Patent Grant
7938271
This application is a U.S. National Phase of International Application No. PCT/ES2005/000177, filed Apr. 6, 2005, designating the U.S. and published not in English on Oct. 19, 2006 as WO 2006/108884. The content of this application is incorporated herein by reference in its entirety.
This invention relates to the field of the liquid still slops produced from the distillation of fermented sugars with the aim of producing alcohol or yeasts.
The object of the invention is a procedure for the execution of the drying and transformation of concentrated liquid still slops in order to produce the same in powdered format, free of contamination and easily manageable, which allows its storage in sacks.
Another object of the invention is the powdered still slops in themselves, produced by means of this procedure.
The facility, incorporating means associated with a cyclone for collecting the powder obtained from the concentrated liquid still slops is likewise the object of this invention.
Still slops consist of a by-product derived from the distillation of fermented sugars with the aim of producing alcohol or yeasts. The sugars for distillation may come from vegetable juices (sugar cane, beet, maize, cereals, grapes, etc.), from molasses, which are by-products formed in the production of sugar, or from intermediate honey.
The still slops produced, due to their high organic load, ferment with the greatest of ease, and their fermentation is aerobic; for this reason their BOD (Biochemical Oxygen Demand) load is very high and they consume all the oxygen in their surroundings, destroying the biosystem. For this reason they are listed as highly pollutant waste.
Still slops consist at origin of a significant quantity of water and a small percentage of soluble and insoluble solids.
The insoluble solids are mainly sulphates, such as calcium sulphate or plaster in a greater percentage, potassium sulphate, etc. and some other salts which depend on the starting vegetable material, and also the yeasts which have been used for the fermentation of the sugars.
The Spanish patent ES 2 158 751 discloses a procedure for the preparation of polymeric complexes from effluent by-products of distilleries; these normally consist of still slops.
A high percentage of the soluble solids are of an organic nature; this also depends on the starting vegetable material, but it is usually in the region of 85% to 90%, and these together are a polymeric complex. The remaining percentage is of an inorganic nature, comprised of salts of potassium, manganese, calcium, etc.
The volumes of concentrated still slops produced in distilleries are very high and require important and highly costly logistics using tanks; all of this makes their use in locations some distance from the point of production unprofitable.
In practice, it may be seen that manipulation of the concentrated liquid still slops is difficult, basically because it requires storage tanks at the locations at which it is desired to carry this out, and it entails, apart from the drawbacks derived from costly outlays and the handling of a viscous liquid (between 180 and 250 cps), the latent danger of contamination of the liquid by a yeast spore or by any bacteria.
Still slops, due to their pH—approximately 4.5— and their organic acids, are corrosive, and require preferably stainless steel tanks, which entails a heavy outlay, as carbon steel tanks have a relatively short life as they are destroyed by the heavy corrosion, or require highly expensive maintenance as they must be cleaned thoroughly and coated with special paints every few years.
It should be highlighted that concentrated still slops are organic matter in their vast majority, and although in strong concentrations contamination by bacteria, fungi and yeast does not spread easily, effects as simple as warm temperatures and condensation in the storage tanks can unleash heavy contamination which spreads in a short time interval.
This contamination first generates heavy emissions of carbon dioxide, and thick layers of fungi on the surfaces of the tanks. When the contaminated liquid is used, the bacteria contained in the same spread to the locations where the liquid is applied.
The only way of preventing these contaminations is by means of the use of potent biocides, which are highly costly, and the majority of which are to be banned due to their carcinogenic characteristics (formol, for example) and another particularity is that their effects are short-term and it is necessary to repeat their application frequently.
On the other hand, concentrated liquid still slops tend to decant their dissolved solids which flocculate constantly, and to deposit their organic matter on the base of the tank, creating a sludge which is rich in organic matter; this makes it very difficult for the richness or characteristics of the liquid to be constant and known. This richness or uniformity of content varies in accordance with the height of the tank, the time the still slops have been stored, the ambient temperature, etc. and the consequence is that at different layers or levels in the tank the characteristics of the still slops are different. Accordingly, the handling of these still slops stored in a vessel is banned at well-defined formulations. They are only valid for blends in proportions in which the variations in this component are not of great importance as they are applied in flood irrigation or similar applications.
Furthermore, concentrated liquid still slops contain a percentage of water of approximately 50%, which prevents their use for the majority of formulations.
The aforementioned difficulties regarding transport, storage, preservation and formulation prevent the use of concentrated liquid still slops in a host of applications which would represent a practical, productive use for this product; among these the following may be highlighted:
With regard to the drying of the still slops, likewise the powder produced when hot and damp, there must be no contact between the powder and any artefact not at speed, as the powder will be deposited on it and will adhere firmly, subsequently collecting the powder which continues to arrive. The powder must be in continuous movement and must, during its journey or transport in motion, be dried and cooled, which requires that there shall not be artefacts which interrupt its speed until its temperature and humidity so permit.
It is well-known that a cyclone consists of a body in the shape of an inverted cone, into which an air draught enters tangentially, carrying the powder. A downward air draught, also called cyclone, is generated towards the vertex of the cyclone, and the solid particles descend, sliding down the wall, while spinning at great speed. When the cyclone-shaped air draught reaches the bottom or zone of the vertex of the cone, it is absorbed upwards by the cyclone at the centre or axis of the cone. It is necessary for cyclones to be closed at the bottom in order to prevent the entry of air which would be sucked by the cyclone and which would draw the powder towards the top and out of the cyclone, preventing collection of the powder.
If the bottom of the artefact or zone of the vertex is closed or features a closed tray connected at this point, the powder falls into the tray and the air moves upward at the centre of the artefact and exits at the top towards an evacuation flue.
In the case of the still slops, if the cyclone were to have at its base a closed tray or a rotary shut-off valve, the powder would be halted and, due to being in contact with the device or the tray, would become compacted, producing a block of hard, compacted powder which would eventually block the cyclone, and should the powder not be removed, it would be drawn up to the flue by the air draught.
The procedure and associated facility proposed in this invention for the drying and transformation into powder of concentrated liquid still slops solves the problem outlined above by means of the solution of incorporating a closing system at the bottom of a powder collecting cyclone which does not come into contact with the powder, it being simply a swirling air draught which counters the cyclone suction draught, thus acting as a rotary shut-off valve.
It is therefore necessary that at the bottom or vertex of the cyclone there should be no contact between the powder and any element, and that the powder should be evacuated from the cyclone; also that the powder should be cooled in the absence of moisture, as the powder is highly hygroscopic and if it absorbs moisture it reverts to a sticky paste.
To do this, it is necessary to create an air draught formed like a cyclone or whirlpool, by means of a duct located around the outlet aperture of the cyclone, which counters the suction draught of the cyclone and which consists of dry air with a Relative Humidity of approximately 15% to 40% and at a temperature of approximately 18° to 35° C.
The air drawn into the aforementioned duct is a dry air produced by means of a cooler of industrial manufacture in order to lower its temperature to dewpoint, releasing the water in suspension, subsequently, this air is heated sufficiently to lower the relative humidity.
The aforementioned duct is of a circular configuration, in the shape of a snail or a logarithmic spiral and it generates a whirlpool-like air draught at the lower aperture of the collecting cyclone, opposing the suction effect of the cyclone which would tend to raise the powder, thus achieving the opposite effect, that is, the falling of the powder.
The dry air enters via the external inlet of said duct and exits the same via a central outlet which coincides with the lower aperture of the collecting cyclone. Thus, two draughts or “air cyclones” are to be found at the vertex of the cyclone; these counter each other and cause the upper powder collecting cyclone to deliver the powder towards a discharge aperture located below the central outlet of the duct and cause the outgoing dry air draught, like a cyclone, to draw the powder with it, to cool the same without moistening it, and to transport it to a place where it may be handled and bagged.
The installation is complemented by an inverted conical disc, located at the bottom of and inside the cyclone, which leaves a space of 2 to 4 centimeters approximately between its edge and the wall of the cyclone, so that the powder may slide down towards the discharge aperture and subsequently be evacuated. The air of the cyclone glides over the upper side of the conical disc and is drawn towards the axis of the cyclone and upwards, to be directed towards a flue.
The procedure for the obtaining of the powdered still slops progresses according to the following steps:
By means of this procedure a new powdered product, which may or may not contain insoluble solids, may be produced.
In the case of powdered still slops with insoluble solids, it may embody the following composition:
In the case of powdered still slops without insoluble solids, it may embody the following composition:
The advantages derived from the production of powdered still slops are listed below:
The facility described would be likewise applicable for the collection in cyclones, without any elements of contact, of the powder produced from sugar-loaded liquids and clinging liquids in general.
To complement the description which is being made, and with the purpose of contributing to a better understanding of the characteristics of the invention, in accordance with a preferred embodiment of the same, a set of drawings with an illustrative and non-limitative character is attached as an integral part of said description, in which the following is portrayed:
With reference to the figures, a preferred embodiment of the facility for the production of powdered still slops, which is the object of the invention, is disclosed below.
In
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/ES2005/000177 | 4/6/2005 | WO | 00 | 10/4/2007 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2006/108884 | 10/19/2006 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 2375288 | Wolcott | May 1945 | A |
| 3721568 | Wilson | Mar 1973 | A |
| Number | Date | Country |
|---|---|---|
| 2 059 283 | Nov 1994 | ES |
| 2 113 820 | May 1998 | ES |
| 27300 | Jan 1913 | GB |
| 439595 | Dec 1935 | GB |
| Number | Date | Country | |
|---|---|---|---|
| 20080190416 A1 | Aug 2008 | US |
