Method for producing a double aerosol device and container therefor

Information

  • Patent Grant
  • 6345739
  • Patent Number
    6,345,739
  • Date Filed
    Monday, August 3, 1998
    26 years ago
  • Date Issued
    Tuesday, February 12, 2002
    23 years ago
Abstract
A process for producing a double dispensing device having a piston (2) functioning a check valve for allowing a gas to move from below to the above the piston, while preventing it from moving from above to below, said process comprising steps of loading a pressurized gas insoluble in a stock solution into a first chamber (N1) to below said piston (2) through a valve (6), allowing said pressurized gas to move into a second chamber (N2) above said piston (process S2), and transferring said pressurized gas in said first chamber (N1) into said second chamber (N2) by similarly loading stock solution into said first chamber (N1) (process S3).
Description




FIELD OF ART




The present invention relates to a process for producing a double dispensing device like an aerosol device and a container therefor, and more particularly, to a process for producing a double dispensing device characterized in steps of loading stock solution or concentrate and pressurized gas, and to a double dispensing container adapted to the process.




BACKGROUND ART




Generally, as known dispensing devices, there are two types of devices, that is, a general type in which stock solution is loaded into a container together with propellant, and a so called “double dispensing device” in which stock solution is loaded into a container, and the stock solution is separated from the propellant by means of a barrier wall such as a piston or an inner bag such that the stock solution is pressurized by the propellant through the barrier wall. The latter is used for loading liquid food or the like which is not preferable to be blended with propellant, or stock solution which might react with propellant when they are blended with each other. As the barrier, a collapsible inner bag or a piston that is movable up and down in the container is used generally. In some devices in which a piston is used as a barrier wall, the upper chamber is loaded with stock solution, and the lower chamber is loaded with propellant (liquefied gas or compressed gas). In another case, the upper chamber is loaded with a pressurized gas and the lower chamber is loaded with a stock solution. The latter case is reasonable, since the pressurized gas is low in specific gravity. However, such type of device needs a tube extending bellow from a dispensing valve (aerosol valve) through the piston. In this case, the piston moves by sliding along the tube and an inner wall of the container.




Further, when a stock solution and propellant are loaded into a container, stock solution which can be loaded under atmospheric pressure is loaded fore in a general case, and pressurized gas is thereafter loaded through a gas-loading-valve or by so-called under-cup-loading. The gas-loading-valve might be provided in a bottom of the container or a mounting cup of the dispensing valve. However, the gas-loading-valve attached separately provides excess cost, and the loading process is troublesome. For example, the above-mentioned passing through the piston is produced by the following steps. That is to say, a pipe-like nozzle is inserted through a tube-inserting hole of a piston, and a stock solution is loaded below the piston thereby lifting the piston by means of pressure or buoyancy. Then, under an unstable state that the piston lifts on the way, a tube fixed to the dispensing valve is inserted through the tube-inserting hole of the piston. Then, a pressurized gas is loaded with under-cup-loading through a gap between the dispensing valve and an opening of the container, and immediately after the gas-loading, the dispensing valve is crimped, or the pressurized gas is loaded through a gas-loading-valve separately provided on the container. Therefore, some gap is required between the tube-inserting hole and the tube, and the propellant might leak through the gap.




Therefore, in such type of dispensing device that propellant is loaded in the lower side of the piston, a gas-loading-valve is necessary to be provided in the bottom of the container. Therefore, high cost is required, the loading work is troublesome, and production efficiency is low. In addition, there is probability of leak through the propellant-loading-valve.




In a case of double dispensing device using an inner bag, the loading process is troublesome when under-cup-loading is employed. Specifically, when a loading valve is attached at a bottom of container, cost is high, and there is probability of leak of propellant.




Further, when compressed gas is employed as propellant, the gas-leak problem among the above-mentioned problems becomes important especially, since the loaded amount of the pressurized gas depends on the volume and the upper bound of pressure, and the propellant cannot be loaded in excess. That is to say, when compressed gas is used, the device is very sensitive to leak of gas not similar to the case of liquefied gas.




The object of the present invention is to provide a process for producing a double dispensing device which is easily loaded and propellant does not easily leak. Another object of the present invention is to provide a double dispensing container to be used go for the process.




DISCLOSURE OF INVENTION




According to the present invention, there is provided a process for producing a double dispensing device, by providing a pressure-transmittable barrier wall to separate an inside of a vessel (or body of container) into a first chamber and a second chamber, a dispensing valve, a passage to connect the dispensing valve with the first chamber, and a check valve means capable of flowing liquid from the first chamber to the second chamber in a pressure vessel; loading pressurized gas substantially insoluble to stock solution into the first chamber from the valve through the passage, and further bringing the pressurized gas to the second chamber through the check valve means; and loading stock solution into the first chamber through the passage from the valve.




At the step of loading a stock solution from the valve, the gas remaining in the first chamber might be forcibly brought to the second chamber by means of a stock solution loaded into the first chamber. The gas remaining in the first chamber might also be discharged through the valve after the step of loading the gas and before the first chamber is loaded with the stock solution. In the step of loading stock solution in the first chamber, it is preferable to load the stock solution so sufficiently that some stock solution overflow the first chamber to the second chamber.




The double dispensing container of the present invention comprises a pressure vessel; a dispensing valve mounted on a top opening of the vessel; a pressure-transmittable barrier wall for separating an inside of the vessel with airtight manner into a first chamber to be loaded with stock solution and a second chamber to be loaded with pressurized gas; a passage for connecting the valve with the first chamber; and a check valve means for enabling movement of gas from first chamber to the second chamber when pressure in the first chamber is higher than that of the second chamber and for preventing movement of gas from the second chamber to the first chamber when pressure in the second chamber is higher than that of the first chamber. However, it is not necessary to seal perfectly the movement in the reverse direction.




The above-mentioned barrier wall might be a piston which separates the inside of the vessel and is slidable in an up-down direction. The piston might be constructed so as to function as the check valve means for enabling gas movement from the first chamber to the second chamber and for preventing reverse movement. In this case, when the lower side is the first chamber, the above-mentioned passage might be a tube for connecting the valve with the first chamber. When the upper side is the first chamber, the valve might be directly connected with the first chamber.




When the piston functions as a check valve means, it is preferable that the periphery of the piston is yieldable elastically toward inside so that the piston can function as a check valve. Further, a stopper is preferably interposed between the vessel or valve and the piston so as to secure some space for the second chamber with a predetermined volume when the piston moves to decrease the volume of the second chamber. The above-mentioned predetermined volume is preferably 30 to 50% of the volume of the vessel. The stopper can be obtained by an inner face of the vessel or a lower face of the valve to be abutted against the piston.




The above-mentioned barrier wall can be made of a collapsible or deformable inner bag of which inside becomes the first chamber. In this case, the inner bag is preferably provided with a check valve at the bottom of the inner bag or the top of the inner bag or at position near the dispensing valve.




Further, the above-mentioned double dispensing container is preferably provided with a means for forcibly connecting the second chamber with the valve or the first chamber when the barrier wall moves or is deformed to reduce the volume of the first chamber. As the forcibly connecting means for the piston-type-device, a through hole in the tube capable of connecting the inside of the tube with the second chamber, or an element capable deforming or piercing the piston, when the piston moves to reduce the volume of the first chamber, can be employed. As a case of the inner-bag-type, an element to pierce the inner bag to connecting the outer side of the inner bag with the inside of the inner bag or the valve, when the inner bag shrinks, can be employed.




In the case of the above-mentioned piston-type double dispensing container with a tube, a dispensing device can be produced by loading a pressurized gas substantially insoluble to a stock solution into the first chamber from the valve through the tube, and loading a stock solution in the first chamber from the valve through the tube with keeping the container in a right-standing posture to provide motion of the pressurized gas in the first chamber to the second chamber.




In a case of piston-type double dispensing container without a tube, a dispensing device can be produced by loading a pressurized gas substantially insoluble to a stock solution into the first chamber from the valve; and loading a stock solution in the first chamber from the valve with keeping the container in an inverted posture to provide motion of the pressurized gas remaining in the first chamber to the second chamber.




In a case of the inner-bag-type double dispensing container with a check valve at a bottom or top portion, a double dispensing device can be produced by loading a pressurized gas substantially insoluble to stock solution from a valve; and loading a stock solution into the first chamber from the valve with keeping the container in a right standing or inverted posture to provide motion of the pressurized gas remaining in the first chamber toward the second chamber.




In any case of double dispensing containers mentioned above, the pressurized gas in the first chamber might be discharged once after the pressurized gas is loaded, and the stock solution therefore might be loaded into the first chamber.




In the process for producing a double dispensing device of the present invention, not similarly to conventional process, pressurized gas is loaded at first, and stock solution is loaded thereafter. That is to say, when the pressurized gas is loaded into the first chamber from a valve through a passage, such as a tube, at first, the first chamber is filled with the pressurized gas with moving or deforming a barrier wall. Then, the pressurized gas in the first chamber moves to the second chamber through the check valve means. At this situation the pressure in the first chamber is the same as the second chamber. Next, as loading a stock solution into the first chamber from the same valve, the first chamber is filled with the stock solution. During the loading of the stock solution, the pressurized gas do not leak from the second chamber to the first chamber due to the function of the check valve means.




In the process of the present invention, contents can be loaded after the dispensing container has been assembled entirely without employing under-cup-loading. Further, since pressurized gas and stock solution can be loaded from the same valve, any additional gas-loading-valve is not necessary at a bottom of the vessel or the like. Further, loading process is easy, and production efficiency is high. Further, after the loading process, the stock solution in the first chamber is interposed between the pressurized gas in the second chamber and the valve. Therefore, the pressurized gas is in a liquid-sealed condition, and the gas is hard to leak. Therefore, it is convenient to use a compressed gas which is sensitive to leak as propellant.




Beside, at a situation that only pressurized gas is loaded, that is, before the stock solution is loaded, it can be easily confirmed whether there is leak or not.




Among the above-mentioned producing processes, when the process in which the pressurized gas remains in the first chamber and is moved to the second chamber as loading stock solution into the first chamber, is employed, the initial loading pressure of the pressurized gas might be low, and gas-discharging step is not necessary.




In contrast with the above-mentioned, the process in which stock solution is loaded after the pressurized gas in the first chamber is discharged through the valve, has an advantage that the container is not required to stand reversely even if the first chamber is upper side of the vessel. Further, when the pressurized gas is discharged from the first chamber, the pressurized gas is hard to leak from the second chamber to the first chamber by virtue of the function of check valve means.




In the piston-type double dispensing container of the present invention, the pressurized gas can smoothly move from the first chamber to the second chamber since a piston functions as a check valve. Therefore, by loading stock solution into the first chamber with keeping the container in a right stand posture, in which the first chamber to be loaded with stock solution is lower side, or in an inverted posture, only the pressurized gas can be easily loaded into the second chamber through the piston capable of functioning as a check valve. The dispensing container having a stopper for securing a predetermined space at end of stroke of the piston has advantage that the pressurized gas can securely move to the second chamber.




In the inner-bag-type double dispensing device of the present invention, by loading stock solution with the container standing in right or inverted posture in dependent to the position of the check valve, only the pressurized gas can be easily moved to the second chamber through the check valve. Further, in the double dispensing container with means for forcibly connecting, the second chamber is connected with the first chamber or the dispensing valve when the stock solution is used up. Therefore, the pressurized gas remaining in the second chamber can be exhausted outward through the first chamber and the dispensing valve. Therefore, the interior pressure can be reduced before the container is abandoned, and the container can be safely abandoned.











Hereinafter, referring to the attached drawings, the process for producing a double dispensing device and a double dispensing container used therefor of the present invention will be explained.




BRIEF DESCRIPTION OF DRAWINGS





FIG. 1

is a process drawing showing an embodiment of the process for producing a dispensing device of the present invention.





FIG. 2

is a sectional view showing an embodiment of the dispensing container of the present invention to be used for the process.




FIG.


3


and

FIG. 4

are sectional views showing another embodiments of the dispensing device of the present invention, respectively.





FIGS. 5

to


7


are process drawings showing another embodiment of the producing process of the present invention.





FIG. 8



a


is a sectional view in part showing another embodiment of the dispensing container of the present invention, and

FIG. 8



b


is a sectional view in part showing an operating state thereof.




FIG.


9


and

FIG. 10

are sectional views in part showing further another embodiments of the dispensing container of the present invention, respectively.





FIG. 11



a


is a sectional view in part showing another embodiment of the dispensing container of the present invention, and





FIG. 11



b


is a sectional view along line XI—XI thereof.





FIGS. 12

,


13


,


14


and


15


are sectional views in part showing further another embodiments of the present invention.





FIGS. 16

,


17


and


18


are process drawings showing further another embodiment of the producing process of the present invention.





FIG. 19

is a sectional view showing another embodiment of an inner bag relating to the present invention.





FIG. 20

is a sectional view showing another embodiment of a check valve relating to the present invention.











BEST MODE FOR CARRYING OUT THE INVENTION




At first, referring to

FIG. 2

, an embodiment of a dispensing container will be explained. The dispensing container A has a vessel


1


, a piston


2


housed therein movably up and down as a barrier wall, a tube


4


inserted in a hole


3


formed in the center of the piston


2


and a dispensing valve (hereinafter, referred to merely as “valve”)


6


which is connected to an upper end of the tube


4


and closes an upper opening


5


of the vessel


1


. The vessel


1


is a known deep-drawn can having a trunk


7


, shoulder


8


and a dome-like bottom


9


formed as one body. The vessel


1


can be produced of an aluminium sheet for example. In addition to the deep drawn can, a vessel assembled by a trunk made of a cylindrically curled steel sheet, a bottom part and a shoulder part can be employed. Further another vessel made of synthetic resin or glass can also be used.




The inside of the vessel


1


is separated by the piston


2


into the lower first chamber (stock solution chamber) N


1


and the upper second chamber (pressurized gas chamber) N


2


. As the piston


2


moving up and down, volumes of the chambers N


1


, N


2


vary.




The piston


2


has a bottom plate


10


having a dome shape according to the shape of bottom


9


of the vessel


1


, a side wall


11


rising from the periphery thereof, a boss


12


provided on the center of the bottom plate


10


, and rib plates


13


connecting the side wall to the upper end of the boss, so as to form a cup-like shape with upper opening. The center of boss


12


is formed with the above-mentioned hole


3


. The side wall


11


slides along an inner surface of the vessel


1


and is elastically bendable. The free end or upper end of the side wall


11


can be elastically deformed inwardly in some extent, so that the side wall


11


can function as a check valve to allow motion of gas from the first chamber N


1


under the piston


2


to the second chamber N


2


, but not easily allow the motion of gas in the opposite direction. Beside, the boss


12


can be formed so that a gap between the boss


12


and the tube


14


functions as a check valve. The above-mentioned side wall


11


abuts against the lower face of the shoulder


8


of the vessel


1


when the piston


2


lifts up so that the piston cannot move upward further. That is, the side wall


11


functions as a stopper.




The above-mentioned piston


2


can be made of synthetic resin such as polyethylene, polypropylene, polyacetal, polyamide(nylon), polyvinyl chloride, ethylen-vinyl acetate copolymer(EVER), poleythylene terephthalate, and the like, especially engineering plastic, synthetic resin elastmer, rubber such as NBR (butadien-acrylonitrile rubber), or composition thereof or combination thereof. Further, the piston can be made by combining some parts or members. Each part might be made of sole material or some materials.




The above-mentioned valve


6


has been known. The valve


6


has a mounting cup


15


, a housing


16


held by the mounting cup


15


, a stem


17


housed in the housing


16


movably in up-down direction, a spring


18


for urging the stem upward, a gasket


19


interposed between the housing and the mounting cup, another gasket


21


to be attached in periphery of the mounting cup


15


for sealing between the mounting cup and a bead


20


of the vessel


1


, and the like.




The above-mentioned tube


4


can be made of a synthetic resin similar to the piston


2


and is preferably bendable elastically in some extent. However, a hard tube without bendability also can be used. The tube


4


is attached to the lower end of the housing


16


and functions as a passage to connect the inside of the housing to the first chamber N


1


under the piston


2


.




The above-mentioned dispensing container A can be produced as explained hereinafter, for example. At first, referring to step S


1


in

FIG. 1

, a piston


2


is inserted into the inside of a vessel


1


of which shoulder


8


is not formed as shown by imaginary line


8




a.


Then, the upper portion of the vessel


1


is drawn as shown by arrow mark H to form a shoulder


8


. Further, the cylindrical upper end portion is curled to form a bead


20


. Then, as inserting a tube


4


into a hole


3


of the piston


3


as shown by arrow mark J, the dispesing valve


6


is mounted on the bead


20


. Further, the mounting cup


15


of the valve


6


is crimped against the bead


20


to joint to the vessel as one body. By those steps, a dispensing container A before loading of stock solution and propellant is produced.




Hereinafter, referring to

FIG. 1

, a process for producing a dispensing device by loading pressurized gas and stock solution into the empty dispensing container A will be explained. In

FIG. 1

, Si shows the above-mentioned step for assembling a dispencing container A, and S


2


and S


3


are a step for loading pressurized gas and a step for loading stock solution, respectively. The pressurized-gas-loading step S


2


is a step for injecting pressurized gas into the first chamber N


1


from the valve


6


through the tube


4


to fill the first chamber with the pressurized gas. As loading of the pressurized gas proceeds, the piston


2


lifts with compressing the second chamber N


2


, and further, the piston makes the pressurized gas to move into the second chamber gradually by means of the check valve function. In this situation, the side wall


11


functions as a stopper. The air in the vessel


1


might be remained in this step. However, the remaining air might be discharged. Such discharge of air can be performed by means of vacuum discharging in accordance with well known method when the valve is crimped on the vessel, or by opening the valve and sucking with vacuum from the stem after crimping of the valve. In such case that the pressurized gas to be loaded is air, it is not necessary to discharge the remaining air in the vessel


1


. In general case, the piston is stopped when the side wall


11


abuts against the lower face of the shoulder


8


of the vessel


1


, and a part of the pressurized gas moves to the second chamber N


2


side through a gap between the piston


2


and the vessel


1


.




Next, at the stock-solution-loading step S


3


, stock solution is loaded from the valve


6


through the tube


4


. The stock solution is forcibly loaded under pressure against the pressure of the pressurized gas. Then, the stock solution pushes out the pressurized gas from the first chamber, and then the stock solution fills the first chamber with replacing the pressurized gas.




The stock solution is preferably sufficiently loaded so as to leak slightly to the second chamber N


2


, such that the pressurized gas cannot remain in the first chamber N


1


. Thus, a dispencing device B is completed.




As the above-mentioned pressurized gas, gas which substantially insoluble to the stock solution is employed. For example, compessed gas of nitrogen (N


2


), carbon dioxide (CO


2


), air, oxygen (O


2


), argon (Ar


2


), and the like can be employed. Liquefied gas is not used usually. As the stock solution, liquid such as aqueous solution, alcoholic solution, and the like, semi-solid material such as creamy food, toothpaste, and the like can be employed. The ratio of pressurized gas and the stock solution is in an extent about 30:70-50:50, preferably 35:65-45:55 in volume ratio. In the above-mentioned embodiments, the height of the side wall


11


of piston


2


, which functions as a stopper, is preferably determined according to the loading ratio.




As described above, in the producing process of the present invention, inversely to a conventional process, pressurized gas is loaded at first, and stock solution is loaded thereafter. And the pressurized gas and the stock solution are loaded from the same valve


6


. Therefore, the loading work is easy, and separated gas-loading-valve is not necessary. The dispensing device B produced as mentioned above can be used similarly to a conventional device. That is to say, when the first chamber N


1


is opened by pushing a push button (reference mark


22


in FIG.


2


), the pressurized gas in the second chamber N


2


press the stock solution in the first chamber N


1


through the piston


2


. Then, the stock solution can be released through the tube


4


and a nozzle or spout of the push button


22


.




In the above-mentioned embodiment, the side wall


11


of the piston


2


is abutted against the lower face of the shoulder


8


of the vessel


1


so as to function as a stopper. However, as shown in

FIG. 3

, the boss


12


might be extended over the side wall


11


so that the boss


12


can be used as a stopper for abutting against the lower end of the valve. Beside, as shown in

FIG. 3

, the vessel


1


might be made by assembling a curled trunk


7


, a bottom


9


and a shoulder produced separately. In such case, the piston


2


can be inserted from a bottom side opening, and the bottom


9


can be fixed by curling to the trunk thereafter.




Beside, in the above-mentioned embodiment, the piston


2


has a cup-like shape which opens upward. However, shape of the piston is not limited in the dispensing container of the present invention. As shown in

FIG. 4

, the piston


2


can be formed to a hollow float. In this case, permeation of the contents through the piston can be sufficiently prevented. In the piston


2


of

FIG. 4

, the upper plate


13


has a bowl-like shape so as not to interact with the valve when the piston


2


lifts up.




In the above-mentioned embodiment, the pressurized gas is loaded at the upper side, and the stock solution is loaded at the lower side chamber N


1


. However, as shown in

FIG. 5

, the upper side can be a first chamber N


1


to be filled with stock solution, and the lower side can be a second chamber N


2


to be filled with pressurized gas.

FIG. 5

shows an embodiment of a process for producing such dispensing device. This producing process, similarly to the case of

FIG. 1

, comprises a container-assembling step S


1


, a pressurized-gas-loaded step S


2


and a stock-solution-loading step S


3


.




The dispensing container does not need any tube (


4


in FIG.


1


). The piston


2


is inserted with an inverted posture upside down. Therefore, the piston


2


has check valve function to allow flow of fluid from the upper first chamber N


1


to the lower second chamber N


2


, but restrict the flow in the inverse direction. In this case, the side wall


11


of the piston can also function as a stopper for securing volume of the second chamber N


2


.




The container-assembling step S


1


and the pressurized-gas-loaded step S


2


are the same as the case of FIG.


1


. However, in the stock solution loading step S


3


, the stock solution is loaded with setting the container upside down, since the pressurized gas should be moved before the stock solution reach to the second chamber N


2


. This is different point from the case of FIG.


1


. The stock solution loading step S


3


in

FIG. 5

shows a state of half way of the loading. At last, the first chamber N


1


is sufficiently filled with stock solution so that the stock solution rather overflow to the second chamber N


2


. Beside, the lower plate


11


of the piston is preferably curved to project upward (downward in step S


3


) so that the pressurized gas remaining in the first chamber N


1


is reduced as far as possible.




In the above-mentioned embodiments, a piston


2


is employed as a barrier wall. However, as shown in FIG.


6


and

FIG. 7

, a known deformable inner bag


23


can also be employed as a barrier wall. In the embodiment of

FIG. 6

, the inner bag


23


is made of two sheets or films of which peripheries are welded, heat sealed or adhered with each other to form a bag. The inner bag


23


is fixed to a valve


6


having a tubular portion


24


extending downward. The tubular portion


24


is sandwiched between sheets of the inner bag


23


. However, another shape of inner bag can be employed. For example, an inner bag having a periphery or flange around an opening to be crimped on an bead


20


around an opening


5


of the vessel together with a mounting cup


15


, can be employed. A mono-film synthetic resin, a laminated film of synthetic resin films, a laminated film of a synthetic resin film and a metal foil, and the like can be used for the sheet of the inner bag


23


. If demanded, a container made of thin metal sheet, for example 0.2-0.4 mm in thickness, which is collapsible under pressure, can be employed.




In this embodiment of dispensing container, the inner bag


23


is provided with a check valve


25


at the upper end thereof. The check valve


25


allows the flow of fluid from the inside of the inner bag


23


(first chamber N


1


) to the out side (second chamber N


2


) which is a space between the inner bag


23


and the vessel


1


, but does not allow the inverse flow substantially from the out side to the inside. In this case, the flow from the out side to the inside might be in an extent merely to be resisted by the check valve. It is preferable to attach a tube


4


to the tubular portion


24


of the valve


6


so that the stock solution can fill the inner bag


23


gradually from the bottom side thereof.




As shown at the container-assembling step Si, the inner bag


23


is folded along longitudinal lines when the bag is inserted into the vessel


1


and is expanded at the inside of the vessel


1


. By crimping the mounting cup


15


on the bead


20


of the vessel


1


under this situation, a container is completely assembled.




At the pressurized-gas-loading step S


2


, pressurized gas is loaded from the stem


17


into the first chamber N


1


in the inner bag to expand the inner bag, and further the pressurized gas is also loaded in the second chamber N


2


between the inner bag


23


and the vessel


1


through the check valve


25


. In this case, the pressure in the vessel


1


becomes 5-12 kgf/cm


2


for example. However, since the inside and the out side of the inner bag


23


are balanced in pressure, the inner bag


23


is not broken.




Next, at the stock-solution-loading step S


3


, stock solution is charged from the same stem


17


under pressure. Therefore, the pressurized gas in the inner bag


23


moves to the second chamber N


2


through the check valve


25


, and the inner bag


23


is filled with the stock solution without pressurized gas. In this case, it is preferable that the stock solution overflow slightly to the second chamber N


2


.




A dispensing container shown in

FIG. 7

has a check valve


25


at the lower end of the inner bag


23


and is not provided with any tube. The remaining construction is substantially the same as that of FIG.


6


. In this embodiment, when the stock-solution-loading step S


3


, the container is kept upside down so that only pressurized gas moves to the second chamber N


2


through the check valve


25


.




The check valve


25


can be obtained, for example, by forming a through hole


25




b


in the side wall of the tubular portion


25




a


having a closed end, and by fitting an elastically deformable tube


25




c


around the tubular portion


25




a.


Further, a known check valve having a ball urged by a spring can also be employed.




The dispensing device assembled as mentioned above is completed at last by mounting a push button or spout on the stem


17


. By pushing the push button of the obtained dispensing device B to open the valve


6


, the stock solution in the inner bag


23


pressurized by the pressurized gas in the second chamber N


2


can be released through the nozzle or the like of the push button.




In any embodiment mentioned above, since the pressurized gas in the second chamber N


2


is sealed by the stock solution in the first chamber N


1


by means of “liquid seal”, sealing effect is high. Therefore, the device is especially advantageous for a dispensing device in which compressed gas sensitive to leakage is used as a propellant. However, when the pressurized gas is discharged in order to reduce the inner pressure of a used container for safe abandonment, the good seal function is inconvenient on the contrary. Then, it is preferable to provide a forcibly-connecting-means capable of automatically cancelling the seal function of the barrier wall when the container is used entirely.





FIG. 8



a


shows a type of dispensing container in which a first chamber for stock solution under a piston is connected with a valve through a tube. The tube


4


is slightly short such that the lower end of the tube


4


comes out of a boss


12


of the piston


2


when the piston as a barrier wall reaches the bottom. Therefore, when the stock solution is used almost entirely, the second Ad chamber N


2


is connected with inside of the tube


4


. Then the pressurized gas can be discharged through the valve


6


. Therefore, the device can be thrown away safely with reduced inner pressure. Further, the device is preferably provided with a temporary stopping leg


26


such as a coil spring or the like between a bottom


9


of the vessel


1


and a lower plate


10


of the piston


2


such that the piston


2


does not slip off the tube


4


before loading of pressurized gas. The temporary stopping leg


26


has such strength (repulsing force of spring in this embodiment) that the piston


2


can be prevented from slipping off the tube


4


, and the piston


2


can slip off the tube


4


by means of pressure of the pressurized gas when the stock solution is used almost entirely by using up the dispensing device.




In addition to a spring with predetermined repulsive force, such temporary-stopping leg


26


can be made of a leg or legs extending downward from periphery of the piston, capable of being broken with predetermined compressive force, or the like.





FIG. 9

shows a dispensing container similar to the dispensing containers of

FIG. 8



a


and


8




b.


In this embodiment, a tube


4


having a through hole


27


formed at a half way instead of the above-mentioned short tube. In this dispensing container, when the stock solution is used up and the piston comes to the bottom, the second chamber N


2


is connected with the inside of the tube


4


. The dispensing container is also preferably provided with a temporary-stopping leg


26


.





FIG. 10

shows another embodiment of forcibly connecting means having a pin or spike


28


fixed at the bottom


9


of the vessel


1


so as to direct upward. In this embodiment, when the piston


2


as a barrier wall comes to the bottom, the spike


28


can break through the lower plate


10


of the piston


2


to connect the first chamber N


1


to the second chamber N


2


. This embodiment is also preferably provided with a temporary-stopping leg similar to a temporary-stopping leg


26


as seen in

FIG. 8



a


and the like.




Further, another type of forcibly connecting means can be obtained by providing a projection or the like at a trunk, a bottom or a shoulder of the vessel


1


. The projection can engage with the piston to deform the piston


2


so as to cancel the seal function of the piston


2


.





FIG. 11



a


shows one of the embodiments of such type of dispensing container. In this embodiment, a first chamber N


1


for stock solution is set at the upper side of piston


2


, and the trunk of the vessel


1


is provided with a rib or ribs (see

FIG. 11



b


)


29


projecting inward at the upper portion of the trunk. In this embodiment, when the stock solution is used up and the piston comes to the upper end, the side wall


11


of the piston runs on the ribs


29


to be deformed. Therefore, seal function is released and the first chamber N


1


is connected with the second chamber N


2


. As shown by imaginary lines in FIG. lla, the piston


2


might be provided with an extending portion


30


at the upper end thereof, which abuts with the shoulder


8


of the vessel


1


and deforms the piston so as to connect the first chamber N


1


to the second chamber N


2


when the piston


2


lifts to the upper end.





FIG. 12

shows a type of dispensing container in which stock solution is loaded in the upper side of the piston


2


. In this container, a valve


6


has a hard tube or tubular portion


24


at the lower side thereof, and a sharp edge


31


is formed at the lower end of the tubular portion


24


. In addition, a lower plate


10


of the piston


2


has a thin portion


32


to be broken by the sharp edge


31


. Therefore, when the piston goes to the upper end, the second chamber N


2


is connected with the inside of the tube


4


through the tube


4


piercing through the piston


2


.





FIG. 13

shows a dispensing device having an inner bag


23


and a tube or tubular portion


24


at the lower side of the valve


6


. The tubular portion


24


has spikes


33


projecting in the side directions. In this embodiment, when the stock solution in the inner bag


23


is used up, the inner bag


23


is broken by the spikes


33


, and the first chamber N


1


is connected with the second chamber N


2


. In stead of the spikes


33


, a tubular projection with sharp edge at the free end thereof might be employed. In this embodiment, when the inner bag


23


is broken, the second chamber N


2


is directly connected to the inside of the tube


4


. Those forcibly connecting means can be applied not only to a dispensing container having a check valve at the upper side of the inner bag


23


, but also to a dispensing container having a check valve at the lower side of the inner bag.





FIG. 14

shows an embodiment of a dispensing container similar to the dispensing container of FIG.


2


. This embodiment has a piston


2


provided with a check valve


34


, which can function as a forcibly connecting means, at a lower plate


10


thereof. The check valve


34


has a hole


35


through a lower plate


10


of the piston


2


, a valve body


36


and a spring


37


for urging the valve body


36


toward the lower plate


10


side. The valve body


36


has a seat


36




a


for closing the hole


35


from the second chamber N


2


side and a shaft


36




b


projecting to the first chamber N


1


side through the hole


35


. The check valve


34


functions as a check valve for allowing the flow of fluid from the first chamber N


1


to the second chamber N


2


in ordinary case. In addition, when the piston goes to the bottom


9


of the vessel


1


, the shaft


36




b


of the valve body


36


abuts against the bottom


9


so as to lift the valve body


36


and to connect the first chamber N


1


to the second chamber N


2


. Therefore, in this situation, the check valve


34


functions as a forcibly connecting means.





FIG. 15

shows a dispensing device similar to the dispensing device of FIG.


2


. In this embodiment, the piston


2


has a lower plate made of a dome-like thin plate projecting upward and deformable in the inverse direction. The piston


2


has a boss


12


projecting downward from the center of the thin plate. In addition, the bottom


9


of the vessel I is provided with an abutting member


38


at periphery thereof capable of abutting with the lower periphery of the piston


2


. Therefore, when the piston reaches the bottom, the lower periphery thereof abuts with the abutting member


38


at the bottom


9


of the vessel


1


, and the lower plate


10


is deformed to project downward. Therefore, a gap is generated between the side wall


11


and the trunk


7


of the vessel


1


, and the first chamber N


1


is connected to the second chamber N


2


. Therefore, this member is also a forcibly connecting means.




Hereinafter, referring to

FIGS. 16 through 18

, another embodiment of the process for producing a dispensing device of the present invention will be explained. Those embodiments have a step S


2


A for sucking or discharging pressurized gas from the first chamber N


1


after a pressurized-gas-loading step S


2


and before a stock-solution-loading step S


3


, not similar to the above-mentioned producing process.




In the process of

FIG. 16

, a dispensing container substantially same as

FIG. 1

is employed. Therefore, if the same stock solution and the same pressurized gas are used, the same dispensing device can be obtained.




The left end step Si in

FIG. 16

is a step for assembling a container in which a piston


2


, a tube


4


and a valve


6


are assembled to a vessel


1


substantially same as FIG.


1


. Sequentially to the step, pressurized-gas-loading step S


2


for loading pressurized gas into the first chamber N


1


through a valve


6


and a tube


4


, and further into the second chamber N


2


, is performed. In this embodiment, the pressure of the pressurized gas loaded at the step S


2


is higher than the case of

FIG. 1






Then, pressurized-gas-discharging step S


2


A for discharging the pressurized gas from the first chamber N


1


is performed. In this step S


2


A, the pressurized gas can be collected in a bomb for example through a valve by decreasing the loading pressure lower than the pressure in the container. Further, in a case that the pressurized gas is safe gas such as air, the pressurized gas can be discharged into the atmosphere. In addition, a vacuum can suck the gas from the first chamber N


1


. In any case, only the pressurized gas in the first chamber N


1


is discharged, and the pressurized gas in the second chamber N


2


is not discharged by virtue of the function of the check valve. Then, the piston


2


goes down by means of pressure of the pressurized gas remaining in the second chamber N


2


, and the volume of the first chamber N


1


becomes about O as shown in the step S


2


A in the drawing.




Under the situation, a stock-solution-loading step S


3


for loading stock solution through the valve is performed. This step is the same as the case of FIG.


1


. When the step is completed, a dispensing device B which is substantially same as the case of

FIG. 1

is obtained. Though this embodiment requires an additional pressurized-gas-discharging step S


2


A in contrast with the case of

FIG. 1

, there is an advantage that the pressurized gas is not easily blended in the stock solution. However, merit of the process of this embodiment is further realized for a piston-type dispensing device having a second chamber at lower side and a first chamber at upper side as explained hereinafter.




In the producing process of

FIG. 17

, at first, a container-assembling step S


1


is performed with using the same vessel


1


, piston


2


and valve


6


as the producing process shown in FIG.


5


. Then, a pressurized-gas-loading step S


2


is performed. Though those steps are the same as the case of

FIG. 5

, pressure of the pressurized gas is higher. Then, a pressurized-gas-discharging step S


2


A is performed. By this step, the pressurized gas in the first chamber N


1


is discharged, and the pressurized gas remains only in the second chamber by means of the check-valve-function of the piston


2


. By means of the pressure of the remaining pressurized gas, the piston is lifted to the upper end, and the volume of the first chamber N


1


becomes about O.




Then a step S


3


for loading stock solution into he first chamber N


1


is performed. It is not necessary to urn the vessel


1


upside down in contrast to the case of

FIG. 5

, since pressurized gas do not remain in the first chamber. As mentioned above, in the embodiment, step and apparatus for turning over the vessel during process are not required, and process control is simplified greatly.





FIG. 18

shows an embodiment of process for producing an inner-bag-type double dispensing device, to which the process having a pressurized-gas-discharging step S


2


A is applied. That is to say, as same as the process of

FIG. 7

, a step S


1


for assembling as inner bag


23


with a check valve at the lower end and a valve


6


to a vessel


1


is performed. Then, a step S


2


for loading pressurized gas into the first chamber N


1


in the inner bag


23


through the valve


6


, and for loading the pressurized gas into the second chamber N


2


through the check valve


25


at the same time, is performed.




Next, a step S


2


A for discharging the pressurized gas from the first chamber N


1


through the valve


6


is performed. In this situation, the pressurized gas in the second chamber N


2


is not discharged by means of the function of the check valve


25


, and the pressurized gas still remain only in the second chamber N


2


. Therefore, the inner bag


23


is folded as same as the initially inserted state (step. S), and volume of the inner bag becomes about O.




Next, in the step S


3


, stock solution is loaded into the inner bag


23


through the valve


6


. In this situation, since no pressurized gas remain in the inner bag


23


, it is not necessary to return the vessel


1


upside down.




The producing process with pressurized-gas-discharging step can also be applied to the dispensing device having a check valve


25


at the upper side of the inner bag. Though the check valve


25


is provided at the upper side of the inner bag


23


, the process is the same as the process of

FIG. 18

substantially. Therefore, the process is not shown with drawings.




The inner bag


23


used in the producing process of

FIG. 18

has a flange


40


to be engaged with a bead


20


or curled portion at upper end thereof, which is not similar to the case of

FIGS. 6 and 7

. In addition, as seen in

FIG. 19

the inner bag


31


can shrink along longitudinal folding lines


41


which project outward and inward alternately as shown by real line, and the inner bag can be expanded with inner pressure as shown by imaginary lines


23


. Such inner bag


23


can be produced by blow-moulding, for example. The check valve


25


is the same as the case of

FIGS. 6 and 7

substantially, and can be constructed by a tubular projection


42


projecting from the bottom of the inner bag


23


and a tube


43


elastically fit around the projection


42


.




As seen, for example, in

FIG. 20

, the tube


43


is made of rubber or the like and is elastically deformable. The tube


43


is preferably engaged with a step portion


44


formed at the lower portion of the projection


42


. The tubular projection


42


has a side wall formed with a through hole


45


.




In the process for producing a dispensing device of the present invention, steps for loading pressurized gas and stock solution are easy, and it is not necessary to provide any excess gas-loading valve.




By using the dispensing container of the present invention, the above-mentioned process can be easily performed. The dispensing container has a good sealing function of the second chamber filled with pressurized gas.




In addition, in the dispensing device with a forcibly connecting means, inner pressure can be easily lowered after the container is used up entirely.



Claims
  • 1. A process for producing a double dispensing device;by providing a pressure-transmittable barrier wall to separate an inside of a vessel into a first chamber and a second chamber, a dispensing valve, a passage to connect the dispensing valve with the first chamber, and a check valve means capable of flowing fluid from the first chamber to the second chamber in a pressure vessel; loading pressurized gas substantially insoluble to stock solution into the first chamber from the valve through the passage, and further bringing the pressurized gas to the second chamber through the check valve means; and loading stock solution into the first chamber through the passage from the valve.
  • 2. The producing process of claim 1, wherein:at the step of loading stock solution from the valve, the gas remaining in the first chamber is forcibly brought to the second chamber by means of a stock solution loaded into the first chamber.
  • 3. The producing process of claim 1, wherein:the gas remaining in the first chamber is discharged through the valve after the step of loading the gas; and thereafter, the first chamber is loaded with the stock solution.
  • 4. The producing process of claim 1, wherein,in the step of loading stock solution in the first chamber, the stock solution is loaded so sufficiently that some stock solution overflow the first chamber to the second chamber.
  • 5. A double dispensing container comprising:a pressure vessel: a dispensing valve mounted on a top opening of the vessel; a pressure-transmittable barrier wall for separating an inside of the vessel with airtight manner into a first chamber to be loaded with stock solution and a second chamber to be loaded with pressurized gas; a passage for connecting the valve with the first chamber; and a check valve means for enabling movement of gas from first chamber to the second chamber when pressure in the first chamber is higher than that of the second chamber and for preventing movement of gas from the second chamber to the first chamber when pressure in the second chamber is higher than that of the first chamber.
  • 6. The double dispensing container of claim 5, wherein:the barrier wall is a piston which separates the inside of the vessel and is slidable in up-down direction; and the piston is constructed so as to function as the check valve means for enabling gas movement from the first chamber to the second chamber and for preventing reverse movement.
  • 7. The double dispensing container of claim 6, wherein:the first chamber is placed at lower side of the piston; and the passage is a tube for connecting the valve with the first chamber.
  • 8. A process for producing a dispensing device,by loading pressurized gas substantially insoluble to stock solution into the first chamber of the double dispensing container of claim 7 from the valve thereof; and loading stock solution into the first chamber from the valve through the tube with keeping the container in a standing posture upside down, to provide motion of the pressurized gas in the first chamber to the second chamber.
  • 9. The double dispensing container of claim 6, wherein:the first chamber is placed at upper side of the piston; and the valve is directly connected with the first chamber.
  • 10. The double dispensing container of claim 6, wherein:a periphery of the piston is yieldable elastically toward inside so that the piston can function as a check valve.
  • 11. The double dispensing container of claim 6, wherein:a stopper is interposed between the vessel and the piston so as to secure some space for the second chamber with a predetermined volume when the piston moves to decrease the volume of the second chamber.
  • 12. The double dispensing container of claim 11, wherein:the predetermined volume is 30 to 50% of the volume of the vessel.
  • 13. The double dispensing container of claim 11, wherein:the stopper is obtained by an inner face of the vessel to be abutted against the piston.
  • 14. The double dispensing container of claim 11, wherein:the stopper is obtained by a lower face of the valve to be abutted against the piston.
  • 15. The double dispensing container of claim 6, further comprising a means for forcibly connecting the second chamber with the valve or the first chamber by deforming or piercing the piston, when the piston moves to reduce the volume of the first chamber.
  • 16. The double dispensing container of claim 11, wherein:a stopper is interposed between the valve and the piston so as to secure some space for the second chamber with a predetermined volume when the piston moves to decrease the volume of the second chamber.
  • 17. The double dispensing container of claim 16, wherein:the predetermined volume is 30 to 50% of the volume of the vessel.
  • 18. The double dispensing container of claim 5, wherein:the barrier wall is made of a collapsible or deformable inner bag of which inside becomes the first chamber; and the inner bag is provided with a check valve.
  • 19. The double dispensing container of claim 18, wherein:the check valve is placed at the bottom of the inner bag.
  • 20. A process for producing a dispensing device,by loading pressurized gas substantially insoluble to stock solution into the inner bag from a valve of the double dispensing container of claim 19; and loading a stock solution into the inner bag from the valve with keeping the container in a standing posture upside down to provide motion of the pressurized gas remaining in the inner bag toward the second chamber between the pressure vessel and the inner bag.
  • 21. The double dispensing container of claim 18, wherein:the check valve is placed at top of the inner bag or at position near the dispensing valve.
  • 22. The double dispensing container of claim 18, further comprising a forcibly connecting means for connecting an out side of the inner bag and an inner side of the inner bag or the valve by piercing the inner bag when the inner bag shrinks.
  • 23. The double dispensing container of claim 5, further comprising a means for forcibly connecting the second chamber with the valve or the first chamber when the barrier wall moves or is deformed to reduce the volume of the first chamber.
PCT Information
Filing Document Filing Date Country Kind
PCT/JP96/00245 WO 00
Publishing Document Publishing Date Country Kind
WO97/28068 8/7/1997 WO A
US Referenced Citations (8)
Number Name Date Kind
3099370 Hein Jul 1963 A
3961725 Clark Jun 1976 A
4867208 Fitzgerald et al. Sep 1989 A
5065900 Scheindel Nov 1991 A
5178300 Haviv et al. Jan 1993 A
5179982 Berube et al. Jan 1993 A
5775549 De Laforcade Jul 1998 A
5878922 Boring Mar 1999 A