Claims
- 1. A method for preparing a diaryl carbonate which comprises contacting at least one hydroxyaromatic compound with oxygen and carbon monoxide in the presence of an amount effective for carbonylation of at least one catalytic material including an effective proportion of a source of bromide or chloride, said source being at least one hexaalkylguanidinium bromide or chloride.
- 2. A method according to claim 1 wherein the catalytic material comprises palladium or a compound thereof, an inorganic cocatalyst and an organic cocatalyst.
- 3. A method according to claim 2 wherein the hydroxyaromatic compound is phenol.
- 4. A method according to claim 2 wherein the catalytic material comprises a palladium(II) salt of a C.sub.2-6 aliphatic carboxylic acid.
- 5. A method according to claim 4 wherein the palladium(II) salt is palladium(II) acetate.
- 6. A method according to claim 2 wherein the catalytic material comprises a palladium(II) salt of a .beta.-diketone.
- 7. A method according to claim 6 wherein the palladium(II) salt is palladium(II) 2,4-pentanedionate.
- 8. A method according to claim 2 wherein the inorganic cocatalyst is a cobalt(II) salt with an organic compound capable of forming a pentadentate complex.
- 9. A method according to claim 8 wherein the organic compound is bis�3-(salicylalamino)propyl!methylamine.
- 10. A method according to claim 2 wherein the organic cocatalyst is a terpyridine, phenanthroline, quinoline or isoquinoline compound.
- 11. A method according to claim 10 wherein the organic cocatalyst is 2,2':6',2"-terpyridine.
- 12. A method according to claim 2 wherein the alkyl groups in the hexaalkylguanidinium salt contain 2-6 carbon atoms.
- 13. A method according to claim 12 wherein the source is a hexaalkylguanidinium bromide.
- 14. A method according to claim 13 wherein the hexaalkylguanidinium bromide is hexaethylguanidinium bromide.
- 15. A method according to claim 2 wherein the proportions of oxygen and carbon monoxide are about 2-50 mole percent oxygen, with the balance being carbon monoxide.
- 16. A method according to claim 2 wherein the proportion of palladium is about 1 gram-atom per 2,000-5,000 moles of hydroxyaromatic compound.
- 17. A method according to claim 16 wherein about 0.5-1.5 gram-atoms of cobalt, about 0.3-1.0 mole of organic cocatalyst and about 20-50 moles of hexaalkylguanidinium halide are employed per gram-atom of palladium.
CROSS-REFERENCE TO RELATED APPLICATION
This application claims priority from provisional application Ser. No. 60/40,300, filed Feb. 13, 1997.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
5202454 |
Wooden et al. |
Apr 1993 |
|