acid solution in at least one pickling tank while conveying the steel plate; a step of circulating the acid solution, through a circulation line connected to any of the at least one pickling tank, between the pickling tank and an oxidizing device disposed in the circulation line; a step of oxidizing Fe3+ in the acid solution to Fe3+ by the oxidizing device using a gaseous oxidant; and a feeding start step of, upon switching from pickling of the first steel plate portion to pickling of the second steel plate portion, starting feeding of a liquid oxidant for oxidizing Fe3+ in the acid solution to Fe3+ to any of the at least one pickling tank or to the circulation line.
In a case where the liquid oxidant is used, an oxidant is dissolved in a solution, and thus the oxidation reaction of iron ion during pickling proceeds more quickly compared to a case in which a gaseous oxidant is used. Thus, it is easier to increase the concentration of Fe3+ in the acid solution quickly. In this regard, according to the above method (1), upon switching from pickling of the first steel plate portion to pickling of the second steel plate portion, the liquid oxidant is supplied to the pickling tank or to the circulation line. Thus, when switching to pickling of the second steel plate portion (pickling-resistant member) which requires a longer time to be pickled under the same condition, it is possible to quickly increase Fe3+ in the acid solution in the pickling tank. Accordingly, it is possible to maintain the conveyance speed (line speed) of the steel plate at a high speed even when the kind of steel to be pickled is switched, and thus it is possible to improve the production efficiency of the steel plate.
(2) In some embodiments, in the above method (1), feeding of the liquid oxidant to the at least one pickling tank or the circulation line is started within a period of time during which a first connection portion being a connection portion connecting the first steel plate portion and the second steel plate portion exists in the at least one pickling tank.
According to the above method (2), feeding of the liquid oxidant is started within a period of time during which the first connection portion being a connection portion connecting the first steel plate portion and the second steel plate portion exists in the pickling tank, and thus it is possible to increase the concentration of Fe3+ in the acid solution quickly after starting pickling of the second steel plate portion. Thus, it is easier to maintain the conveyance speed of the steel plate at a high speed after starting pickling of the second steel plate portion being a pickling-resistant member, and thus it is possible to improve the production efficiency of the steel plate effectively.
(3) In some embodiments, in the above method (1) or (2), the pickling method further includes a speed reduction step of, upon switching from pickling of the first steel plate portion to pickling of the second steel plate portion, reducing a conveyance speed of the steel plate.
By feeding the liquid oxidant to the acid solution, it is possible to increase the concentration of Fe3+ in the acid solution relatively quickly, but it takes some time until the concentration of Fe3+ in the acid solution reaches the target value. With this regard, according to the above method (3), upon switching from pickling of the first steel plate portion to pickling of the second steel plate portion, the conveyance speed of the steel plate is reduced, and thus it is possible to appropriately pickle the second steel plate portion by reducing the conveyance speed of the steel plate after starting pickling of the second steel plate portion and before the concentration of Fe3+ in the acid solution in the pickling tank increases sufficiently. Accordingly, it is possible to suppress deterioration of the product quality.
(4) In some embodiments, in the above method (3), the pickling method further includes: a step of obtaining information on a position, in the conveyance direction, of a first connection portion being a connection portion connecting the first steel plate portion and the second steel plate portion; and a step of deciding a timing to reduce the conveyance speed of the steel plate on the basis of the information.
According to the above method (4), the timing to reduce the conveyance speed of the steel plate is determined on the basis of the information on the position of the first connection portion in the conveyance direction, and thus, for instance, it is possible to reduce the conveyance speed of the steel plate at an appropriate timing in accordance with the timing to start pickling of the second steel plate portion (that is, the timing when the second steel plate portion reaches the pickling tank). Accordingly, it is possible to pickle the second steel plate portion appropriately, and suppress deterioration of the product quality.
(5) In some embodiments, in the above method (3) or (4), the pickling method further includes: a step of, after the feeding start step and the speed reduction step, increasing the conveyance speed of the steel plate.
According to the above method (5), upon switching from pickling of the first steel plate portion to pickling of the second steel plate portion, feeding of the liquid oxidant to the acid solution is started and the conveyance speed of the steel plate is reduced, and then the conveyance speed of the steel plate is increased. Accordingly, it is possible to increase the conveyance speed of the steel plate in accordance with an increase in Fe3+ during pickling, and thereby it is possible to maintain the conveyance speed of the steel plate at a high speed during pickling of the second steel plate portion (pickling-resistant member). Thus, it is possible to improve the production efficiency of the steel plate.
(6) In some embodiments, in any one of the above methods (1) to (5), the pickling method further includes a step of, upon switching from pickling of the first steel plate portion to pickling of the second steel plate portion, increasing at least one of a supply amount of the gaseous oxidant to the acid solution by the oxidizing device or a circulation flow rate of the acid solution between the oxidizing device and the at least one pickling tank to increase a concentration of Fe3+ in the acid solution in the pickling tank.
According to the above method (6), upon switching from pickling of the first steel plate portion to pickling of the second steel plate portion, Fe3+ derived from oxidation reaction using the gaseous oxidant by the oxidizing device (Fe3+ derived from the oxidizing device) is increased to raise the concentration of Fe3+ in the acidic solution in the pickling tank. Thus, when the concentration of Fe3+ in the acid solution in the pickling tank is sufficiently high, it is possible to stop feeding of the liquid oxidant, which is relatively expensive. Accordingly, it is possible maintain the conveyance speed of the steel plate at a high speed and improve the production efficiency of the steel plate, while suppressing an increase in the cost for pickling the steel plate.
(7) In some embodiments, in any one of the above methods (1) to (6), the pickling method further includes: a step of, during pickling of the steel plate in the at least one pickling tank, stopping supply of the liquid oxidant to the at least one pickling tank or the circulation line.
According to the above method (7), supply of the liquid oxidant is stopped during pickling of the steel plate, and thus it is possible to supply the liquid oxidant to the pickling tank or the circulation line for a relatively short period of time. Accordingly, it is possible maintain the conveyance speed of the steel plate at a high speed and improve the production efficiency of the steel plate, while suppressing an increase in the cost for pickling the steel plate by suppressing the usage amount of the liquid oxidant, which is relatively expensive.
(8) In some embodiments, in the above method (7), the steel plate includes a third steel plate portion which is connected to a tail end of the second steel plate portion and which requires a shorter time to be pickled than the second steel plate portion when pickled under the same condition, and the pickling method further includes a step of, upon switching from pickling of the second steel plate portion to pickling of the third steel plate portion, reducing at least one of a supply amount of the gaseous oxidant to the acid solution by the oxidizing device or a circulation flow rate of the acid solution between the oxidizing device and the at least one pickling tank to reduce a concentration of Fe3+ in the acid solution in the pickling tank.
According to the above method (8), upon switching from pickling of the second steel plate portion to pickling of the third steel plate portion, Fe3+ derived from the oxidizing device is reduced to lower the concentration of Fe3+ in the acid solution in the pickling tank, and thereby it is possible to suppress excessive pickling of the third steel plate portion which requires a shorter period of time to be pickled under the same condition. Thus, it is possible to reduce pickling loss of the steel plate and improve the yield ratio, thereby improving the production efficiency of the steel plate.
(9) In some embodiments, the above method (8) further includes a step of, upon switching from pickling of the second steel plate portion to pickling of the third steel plate portion, increasing a conveyance speed of the steel plate.
The third steel plate portion requires a shorter period of time to be pickled than the second steel plate portion under the same condition, and thus it is possible to pickle the third steel plate portion sufficiently even when the conveyance speed of the steel plate is increased upon switching to the third steel plate portion. According to the above method (9), upon switching from pickling of the second steel plate portion to the third steel plate portion, the conveyance speed of the steel plate is increased, and thereby it is possible to maintain the conveyance speed of the steel plate at a high speed while pickling the third steel plate portion sufficiently. Thus, it is possible to improve the production efficiency of the steel plate.
(10) In some embodiments, in any one of the above methods (1) to (9), the at least one pickling tank includes a plurality of pickling tanks arranged along a conveyance direction of the steel plate. The pickling method includes a step of transferring the acid solution in the pickling tank positioned at a downstream side in the conveyance direction to the pickling tank positioned at an upstream side in the conveyance direction. The feeding start step includes feeding the liquid oxidant to at least one of the plurality of pickling tanks or to the circulation line connected to the at least one of the plurality of pickling tanks.
According to the above method (10), with the pickling apparatus including the plurality of pickling tanks, upon switching from pickling of the first steel plate portion to pickling of the second steel plate portion, the liquid oxidant is supplied to any of the pickling tanks or to the circulation line connected to any of the pickling tanks. Thus, when switching to pickling of the second steel plate portion (pickling-resistant member) which requires a longer time to be pickled under the same condition, it is possible to quickly increase the concentration of Fe3+ in the acid solution in the pickling tank. Accordingly, it is possible to maintain the conveyance speed of the steel plate at a high speed even when the kind of steel to be pickled is switched, and thus it is possible to improve the production efficiency of the steel plate.
(11) In some embodiments, in the above method (10), feeding of the liquid oxidant to the plurality of pickling tanks or the circulation line connected to the pickling tanks is started sequentially in an order of passing of a first connection portion being a connection portion connecting the first steel plate portion and the second plate portion.
According to the above method (11), feeding of the liquid oxidant to the plurality of pickling tanks or the circulation line connected to the pickling tanks is started sequentially in an order of passing of a first connection portion being a connection portion connecting the first steel plate portion and the second plate portion. Thus, it is possible to increase the concentration of Fe3+ in the acid solution in the plurality of pickling tanks quickly, and thus it is easier to maintain the conveyance speed of the steel plate at a high speed after switching to pickling of the second steel plate portion. Thus, it is possible to improve the production efficiency of the steel plate effectively.
(12) In some embodiments, in any one of the above methods (1) to (11), the method further includes: a step of obtaining information on a position of the first connection portion in the conveyance direction; and a step of deciding a timing to start supply of the liquid oxidant on the basis of the information.
According to the above method (12), the timing to start supplying the liquid oxidant is determined on the basis of the information on the position of the first connection portion in the conveyance direction, and thus, for instance, it is possible to start feeding of the liquid oxidant at an appropriate timing in accordance with the timing to start pickling of the second steel plate portion (that is, the timing when the second steel plate portion reaches the pickling tank). Thus, upon switching to pickling of the second steel plate portion, it is possible to increase the concentration of Fe3+ in the acid solution in the pickling tank at an appropriately timing, and thus it is easier to maintain the conveyance speed of the steel plate at a high speed. Thus, it is possible to improve the production efficiency of the steel plate.
(13) In some embodiments, in any one of the above methods (1) to (12), the method further includes: a step of detecting a concentration of Fe3+ in the acid solution in the pickling tank; and a step of deciding a supply amount of the liquid oxidant on the basis of a difference between the detected concentration of Fe3+ and a target concentration of Fe3+ in the acid solution in the pickling tank for pickling of the second steel plate portion.
According to the above method (13), the concentration of Fe3+ in the pickling tank is detected, and the supply amount of the liquid oxidant is determined on the basis of the difference between the detected concentration of Fe3+ and the target concentration of Fe3+ in the acid solution in the pickling tanks for pickling of the second steel plate portion. Therefore, by supplying the liquid oxidant on the basis of the supply amount determined accordingly, it is possible to increase Fe3+ in the acid solution in the pickling tank, and maintain the conveyance speed of the steel plate at a high speed. Thus, it is possible to improve the production efficiency of the steel plate.
(14) In some embodiments, in any one of the above methods (1) to (13), the method further includes a step of, during pickling of the second steel plate portion and after stopping supply of the liquid oxidant to the at least one pickling tank or to the circulation line, adjusting at least one of a supply amount of the gaseous oxidant or a circulation flow rate of the acid solution between the oxidizing device and the at least one pickling tank so as to maintain a concentration of Fe3+ in the acid solution in the pickling tank within a predetermined range including a target concentration of Fe3+ in the acid solution in the pickling tank for pickling of the second steel plate portion.
According to the above method (14), by adjusting at least one of the supply amount of gaseous oxidant in the oxidizing device or the circulation flow rate of the acid solution between the oxidizing device and the pickling tank during pickling of the second steel plate portion and after stopping supply of the liquid oxidant, the concentration of Fe3+ in the acid solution in the pickling tank is maintained in the above described predetermined range. Thus, it is possible to maintain the concentration of Fe3+ in the acid solution in the pickling tank appropriately after stopping supply of the liquid oxidant and maintain the conveyance speed of the steel plate at a high speed, and improve the production efficiency of the steel plate. Furthermore, a gaseous oxidant, which is relatively inexpensive, is used to adjust the concentration of Fe3+ in the acid solution in the pickling tank, and thus it is possible to suppress a cost increase.
(15) According to at least one embodiment of the present invention, a pickling apparatus for pickling a steel plate having a first steel plate portion and a second steel plate portion which is connected to a tail end of the first steel plate portion and which requires a longer time for pickling than the first steel plate portion when pickled under the same condition, includes: at least one pickling tank storing an acid solution; a conveyance part configured to convey the steel plate while immersing the steel plate in the acid solution in the at least one pickling tank; a circulation line for circulating the acid solution inside any of the at least one pickling tank, the circulation line being connected to the at least one pickling tank; an oxidizing device disposed in the circulation line and configured to oxidize Fe3+ in the acid solution to Fe3+ by using a gaseous oxidant; and a liquid oxidant feeding part capable of feeding a liquid oxidant for oxidizing Fe2+ in the acid solution to Fe3+ to any one of the at least one pickling tank or to the circulation line.
According to the above configuration (15), upon switching from pickling of the first steel plate portion to pickling of the second steel plate portion, the liquid oxidant is supplied to the pickling tank or the circulation line. Thus, when switching to pickling of the second steel plate portion (pickling-resistant member) which requires a longer time to be pickled under the same condition, it is possible to quickly increase the concentration of Fe3+ in the acid solution in the pickling tank. Accordingly, it is possible to maintain the conveyance speed (line speed) of the steel plate at a high speed even when the kind of steel to be pickled is switched, and thus it is possible to improve the production efficiency of the steel plate.
Embodiments of the present invention were described in detail above, but the present invention is not limited thereto, and various amendments and modifications may be implemented.
Further, in the present specification, an expression of relative or absolute arrangement such as “in a direction”, “along a direction”, “parallel”, “orthogonal”, “centered”, “concentric” and “coaxial” shall not be construed as indicating only the arrangement in a strict literal sense, but also includes a state where the arrangement is relatively displaced by a tolerance, or by an angle or a distance whereby it is possible to achieve the same function.
For instance, an expression of an equal state such as “same” “equal” and “uniform” shall not be construed as indicating only the state in which the feature is strictly equal, but also includes a state in which there is a tolerance or a difference that can still achieve the same function. Further, for instance, an expression of a shape such as a rectangular shape or a cylindrical shape shall not be construed as only the geometrically strict shape, but also includes a shape with unevenness or chamfered corners within the range in which the same effect can be achieved.
On the other hand, an expression such as “comprise”, “include”, “have”, “contain” and “constitute” are not intended to be exclusive of other components.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2020/000460 | 1/9/2020 | WO | 00 |
