METHOD FOR PRODUCING COOKED AND FROZEN PASTA

Information

  • Patent Application
  • 20140363557
  • Publication Number
    20140363557
  • Date Filed
    December 21, 2012
    11 years ago
  • Date Published
    December 11, 2014
    9 years ago
Abstract
Cooked and frozen pastas which can be stored in a frozen state for a long time and which retains favorable appearance and texture comparable to freshly boiled fresh pastas even after being thawed are provided. A method for producing cooked and frozen pastas, comprising boiling fresh pastas obtained by extruding dough into pasta noodles at a pressure of from 80 kgf/cm2 to 200 kgf/cm2, and then freezing the pastas.
Description
TECHNICAL FIELD

The present invention relates to a method for producing cooked and frozen pastas. In more detail, the present invention relates to a method for producing cooked and frozen pastas which can be stored for a long time in a state such that the pastas is cooked by boiling fresh pasta noodles, followed by freezing, and which retain good appearance and texture comparable to freshly boiled fresh pasta even after being thawed.


BACKGROUND ART

Fresh pastas are popular foods because, unlike dried pastas, they attain a unique chewy and resilient (mochimochi) texture after they are boiled. However, because fresh pastas have poor storage stability due to high water content, processes such as kneading, and rolling out of dough must be performed before each serving. Thus, fresh pastas are a food requiring complex preparation before serving. Although fresh pastas in a chilled or frozen state are commercially available, chilled products can be distributed only through limited marketing channels due to the infeasibility of prolonged storage. Meanwhile, there is a problem that even if fresh pastas which have been cooked or not are frozen-stored, the noodle surface of the pasta presents a rough appearance, and resilience (koshi) and viscoelasticity are lost, resulting in failure of maintenance of their good texture before frozen-storage. Further, there is a problem that because the noodle surface of boiled fresh pasta becomes rough during frozen-storage, when pasta is frozen with sauce on top, the sauce penetrates into the pasta during storage, causing deterioration in the quality.


Fresh pastas which can be stored for a long time have already been proposed before. For example, Patent Literature 1 describes a method for producing quickly-rehydratable fresh pastas having storage stability, comprising drying dough, which has been extruded at a specific pressure under specific vacuum conditions, to certain water content, and then sealing and sterilizing the dough. However, because the above fresh pastas have been subjected to a drying process, they have a similar texture to that of boiled dried pasta, failing in providing a satisfactory unique chewy and resilient (mochimochi) texture required for fresh pastas.


Patent Literature 2 describes a method, comprising frozen-storing semi-fresh pastas, which have been boiled and cooked, and cooking the pastas with water in a microwave oven before serving. However, because pastas provided by the above cooking method are semi-cooked pasta prepared by boiling dried pasta, they have a completely different texture from so-called boiled fresh pasta prepared by boiling fresh pasta.


Patent Literature 3 describes a method for producing fresh noodles with excellent storage stability, comprising kneading wheat flour or wheat semolina, activated gluten powder and/or egg white with water, and then subjecting the resulting mixture to extrusion under reduced pressure. However, although the resulting fresh noodles had a good appearance, they were unsatisfactory in terms of storage stability.


Patent Literature 4 describes pasta, characterized by subjecting dough, which has been kneaded under reduced pressure and then extrusion into chips, to further kneading and extrusion. However, because this pasta was intended to provide less stickiness and excellent smoothness and hardness with adequate elasticity by diversifying the direction of the gluten network of the dough, two extrusion steps were necessary, resulting in the pasta having a very hard texture and lacking a chewy and resilient (mochimochi) texture.


In light of the above, in a practical situation, there is a demand for cooked pastas which can be stored in a frozen state for a long time, while maintaining a unique chewy and resilient (mochimochi) texture of boiled fresh pasta even after frozen-storage.


CITATION LIST
Patent Literature

[Patent Literature 1] JP-B-S63-32424


[Patent Literature 2] JP-A-H10-295302


[Patent Literature 3] JP-A-2001-245617


[Patent Literature 4] JP-A-2001-346533


SUMMARY OF INVENTION
Technical Problem

In light of the practical situation described above, an object of the present invention is to provide cooked and frozen pastas which can be stored in a frozen state for a long time and which retain good appearance and texture comparable to freshly boiled fresh pastas even after being thawed.


Solution to Problem

The present inventors conducted various studies to achieve the aforementioned object. As a result, they found that cooked and frozen pastas, which were produced by boiling fresh pasta obtained by extruding dough into pasta noodles at a specific pressure and then freezing the pastas, are highly resistant to freezing, and thus can be stored in a frozen state for a long time while presenting good appearance and texture comparable to freshly boiled fresh pasta after being thawed, thereby completing the present invention.


That is, the present invention achieved the aforementioned object by a method for producing cooked and frozen fresh pastas, comprising boiling fresh pastas obtained by extruding dough into pasta noodles at a pressure of from 80 kgf/cm2 to 200 kgf/cm2, and then freezing the pastas.


Advantageous Effects of Invention

The cooked and frozen pastas obtained by the production method of the present invention are highly resistant to freezing, can be stored in a frozen state for a long time while maintaining the smooth appearance of the pasta noodles and can retain good appearance and texture after being thawed as obtained when conventional fresh pastas are consumed immediately after being boiled. Moreover, since the cooked and frozen pastas obtained by the production method of the present invention can maintain the smooth appearance of the pasta noodles even when they are frozen, when the pastas are frozen-stored with sauce on top, deterioration of quality caused by the penetration of sauce into pasta during storage can be prevented.







DESCRIPTION OF EMBODIMENTS

In general, fresh pastas are produced by rolling out noodle dough while applying pressure and cutting the resulting dough into noodles or by extruding noodle dough to make noodles while applying pressure in accordance with various noodle production methods such as rolling, rolling, and extruding. However, in either case, noodle production was not carried out under high pressure because there was no need to dry noodles according to conventional production methods of fresh pastas, and moreover, in order to preserve the moderately hard and chewy and resilient (mochimochi) texture of noodles. According to conventional production methods of fresh pastas, pressure applied to noodle dough during noodle production is approximately 0 kgf/cm2 in the case of rolling, and it is approximately 20 kgf/cm2 even in the case of extrusion.


However, the method for producing cooked and frozen pastas according to the present invention is characterized by preparing fresh pastas by applying, to dough, unusually high pressure as a pressure to be applied to fresh pastas. For example, according to the present method, dough can be extruded into noodles at a pressure of from 80 kgf/cm2 to 200 kgf/cm2. The extrusion pressure used in the method of the present invention is equal to or higher than the extrusion pressure normally used in the production of dried pasta (approximately from 70 to 160 kgf/cm2), and is extremely high as a pressure to be applied to fresh pastas.


Dough for fresh pastas used in the production method of the present invention is noodle dough obtained by adding kneading water to 100% wheat flour or a flour ingredient containing wheat flour as the main component, followed by kneading. Wheat flour used for the aforementioned flour ingredient is not particularly limited as long as it is one that can be used for pastas, and examples thereof include wheat flour such as hard wheat flour, semi-hard wheat flour, moderate wheat flour, soft wheat flour, and durum wheat flour, and semolina wheat flour such as durum semolina. These wheat flours can be used singly or in combinations of two or more thereof.


As the aforementioned wheat flour, it is preferable to use a mixture of durum wheat flour and regular wheat flour other than durum wheat flour since the chewy and resilient (mochimochi) texture of the pasta obtained can be improved compared to that obtained by use of durum wheat flour alone. Examples of the regular wheat flour include hard wheat flour, semi-hard wheat flour, moderate wheat flour, soft flour, and a mixture of these flours, among which moderate wheat flour is preferable.


Alternatively, it is preferable to further blend, in addition to the aforementioned wheat flour, starch or processed starch in the aforementioned flour ingredient of dough of fresh pastas since the texture of the pasta obtained can be further improved. Examples of the starch include one which can be normally used in pastas such as tapioca starch, potato starch, wheat starch, corn starch, and waxy corn starch. Examples of the processed starch include one obtained by subjecting the above starch to processing such as acetylation, hydroxypropylation, etherification, cross-linking, oxidation and pregelatinization or physical treatment. The aforementioned starches and processed starches can be used singly or in combinations of two or more thereof. Among the aforementioned starches and processed starches, hydroxypropylated starch is preferable since it improves the chewy and resilient (mochimochi) texture of pasta.


The aforementioned flour ingredient of dough of fresh pastas preferably contains durum wheat flour and at least one selected from the group consisting of starch, processed starch and regular wheat flour. The flour ingredient more preferably contains durum wheat flour, regular wheat flour, and at least one selected from the group consisting of starch and processed starch. The blending ratio of durum wheat flour to at least one selected from the group consisting of starch, processed starch and regular wheat flour in the flour ingredient is preferably from 30:70 to 95:5, more preferably from 60:40 to 90:10.


In addition to the aforementioned wheat flour, starches, and processed starch, other ingredients normally used for the production of fresh pastas such as sugars, gluten, eggs, salt, oil and fat, emulsifiers, and thickeners can be added to the aforementioned flour ingredient. The amount of these other ingredients added may be from 0 to 30 parts by mass relative to 100 parts by mass of the aforementioned wheat flour, starches and processed starch.


As the kneading water used for the production of dough, any kind of water used for routine noodle production such as of water, salt water, and lye water can be used. Considering that the dough obtained is subjected to such a high extrusion pressure as described above, the amount of kneading water added is preferably from 15 to 35 parts by mass, more preferably from 18 to 35 parts by mass, even more preferably from 20 to 30 parts by mass, and still more preferably from 24 to 27 parts by mass relative to 100 parts by mass of the flour ingredient. When the amount of kneading water added is less than 15 parts by mass, the extruded noodle strands become fragile and easily fragmented. On the other hand, when the amount of kneading water added exceeds 35 parts by mass, the dough becomes weak and susceptible to damage, resulting in failure of the fresh pastas thus obtained to achieve the desired appearance or texture.


According to the production method of the present invention, fresh pastas are obtained by preparing noodles using the aforementioned dough under high pressure. That is, according to the production method of the present invention, fresh pastas may be prepared by extruding the above dough into noodles at a pressure of, for example, from 80 kgf/cm2 to 200 kgf/cm2, preferably from 120 to 160 kgf/cm2. The degree of pressure reduction during extrusion may be from −200 mmHg to vacuum, preferably from −600 mmHg to vacuum. The extrusion can be carried out by using, for example, an extrusion noodle making machine used for the production of dried pasta. According to the present method, in the preparation process of the fresh pastas, noodles may be prepared by extruding dough which has been obtained by kneading ingredients; therefore, the kneading step and the noodle preparation-by-extrusion step may each be performed once. According to the present method, in the preparation process of the fresh pastas, the kneading step and the noodle preparation-by-extrusion step need not be performed twice or more, meaning that the dough made into noodles needs not be kneaded again or subjected to another noodle preparation process.


In the present invention, the shape of the fresh pastas is not particularly limited, and after extruding noodle dough into noodle sheets, they can be made into the desired shape such as noodle strands by, for example, rolling, cutting and the like in accordance with a routine method. Alternatively, pastas having the desired shape can be made by extrusion through a die having openings of appropriate shape.


Subsequently, the fresh pastas thus obtained are directly boiled without being subjected to a drying step, etc. Boiling can be performed by a regular boiling method used for fresh pasta. In general, fresh pastas are cooked in boiling water for two to eight minutes. After optionally draining hot water and cooling the boiled pastas, they are subjected to a freezing process.


For the freezing process in the production method of the present invention, a freezing process routinely performed on noodles can be adopted. For example, it is preferable that the pastas boiled as described above be divided into certain portions, for example, 150 to 300 g for one person, and served on trays, etc., and then subjected to freezing process. For the freezing process, either quick freezing or slow freezing may be feasible; however, quick freezing is preferable. Once the pastas are frozen by quick freezing, they can be stored under normal frozen-storage conditions.


In the aforementioned freezing process, the boiled pastas may be frozen with sauce. For example, sauce may be poured on top of the boiled pastas divided into trays as described above and the same is frozen, or sauce may be mixed with the boiled pastas and the same is served on trays and then frozen. As the sauce, any regular pasta sauce may be used, and examples thereof include a tomato-based sauce such as meat sauce, Neapolitan sauce, and arrabbiata sauce, a white sauce such as carbonara sauce, and a brown sauce; however, the sauce is not limited to these examples.


The cooked and frozen pastas produced in accordance with the production method of the present invention have improved resistance to freezing compared to conventional frozen product of fresh pastas or boiled fresh pastas, and can maintain the smooth noodle surface even when they are frozen. Accordingly, these cooked and frozen pastas present a smooth appearance and a favorable texture comparable to those obtained with freshly boiled fresh pastas even after being thawed or re-heated. Also, since cooked and frozen pastas produced in accordance with the production method of the present invention maintain a smooth surface even when they are frozen, deterioration of the quality of texture or appearance of the pastas caused by excessive penetration of sauce into pastas is prevented, even when they are frozen-stored with sauce.


EXAMPLES

Hereinbelow, the present invention will be further described in detail with reference to Examples. However, the present invention is not limited to these Examples.


Production Examples 1 to 8


Durum wheat semolina flour (Leone G: the product of Nisshin Flour Milling Inc.) (100 parts by mass) and water (26 parts by mass) were mixed and then kneaded to prepare noodle dough. Under a reduced pressure condition of −600 mmHg, the dough was extruded into noodles by a pasta making machine under each of the following pressure conditions of 30, 70, 80, 120, 160, 200, 210 and 250 kgf/cm2, whereby eight kinds of fresh spaghetti (1.8 mm in diameter) were obtained.


The fresh spaghetti thus obtained was boiled in hot water for five minutes and then cooled with water, whereby boiled spaghetti was produced.


The boiled spaghetti was dividedly served on trays (160 mm×120 mm; made of polypropylene) at 180 g per tray, and further, for half of the trays, 100 g of commercially available canned meat sauce (the product of Nisshin Foods Inc.) was poured on top of the noodle mass. The resulting spaghetti was quickly frozen at −35° C., whereby the cooked and frozen spaghetti of Production Examples 1 to 8 (each with and without sauce) were produced.


Test Example 1

The cooked and frozen spaghetti of Production Examples 1 to 8 was removed from the trays, packed in polypropylene bags, and then stored at −18° C. After one week, the frozen spaghetti was removed from the bags and then thawed by heating in a microwave oven (600 W). Spaghetti without sauce was heated for three minutes, whereas spaghetti with sauce was heated for 4 minutes and 30 seconds. The appearance and texture of the spaghetti after being thawed were evaluated. The spaghetti with sauce was lightly mixed after heating and the appearance and texture of the spaghetti with sauce were evaluated. Evaluation was conducted by 10 panelists based on the evaluation criteria shown in Table 1, and average scores were obtained. The results are shown in Table 2.











TABLE 1







Appearance of
5
Very smooth noodle surface, appearing to


spaghetti

have a smooth texture.



4
Fairly smooth noodle surface, appearing to




have a slightly smooth texture.



3
The noodle surface is relatively smooth




without roughness.



2
The noodle surface is slightly coarse and




rough, or slightly melted.



1
The noodle surface is coarse and rough, or




melted.


Texture of
5
Excellent texture with sufficient unique


spaghetti

resilience (koshi) and elasticity of fresh




spaghetti.



4
Good texture with unique resilience




(koshi) and elasticity of fresh spaghetti.



3
Acceptable texture relatively having




resilience (koshi) and elasticity.



2
Slightly too soft or slightly too hard,




lacking the unique texture of fresh




spaghetti.



1
Too soft or too hard, lacking the unique




texture of fresh spaghetti.


Appearance of
5
Sauce excellently and evenly clings to


spaghetti with

noodles.


sauce
4
Sauce clings to noodles well.



3
Sauce moderately clings to noodles.



2
Sauce poorly or unevenly clings to




noodles.



1
Sauce very poorly and unevenly clings to




noodles.


Texture of
5
Excellent texture with sufficient


spaghetti with

resilience (koshi) and elasticity,


sauce

harmonized well with sauce.



4
Good texture with resilience (koshi) and




elasticity along with sauce.



3
Average texture relatively having




resilience (koshi) and elasticity.



2
Slightly too soft or slightly too hard,




somewhat poor texture with noodles




absorbing a small amount of sauce.



1
Too soft or hard, poor texture with




noodles absorbing a large amount of sauce.

























TABLE 2







Production
Production
Production
Production
Production
Production
Production
Production



Example 1
Example 2
Example 3
Example 4
Example 5
Example 6
Example 7
Example 8
























Extrusion
30
70
80
120
160
200
210
250


pressure


(kgf/cm2)


Appearance
1.5
2.8
3.9
4.8
4.5
4.5
4.3
4.3


of


spaghetti


Texture of
2.4
3.4
3.7
4.7
4.6
4.0
3.2
2.5


spaghetti


Appearance
2.3
3.3
4.0
4.5
4.4
4.0
3.5
2.8


of


spaghetti


with sauce


Texture of
1.8
2.5
3.7
4.1
4.0
3.2
2.5
2.1


spaghetti


with sauce









Production Examples 9 to 16

Except for adding water in amounts shown in Table 3 to 100 parts by mass of durum wheat semolina flour (Leone G: Nisshin Flour Milling Inc.), the cooked and frozen spaghetti of Production Examples 9 to 16 (each with and without sauce) were produced by the same procedure as in Production Example 5 (noodle extrusion pressure: 160 kgf/cm2).


Using the cooked and frozen spaghetti of Production Examples 9 to 16, the appearance and texture of the spaghetti or spaghetti with sauce after being thawed were evaluated by the same procedure as in Test Example 1. The results are shown in Table 3.


















TABLE 3








Production
Production
Production
Production
Production
Production
Production



Production
Example
Example
Example
Example
Example
Example
Example



Example 9
10
11
12
13
14
15
16
























Water
15
18
20
24
27
30
35
37


(parts by


mass)


Appearance
3.2
3.7
3.8
4.2
4.5
4.6
4.5
4.4


of


spaghetti


Texture of
3.3
3.5
3.6
4.0
4.6
4.1
3.7
2.3


spaghetti


Appearance
3.2
3.7
3.7
4.1
4.4
4.1
3.9
2.8


of


spaghetti


with sauce


Texture of
3.6
3.7
3.7
3.8
4.0
3.9
3.6
2.7


spaghetti


with sauce









Production Examples 17 to 23

Except for adding durum wheat semolina flour (Leone G: Nisshin Flour Milling Inc.) and hydroxypropylated starch (Yuri: the product of Matsutani Chemical Industry Co., Ltd.) in amounts shown in Table 4, the cooked and frozen spaghetti of Production Examples 17 to 23 (each with and without sauce) were produced by the same procedure as in Production Example 11 (addition of water: 20 parts by mass, noodle extrusion pressure: 160 kgf/cm2).


Using the cooked and frozen spaghetti of Production Examples 17 to 23, the appearance and texture of the spaghetti or spaghetti with sauce after being thawed were evaluated by the same procedure as in Test Example 1. The results are shown in Table 4. Also, the results of Production Example 11 are shown again in Table 4.


















TABLE 4







Production
Production
Production
Production
Production
Production
Production
Production



Example
Example
Example
Example
Example
Example
Example
Example



17
18
19
20
21
22
23
11
























Durum
20
30
40
60
80
90
95
100


semolina


flour


(parts by


mass)


Hydroxy-
80
70
60
40
20
10
5
0


propylated


starch


(parts by


mass)


Appearance
3.0
3.8
3.9
4.2
4.5
4.6
4.2
3.8


of


spaghetti


Texture of
3.2
4.1
4.2
4.6
4.9
4.7
4.2
3.6


spaghetti


Appearance
2.7
3.8
3.9
4.1
4.4
4.1
4.0
3.7


of


spaghetti


with sauce


Texture of
2.8
4.1
4.3
4.6
4.8
4.7
4.3
3.7


spaghetti


with sauce









Production Examples 24 to 30

Except for adding durum wheat semolina (Leone G: Nisshin Flour Milling Inc.), hydroxypropylated starch (Yuri: the product of Matsutani Chemical Industry Co., Ltd.), and regular wheat flour (Shirotsubaki: a moderate wheat flour produced by Nisshin Flour Milling Inc.) in amounts shown in Table 5, the cooked and frozen spaghetti of Production Examples 24 to 30 (each with and without sauce) were produced by the same procedure as in Production Example 11 (addition of water: 20 parts by mass, noodle extrusion pressure: 160 kgf/cm2).


Using the cooked and frozen spaghetti of Production Examples 24 to 30, the appearance and texture of the spaghetti or spaghetti with sauce after being thawed were evaluated by the same procedure as in Test Example 1. The results are shown in Table 5. Also, the results of Production Example 11 are shown again in Table 5.


















TABLE 5







Production
Production
Production
Production
Production
Production
Production
Production



Example
Example
Example
Example
Example
Example
Example
Example



24
25
26
27
28
29
30
11
























Durum semolina
20
30
40
60
80
90
95
100


flour (parts


by mass)


Hydroxy-
0
0
0
20
10
5
0
0


propylated


starch (parts


by mass)


Regular wheat
80
70
60
20
10
5
5
0


flour (parts


by mass)


Appearance of
2.9
3.8
3.9
4.2
4.5
4.6
4.2
3.8


spaghetti


Texture of
3.0
3.9
4.0
4.9
4.8
4.8
3.9
3.6


spaghetti


Appearance of
2.7
3.8
3.8
4.0
4.4
4.1
4.0
3.7


spaghetti with


sauce


Texture of
2.7
3.8
4.0
4.9
4.8
4.7
3.9
3.7


spaghetti with


sauce









Production Example 31


Durum wheat semolina flour (Leone G: Nisshin Flour Milling Inc.) (100 parts by mass) and water (26 parts by mass) were mixed and then kneaded to prepare noodle dough. Under a reduced pressure condition of −600 mmHg, the resulting dough was extruded into spaghetti once (1.8 mm in diameter) using a pasta making machine. Subsequently, the resulting spaghetti was cut into chips which are 15 mm in length, kneaded again, then put in the pasta making machine, and extruded under a pressure condition of 120 kgf/cm2, whereby the fresh spaghetti (1.8 mm in diameter) of Production Example 31 was obtained. The fresh spaghetti thus obtained was boiled in a similar manner to Production Example 4, whereby cooked and frozen spaghetti (with and without sauce) was produced.


Using the cooked and frozen spaghetti of Production Example 31, the appearance and texture of the spaghetti or spaghetti with sauce after being thawed were evaluated by the same procedure as in Test Example 1. The results are shown in Table 6. Also, the results of Production Example 4 are shown again in Table 6. The spaghetti of Production Example 31, which was produced from twice-kneaded dough, was very hard without elasticity, failing in achieving a unique texture of fresh spaghetti.












TABLE 6







Production
Production



Example 4
Example 31




















Number of
1
2



extrusion



Appearance
4.8
3.9



of spaghetti



Texture of
4.7
2.5



spaghetti



Appearance
4.5
3.8



of spaghetti



with sauce



Texture of
4.7
2.6



spaghetti



with sauce









Claims
  • 1. A method for producing cooked and frozen pasta, comprising boiling fresh pasta obtained by extruding dough into pasta noodles at a pressure of from 80 kgf/cm2 to 200 kgf/cm2, and then freezing the boiled pasta.
  • 2. The method according to claim 1, wherein the dough is obtained by adding from 18 to 35 parts by mass of kneading water to 100 parts by mass of a flour ingredient, followed by kneading the dough.
  • 3. The method according to claim 1, wherein the extrusion is performed at −200 mmHg to under vacuum.
  • 4. The method according to claim 2, wherein the flour ingredient comprises durum wheat flour and at least one selected from the group consisting of starch, processed starch and regular wheat flour at a blending ratio of from 30:70 to 95:5.
  • 5. The method according to claim 1, wherein the boiled pasta is frozen with sauce.
  • 6. The method according to claim 2, wherein the extrusion is performed at −200 mmHg to under vacuum.
  • 7. The method according to claim 3, wherein the flour ingredient comprises durum wheat flour and at least one selected from the group consisting of starch, processed starch and regular wheat flour at a blending ratio from 30:70 to 95:5.
  • 8. The method according to claim 6, wherein the flour ingredient comprises durum wheat flour and at least one selected from the group consisting of starch, processed starch and regular wheat flour at a blending ratio from 30:70 to 95:5.
  • 9. The method according to claim 2, wherein the boiled pasta is frozen with sauce.
  • 10. The method according to claim 3, wherein the boiled pasta is frozen with sauce.
  • 11. The method according to claim 4, wherein the boiled pasta is frozen with sauce.
  • 12. The method according to claim 6, wherein the boiled pasta is frozen with sauce.
  • 13. The method according to claim 7, wherein the boiled pasta is frozen with sauce.
  • 14. The method according to claim 8, wherein the boiled pasta is frozen with sauce.
  • 15. (canceled)
Priority Claims (2)
Number Date Country Kind
2011-281089 Dec 2011 JP national
201210069985.4 Mar 2012 CN national
PCT Information
Filing Document Filing Date Country Kind 371c Date
PCT/JP12/83208 12/21/2012 WO 00 6/11/2014