Method for producing a cylinder liner surface and cylinder liner

Information

  • Patent Grant
  • 9488126
  • Patent Number
    9,488,126
  • Date Filed
    Wednesday, July 4, 2012
    12 years ago
  • Date Issued
    Tuesday, November 8, 2016
    8 years ago
Abstract
A method for producing a cylinder liner surface for a cylinder crankcase of an internal combustion engine has the following method steps: (a) preliminary honing of the inner surface of a cylinder liner consisting of a cast iron material to form depressions in the surface; (b) application of a coating material containing zinc to the honed surface; (c) final honing of the coated surface in such a way that the coating material containing zinc remains only in the depressions formed by the preliminary honing.
Description
CROSS REFERENCE TO RELATED APPLICATIONS

This application is the National Stage of PCT/DE2012/000668 filed on Jul. 4, 2012, which claims priority under 35 U.S.C. §119 of German Application No. 10 2011 106 564.8 filed on Jul. 5, 2011, the disclosures of which are incorporated by reference. The international application under PCT article 21(2) was not published in English.


The present invention relates to a method for the production of a cylinder working surface and to a cylinder liner for a cylinder crankcase of an internal combustion engine.


Cylinder liners are generally produced from a steel material or a cast-iron material. Cylinder liners composed of a cast-iron material are, however, susceptible to corrosion. It is true that it is known to provide the working surfaces of cylinder liners with a corrosion-resistant and abrasion-resistant coating galvanically, for example on the basis of chromium. However, this has a disadvantageous effect on the material costs and on the costs of the production method.


The present invention is therefore based on the task of increasing the corrosion resistance of cylinder liners composed of a cast-iron material. Furthermore, the material—production costs are supposed to be reduced.


The solution consists in a method having the following method steps: (a) pre-honing of the inner surface of a cylinder liner composed of a cast-iron material, with the formation of depressions in the surface; (b) application of a zinc-containing coating material onto the pre-honed surface; (c) finish-honing of the coated surface, in such a manner that the zinc-containing coating material remains only in the depressions formed by means of the pre-honing.


Furthermore, a cylinder liner that can be produced according to the method according to the invention, composed of a cast-iron material, for a cylinder crankcase, is an object of the present invention.


The method according to the invention is characterized in that the protective effect against corrosive attack is achieved by means of a cathodic protective effect. During the corrosion process, zinc is first oxidized in place of the iron contained in the cast-iron material. Only after the zinc contained in the coating has been completely oxidized can a corrosive attack on the iron be observed. In the end result, corrosive damage to the cast-iron material is significantly delayed, and the useful lifetime of the cylinder liner treated according to the invention is significantly increased.


Using the method according to the invention, a coating on the inner surface of the cylinder liner is obtained, in which the zinc-containing coating material remains only in the depressions that were introduced into the surface by means of the pre-honing. Thus, effective corrosion protection is achieved with very little expenditure of coating material.


Advantageous further developments are evident from the dependent claims.


It is practical if the pre-honed surface is coated with a zinc film in step (b), i.e. provided with the zinc-containing coating without any heat effect.


Suitable zinc-containing coating materials for use in step (b) are, in particular, zinc varnishes on an inorganic basis, for example water-based inorganic zinc silicates with zinc powder, which contain at least 92 wt.-% zinc. These zinc varnishes are temperature-resistant up to 600° C. A typical product available on the market is the zinc varnish “Aquazinga” from the Zinga company, Germany.


Preferably, in step (b), the zinc-containing coating is applied by means of a scraping method, in order to guarantee that the depressions introduced into the surface by means of the pre-honing are filled with the coating material as completely as possible.


However, in step (b), the coating material can also be applied by means of thermal spraying, by means of cold-gas spraying, or by means of vacuum suction blasting, using a zinc-containing wire or a zinc-containing powder.


A particularly preferred embodiment of the method according to the invention consists in that after the pre-honing and before the application of the zinc-containing material, pocket-shaped depressions are introduced into the pre-honed surface. Such depressions or “pockets” bring about the result that after finish-honing, a greater amount of zinc-containing coating agent remains on the finished working surface of the cylinder liner, because the zinc-containing coating agent remains not only in the depressions introduced into the surface by means of the pre-honing, but also in the pocket-shaped depressions introduced into the surface subsequent to the pre-honing.


It is practical if the pocket-shaped depressions are introduced into the surface with a maximal depth of 100 μm and/or with a diameter of 30 μm to 50 μm, in order to allow a uniform distribution on the surface.


Preferably, the pocket-shaped depressions are introduced into the surface with an area proportion of 2% to 10%. In this way, an optimal relationship of corrosion protection and consumption of coating material can be achieved.


The pocket-shaped depressions can be introduced into the surface by means of laser beam treatment, for example.







Exemplary embodiments of the present invention will be described in greater detail below.


The inner surface of a cylinder liner composed of a commercially available cast-iron material is worked according to the invention. For this purpose, inner drilling by means of a drilling tool takes place first, in known manner. In this connection, the inside diameter is adjusted to a defined dimension, a defined cylindricity, and a defined roughness. In this way, the inner surface of the cylinder liner is prepared for the subsequent method steps.


In the subsequent method step, the inner surface of the cylinder liner is worked by means of rough honing, using a honing tool, whereby the honing stones of the honing tool remove material from the inner surface of the cylinder liner. In this connection, the precision of the inside diameter is improved in terms of dimension, cylindricity, and roughness. At the same time, defined depressions (“honing grooves”) are introduced into the inner surface of the cylinder liner. The number of depressions, their depth, and their distribution on the inner surface of the cylinder liner can be determined by means of the selection of the grain size of the honing stones, in known manner.


Subsequent to the rough honing, the inner surface of the cylinder liner is coated with a zinc varnish by means of spray application. In this connection, the depressions introduced by the honing tool are filled with the zinc varnish.


After the zinc varnish has hardened, base honing takes place in the next method step. In this connection, the zinc varnish outside of the depressions is removed over the full area, until the material of the cylinder liner has been reached. In the end result, only the zinc varnish that has collected in the depressions remains in the region of the inner surface of the cylinder liner. A defined area proportion of the zinc varnish is adjusted by means of the selection of the grain size of the honing stones and of the amount of the removed material of the cylinder liner. At the same time, the roughness of the inner surface is reduced, and the cylindricity is improved.


In a final method step, plateau honing takes place in known manner, from which plateau-like leveling of the surface structure of the inner surface of the cylinder liner results, as a function of the selected grain size of the honing stones and of the amount of the material removal. Furthermore, the final desired surface proportion of the zinc varnish is adjusted, and the cylindricity is optimized.


The parameters of this working of the inner surface of a cylinder liner, as an example, can be found in Table 1.














TABLE 1






Inner
Rough

Base
Plateau


Parameter
drilling
honing
Coating
honing
honing




















Material
500
200 

50
3


removal,


radial [μm]


Cylindricity
140
12

10
8


[μm]


Coating,


100
15
10


area


proportion


[%]


Roughness Rz
 45
35
 10
5
3


[μm]









In a further exemplary embodiment, an inner surface composed of a cast-iron material is worked as described above. As the single difference, a further surface treatment by means of laser beams takes place after the rough honing and before the coating process, to introduce additional pocket-shaped depressions into the honed inner surface of the cylinder liner.


The parameters of this working of the inner surface of a cylinder liner, as an example, can be seen in Table 2.















TABLE 2






Inner
Rough
Laser

Base
Plateau


Parameter
drilling
honing
treatment
Coating
honing
honing





















Material
500
200


50
3


removal,








radial [μm]








Cylindricity
140
12


10
8


[μm]








Coating,



100
10.5
10


area








proportion








[%]








Roughness Rz
45
35
100
10
5
3


[μm]








Claims
  • 1. A method for the production of a cylinder working surface for a cylinder crankcase housing of an internal combustion engine in which the working surface is protected from corrosion via a cathodic protective effect, comprising the following method steps: (a) pre-honing of the inner surface of a cylinder liner composed of a cast iron material, with the formation of depressions in the surface using a honing tool having honing stones;(b) application of a zinc-containing coating material onto the pre-honed surface;(c) finish-honing of the coated surface, in such a manner that the zinc-containing coating remains only in the depressions formed by means of the pro-honing, such that the remaining zinc coating material forms a cathodic protective effect against corrosive attack on said cast-iron material.
  • 2. The method according to claim 1, wherein in step (b), the pre-honed surface is coated with a zinc film.
  • 3. The method according to claim 1, wherein in step (b), a zinc varnish on an inorganic basis is used.
  • 4. The method according to claim 1, wherein in step (b), the zinc-containing coating is applied by means of a scraping method.
  • 5. The method according to claim 1, wherein in step (b), the coating material is applied by means of thermal spraying, by means of cold-gas spraying, or by means of vacuum suction blasting, using a zinc-containing wire or a zinc-containing powder.
  • 6. The method according to claim 1, wherein between step (a) and step (b), pocket-shaped depressions are introduced into the pre-honed surface.
  • 7. The method according to claim 6, wherein the pocket-shaped depressions cover 2% to 10% of an area of the surface.
  • 8. The method according to claim 6, wherein the pocket-shaped depressions are introduced into the surface using a laser beam method.
  • 9. The method according to claim 6, wherein the pocket-shaped depressions are introduced into the surface with a diameter of 30 μm to 50 μm.
  • 10. The method according to claim 6, wherein the pocket-shaped depressions are introduced into the surface with a maximal depth of 100 μm.
  • 11. Cylinder liner composed of a cast-iron material, for a cylinder crankcase of an internal combustion engine, which can be produced by means of a method according to claim 1.
Priority Claims (1)
Number Date Country Kind
10 2011 106 564 Jul 2011 DE national
PCT Information
Filing Document Filing Date Country Kind 371c Date
PCT/DE2012/000668 7/4/2012 WO 00 1/28/2014
Publishing Document Publishing Date Country Kind
WO2013/004213 1/10/2013 WO A
US Referenced Citations (37)
Number Name Date Kind
2292662 Sanders Aug 1942 A
3165983 Thomas Jan 1965 A
3435502 Morgan et al. Apr 1969 A
3620137 Prasse Nov 1971 A
3720510 Isobe et al. Mar 1973 A
3808955 Hamada et al. May 1974 A
4260658 Erickson Apr 1981 A
4676877 Castillo et al. Jun 1987 A
4774393 Tarumoto et al. Sep 1988 A
5149937 Babel et al. Sep 1992 A
5179994 Kuhn Jan 1993 A
5183025 Jorstad et al. Feb 1993 A
5333668 Jorstad et al. Aug 1994 A
5363821 Rao et al. Nov 1994 A
5549086 Ozawa et al. Aug 1996 A
5655955 Nagel et al. Aug 1997 A
5879816 Mori et al. Mar 1999 A
6622685 Takahashi et al. Sep 2003 B2
6634179 Heinemann et al. Oct 2003 B2
7279227 Obara Oct 2007 B2
7438038 Azevedo et al. Oct 2008 B2
7513236 Miyamoto et al. Apr 2009 B2
8492318 Barbezat et al. Jul 2013 B2
8667945 Sasaki Mar 2014 B2
8869737 Takahashi et al. Oct 2014 B2
20010013401 Fukai et al. Aug 2001 A1
20020025386 Heinemann et al. Feb 2002 A1
20040023078 Rosenflanz Feb 2004 A1
20050191099 Yamaguchi et al. Sep 2005 A1
20050235944 Michioka Oct 2005 A1
20070009669 Miyamoto et al. Jan 2007 A1
20070116886 Refke May 2007 A1
20070143996 Michioka Jun 2007 A1
20090246384 Liao et al. Oct 2009 A1
20090258140 Bucher Oct 2009 A1
20090305917 Tanizawa et al. Dec 2009 A1
20110142384 Hofmann Jun 2011 A1
Foreign Referenced Citations (34)
Number Date Country
1340110 Mar 2002 CN
1341156 Mar 2002 CN
101939462 Jan 2011 CN
28 24 770 Dec 1979 DE
38 13 617 Oct 1989 DE
695 23 215 Apr 2002 DE
10334701 Feb 2005 DE
10 2008 053 642 May 2010 DE
0 040 054 Nov 1981 EP
0 690 250 Jan 1996 EP
1 589 212 Oct 2005 EP
2 361 759 Oct 2001 GB
2 361 982 Nov 2001 GB
S61-144469 Jul 1986 JP
S61-166962 Jul 1986 JP
S62-192534 Aug 1987 JP
S62-253779 Nov 1987 JP
S62-256960 Nov 1987 JP
H02-294423 Dec 1990 JP
H07-83109 Mar 1995 JP
H08-21297 Jan 1996 JP
2002-534634 Oct 2002 JP
2002-534635 Oct 2002 JP
2005-307857 Nov 2005 JP
2007-278090 Oct 2007 JP
2007-284706 Nov 2007 JP
2007-285312 Nov 2007 JP
2009-507159 Feb 2009 JP
2010-255846 Nov 2010 JP
2010-255847 Nov 2010 JP
2011-117079 Jun 2011 JP
2012-500365 Jan 2012 JP
WO 9831850 Jul 1998 WO
0049328 Aug 2000 WO
Non-Patent Literature Citations (6)
Entry
International Search Report of PCT/DE2012/000668, mailed Dec. 6, 2012.
German Search Report dated Feb. 20, 2012 in German Application No. 10 2011 106 564.8 with English translation.
Japanese Office Action dated Mar. 22, 2016 in Japanese Application No. 2014-517452.
English translation of Chinese Office Action issued Dec. 16, 2014 in Chinese Application No. 201280033530.5.
Japanese Office Action dated Mar. 22, 2016 in Japanese Application No. 2014-517452 with English translation.
Japanese Office Action dated Aug. 1, 2016 in Japanese Application No. 2014-517452 with English translation.
Related Publications (1)
Number Date Country
20140144404 A1 May 2014 US