A method for producing a radiation-emitting semiconductor body, and a radiation-emitting semiconductor body, are specified.
Radiation-emitting semiconductor bodies are specified for example in the publication DE 10 2010 047 451 A1.
The aim is to specify an improved radiation-emitting semi-conductor body which is set up to generate electromagnetic radiation of different wavelength ranges. A further aim is to specify a simplified method for producing a radiation-emitting semiconductor body of this kind.
These objects are achieved by a method having the steps of claim 1 and by a radiation-emitting semiconductor body having the features of claim 10.
Advantageous embodiments and developments of the method and of the radiation-emitting semiconductor body are specified in the dependent claims.
According to one embodiment of the method for producing a radiation-emitting semiconductor body, a growth substrate having a main face is first provided.
According to a further embodiment of the method, a multiplicity of distributor structures are generated on the main face of the growth substrate.
According to a further embodiment of the method, a compound semiconductor material is deposited epitaxially on the main face of the growth substrate, wherein the epitaxial growth of the compound semiconductor material varies along the main face because of the distributor structures, and so the epitaxial depositing produces an epitaxial semiconductor layer sequence having at least a first emitter region and a second emitter region on the main face. More preferably the distributor structures take the form of nongrowth areas, to which no homogeneously epitaxially deposited material is applied.
The compound semiconductor material comprises at least two different chemical elements. The compound semiconductor material is for example a III/V semiconductor material or a II/VI semiconductor material. A III/V compound semiconductor material in this case comprises at least one chemical element from the third group of the periodic table and at least one chemical element from the fifth group of the periodic table. A II/VI compound semiconductor material, conversely, comprises at least one chemical element from the second group of the periodic table and at least one chemical element from the sixth group of the periodic table.
The distributor structures are set up to vary the epitaxial growth of the semiconductor layer sequence along the main face. Properties of the epitaxial semiconductor layer sequence thus deposited are, in other words, different along the main face of the growth substrate. For example, a thickness or a chemical composition of the epitaxial semiconductor layer sequence varies along the main face. In general the epitaxial semi-conductor layer sequence is formed completely on regions of the main face that are free from the distributor structures. In other words, the main face is initially covered completely with the epitaxial semiconductor layer sequence, except for the regions in which the distributor structures are disposed.
According to a further embodiment of the method, the first emitter region and the second emitter region are disposed laterally next to one another in plan view onto a main face of the semiconductor body. More particularly the first emitter region and the second emitter region are not stacked atop one another in a stacking direction of the epitaxial semiconductor layer sequence.
According to a further embodiment of the method, the first emitter region and the second emitter region generate electro-magnetic radiation of different wavelength ranges. The first emitter region and the second emitter region preferably generate visible light. More preferably the first emitter region generates blue light and the second emitter region generates green light. It is, however, also possible for the emitter regions to generate visible light of other colors.
Furthermore, the method for producing a radiation-emitting semiconductor body is not limited to the generation only of two emitter regions. It is instead presently envisaged that more than two emitter regions are comprised by the epitaxial semi-conductor layer sequence to be deposited or form the epitaxial semiconductor layer sequence. More particularly all of the emitter regions which are comprised by the epitaxial semi-conductor layer sequence or which form it are disposed laterally next to one another in plan view onto the main face of the semiconductor body. The text below addresses only two emitter regions, for reasons of clarity. The corresponding features and embodiments may in each case also be embodied in the context of more than two emitter regions.
According to one embodiment, the method for producing a radiation-emitting semiconductor body comprises in particular the following steps:
More preferably the steps recited above are carried out in the specified order.
According to one embodiment of the method, the compound semi-conductor material is a III/V compound semiconductor material. More preferably the III/V compound semiconductor material is a nitride compound semiconductor material and conforms to the following formula: InxAlyGa1-x-yN with 0≤x≤1, 0≤y≤1 and x+y≤1.
According to a further embodiment of the method, the distributor structures are set up to vary the amount, available on the main face of the growth substrate, of a constituent of a precursor material of the compound semiconductor material to be deposited.
In general, for the epitaxial deposition of the semiconductor compound material, the growth substrate is provided in a closed-off volume. In the closed-off volume, in general, there is further provided a respective precursor material with a constituent for each or two or more of the chemical elements of the compound semiconductor material. For the deposition of a III/V compound semiconductor material, for example, at least one precursor material with a constituent for the group III chemical element subsequently present in the deposited epitaxial semiconductor layer sequence is provided. In the closed-off volume, the precursor material divides up in general into its constituents, and so the constituent of the precursor material for the group III element is available at the main face of the growth substrate.
Additionally provided is a precursor material with a constituent for the group V chemical element subsequently present in the deposited epitaxial semiconductor layer sequence. The distributor structures, then, are set up to vary the amount, available on or over the main face of the growth substrate, of a constituent of the precursor materials. For example, the distributor structures may increase or reduce the amount of one of the constituents of the precursor materials that is available on the main face of the growth substrate. Alternatively or additionally it is also possible for the distributor structures to establish a specific growth rate during epitaxial deposition of the epitaxial semiconductor layer sequence.
The epitaxial deposition more preferably comprises an organo-metallic vapor phase epitaxy (MOVPE for short).
As precursor materials for the group III chemical element indium, for example, one of the following materials is used: trimethylindium, dimethylaminopropyldimethylindium.
As precursor materials for the group III chemical element aluminum, for example, one of the following materials is used: trimethylaluminum (TMA), triethylaluminum (TEA).
As precursor materials for the group III chemical element gallium, for example, one of the following materials is used: trimethylgallium (TMG), triethylgallium (TEG).
As precursor materials for the group V chemical element nitrogen, for example, one of the following materials is used: phenylhydrazine, dimethylhydrazine, tert-butylamine, ammonia.
According to a further embodiment of the method, an amount, available during the epitaxial depositing, in the first emitter region, of a constituent of the precursor material of the compound semiconductor material to be deposited is different from the amount, in the second emitter region, of the constituent of the precursor material of the compound material to be deposited.
A distributor structure is formed, for example, by a recess in the main face of the growth substrate. The recess may be a trench or a hole. The trench or the hole has, for example, a round, a hexagonal, a rectangular or a triangular base area. Moreover, side faces of the trench and/or side faces of the hole may take the form of facets. Additionally, a distributor structure may also be formed by a porous region, which may be generated for example by etching in the main face of the growth substrate. Furthermore, a distributor structure may take the form of a ridge. The ridge for example comprises underetched sidewalls.
According to a further embodiment of the method, the distributor structure is formed by a coating which is applied on the main face of the growth substrate. The coating in this case is formed only in places on the main face of the growth substrate so as to form the distributor structure. The coating may for example comprise a dielectric or consist of a dielectric. Examples of suitable materials for the coating are the following: silicon nitride, silicon oxide.
A coating which comprises silicon nitride or silicon oxide or consists of one of these materials serves in general to increase the constituent of the precursor material for the group III element, by the coating influencing the growth of the epitaxial semiconductor layer through diffusion processes at the main face of the growth substrate or through alteration of the gas concentration over the growth substrate during the epitaxial deposition.
According to a further embodiment of the method, a distributor structure is formed by a region of the main face of the growth substrate that has a different tension from the rest of the main face. A change of this kind in the tension may be achieved, for example, through a different doping of the growth substrate in the region of the distributor structure.
According to a further embodiment of the method, the distributor structures are suitable for increasing the amount of the constituent of the precursor material for the compound semiconductor material over the main face of the growth substrate. Where the compound semiconductor material to be deposited is a III/V compound semiconductor material, the distributor structure increases, for example, the amount of the constituent of the precursor material for the group III element. For example, a coating which comprises silicon nitride or silicon oxide or consists of silicon nitride or silicon oxide is suitable for increasing the amount of a group III element over the main face of the growth substrate.
According to a further embodiment of the method, the distributor structures are suitable for reducing the amount of the constituent of the precursor material for the compound semiconductor material over the main face of the growth substrate. Where a III/V compound semiconductor material is to be deposited, then, for example, recesses, such as trenches, holes and/or porously etched regions, are suitable as distributor structures for reducing the amount of the constituent of the precursor material for the group III element over the main face of the growth substrate.
According to a further embodiment of the method, a distance between two directly adjacent emitter regions is not greater than 5 millimeters, preferably not greater than 1 millimeter and more preferably not greater than 100 micrometers.
The method described so far is suitable for generating a radiation-emitting semiconductor body, which is described in more detail below. All embodiments and features described in connection with the method may also be embodied in the case of the radiation-emitting semiconductor body, and vice versa.
According to one embodiment, the radiation-emitting semiconductor body comprises an epitaxial semiconductor layer sequence which comprises a compound semiconductor material. The epitaxial semiconductor layer sequence preferably comprises at least a first emitter region and a second emitter region. It is also possible, furthermore, for the epitaxial semiconductor layer sequence to be formed of the emitter regions. The first emitter region and the second emitter region are set up to generate, in operation, electromagnetic radiation of different wavelength ranges.
According to a further embodiment of the radiation-emitting semiconductor body, the first emitter region and the second emitter region are disposed laterally next to one another in plan view onto a main face of the semiconductor body.
According to a further embodiment of the radiation-emitting semiconductor body, a peak wavelength of an emission spectrum of the electromagnetic radiation which is emitted from the first emitter region is different by at least 2 nanometers, preferably by at least 5 nanometers, more preferably by at least 10 nanometers, more preferably by at least 50 nanometers, and very preferably by at least 100 nanometers from a peak wavelength of an emission spectrum of the electromagnetic radiation of the second emitter region.
According to a further embodiment of the radiation-emitting semiconductor body, the epitaxial semiconductor layer sequence is disposed on a main face of a growth substrate of the epitaxial semiconductor layer sequence, wherein the main face comprises a multiplicity of distributor structures.
The growth substrate comprises, for example, one of the following materials or is formed of one of the following materials: silicon carbide, sapphire, gallium nitride. These materials are especially suitable as growth substrate for a nitride compound semiconductor material.
According to a further embodiment of the radiation-emitting semiconductor body, the first emitter region and the second emitter region are disposed between two distributor structures or laterally on one side next to at least two distributor structures.
According to a further embodiment of the radiation-emitting semiconductor body, the distributor structures take the form of trenches in the main face of the growth substrate.
The trenches formed as distributor structures in the main face of the growth substrate have a width, for example, of more than 0.5 micrometer, preferably of at least 2 micrometers and more preferably of at least 4 micrometers. Moreover, the trenches formed as distributor structures in the main face of the growth substrate have a depth, for example, of at most 25 micrometers, preferably of at most 10 micrometers and more preferably at most 6 micrometers.
According to a further embodiment of the radiation-emitting semiconductor body, at least one distributor structure comprises at least two segments which are separate from one another and are embodied in the same way.
According to a further embodiment of the radiation-emitting semiconductor body, the first emitter region and the second emitter region comprise an active zone in which, in operation, electromagnetic radiation is generated. The active zone preferably comprises a first quantum film structure and at least one second quantum film structure, wherein the first quantum film structure within the first emitter region has a different thickness than within the second emitter region. Alternatively or additionally, the second quantum film structure within the first emitter region has a different thickness than within the second emitter region. In this way it is possible with advantage to generate two emitter regions, whose electromagnetic radiation exhibits emission spectra with peak wavelengths differing by at least 50 nanometers, preferably by at least 100 nanometers.
According to a further embodiment of the radiation-emitting semiconductor body, the first emitter region and the second emitter region are each comprised by a ridge waveguide. In other words, the two emitter regions are comprised by different ridge waveguides. In this way it is possible to generate a semiconductor body which emits electromagnetic laser radiation of different wavelength ranges from facets on side faces of the semiconductor body.
For the generation of electromagnetic laser radiation, the active zone takes the form of a laser medium, in which in operation a population inversion is generated in conjunction with a suitable resonator. Because of the population inversion, the electromagnetic radiation in the active region is generated by stimulated emission, leading to the formation of electro-magnetic laser radiation. Because of the generation of the electromagnetic laser radiation by stimulated emission, the electromagnetic laser radiation, in contrast to electromagnetic radiation generated by spontaneous emission, in general has a very high coherence length, a very narrow emission spectrum and/or a high degree of polarization.
According to a further embodiment of the radiation-emitting semiconductor body, a first contact point for electrically contacting the first emitter region is disposed on the first emitter region. Alternatively or additionally a second contact point for electrically contacting the second emitter region is disposed on the second emitter region. Hence electromagnetic radiation is generated in emitter regions within the epitaxial semiconductor layer sequence that are electrically separated from one another and are distanced from one another.
The radiation-emitting semiconductor body described here is suitable in particular to be used in a semiconductor laser chip. The semiconductor laser chip is, for example, an edge-emitting laser, which emits laser radiation from a laterally disposed facet. Additionally it may also be a surface-emitting laser, for instance a VCSEL (short for vertical cavity surface emitting laser), which emits laser radiation from a main face.
Alternatively it is also possible for the radiation-emitting semiconductor body to be part of a semiconductor light-emitting diode chip, which in particular emits electromagnetic radiation which has not been generated by population inversion.
With the method described here it is possible in a simple way to generate multiple emitter regions at wafer plane which emit electromagnetic radiation of different wavelengths. This offers the advantage that operating parameters of the emitter regions are influenced only a little. Moreover it is possible in particular to avoid a difficult production process by means of pick-and-place of individual semiconductor bodies emitting electromagnetic radiation of different emission spectra.
Further advantageous embodiments and developments of the radiation-emitting semiconductor body and of the method for producing it are evident from the exemplary embodiments described below in conjunction with the figures.
The method according to exemplary embodiments 1 to 4 is elucidated in more detail on the basis of
A radiation-emitting semiconductor body according to a further exemplary embodiment is elucidated in more detail on the basis of
A radiation-emitting semiconductor body according to a further exemplary embodiment is elucidated in more detail on the basis of
In the figures, elements which are identical, of the same kind or have the same effect are provided with the same reference symbols. The figures and the proportions of the elements represented in the figures to one another should not be considered to be to scale. Instead, individual elements, especially layer thicknesses, may be represented with exaggerated size for improved illustration and/or for improved understanding.
In the case of the method according to the exemplary embodiment of
In a next step, a multiplicity of distributor structures 3 is generated on the main face 2 of the growth substrate 1, wherein presently, for reasons of clarity, only a single distributor structure 3 is represented in
A nitride compound semiconductor material is then deposited epitaxially on the main face 2 of the growth substrate to form an epitaxial semiconductor layer sequence 4 (
Additionally a precursor material with a constituent for the group V element of the III/V compound semiconductor material to be deposited is provided. For example, one of the following materials is suitable as a precursor material for the group III element: phenylhydrazine, dimethylhydrazine, tert-butylamine, ammonia.
The trench is presently set up to vary, more particularly to reduce, the amount of the constituent of the precursor material for the group III element that is available on the main face 2 of the growth substrate 1 during the epitaxial deposition.
Because of the variation in the constituent of the precursor material for the group III element along the main face 2 of the growth substrate 1, there is also variation in the epitaxial growth of the nitride compound semiconductor material along the main face 2. During the epitaxial deposition, because of the distributor structures 3, an epitaxial semiconductor layer sequence 4 is formed with at least a first emitter region 5 and a second emitter region 6 on the main face 2 of the growth substrate 1, these regions having different material compositions and/or thicknesses. Consequently the first emitter region 5 and the second emitter region 6 generate electro-magnetic radiation of different wavelength ranges. The first emitter region 5 and the second emitter region 6 are disposed laterally next to one another in plan view onto the semi-conductor body 1.
In a next step, the epitaxial semiconductor layer sequence 4 is structured, and so now only two mutually distanced emitter regions 5, 6 are disposed on the main face 2, while the rest of the main face 2 is free from the epitaxial semiconductor layer sequence 4 (
Additionally it would also be possible for only the emitter regions 5, 6 to be provided with an electrical contact, and so for only the emitter regions 5, 6, in operation of the radiation-emitting semiconductor body, to be supplied with power, so that electromagnetic radiation is generated only within the two emitter regions 5, 6.
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It is also possible, furthermore, for the area fractions of the segments 13 of the distributor structures 3 to vary (see
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The radiation-emitting semiconductor body according to the exemplary embodiment of
The first emitter region 5 and the second emitter region 6 in the present case have an active zone 8 in which the electro-magnetic radiation is generated in operation. The active zone 8 additionally comprises a first quantum film structure 9 and a second quantum film structure 9′ (
In conjunction with
The radiation-emitting semiconductor body according to the exemplary embodiment of
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Presently, in the figures, in some cases only a single emitter region 5 is shown. This serves merely for greater clarity. All of the semiconductor bodies have at least two emitter regions 5, 6. The semiconductor body also has a multiplicity of distributor structures 3, even if, only for reasons of clarity, a single distributor structure 3 is shown and described.
The invention is not confined to the exemplary embodiments because of the description on the basis of those embodiments. The invention instead encompasses every new feature and also every combination of features, including in particular every combination of features in the claims, even if that feature or that combination is not itself specified explicitly in the claims or exemplary embodiments.
Number | Date | Country | Kind |
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10 2020 119 227.4 | Jul 2020 | DE | national |
This patent application is a national stage entry from International Application No. PCT/EP2021/070237, filed on Jul. 20, 2021, published as International Publication No. WO 2022/018071 A1 on Jan. 27, 2022, and claims priority to German Patent Application No. 10 2020 119 227.4, filed Jul. 21, 2020, the disclosures of all of which are incorporated by reference herein in their entireties.
Filing Document | Filing Date | Country | Kind |
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PCT/EP2021/070237 | 7/20/2021 | WO |