Patent Application
20110236944
This invention relates to a process for the production of an intermediate product that is intended for the production of ethanol, starting from a lignocellulosic raw material.
The invention also relates to the intermediate product that is obtained by this process and its use for producing ethanol.
For several years, numerous studies have been conducted for replacing fossil energy sources by renewable energies. In particular, research has been oriented toward the creation of new fuels: agrofuels or ecofuels.
An ecofuel is a fuel that is produced from renewable organic materials of non-fossil origin.
There are various techniques for production of ecofuels, in particular the production of oil, alcohol or gas fuels from plant or animal biomass, or industrial or community waste.
Currently, numerous agrofuels are being developed in the form of ethanol from fermentation of sugars originating from grains, wheat or corn, or beet scraps.
However, the development of these agrofuels poses significant problems, in particular because they compete directly with food cultivation and the production capacity of raw materials is limited compared to the very significant quantities of fuels that are consumed. It is estimated that only approximately 10% of the requirements could be met by this line.
In contrast, the available quantity of lignocellulosic compounds is very large and represents a potential of 40% of the fuel demand.
These lignocellulosic compounds comprise in particular wood, straw, plants originating from dedicated crops having a high level of dry material, agricultural co-products, collected plant wastes, and industrial or community waste.
The lignocellulosic biomass essentially consists of polysaccharides of cellulose and hemicelluloses, strongly linked to a lignin by covalent bond and hydrogen bond.
The production of ethanol from lignocellulosic compounds is done by hydrolysis of cellulose into molecules of glucose, simple sugars that are then fermented into ethanol by means of glycolysis. It requires a pretreatment for making cellulose accessible so as to facilitate its enzymatic hydrolysis.
In the known processes, lignocellulosic biomass is pretreated chemically for hydrolyzing hemicelluloses and making cellulose accessible.
In general, it involves a pretreatment by hydrolysis in a hot basic medium of the biomass for solubilizing hemicelluloses and a portion of lignin or in a hot weak acid medium for hydrolyzing hemicelluloses.
However, these known pretreatment methods are not satisfactory in terms of yield and require the use of concentrated products.
This is why this invention proposes eliminating the drawbacks of the prior art by proposing an effective and economical process for pretreatment of a lignocellulosic biomass for the purpose of its transformation into ethanol.
For this purpose, the invention has as its object a process for the production of an intermediate product from a lignocellulosic raw material, intended for the production of ethanol, characterized in that it consists in pulping said raw material in an extruder at a temperature of between 60° C. and 180° C. and in the presence of a quantity of water that represents between 200% and 450% of the mass of said raw material.
Preferably, the process according to the invention consists in pulping the lignocellulosic raw material in an extruder at a temperature of between 60° C. and 180° C., in the presence of a quantity of water that represents between 200% and 450% of the mass of said raw material, and in the presence of a strong acid or a strong base that is weakly concentrated relative to the quantity of water, namely at a concentration of between 0.5% and 4% relative to the volume of water.
The invention also has as its object the intermediate product that is obtained by the execution of this process.
Intermediate product in terms of this invention is defined as the biomass that is obtained after pulping.
Advantageously, the process according to the invention makes it possible to obtain an intermediate product that makes it possible to increase by a factor of 8 the yield of the enzymatic hydrolysis of cellulose, and therefore the yield of ethanol production.
The invention is now described in detail.
The object of the invention is a process for pretreatment of a lignocellulosic biomass for producing an intermediate product that is intended to be transformed into ethanol.
Lignocellulosic raw material or lignocellulosic biomass in terms of the invention is defined as any lignocellulosic compound, in particular:
The process according to the invention consists in pulping the lignocellulosic raw material or biomass in an extruder at a temperature of between 60° C. and 180° C. and in the presence of a quantity of water that represents between 200% and 450% of the mass of said raw material.
Preferably, the lignocellulosic raw material is also pulped in the presence of a strong acid or a strong base at a concentration that is between 0.5% and 4% relative to the volume of water.
An extruder is a device that consists primarily of one or more endless screws turning at a determined speed inside a temperature-regulated cylindrical case.
Preferably, the process according to the invention uses a single-screw or twin-screw extruder.
A twin-screw extruder is an extruder that consists of two cooperating screws that turn in the same direction and a case that envelops these two screws. The two screws are identical and consist of modules that comprise a material-conveying element that is equipped with windows or slots cut into the threads.
Advantageously, the extruder makes it possible in a single stage to execute one or more operation(s), in particular the pulping of the lignocellulosic biomass by the combination of compression and shearing actions that makes it possible to separate the fibers and to release the cellulose by freeing it from the lignin network, and the solubilization of the hemicelluloses.
According to the invention, the temperature of the extruder is between 60° C. and 180° C., preferably between 90° C. and 120° C., and even more preferably between 100° C. and 110° C.
Furthermore, the quantity of water that is used in the extruder is between 200% and 450% of the mass of said lignocellulosic raw material, preferably between 300% and 450%, and even more preferably between 300% and 400%, of the mass of the lignocellulosic raw material.
Likewise, the quantity of strong acid or strong base is between 0.5% and 4% relative to the volume of water, preferably between 0.5 and 1.5%, and even more preferably between 0.8% and 1.2%. It may involve, for example, hydrochloric acid, sulfuric acid, or sodium hydroxide. The strong acid can be mineral or organic.
The combination of these parameters, temperature, quantity of water and/or quantity of particular strong acid or strong base makes it possible to obtain a lignocellulosic intermediate product that can be hydrolyzed at a particularly high rate.
An example of a particularly suitable process according to the invention comprises the following stages:
Tests have been carried out by executing this process by varying the parameters of temperature, quantity of water, and the presence or absence of a strong acid or a strong base.
Two grams of the intermediate product obtained were then hydrolyzed in 50 ml per 5 ml of cellulases (Trichoderma longibrachiatum) at pH 5 and 50° C.
The results that are obtained are presented in the table below:
It is noted that for the range of values of water quantity, temperature and/or concentration of strong acid or strong base according to the invention, the hydrolysis yield is very greatly increased.
The optimized conditions of the process according to the invention are an extrusion temperature of 105° C. and a quantity of water of 300% (200% premixed with the biomass and 100% directly into the case of the extruder).
The execution of the process according to the invention under these conditions can make it possible to increase by a factor of 8 the yield of the enzymatic hydrolysis of the treated biomass.
According to the invention, any lignocellulosic material can be used.
A particularly suitable variant consists in using recycled textile cotton, in particular recycled textile cotton that consists of at least 90% cellulose that makes it possible also to increase the yields, as a raw material. A recycled textile cotton that consists of 92-93% cellulose, treated by the execution of the process according to the invention at 105° C. and a quantity of water of 300%, makes it possible to obtain a gain of hydrolysis of 23%.
According to another aspect, the invention relates to the intermediate product that is obtained by the execution of the process according to the invention.
It involves a treated lignocellulosic biomass that can advantageously be used for producing ethanol by the execution of any suitable process. A preferred process comprises the following stages:
Preferably, it comprises the following stages:
Such a process makes it possible to produce significant yields of bioethanol, in particular using an intermediate product, lignocellulosic biomass that is treated by the process according to the invention.
The ethanol that is obtained can advantageously be used as a fuel in a gasoline-powered vehicle, alone or combined with one or more other fuels.
| Number | Date | Country | Kind |
|---|---|---|---|
| 0858306 | Dec 2008 | FR | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/FR2009/052416 | 12/4/2009 | WO | 00 | 6/6/2011 |
