1. Field of the Invention
The present invention relates to a method for producing an optical fiber.
2. Description of the Related Art
Optical fibers including cores that contain alkali metal elements are known (see Japanese Unexamined Patent Publication (Translation of PCT Application) Nos. 2005-537210, 2007-504080, 2008-536190, 2009-541796, 2010-501894, and 2010-526749, U.S. Patent Application Publication No. 2006/0130530, U.S. Pat. No. 5,146,534, and International Publication No. 98/002389). It is believed that the incorporation of an alkali metal element into a core reduces the viscosity of the core in drawing an optical fiber preform to produce an optical fiber and allows the relaxation of the glass network structure to proceed, thereby reducing the attenuation of the optical fiber.
In addition, optical fibers including cores that are composed of pure silica glass free from an alkali metal element are known as other low-loss optical fibers. It is known that in the production of such an optical fiber, an annealing furnace is arranged below a drawing furnace to prolong the heating time in order to promote the relaxation of the glass network structure.
It is an object of the present invention to provide a method for producing an optical fiber including a core that contains an alkali metal element, the optical fiber having low attenuation.
According to an aspect of the present invention, a method for producing an optical fiber includes drawing a silica-based optical fiber preform that includes a core part and a cladding part, the core part having an average concentration of an alkali metal element of 5 atomic ppm or more, in which the time the temperature of glass is maintained at 1500° C. or higher during the drawing is 110 minutes or less.
In the method for producing an optical fiber according to an embodiment of the present invention, the average concentration of the alkali metal element in the core part of the optical fiber preform is preferably 500 atomic ppm or less. Preferably, the core part of the optical fiber preform contains the alkali metal element and a halogen element, and the average concentration of an additive element other than these elements in the core part is equal to or lower than the average concentration of the halogen element in the core part. The average concentration of the halogen element in the core part of the optical fiber preform is preferably in the range of 1,000 atomic ppm to 20,000 atomic ppm. The alkali metal element is preferably potassium.
In the method for producing an optical fiber according to an embodiment of the present invention, the drawing speed during the drawing of the optical fiber preform is preferably 1200 m/min or more and more preferably in the range of 1200 m/min to 2500 m/min. The optical fiber preform preferably has a diameter of 70 mm to 170 mm. The drawing tension (a force applied to a glass portion) during the drawing of the optical fiber preform is preferably in the range of 30 g (0.29 N) to 150 g (1.47 N).
In the method for producing an optical fiber according to an embodiment of the present invention, preferably, during the drawing of the optical fiber preform, the drawn glass fiber having a diameter of 200 μM or less is heated at 1500° C. or higher for 0.3 seconds or less, and the residence time in which an individual position of the optical fiber preform stays in a drawing furnace is 4 hours or less. More specifically, the residence time is defined as the length of time from the time when one position of the optical fiber preform passes through the upper end of the drawing furnace to the time when the position passes through the lower end of the drawing furnace. The drawn glass fiber having a diameter of 200 μm or less is heated at 1500° C. or higher for preferably 0.01 seconds or more. In the drawing of the optical fiber preform, the residence time of any position of the optical fiber preform in the drawing furnace is preferably 4 hours or less.
A method for producing an optical fiber according to an embodiment of the present invention is a method for producing an optical fiber that includes a core part and a cladding part surrounding the core part, in which the core part of the optical fiber preform has an average concentration of an alkali metal of 5 atomic ppm or less and an average concentration of a halogen element of 1000 atomic ppm or more, the average concentration of an additive element other than the alkali metal or the halogen element in the core part is equal to or lower than the average concentration of the halogen element in the core part, the optical fiber preform has a diameter of 70 mm to 170 mm, the drawing speed of the optical fiber when the optical fiber is drawn is 600 m/min or more, and a force applied to a glass portion is in the range of 30 g (0.29 N) to 150 g (1.47 N). The drawing speed of the optical fiber is preferably in the range of 1200 m/min to 3000 m/min.
Furthermore, there is provided an optical fiber produced by the method for producing an optical fiber according to an embodiment of the present invention, in which the optical fiber has an attenuation of 0.18 dB/km or less at 1550 nm.
According to an embodiment of the present invention, it is possible to produce an optical fiber having low attenuation, the optical fiber including a core that contains an alkali metal element.
Embodiments of the present invention will be described below with reference to the attached drawings. The drawings are provided for illustrative purposes and are not intended to limit the scope of the invention. In the drawings, the same elements are designated using the same reference numerals, and redundant description is not repeated. The ratios of dimensions in the drawings are not always the same as those of the actual objects described in the respective drawings.
According to findings of the inventors, in the case of producing an optical fiber including a core that contains an alkali metal element, when a heating time is prolonged by arranging an annealing furnace below a drawing furnace as in the production of an optical fiber composed of pure quartz, the resulting optical fiber has an increased attenuation, in some cases. Thus, in a method for producing an optical fiber according to the present invention, when an optical fiber preform including a core that contains an alkali metal element is drawn, a time that the optical fiber preform is heated in a drawing furnace is reduced.
In a method for producing an optical fiber according to an embodiment of the present invention, the average concentration of an alkali metal element (for example, potassium) added to a core of an optical fiber preform is 5 atomic ppm or more and preferably 50 atomic ppm or less in order to suitably achieve a reduction in loss. A higher potassium concentration results in a higher loss due to radiation exposure. Thus, the upper limit of the average potassium concentration in the core is 500 atomic ppm. The time the temperature of glass is maintained at 1500° C. or higher in a drawing furnace is 110 minutes or less. The drawing speed is preferably 1200 m/min or more and more preferably 1500 m/min to 2300 m/min. The optical fiber preform preferably has a diameter of 70 mm to 170 mm and more preferably 90 mm to 150 mm.
In this case, the optical fiber preform had a diameter of 140 mm. The drawing tension during the drawing of the optical fiber preform was 30 g (0.29 N) to 150 g (1.47 N). The glass fiber having a diameter of 200 μm or less was heated at 1500° C. or higher for 0.01 seconds to 0.3 seconds.
The core part of the drawn optical fiber is composed of a silica-based glass containing potassium, chlorine, and fluorine. The cladding part is composed of a silica-based glass containing fluorine and chlorine. The core part had an average potassium concentration of 0.1 atomic ppm to 100 atomic ppm. The core part of the drawn optical fiber had an average chlorine concentration of about 10,000 atomic ppm. The core part does not substantially contain dopants, such as a transition metal and GeO2, other than potassium, chlorine, and fluorine. The concentration of the dopants other than potassium, chlorine, and fluorine in the core part is 1 ppm or less.
When the drawing tension during the drawing of the optical fiber preform is higher or lower than the range of 30 g (0.29 N) to 150 g (1.47 N), the attenuation of the optical fiber is increased.
As illustrated in
An increase in tension applied to the glass increases the amount of residual stress change around the core. For example, the maximum amount of stress change per micrometer in a region extending from the center of the core to a radius of 15 μm (the region with a diameter of three times the MFD) is 16 MPa/μm at a force applied to the glass of 150 g (1.47 N). However, the maximum amounts of stress change per micrometer are 25 and 23 MPa/μm at 175 g (1.72 N) and 200 g (1.96 N), respectively. That is, the change in stress is significantly increased in the radial direction. This leads to a nonuniform glass structure, thereby disadvantageously increasing the attenuation. Accordingly, an optimum force applied to the glass during drawing is in the range of 30 g (0.29 N) to 150 g (1.47 N).
Also in this case, the optical fiber preform had a diameter of 140 mm.
As illustrated in
An optical fiber preform is drawn with the drawing apparatus 1 illustrated in
As illustrated in
An increase in drawing speed enables the diffusion of potassium to be inhibited. However, the upper limit of the drawing speed is 3000 m/min from the viewpoint of productivity and the power of the drawing furnace. Thus, the optical fiber preform preferably has a diameter of 70 mm to 170 mm and more preferably 90 mm to 150 mm. The drawing speed is preferably in the range of 1200 m/min to 2500 m/min and more preferably 1500 m/min to 2300 m/min.
In this case, the optical fiber preform had a diameter of 140 mm. The residence time in the drawing furnace is preferably 4 hours or less and more preferably 3 hours or less.
Optical fiber preforms each including a core that has an average potassium concentration of 5 atomic ppm were drawn with a drawing apparatus illustrated in
The drawing furnace has a short length, so that the resulting fiber is readily exposed to air. It is thus speculated that the length of time the fiber is maintained at 1500° C. or higher is reduced. Hence, the residence time in the furnace can be reduced even when the optical fiber preforms are drawn at low linear velocity, thereby reducing the attenuation.
Each of the optical fibers in Example 1 had a refractive index profile (the vertical axis representing the relative refractive-index difference with respect to the refractive index of pure SiO2) illustrated in
As described above, the resulting optical fibers had low attenuations and other satisfactory characteristics.
An optical fiber in Example 2 was produced by drawing an optical fiber preform at a linear velocity of 1700 m/min and a drawing tension of 50 g (0.49 N), the optical fiber preform having a diameter of 125 mm, a potassium-containing core, and a refractive index profile different from that in Example 1. The optical fiber had a refractive index profile (the vertical axis representing the relative refractive-index difference with respect to the refractive index of pure SiO2) as illustrated in
The core part may have a diameter of 6 μm to 20 μm. The relative refractive-index difference between the core part and the cladding part may be in the range of 0.2% to 0.5%. When the cladding part contains fluorine, the average refractive index of the cladding part is lower than the refractive index of the core part, the core part is made of silica-based glass which contains an alkali metal element as well as chlorine and fluorine elements, which are halogens, and the halogen concentration is the highest of all the additional elements in the core part, the attenuation is reduced. Furthermore, in the optical fiber preform, each of the core part and the cladding part may have a refractive-index structure. For example, while refractive index profiles as illustrated in
Number | Date | Country | Kind |
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2011-133307 | Jun 2011 | JP | national |
2012-063960 | Mar 2012 | JP | national |