The present invention relates to a method of producing corrosion-resistant and workable sheet metals and also relates to a device for applying a metallic coating to butt-joint welds in steel sheets.
Sheet metals produced with this method can be used for the production of containers for packing foodstuffs, for example, cans of tinned food or beverage cans or even in other fields in which corrosion-resistant sheet metals with good workability are required, for example for production of automotive body panels. The sheet metals must be corrosion-resistant for use of sheet metals in the production of food packages or automotive body panels. In the case of food packages, the sheet metal must be corrosion-resistant such that the sheet metal surface is not attacked by the aggressive filling. For this reason, steel sheets that are used for the production of food packages are provided with a corrosion-resistant coating. In this case, it can be a metallic coating as is the case with tin plate (tinned steel sheet).
For producing food packages, the coated sheet metal must then be reshaped, for example, in a deep-drawing process. During the production of coated sheet metals, defective or damaged spots in the sheet metal are cut out and the defect-free sheet metal parts are subsequently welded together to form a sheet metal strip of standard length that is wound on to a reel. Such sheet metal strips that have been welded together from many pieces of sheet metal have unsatisfactory forming behavior because the sheet metal in the region of welds cannot be shaped in a satisfactory manner. For example, corrosion-resistant steel sheets are used for producing tin cans which comprise one welded body and two folded lids. In the region of welds, the sheet metal which is composed of individual steel sheets has a distinctly higher hardness than the individual steel sheets, resulting in inferior workability of sheet metal in the region of welds.
Therefore, in the prior art, methods have been recommended for producing workable steel sheets with which reducing the hardness of welds of at least two steel sheets that are joined together is achieved in order to improve their workability. EP 540 382 A1 describes a method for producing a deep-drawn steel sheet formed from at least two elements in which the edges of the elements are welded by beam welding wherein the welded edges of the elements are swept with a laser beam before welding to reduce the hardness of the weld, and oxygen is fed simultaneously. Thus, decarburization and oxidation of edges is achieved.
The preparatory laser beam affects the geometrical formation of the sheet edge in the case of thin sheet thicknesses in a disadvantageous manner, since the material is stretched above its plastic limit due to thermal energy inputs. This leads to increased internal stresses and leads to component warping at the sheet edge. An accurate implementation of subsequent laser welding without height offsets, and alternating weld widths, and with uniform seam geometry seems improbable to achieve, but it must be available for optimum shaping results. Furthermore, this type of heat treatment in combination with material decarburization leads to the formation of distinct heat-affected zones with very soft microstructures at which the material always fails during the shaping operations. The introduction of oxygen in the welding region also disguises the danger of material embrittlement and of surface oxidation phenomena in the regions close to the weld where the temperature remains below the decomposition temperature of FeO2 into Fe and O2.
Based on this, the task of the invention is to produce as much as possible a corrosion-resistant and easily workable sheet metal which is put together from individual steel sheets that are welded to each other.
This problem is solved with the method as set forth in the claims. Preferred embodiments of this method are to be taken from the subclaims.
The invention is better explained in the following with the help of embodiments with reference to the attached drawings. The drawings show:
a: Cross section through a device for electrodeposition on a weld in a steel sheet with a metallic coating, shown in the process step during the electrodeposition on the weld;
b: sectional representation of device of
c: Top view of the upper anode strip of the device of
According to a method of the invention, a corrosion-resistant and easily workable sheet metal is produced from two or more uncoated steel sheets with sheet thicknesses between 0.10 mm and 0.70 mm in which the bare steel sheets are first placed next to each other in a butting relationship, and subsequently each joint groove is welded by butt-joint welding by means of a welding beam forming a weld. The welding beam can be a laser welding beam or an electron welding beam. A thermal treatment of each weld is effected by means of an annealing beam during or directly after welding; this annealing beam is preferably formed from a laser beam. After cooling of the welds, the sheet metal which is formed from the steel sheets welded together is coated with a metallic coating at least on one side or even on both sides, wherein the or each weld is also coated on one side or both sides.
According to another method of the invention, a corrosion-resistant and easily workable sheet metal is produced from two or more steel sheets that are coated with a metallic coating, wherein the coated steel sheets are first placed next to each other in an abutting relationship, and subsequently the joint grooves or each joint groove is welded by butt-joint welding by means of a welding beam forming a weld along the respective joint grooves. During or directly after welding, each weld is treated thermally by means of an annealing beam. After cooling of the welds, each weld is covered with a strip-shaped, metallic coating on one side or both sides. The coating of welds is in this case preferably effected by electrodeposition on the respective weld.
Because of the thermal treatment of welds during or directly after welding, the temperature changes of the weld during cooling can be passed through over a designated period of time in a controlled manner. It has been observed that there is an increase in hardness of welds due to martensite and bainite formation, and also due to residual welding stresses during cooling of the weld. The cooling range between 800° C. and 500° C. is especially critical for martensite formation. If this temperature range is controlled during cooling of the weld and passed through more slowly than was specified at the natural cooling rate, martensite and bainite formation can be suppressed and the internal welding stresses can be reduced, and thus an increase in weld hardness can be avoided. Due to lower weld hardness, the sheet metal which has been welded together from steel sheets then has better workability.
Finally, the welds are protected against corrosion by metallic coating of the welds in the subsequent process step, such that an easily workable and simultaneously corrosion-resistant sheet metal can be produced with the inventive method.
It has been shown that the martensite and bainite formation in the welds can be suppressed very efficiently if the temperature of the weld during cooling is held in the temperature range between 800° C. and 500° C. that is critical for structural composition for a period of 1-3 sec, preferably 1.5-2 sec, by the annealing beam.
The laser beam can be preferably a welding beam or even an annealing beam, wherein the welding beam is directed in the form of a highly focused point in the region of the joint groove on the surface of the steel sheets to be joined, while the annealing beam is directed onto the surface of the weld as a line focus or even as a round, rectangular or elliptical focus with the application area being considerably greater compared to the focus of the welding beam. Preferably, the annealing beam follows the welding beam in the welding direction. Then, a thermal post-treatment of the weld is undertaken in short time intervals after the end of the welding period. The diameter of the annealing beam focus is preferably selected such that at least the entire width of the weld is covered by the annealing beam focus. The diameter of the annealing beam focus can be adjusted to be even bigger in order to encompass, for example, the heat-affected zone in the lateral direction around the weld or even regions outside its heat-affected zone. The application time of the annealing beam can be adjusted either via the speed of welding or via the length of the annealing beam focus at a constant welding speed. The annealing beam is preferably formed from a laser beam because great variation of the thermal energy coupled into the weld is thus possible. Inductive or conductive heat sources can also be used for producing the annealing beam, wherein these require distinctly more energy for achieving the same results due to their lower energy densities. This has proven to be disadvantageous due to the higher internal stresses and warping or creasing generated in the weld region of.
A double laser system is preferably used for the thermal treatment of the weld during welding. This system provides the welding beam in the form of a welding laser beam and the annealing beam in the form of an annealing laser beam. Thus the thermal treatment can take place directly at and synchronously with the front of the weld pool advancing in the direction of welding during welding.
In
In
The butt-joint welding method described above with simultaneous or subsequent thermal treatment of the weld by the annealing beam is applied in the same way for both of the inventive methods. In one inventive method, two uncoated steel sheets 1, 1′ are first welded to each other in this way and are subsequently coated over the full surface with a metallic coating after welding, wherein the or each weld 2 is also coated with the metallic coating. The full surface coating of the joined steel sheets 1, 1′ is in this case effected in the known way, for example, by galvanic tinning or chrome plating in a known strip tinning and/or strip chrome plating plant.
In the second inventive method, steel sheets 1, 1′ that have already been provided with a metallic coating are welded by the butt-joint welding method described above and treated thermally during or after the welding by means of annealing beam 15. After cooling of the welds, these are provided with a strip-shaped metallic coating by electrodeposition. In
The device shown in
The length of the two anode strips 4, 5 is at least the maximum width of steel sheet 1 to be treated (corresponding to the maximum length of the weld 2 to be treated). In
The application device for applying electrolyte onto the weld 2 is arranged inside the hollow anode strips 4, 5, wherein this application device of the embodiment shown in
For electrodeposition on a weld 2, the steel sheets 1, 1′ which are joined to each other by the earlier described butt-joint welding method, are introduced into the treatment device and positioned such that the weld 2 runs parallel to the two anode strips 4, 5. The treatment device comprises a clamping device 11 for positioning and fixing the steel sheets 1, 1′ in this position. This clamping device 11 comprises two pairs of clamping jaws 11a and 11b as shown in the embodiment of
After (or even before) positioning and clamping the steel sheet in the clamping device 11, the two anode strips 4, 5 are placed on either side of the steel sheets 1, 1′ in the region of weld 2, with the anode strips 4, 5 being moved in their respective guide 30 in the direction perpendicular to the surface of the steel sheets 1, 1′. In that case, the pad 7 is pressed onto the weld 2 with a prescribed pressure. Subsequently, an electrical voltage is applied between anode 8 and steel sheets 1, 1′, and simultaneously an electrolyte fluid is led through the feed device to the application device, by means of which the pad 7 is soaked with electrolyte fluid. An electrolyte film is formed on the surface of the steel sheets 1, 1′. This is shown in
To ensure constant process parameters for each electrodeposition process of a weld 2, the pad 7 must be renewed at regular time intervals and/or regenerated, since the open-cell structure of pad 7 can be adversely affected, especially due to salting out, and thus, a regular flow of electrolyte onto the surface of the steel sheet could be locally prevented. The replacement and/or regeneration of pad 7 can be effected by the replacement of anode strips 4, 5. Alternatively, an automated pad changing unit can be used, as is shown schematically in
As soon as a sufficiently thick metallic layer is electrodeposited on the weld, the electrical voltage between the steel sheets 1, 1′ and anode 8 is switched off and the supply of electrolyte is shut off. The electrolyte fluid which remains on the steel sheet surface is kept in circulation to avoid salting out, and the anode strips 4, 5 are driven to their initial position away from the sheet surface after turning off the electrical voltage and electrolyte supply, as is shown in
Finally, cleaning of the surface of the steel sheet is performed by removal of electrolyte residues that remain on the surface of the steel sheet. For this purpose, the device has a cleaning device 13 with cleaning slides 13a, 13b that run in the horizontal direction parallel to the surface of the steel sheet, wherein a cleaning slide 13a and 13b, respectively is assigned to the top side and bottom side of the steel sheet. In
In
To implement the cleansing step, each cleaning slide 13a, 13b is driven over the steel sheet surface from its original position shown in
The electrolyte fluid is supplied through the tube 6 in the embodiment of the coating device shown in
In another embodiment, which is shown in
Both of the rectangular tubes 20, 26 are connected to a reservoir 22 of an electrolyte fluid (
The welds 2 can be provided with a metallic strip-shaped coating with the described device in order to protect the welds 2 from corrosion. Due to thermal treatment of the welds during or after welding, the joined steel sheets 1, 1′ can be easily workable even in the region of welds 2, and are simultaneously protected against corrosion.
Number | Date | Country | Kind |
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10 2006 036 871.1 | Aug 2006 | DE | national |
10 2007 007 590.3 | Feb 2007 | DE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP2007/057729 | 7/26/2007 | WO | 00 | 10/29/2009 |