Claims
- 1. A method for producing an aromatic polyether ketone having repeating units of the following formula (II): ##STR8## wherein each of R.sup.1 to R.sup.12 is a hydrogen atom, a halogen atom, a hydrocarbon group or an alkoxy group, X is an oxygen atom, provided that part of X may be a direct bond, and n is an integer of from 0 to 2, which consisting of reacting an aromatic ether carboxylic acid fluoride of the following formula (I): ##STR9## wherein R.sup.1 to R.sup.12, X and n are as defined above, under pressure of at least 5 atms in an aprotic organic solvent in the presence of boron trifluoride.
- 2. The method according to claim 1, wherein the aromatic ether carboxylic acid fluoride of the formula (I) is at least one member selected from the group consisting of 4-phenoxybenzoyl fluoride, 4-phenoxy-4'-fluoroformyldiphenyl ether, 3-phenoxybenzoyl fluoride, 3-methyl-4-phenoxybenzoyl fluoride, 3-methoxy-4-phenoxybenzoyl fluoride and 4-phenylmercaptobenzoyl fluoride.
- 3. The method according to claim 1, wherein the aromatic ether carboxylic acid fluoride of the formula (I) is 4-phenoxybenzoyl fluoride.
- 4. The method according to claim 1, wherein the aprotic organic solvent is at least one member selected from the group consisting of methylene chloride, dichloroethane, 1,1,2,2-tetrachloroethane, chloroform, carbon tetrachloride, nitrobenzene, nitromethane, carbon disulfide, o-dibromobenzene, o-dichlorobenzene, m-dichlorobenzene, diphenylsulfone, diphenyl ketone, chlorobenzene, benzene, toluene, acetophenone, tetralin, decalin, hexane, dibutyl ether, heptane and pentane.
- 5. The method according to claim 1, wherein the aprotic organic solvent is chlorinated aromatic hydrocarbon.
- 6. The method according to claim 1, wherein the aprotic organic solvent is o-dichlorobenzene.
- 7. The method according to claim 1, wherein the solvent is used in an amount of from 1 to 100 parts by weight per part by weight of the organic ether carboxylic acid fluoride.
- 8. The method according to claim 1, wherein the boron trifluoride is used in an amount of from 0.5 to 100 parts by weight per part by weight of the aromatic ether carboxylic acid fluoride.
- 9. The method according to claim 1, wherein the reaction is conducted at a temperature of from -10.degree. to +200.degree. C.
Priority Claims (2)
Number |
Date |
Country |
Kind |
2-299253 |
Nov 1990 |
JPX |
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3-226242 |
Sep 1991 |
JPX |
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Parent Case Info
This application is a continuation of application Ser. No. 07/787,793, filed on Nov. 4, 1991, now abandoned.
US Referenced Citations (4)
Foreign Referenced Citations (1)
Number |
Date |
Country |
1062325 |
Mar 1989 |
JPX |
Continuations (1)
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Number |
Date |
Country |
Parent |
787793 |
Nov 1991 |
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