Patent Application
20130102800
The present invention relates to a method for preparing chlorohydrins composition and a method for preparing epichlorohydrin using chlorohydrins composition prepared thereby. In particular, the present invention relates to a method for preparing chlorohydrins composition by reacting polyhydroxy aliphatic hydrocarbon with a chlorination agent in the presence of a catalyst, includes at least one combination of a series of unit operations including a first reaction step, a water removal step, and a second reaction step in the respective order, and additionally includes a step for contacting the chlorohydrins composition derived from a plurality of reaction mixtures discharged from the plurality of reaction steps with an alkaline agent, and removing the catalyst included in the chlorohydrins composition in the form of an alkali metal salt, and a method for preparing epichlorohydrin including a step for contacting the chlorohydrins composition, which was prepared using the method for preparing chlorohydrins composition, with an alkaline agent.
Currently, bio-diesel is competitively developed worldwide and produced, and even in Korea, the production of bio-diesel has been already begun and bio-diesel is commercially available as an additive of diesel oil.
In the procedure of producing bio-diesel, a great quantity of glycerol corresponding to about 10% of the production amount of the bio-diesel is produced. However, glycerol is excessively supplied in view of the demand thereof, and thus, the value of glycerol continuously decreases. Accordingly, there is a need to increase added-value of glycerol by converting glycerol into chlorohydrins, such as dichloropropanol.
Meanwhile, chlorohydrins, such as dichloropropanol, are used as a raw material for preparing epichlorohydrin, and the most of commercially available chlorohydrins are prepared from propylene. In particular, a method for preparing chlorohydrins includes preparing allyl chloride by high-temperature chlorination reaction of propylene and reacting the allyl chloride with a chlorination agent by using excess industrial water to prepare chlorohydrins. However, the method for preparing chlorohydrins using propylene has many problems including an unstable supply of propylene due to its price increase, generation of great quantities of waste water and waste matter, and excessive initial investment costs due to the two-step method and resulting difficulty in newly constructing/modifying manufacturing apparatuses.
Accordingly, a one-step method for directly preparing chlorohydrins including reacting polyhydroxy aliphatic hydrocarbon, such as glycerol, which is a by-product of bio-diesel, with a chlorination agent in the presence of a catalyst is economical. The one-step method for preparing chlorohydrins by using polyhydroxy aliphatic hydrocarbon, such as glycerol, as reaction raw materials may have lower manufacturing costs due to the use of cheap polyhydroxy aliphatic hydrocarbon. In addition, during the preparation process, industrial water is not used, and thus, generation of waste water and waste matter may be predominantly reduced, thereby being environmentally friendly. Furthermore, the one-step method may contribute to a decrease in process and environment-related investment costs, leading to a lower initial investment costs.
However, the method for preparing chlorohydrins produces water as a by-product and the generated water inhibits a chlorination reaction of polyhydroxy aliphatic hydrocarbon, such as glycerol, so that as the reaction progresses, the reaction rate gradually decreases, the reaction time increases, and selectivity of chlorohydrins decreases.
An embodiment of the present invention provides a method of preparing chlorohydrins by reacting polyhydroxy aliphatic hydrocarbon with a chlorination agent in the presence of a catalyst, wherein the method includes at least one combination of a series of unit operations in the order of a first reaction step, a water removal step, and a second reaction step, wherein the method for preparing chlorohydrins additionally comprises a step for contacting the chlorohydrins composition derived from a plurality of reaction mixtures discharged from the plurality of reaction steps with an alkaline agent, and removing the catalyst included in the chlorohydrins composition in the form of an alkali metal salt.
Another embodiment of the present invention provides a method for preparing chlorohydrins composition, wherein the method includes contacting chlorohydrins composition prepared by using the method for preparing chlorohydrins composition with an alkaline agent.
According to an embodiment of the present invention, a method for preparing chlorohydrins composition by reacting polyhydroxy aliphatic hydrocarbon with a chlorination agent in the presence of a catalyst, wherein the method includes at least one combination of a series of unit operations including the following steps in the following stated order; a first reaction step for reacting polyhydroxy aliphatic hydrocarbon with a chlorination agent; a water removal step for removing water as a by-product from a reaction mixture discharged from the first reaction step; and a second reaction step for reacting at least one constituent of the reaction mixture from which water is removed, with at least one of the chlorination agent and an additional chlorination agent, wherein the method additionally comprises a step for reacting the chlorohydrins composition derived from a plurality of reaction mixtures discharged from the plurality of reaction steps with an alkaline agent, and removing the catalyst included in the chlorohydrins composition in the form of an alkali metal salt.
The method may further include mixing at least a portion of a reaction mixture discharged from at least one reaction steps from among the plurality of reaction steps, with an additional chlorination agent and then recycling the resultant mixture to the reaction step from which the reaction mixture was discharged.
According to another embodiment of the present invention, a method for preparing chlorohydrins composition, the method including: introducing polyhydroxy aliphatic hydrocarbon, a catalyst, and a chlorination agent into a first reactor in which the temperature is maintained in a range of 50 to 200° C.; discharging an effluent of the first reactor including water as a by-product from the first reactor; introducing at least a portion of the effluent of the first reactor effluent into a water removal device to separate it into a water-rich layer and a water-deficient layer; introducing the water-deficient layer and an additional chlorination agent into a second reactor in which the temperature is maintained in a range of 80 to 200° C.; introducing at least a portion of an effluent of the second reactor into a chlorohydrins purification device to obtain chlorohydrins concentrate; mixing the water-rich layer with the chlorohydrins concentrate, or adding water to the resulting mixture after the mixing to obtain chlorohydrins composition; and contacting the chlorohydrins composition with an alkaline agent to remove the catalyst included in the chlorohydrins composition in the form of an alkali metal salt.
The method may further include at least one of a step of introducing at least a portion of the effluent of the first reactor with an additional chlorination agent into a first mixing device, mixing them together, and recycling the resulting mixture to the first reactor; and a step of introducing at least a portion of the effluent of the second reactor with an additional chlorination agent into a second mixing device, mixing them together, and recycling the resulting mixture to the second reactor.
The polyhydroxy aliphatic hydrocarbon may be a C2 to C20 compound that contains two or more hydroxyl groups bonded to different carbon atoms. The polyhydroxy aliphatic hydrocarbon may include at least one compound selected from the group consisting of 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 3-chloro-1,2-propanediol, 2-chloro-1,3-propanediol, glycerol, 1,2,4-butanetriol, 1,4-butanediol, and esters of these compounds.
The chlorohydrins of the chlorohydrins concentrate may be a compound including at least one hydroxyl group and at least one chlorine atom that are bonded to different carbon atoms.
The chlorohydrins may include at least one compound selected from the group consisting of 3-chloro-1,2-propanediol, 2-chloro-1,3-propanediol, 1,3-dichloropropane-2-ol, and 2,3-dichloropropane-1-ol.
The catalyst may include at least one selected from the group consisting of an organic acid catalyst, a carboxylic acid-based catalyst, a nitrile-based catalyst, and a solid catalyst.
A reaction product of the catalyst and the polyhydroxy aliphatic hydrocarbon may be produced as the intermediate product in the first reactor, and the intermediate product acts as a catalyst in a chlorination reaction of the polyhydroxy aliphatic hydrocarbon.
The polyhydroxy aliphatic hydrocarbon may include glycerol, wherein the catalyst includes an acetic acid, and the intermediate product includes glycerol acetates.
The chlorination agent and the additional chlorination agent may include a hydrogen chloride gas or an aqueous hydrochloric acid solution.
The effluent of the first reactor introduced into the water removal device is discharged when a conversion rate of the polyhydroxy aliphatic hydrocarbon is in a range of 30 to 100% and the yield of the chlorohydrins is in a range of 30 to 95%, in the first reactor.
The effluent of the first reactor introduced into the water removal device may include the polyhydroxy aliphatic hydrocarbon, the chlorohydrins, and the intermediate products at a ratio of about 0 to 90 parts by weight of the polyhydroxy aliphatic hydrocarbon: about 5 to 95 parts by weight of the chlorohydrins: about 5 to 12 parts by weight of the intermediate products.
The effluent of the first reactor introduced into the water removal device may include the chlorination agent and water at a ratio of about 10 to 25 parts by weight of the total of the chlorination agent and the additional chlorination agent: about 75 to 90 parts by weight of water.
A chlorohydrins purification device may include a distillation device.
The chlorohydrins purification device may further include a stripping device at a rear end of the distillation device.
A retention time of the reactor contents in the first reactor may be in a range of 20 minutes to 1 hour, and a retention time of the reactor contents in the second reactor may be in a range of 1 to 3 hours.
The water removal device may be operated by distillation based on a boiling point difference between constituents of the first reactor effluent.
The first reactor and the second reactor may be maintained at an atmospheric pressure or higher, and the water removal device may be maintained at an atmospheric pressure or lower.
The first reactor and the second reactor may be maintained at 1 to 20 atm, and the water removal device may be maintained at 10 to 760 mmHg.
The water removal device may include a vacuum distillation column having a theoretical plate number of 2 to 50.
The effluent of the first reactor may be decompressed in a decompression device and then introduced into the water removal device.
The decompression device may include a decompression valve.
The first reactor and the second reactor may be each independently a continuous stirred tank reactor, a batch reactor, a semi-batch reactor, or a plug flow reactor.
The effluent of the first reactor introduced into the water removal device may be divided into a water-rich layer and a water-deficient layer.
A portion introduced into the chlorohydrins purification device of the effluent of the second reactor may include 0 to 10 parts by weight of the polyhydroxy aliphatic hydrocarbon, 80 to 98 parts by weight of the chlorohydrins, 0 to 10 parts by weight of the total of the chlorination agent and the additional chlorination agent and 1 to 20 parts by weight of water.
The chlorohydrins composition may include 0 to 10 parts by weight of the polyhydroxy aliphatic hydrocarbon, 60 to 96 parts by weight of the chlorohydrins, 0 to 20 parts by weight of the total of the chlorination agent and the additional chlorination agent, and 0 to 30 parts by weight of water.
The chlorohydrins composition may include 0 to 5 parts by weight of the polyhydroxy aliphatic hydrocarbon, 10 to 40 parts by weight of the chlorohydrins, 0 to 5 parts by weight of the total of the chlorination agent and the additional chlorination agent, and 50 to 90 parts by weight of water.
The alkaline agent may include an aqueous sodium hydroxide solution.
According to another embodiment of the present invention, a method for preparing epichlorohydrins includes contacting the composition of chlorohydrins prepared above with an alkaline agent at a temperature of 20 to 100° C., and the composition of chlorohydrins includes 0 to 5 parts by weight of the polyhydroxy aliphatic hydrocarbon, 10 to 40 parts by weight of the chlorohydrins, 0 to 5 parts by weight of the total of the chlorination agent and the additional chlorination agent and 50 to 90 parts by weight of water.
According to an embodiment of the present invention, a method of preparing chlorohydrins provides an improved selectivity of chlorohydrins.
According to another embodiment of the present invention, a method of preparing epichlorohydrin includes reacting chlorohydrins prepared using the method with an alkaline agent.
Hereinafter, a method for preparing chlorohydrins composition and a method for preparing epichlorohydrin, according to an embodiment of the present invention, are described in detail.
The method for preparing chlorohydrins composition according to the present embodiment includes reacting a polyhydroxy aliphatic hydrocarbon with a chlorination agent in the presence of a catalyst.
The method for preparing chlorohydrins composition includes at least one combination of a series of unit operations including a plurality of reaction steps and a water removal step in the following stated order: a first reaction step for reacting polyhydroxy aliphatic hydrocarbon with a chlorination agent; a water removal step for removing water as a by-product from a reaction mixture discharged from the first reaction step; and a second reaction step for reacting at least one constituent of the reaction mixture from which water is removed, with at least one of the chlorination agent and an additional chlorination agent. In the water removal step, a chlorination agent is not additionally added.
In addition, the method for preparing chlorohydrins composition further includes removing the catalyst included in the chlorohydrins composition as an alkali metal salt by contacting the chlorohydrins composition with an alkaline agent, wherein the chlorohydrins composition is derived from a plurality of the reaction mixtures discharged from the plurality of reaction steps.
Hereinafter, the method for preparing chlorohydrins composition will be described in detail with reference to
In this specification, ‘chlorohydrins’ refers to chlorohydrins, esters of chlorohydrins, or a mixture thereof.
The chlorohydrins may be a compound having at least one hydroxyl group and at least one chlorine atom which are bonded to different carbon atoms. For example, the chlorohydrins may include at least one compound selected from the group consisting of 3-chloro-1,2-propanediol, 2-chloro-1,3-propanediol, 1,3-dichloropropane-2-ol, and 2,3-dichloropropane-1-ol. In the present specification, 3-chloro-1,2-propanediol and 2-chloro-1,3-propanediol are collectively referred to as “monochloropropanediol,” and 1,3-dichloropropane-2-ol of and 2,3-dichloropropane-1-ol are collectively referred to as “dichloropropaneol.”
In the method for preparing chlorohydrins composition according to an embodiment of the present invention, 1,3-dichloropropane-2-ol is predominantly produced, and particularly, suitable for use as a reaction raw material to prepare epichlorohydrin.
Referring to
The polyhydroxy aliphatic hydrocarbon may be a C2-C20 compound having at least two hydroxyl groups bonded to different carbon atoms. The polyhydroxy aliphatic hydrocarbon may include at least one compound selected from the group consisting of 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 3-chloro-1,2-propanediol, 2-chloro-1,3-propanediol, glycerol, 1,2,4-butanetriol, 1,4-butanediol, and esters of these compounds.
The catalyst may be an organic acid catalyst, a carboxylic acid-based catalyst, a nitrile-based catalyst, a solid catalyst, or a mixture of at least two of these catalysts.
The organic acid catalyst may include, for example, at least one compound selected from the group consisting of a monocarboxylic acid, a dicarboxylic acid, a polycarboxylic acid, a malonic acid, a levulinic acid, a citric acid, a succinic acid, a propionic acid, and derivatives of these organic acids.
The carboxylic acid-based catalyst may include, for example, at least one compound selected from the group consisting of monocarboxylic acid ester, polycarboxylic acid ester, monocarboxylic acid anhydrides, polycarboxylic acid anhydrides, monocarboxylic acid chlorides, polycarboxylic acid chlorides, monocarboxylic acid salts, polycarboxylic acid salts, and derivatives of these carboxylic acid based compounds.
The nitrile-based catalyst may include, for example, at least one compound selected from the group consisting of acetonitrile, propionitrile, acrylonitrile, valeronitrile, isobutyronitrile, hydroxyacetonitrile, chloroacetonitrile, succinonitrile, glutaronitrile, adiponitrile, and phenylacetonitrile.
The solid catalyst may include, for example, at least one compound selected from the group consisting of an inorganic oxide, an inorganic halide, a strong-acidic organic compound, and mixtures of at least two of these.
The inorganic oxide may include at least one compound selected from the group consisting of metal oxide, composite oxide, oxy acid, and oxy acid salt. The metal oxide may be, for example, SiO2, Al2O3, TiO2, Fe2O3, ZrO2, SnO2, CeO2, Ga2O3, or La2O3. The composite oxide may be, for example, SiO2—Al2O3, SiO2—TiO2, TiO2—ZrO2, SiO2—ZrO2, MoO3—ZrO2, zeolite, a heteropoly acid (i.e., a poly acid including P, Mo, V, W, Si or the like), or a heteropoly acid salt. Examples of the oxy acid and oxy acid salt include BPO4, AlPO4, poly phosphoric acid, acidic phosphate, H3BO3, acidic borate, and niobic acid.
The inorganic halide may be a metal halide such as a metal fluoride, a metal chloride, a metal bromide, or a metal iodide of a Group 3A element such as scandium, yttrium, lanthanum, or actinium; a Group 4A element such as titanium, zirconium, or hafnium; a Group 5A element such as vanadium, niobium, or tantalum; a Group 8 element such as iron, cobalt, nickel, palladium, or platinum; a Group 2B element such as zinc; a Group 3B element such as aluminum or gallium; or a Group 4B element such as germanium or tin.
The strong acidic organic compound may be, for example, an organic sulfonic acid compound such as a sulfonate group-containing ion-exchange resin or a condensed carbon ring-containing sulfonic acid compound.
The amount of the catalyst introduced may be from 1 to 10 parts by weight based on 100 parts by weight of the polyhydroxy aliphatic hydrocarbon. When the amount of the catalyst introduced is within this range, a reaction rate may be satisfactorily improved with an appropriate amount of the catalyst.
In the method for preparing the chlorohydrins composition, the first reactor 110 may be maintained at a temperature from 50 to 200° C. When the temperature of the first reactor 110 is within this range, a high reaction rate may be obtained by the application of an appropriate level of energy. In addition, the first reactor 110 may be maintained at an atmospheric pressure or higher, for example, at 1 to 20 atm. When the pressure of the first reactor 110 is within this range, relatively high reaction activity may be obtained. In this case, even when the pressure of the first reactor 110 is greater than 20 atm, an effect of an increase in reaction activity according to the increase in pressure is not significant. In addition, the first reactor 110 may be a continuous stirred tank reactor (CSTR), but is not limited thereto. For example, the first reactor 110 may be a batch reactor, a semi-batch reactor, or a plug flow reactor. In the first reactor 110, in addition to chlorohydrins as a main product, a reaction product of the catalyst and the polyhydroxy aliphatic hydrocarbon as an intermediate product is produced. The intermediate product may act as a catalyst in the chlorination of the polyhydroxy aliphatic hydrocarbon (e.g., a reaction for producing chlorohydrins which occurs in the first reactor 110 and/or a second reactor 150.) For example, when the polyhydroxy aliphatic hydrocarbon includes glycerol and the catalyst includes acetic acid, the intermediate product may include glycerol acetates. As used herein, the term “glycerol acetates” indicates a substituted or unsubstituted glycerol monoacetate, a substituted or unsubstituted glycerol diacetate, a substituted or unsubstituted glycerol triacetate, or a mixture of these compounds. In addition, the term “substituted” as used herein means that a hydrogen atom of a compound is substituted with a halogen group, a hydroxyl group, an alkyl group, an alkoxy group, an amine group, or a combination thereof. In addition, a retention time of the reactor contents in the first reactor 110 may be from 20 minutes to 1 hour. When the retention time of the reactor contents in the first reactor 110 is within this range, a high conversion rate of the polyhydroxy aliphatic hydrocarbon may be obtained within an appropriate period of time.
The chlorination agent may include a hydrogen chloride gas or an aqueous hydrochloric acid solution.
An example of the reaction occurring in the first reactor 110 is the chlorination reaction of a polyhydroxy aliphatic hydrocarbon (e.g., glycerol) which is represented by Reaction Scheme 1 below:
In the above reaction, the conversion rate of glycerol, the yield of monochloropropanediol (MCP), the yield of dichloropropanol (DCP), the selectivity of monochloropropanediolMCP, and the selectivity of DCP may be calculated respectively by Equations 1 through 5 below:
Conversion rate of glycerol (%)=(number of moles of glycerol reacted)/(number of moles of glycerol introduced)×100; [Equation 1]
Yield of MCP (%)=(number of moles of monochloropropanediol generated)/(number of moles of glycerol introduced)×100; [Equation 2]
Yield of DCP (%)=(number of moles of DCP generated)/(number of moles of glycerol introduced)×100; [Equation 3]
Selectivity of monochloropropanediol (MCP)=(number of moles of MCP generated)/(total number of moles of reaction products)×100; and [Equation 4]
Selectivity of dichloropropanol (DCP)=(number of moles of DCP generated)/(total number of moles of reaction products)×100. [Equation 5]
After the retention time elapses, a first reactor effluent is discharged from the first reactor 110 and flows into a line 3 and/or a line 4. That is, at least a portion of the first reactor effluent flows into a first mixing device 120 via the line 3, and the remaining portion of the first reactor effluent is decompressed in a decompression device 131 and then flows into a water removal device 140 via the line 4. Herein, the first reactor effluent may include a catalyst; chlorohydrins; an intermediate product such as glycerol acetates; water; unreacted polyhydroxy aliphatic hydrocarbon; and/or a chlorination agent. In addition, the chlorination agent is introduced into the first mixing device 120 via the line 2. In the first mixing device 120, the first reactor effluent is mixed with the chlorination agent and then recycled to the first reactor 110.
The first mixing device 120 may include an ejector, an inline mixer, an ultrasonic mixture, or a mixture of at least two of these. When an ejector is used as the first mixing device 120, the first reactor effluent may act as a motive fluid and the chlorination agent may act as a suction fluid.
The decompression device 131 may include a decompression valve.
The additional chlorination agent may include a hydrogen chloride gas or an aqueous hydrochloric acid solution.
The water removal device 140 may be operated by distillation based on a boiling point difference of constituents of the first reactor effluent.
In addition, the water removal device 140 may be maintained at an atmospheric pressure or less, for example, at 10 to 760 mmHg. When the pressure of the water removal device 140 is within this range, a temperature of a downstream effluent (i.e., water-deficient layer) is appropriate, and thus, an amount of high boiling point material generated is decreased and clogging of the water removal device 140 and pipelines may be prevented. The water removal device 140 may include a vacuum distillation column having a theoretical plate number of 2 to 50 (i.e., a dehydration column 141). When the theoretical plate number of the vacuum distillation column is within this range, the amount of moisture remaining in the water-deficient layer may be minimized. As used herein, the term “theoretical plate number” indicates the number of imaginary regions or plates where two phases, such as gas and liquid phases, reach equilibrium, in a separation process using the vacuum distillation column.
The first reactor effluent introduced into the water removal device 140 may be discharged when the conversion rate of the polyhydroxy aliphatic hydrocarbon is in a range of 30 to 100% and the yield of the chlorohydrins is in a range of 30 to 95%, in the first reactor 110. In the first reactor effluent introduced into the water removal device 140, when the conversion rate of the polyhydroxy aliphatic hydrocarbon and the yield of the chlorohydrins are within the ranges described above, a decrease in a reaction rate in the first reactor 110 does not occur and the water removal device 140 may have high water removal effects. In addition, a high selectivity of chlorohydrins in the first reactor 110 may be obtained. For example, the first reactor effluent introduced into the water removal device 140 may include 0 to 90 parts by weight of the polyhydroxy aliphatic hydrocarbon, 5 to 95 parts by weight of the chlorohydrins, and 5 to 12 parts by weight of the intermediate product (e.g., glycerol acetates).
In addition, the first reactor effluent introduced into the water removal device 140 may include 10 to 25 parts by weight of the total of the chlorination agent and the additional chlorination agent and 75 to 90 parts by weight of water. When the amounts of the chlorination agent and the water are within the ranges described above, the first reactor effluent may form an azeotropic mixture, and thus, the solubility of the chlorination agent with respect to the water increases so that a loss of the chlorination agent may be minimized.
The first reactor effluent introduced into the water removal device 140 via the line 4 is separated into a gas phase material and other materials (i.e., a liquid phase material and a solid phase material) in a dehydration column 141. Thereafter, the gas phase material is condensed in a condenser 143 and flows into a line 5, and the other materials are distilled in a reboiler 142 and separated again into a gas phase material and other materials. Afterwards, the gas phase material is recycled to the dehydration column 141 and the other materials flow into the second reactor 150 via a line 6. In particular, a material (hereinafter, referred to as “water-rich layer”) that is condensed in the condenser 143 and flows into the line 5 after being discharged from an upper portion of the dehydration column 141 may include water and a chlorination agent, and a material (hereinafter, referred to as “water-deficient layer”) that does not vaporize in the reboiler 142 and flows into the line 6 after being discharged from a lower portion of the dehydration column 141 may include an unreacted polyhydroxy aliphatic hydrocarbon, chlorohydrins, and/or the above-described intermediate product. The intermediate product is introduced into the second reactor 150 and acts as a catalyst for the chlorination reaction of Reaction Scheme 1, and thus, the reaction may smoothly occur in the second reactor 150 without further adding a catalyst.
The reboiler 142 and the condenser 143 may be maintained at 100 to 200° C. and 0 to 60° C., respectively.
The second reactor 150 may be maintained at 70 to 200° C. When the temperature of the second reactor 150 is within the range described above, chlorohydrins may be obtained with a high yield by the application of an appropriate level of energy. In addition, the second reactor 150 may be maintained at an atmospheric pressure or higher, for example, 1 to 20 atm. When the pressure of the second reactor 150 is within this range, the solubility of the chlorination agent with respect to the contents of the second reactor 150 may be improved. The second reactor 150 may be a CSTR, but is not limited thereto. For example, the second reactor 150 may be a batch reactor, a semi-batch reactor, or a plug flow reactor. In the second reactor 150, chlorohydrins are additionally generated by contacting the above-described intermediate product with an additional chlorination agent that is separately added to the second reactor 150. The retention time of the reactor contents in the second reactor 150 may be from 1 to 3 hours. When the retention time of the second reactor contents is within this range, chlorohydrins may be obtained with a high yield within an appropriate period of time.
The reaction that occurs in the second reactor 150 is the same as or similar to that occurring in the first reactor 110.
After the retention time elapses, a second reactor effluent is discharged from the second reactor 150 and introduced into a line 7 and/or a line 9. That is, at least a portion of the second reactor effluent is introduced into a second mixing device 160 via the line 7, and the remaining portion of the second reactor effluent is decompressed in a second decompression device 132, and then, introduced into a first distillation device 170 via a line 9. In this regard, the second reactor effluent may include a catalyst; chlorohydrins; an intermediate product such as glycerol acetates; water; an unreacted polyhydroxy aliphatic hydrocarbon; and/or a chlorination agent. The additional chlorination agent is introduced into the second mixing device 160 via a line 8. In the second mixing device 160, the second reactor effluent is mixed with the additional chlorination agent, and the resulting mixture is then recycled to the second reactor 150. The additional chlorination agent may be introduced into the second reactor 150 via other paths, in addition to the line 8.
The second mixing device 160 may include an ejector, an inline mixer, an ultrasonic mixture, or a mixture of at least two of these. When an ejector is used as the second mixing device 160, the second reactor effluent may act as a motive fluid and the additional chlorination agent may act as a suction fluid.
The second decompression device 132 may include a decompression valve.
The first distillation device 170 may be operated by distillation based on a boiling point difference between constituents of the second reactor effluent.
In addition, the first distillation device 170 may be maintained at an atmospheric pressure or lower, for example, 10 to 760 mmHg. When the pressure of the first distillation device 170 is within the range described above, chlorohydrins may be separated with a high efficiency. The first distillation device 170 may include a vacuum distillation column having a theoretical plate number of 2 to 50 (i.e., a separation column 171). When the theoretical plate number of the vacuum distillation column is within this range, chlorohydrins may be separated with a high efficiency.
The second reactor effluent introduced into the first distillation device 170 may include 0 to 10 parts by weight of the polyhydroxy aliphatic hydrocarbon, 80 to 98 parts by weight of the chlorohydrins, 0 to 10 parts by weight of the total of the chlorination agent and the additional chlorination agent, and 1 to 20 parts by weight of water. When the amounts of the constituents of the second reactor effluent are within the range described above, the reaction is completed and thus the yield of the chlorohydrins is maximized.
The second reactor effluent that is introduced into the first distillation device 170 via the line 9 is separated into a gas phase material and a liquid phase material in the separation column 171. Thereafter, the gas phase material is condensed in a second condenser 173 and flows into a line 10, and the liquid phase material is distilled in a second reboiler 172 and separated again into a gas phase material and a liquid phase material. Afterwards, the gas phase material is recycled to the separation column 171 and the liquid phase material is introduced into a stripping device 180 via a line 11. In particular, a material that is condensed in the second condenser 173 and flows into the line 10 after being discharged from an upper portion of the separation column 171 may include chlorohydrins, water and/or a chlorination agent, and a high boiling point material that does not vaporize in the second reboiler 172 and flows into the line 11 after being discharged from a lower portion of the separation column 171 may include an intermediate product, such as glycerol acetates. In this regard, a considerable amount of chlorohydrins may flow into the line 11 together with the intermediate product. Herein, the second reboiler 172 and the second condenser 173 may be maintained at a temperature of 100 to 200° C. and 0 to 60° C., respectively.
In the first distillation device 170, a chlorination reaction of the polyhydroxy aliphatic hydrocarbon, i.e., a reaction for generating chlorohydrins, may further occur.
The stripping device 180 separates a low boiling point material such as chlorohydrins that is introduced together with the high boiling point material via the line 11 by using steam that is supplied via a line 12. The low boiling point material that is collected by the stripping device 180 flows into a line 13, and the high boiling point material is discharged to the outside via a line 14.
The first distillation device 170 and the stripping device 180 are collectively referred to as a chlorohydrins refiner.
The materials that are introduced into the lines 10 and 13 are collectively referred to as a concentrate of chlorohydrins.
The materials that are introduced into the lines 5, 10 and 13 may be combined together at a single location to form a first composition of chlorohydrins.
The first composition of chlorohydrins may include 0 to 10 parts by weight of the polyhydroxy aliphatic hydrocarbon, 60 to 96 parts by weight of the chlorohydrins, 0 to 20 parts by weight of the total of the chlorination agent and the additional chlorination agent, and 0 to 30 parts by weight of water.
When the method for preparing the chlorohydrins composition as described above is used, water, which is a by-product, is removed without loss of the chlorination agent and/or the catalyst, and thus, a reduction in reaction rate may be prevented and the selectivity of chlorohydrins may be increased.
The first composition of chlorohydrins may be used to prepare epichlorohydrins. In this regard, the first composition of chlorohydrins may be diluted with water before being used to prepare epichlorohydrins to form a second composition of chlorohydrins. In particular, referring to
The second composition of chlorohydrins may be used as a reactant for the preparation of epichlorohydrins along with an alkaline agent. The second composition of chlorohydrins may include 0 to 5 parts by weight of the polyhydroxy aliphatic hydrocarbon, 10 to 40 parts by weight of the chlorohydrins, 0 to 5 parts by weight of the total of the chlorination agent and the additional chlorination agent, and 50 to 90 parts by weight of water.
When the amounts of constituents of the second composition of chlorohydrins are within the ranges described above, the amounts of by-products decreases, and thus, the yield of the epichlorohydrin may be maximized.
In an inline reactor 190, the second composition of chlorohydrins may contact an alkaline agent (e.g., an aqueous sodium hydroxide solution) introduced via a line 17, which causes the following two reactions to occur. That is, while the second composition of chlorohydrins contacts the alkaline agent, the pH of a mixture of the second composition of chlorohydrins and the alkaline agent gradually increases as the contact time elapses. Herein, when the pH of the mixture thereof is 7 or below, the catalyst of the second composition of chlorohydrins may react with the alkaline agent to form an alkali metal salt. The formed alkali metal salt may be precipitated and then removed in a second distillation device 200, which will be described below. On the other hand, when the pH of the mixture thereof is greater than 7, the chlorohydrins (e.g., dichloropropanol) of the second composition of chlorohydrins may react with the alkaline agent to form epichlorohydrin. Herein, the inline reactor 190 may be maintained at a temperature of 20 to 100° C. and at a pressure of 1 to 2 atm. When the temperature and pressure of the inline reactor 190 are within this range, the reaction may smoothly progress by the application of an appropriate energy.
In addition, the first composition of chlorohydrins may include the above-described catalyst, and accordingly, the second composition of chlorohydrins may also include the catalyst. Consequently, the two reactions may occur in the inline reactor 190; a reaction for forming epichlorohydrin, which is a main product; a reaction for forming an alkali metal salt by contacting the catalyst with the alkaline agent.
As described above with reference to
A material including the epichlorohydrin and the alkali metal salt which has been discharged from the inline reactor 190 is introduced into the second distillation device 200 via a line 18.
The second distillation device 200 may be operated by distillation based on a boiling point difference between constituents of the material including the epichlorohydrin and the alkali metal salt.
In addition, the second distillation device 200 may be maintained at an atmospheric pressure or lower, for example, 10 to 760 mmHg. When the pressure of the second distillation device 200 is within the range described above, epichlorohydrin may be separated with a high efficiency. The second distillation device 200 may include a vacuum distillation column having a theoretical plate number of 2 to 50 (i.e., a separation column 201). When the theoretical plate number of the vacuum distillation column is within this range, epichlorohydrin may be separated with a high efficiency.
The effluent of the inline reactor 190 introduced into the second distillation device 200 via the line 18 is separated into a gas phase material and a liquid phase material in the separation column 201. Thereafter, the gas phase material is condensed in a second condenser 203 and flows into a line 19 and then collected, and the liquid phase material is distilled in a second reboiler 202 and separated again into a gas phase material and a liquid phase material. Afterwards, the gas phase material is recycled to the separation column 201 and the liquid phase material is discharged to the outside via a line 20. In particular, a material that is condensed in the second condenser 203 and flows into the line 19 after being discharged from an upper portion of the separation column 201 may include epichlorohydrin and water, and a high boiling point material that is discharged to the outside via the line 20 without evaporation in the reboiler 202 after being discharged from a lower portion of the separation column 201 may include an alkali metal salt. In this regard, the second reboiler 202 and the second condenser 203 may be maintained at a temperature of 60 to 110° C. and 0 to 60° C., respectively.
In the second distillation device 200, epichlorohydrin may be additionally generated.
These examples are for illustrative purposes only and are not intended to limit the scope of the present invention.
By using the manufacturing process illustrated in
In addition, a total flow rate of materials transported via the respective lines in the manufacturing procedure, constituents of the materials, and flow rates of the respective constituents were respectively measured, and results thereof are shown in Table 2 below. Flow rates of the respective constituents were calculated as follows: the total flow rates of materials transported through the respective lines were measured, component ratios of materials collected from the respective lines were analyzed by a gas chromatograph, and the total flow rates was multiplied by component ratios of the materials.
During reaction, samples were collected from the line 4 and the line 15 at an interval of 5 minutes, and then, constituents of the samples and content ratios of the respective constituents were analyzed by a gas chromatograph. Analysis data obtained after reaching a steady state was used to calculate a conversion rate of glycerol, a yield of monochloropropanediol, a yield of dichloropropanol, selectivity of monochloropropanediol, and selectivity of dichloropropanol, according to Equations 1 to 5. Results thereof are shown in Table 3 below.
Referring to Table 3, the sample collected from line 15 has a very high yield (94.8%) and a very high selectivity (94.8%). In addition, the yield and selectivity of dichloropropanol were much higher than the yield and selectivity of monochloropropanediol.
While the present invention has been particularly shown and described with reference to drawings and exemplary embodiments thereof, it will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the present invention as defined by the following claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10-2010-0063161 | Jun 2010 | KR | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/KR2011/004175 | 6/8/2011 | WO | 00 | 12/26/2012 |
