The present invention relates to a method for producing a separator for use in a lithium-ion secondary battery and a method for slitting a separator original sheet.
Conventionally, a resin film material (such as a film and a sheet) has been widely used as a material of a separator for use in a battery. The resin film material, of which a separator original sheet is made up, is produced by being stretched in a width direction (transverse direction). This causes the resin film material to be a porous film material in which fine pores are formed in submicron order. The original sheet separator, which is made up of such a porous film material, is slit, by a slitting apparatus, into a plurality of separators each having a desired width. The plurality of separators obtained through slitting are separated in different directions by a roller provided on a downstream side of a position at which the separator original sheet is slit, and then wound up by a first take-up roll and a second take-up roll (FIG. 2 of Patent Literature 1).
Japanese Patent Application Publication Tokukai No. 2002-273684 (Publication date: Sep. 25, 2002)
The slitting apparatus described in Patent Literature 1 is arranged such that a position at which the plurality of separators are separated (separation position) is provided on a roller on a downstream side of a position at which the separator original sheet is slit (slit position). Unfortunately, such an arrangement increases a distance from the slit position to the separation position. This causes a long distance of conveyance of the plurality of separators, into which the separator original sheet is slit, being conveyed while being adjacent to each other. This may cause any one of the plurality of separators to be conveyed while skewing and overlapping adjacent one of the plurality of separators.
The object of the present invention is to provide a method for producing a separator and a method for slitting a separator original sheet, each of which prevents any one of a plurality of separators obtained through slitting from being conveyed while skewing and overlapping adjacent one of the plurality of separators.
In order to attain the above object, a method for producing a separator in accordance with the present invention includes: (a) slitting, in a direction in which a separator original sheet is conveyed, the separator original sheet into a plurality of separators; and (b) detaching, from a roller which the plurality of separators obtained through slitting in the step (a) first contact, one or more of the plurality of separators and another one or more of the plurality of separators at different positions provided on the roller in a circumferential direction of the roller.
In order to attain the above object, a method for slitting a separator original sheet in accordance with the present invention includes the steps of: (a) slitting, in a direction in which a separator original sheet is conveyed, the separator original sheet into a plurality of separators; and (b) detaching, from a roller which the plurality of separators obtained through slitting in the step (a) first contact, one or more of the plurality of separators and another one or more of the plurality of separators at different positions provided on the roller in a circumferential direction of the roller.
According to the present invention, it is possible to provide a method for producing a separator and a method for slitting a separator original sheet, each of which prevents any one of a plurality of separators obtained through slitting from being conveyed while skewing and overlapping adjacent one of the plurality of separators.
(a) of
(a) of
The following description will discuss, in order, a lithium-ion secondary battery, a separator, a heat-resistant separator, a method for producing the heat-resistant separator, a slitting apparatus, and a cutting section in accordance with the present embodiment of the present invention.
(Lithium-Ion Secondary Battery)
A nonaqueous electrolyte secondary battery, typically, a lithium-ion secondary battery has a high energy density, and therefore, currently widely used not only as batteries for use in devices such as personal computers, mobile phones, and mobile information terminals, and for use in moving bodies such as automobiles and airplanes, but also as stationary batteries contributing to stable power supply.
As illustrated in
(Separator)
The separator 12 is provided so as to be sandwiched between (i) the cathode 11 which is a positive electrode of the lithium-ion secondary battery 1 and (ii) the anode 13 which is a negative electrode of the lithium-ion secondary battery 1. The separator 12 separates the cathode 11 and the anode 13, allowing lithium ions to move between the cathode 11 and the anode 13. The separator 12 contains, for example, polyolefin such as polyethylene or polypropylene as a material.
As illustrated in (a) of
However, there are, for example, cases in which the temperature of the lithium-ion secondary battery 1 rises due to excessive charging of the lithium-ion secondary battery 1, a high current caused by short-circuiting of the external device, or the like. In such cases, the separator 12 melts or softens, and the pores P are blocked as illustrated in (b) of
However, in a case where a temperature of the lithium-ion secondary battery 1 sharply rises, the separator 12 suddenly shrinks. In this case, as illustrated in (c) of
(Heat-Resistant Separator)
As illustrated in (a) of
As illustrated in (b) of
(Production Steps of Heat-Resistant Separator Original Sheet (Separator Original Sheet))
How to produce the heat-resistant separator 12a of the lithium-ion secondary battery 1 is not specifically limited. The heat-resistant separator 12a can be produced by a well-known method. The following discussion assumes a case where the separator 12 contains polyethylene as a main material. However, even in a case where the separator 12 contains another material, the similar steps can still be applied to production of the separator 12.
For example, it is possible to employ a method including the steps of first forming a film by adding a plasticizer to a thermoplastic resin, and then removing the plasticizer with an appropriate solvent. For example, in a case where the separator 12 is made of a polyethylene resin containing ultrahigh molecular weight polyethylene, it is possible to produce the separator 12 by the following method.
This method includes (1) a kneading step of obtaining a polyethylene resin composition by kneading a ultrahigh molecular weight polyethylene with an inorganic filler such as calcium carbonate, (2) a rolling step of forming a film with the polyethylene resin composition, (3) a removal step of removing the inorganic filler from the film obtained in the step (2), and (4) a stretching step of obtaining the separator 12 by stretching the film obtained in the step (3).
In the removal step, many fine pores are provided in the film. The fine pores of the film stretched in the stretching step become the above-described pores P. The separator 12 formed as a result is a polyethylene microporous film having a prescribed thickness and a prescribed air permeability.
Note that, in the kneading step, 100 parts by weight of the ultrahigh molecular weight polyethylene, 5 parts by weight to 200 parts by weight of a low-molecular weight polyolefin having a weight-average molecular weight of 10000 or less, and 100 parts by weight to 400 parts by weight of the inorganic filler can be kneaded.
Thereafter, in a coating step, the heat-resistant layer 4 is formed on a surface of the separator 12. For example, on the separator 12, an aramid/NMP (N-methylpyrrolidone) solution (coating solution) is applied, and thereby, the heat-resistant layer 4 that is an aramid heat-resistant layer is formed. The heat-resistant layer 4 can be provided on only one surface or both surfaces of the separator 12. Alternatively, the heat-resistant layer 4 can be formed by using, for coating, a mixed solution containing a filler such as alumina/carboxymethyl cellulose.
A method of coating the separator 12 with a coating solution is not specifically limited as long as uniform wet coating can be performed by the method. The method can be a conventionally well-known method such as a capillary coating method, a spin coating method, a slit die coating method, a spray coating method, a dip coating method, a roll coating method, a screen printing method, a flexo printing method, a bar coater method, a gravure coater method, or a die coater method. The heat-resistant layer 4 has a thickness which can be controlled by adjusting a thickness of a coating wet film or a solid-content concentration in the coating solution.
It is possible to use a resin film, a metal belt, a drum or the like as a support with which the separator 12 is fixed or transferred in coating.
It is thus possible to produce a heat-resistant separator original sheet 12b (hereinafter, merely referred to as “separator original sheet 12b”) which is a separator original sheet on which the heat-resistant layer 4 is laminated (forming step). The separator original sheet 12b thus produced is wound around a core 53 having a cylindrical shape. Note that a subject to be produced by the above production method is not limited to the separator original sheet 12b. The above production method does not necessarily include the coating step. In a case where the method includes no coating step, the subject to be produced is a separator original sheet corresponding to the separator 12.
(Configuration of Slitting Apparatus 6)
The slitting apparatus 6 includes a wind-off roller 61. The wind-off roller 61 has a cylindrical shape and is rotatably supported. The core 53, which has a cylindrical shape and around which the separator original sheet 12b is wound, is fitted to the wind-off roller 61. The separator original sheet 12b is wound off from the core 53 to a route U or L. The separator original sheet 12b thus unwound is conveyed to a roller 77 via rollers 62, 63, 75, and 76 at a maximum speed of, for example, 100 m/min., and is wound on the roller 77.
The slitting apparatus 6 includes cutting sections 7. Each of the cutting sections 7 slits the separator original sheet 12b at a position corresponding to the roller 77, in a lengthwise direction (direction in which the separator original sheet 12b is conveyed (MD: Machine Direction)) so that the plurality of separators 12a are formed.
Take-up rollers 69a and 69b (first and second rolling sections) are provided one above the other in the slitting apparatus 6.
Out of the plurality of separators 12a, into which the separator original sheet 12b is slit by the cutting sections 7, odd-numbered separators 12a (one or more of the plurality of separators) and even-numbered separators 12a (another one or more of the plurality of separators) are detached, from the roller 77 which the separators 12a obtained through slitting first contact, at different positions provided on the roller in a circumferential direction of the roller 77 and are then conveyed in different directions. The odd-numbered separators 12a pass through the rollers 65a and 65b and are then wound around a plurality of cores 81a which are fitted to the take-up roller 69a. The plurality of cores 81a correspond to the respective odd-numbered separators 12a. The even-numbered separators 12a pass through the rollers 64a and 64b and are then wound around a respective plurality of cores 81b which are fitted to the take-up roller 69b. The plurality of cores 81b correspond to the respective even-numbered separators 12a. With the arrangement in which the separators 12a are separated upward and downward, respectively, and then wound up, it is possible to provide the take-up rollers 69a and 69b one above the other. This allows a reduction in area where the take-up rollers 69a and 69b are provided, as compared with a case where the take-up rollers 69a and 69b are provided one behind the other.
Note that the present embodiment has described an example in which (i) the odd-numbered separators 12a are wound up by the take-up roller 69a on an upper side and (ii) the even-numbered separators 12a are wound up by the take-up roller 69b on a lower side. However, the present invention is not limited to such a configuration. Alternatively, the odd-numbered separators 12a can be wound up by the take-up roller 69b on the lower side, and the even-numbered separators 12a can be wound up by the take-up roller 69a on the upper side.
Note also that the present embodiment has described an example in which the plurality of separators 12a are separated upward and downward and then wound up. However, the present invention is not limited to such a configuration. The plurality of separators 12a only need to be separated and conveyed in different directions. The slitting apparatus 6 illustrated in
(a) of
(Slit Position and Detachment Position)
(a) of
In the present embodiment, the separator original sheet 12b being conveyed in a direction of an arrow A1 is slit, by the blades 72 (
The separator original sheet 12b can be slit at a position corresponding to the roller 77. For example, the separator original sheet 12b can be slit at a position L5 at which the separator original sheet 12b is not wound on the roller 77 and floats in air, at the position L7 at which the separator original sheet 12b starts to be wound on the roller 77, or at the position L6 at which winding of the separator original sheet 12b on the roller 77 ends.
An odd-numbered one and an even-numbered one of the plurality of separators 12a, into which the separator original sheet 12b is slit at the positions L5, L7, L3, L2, L1, and L6, are detached from the roller 77 which the odd-numbered one and the even-numbered one of the plurality of separators 12a first contact, at the different detachment positions P2 and P3 provided on the roller 77 in a circumferential direction of the roller 77. As to the odd-numbered one of the plurality of separators 12a into which the separator original sheet 12b is slit at the position L6, one end of the odd-numbered one of the plurality of separators 12a, which end is on an upstream side, is in contact with the roller 77 at the position L6. Therefore, the roller 77 corresponds to a roller which the odd-numbered one of the plurality of separators 12a first contacts.
Grooves 77g are formed at respective positions, corresponding to the respective blades 72 of the cutting sections 7, on the circumferential surface of the roller 77. A diameter of the roller 77 is approximately 80 mm. A width in a transverse direction (TD: Transverse Direction) of the separator original sheet 12b is, for example, 300 mm to 2,000 m. A thickness of the separator original sheet 12b is, for example, 5 μm to 30 μm. A pitch between the grooves 77g is, for example, 33 mm to 300 mm. Each width of the grooves 77g is, for example, 0.8 mm. Each depth of the groves 77g is, for example, 5 mm.
A winding angle θ1 at which the separator original sheet 12b and the one or more of the plurality of separators 12a are wound on the roller 77 is preferably not less than 60 degrees so that (i) the separators are stably held and accordingly occurrence of a tear in an unexpected direction is suppressed and (ii) a wrinkle is prevented from occurring in the separators. A winding angle θ3 at which the separator original sheet 12b and the another one or more of the plurality of separators 12a is preferably not more than 225 degrees so that (i) contamination of the separators by a chip or the like is suppressed and (ii) a conveyance route along which the separators are conveyed is easily arranged. An angle (θ3-θ1) is preferably not less than 15 degrees so that interference of adjacent ones of the plurality of separators 12a with each other is suppressed. Accordingly, the winding angle θ1 is preferably not more than 210 degrees. The winding angle θ3 is preferably not less than 75 degrees.
With reference to
An angle θ2 formed by (i) a straight line via which the center of the roller 77 is connected to the slit position P1 and (ii) a straight line via which the center of the roller is connected to the detachment position P2 is approximately 75 degrees. A diameter of the roller 77 is 80 mm. Therefore, a distance on the roller 77 between the slit position P1 and the detachment position P2 is 80×π×(75/360)=52.3 mm.
It is assumed that an angle between (i) a start position P0 at which the separator original sheet 12b starts to be wound on the roller 77 and (ii) the slit position P1 is a winding angle θa. It is also assumed that an angle between (i) the slit position P1 and (ii) an end position P2 at which winding of the odd-numbered separators 12a ends is a winding angle θb (=θ2). It is also assumed that an angle between (i) the separation position P2 and (ii) an end position P3 at which winding of the even-numbered separators 12a ends is a winding angle θc.
The winding angle θa is preferably not less than 30 degrees so that transmission, to the slit position, of vibration of the separator original sheet 12b on an upstream side is suppressed. The winding angle θa is preferably not more than 135 degrees so that a conveyance route is easily arranged. The winding angle θb is preferably not less than 30 degrees so that (i) the plurality of separators 12a are stably held and accordingly occurrence of a tear in an unexpected direction of the plurality of separators 12a is suppressed and (ii) transmission, to the slit position, of vibration of the odd-numbered separators 12a on a downstream side is suppressed. The winding angle θc is preferably not less than 15 degrees so that interference of adjacent ones of the plurality of separators 12a with each other is suppressed. A winding angle (θb+θc) is preferably not more than 90 degrees so that the conveyance route is easily arranged. Therefore, the winding angle θb is preferably not more than 75 degrees. A winding angle (θa+θb+θc), at which the separator original sheet 12b and the plurality of separators 12a are wound on the roller 77, is preferably not more than 225 degrees so that (i) contamination of the plurality of separators 12a by a chip or the like is suppressed and (ii) the conveyance route is easily arranged. Further, the winding (θa+θb+θc) is preferably not less than 75 degrees so that a wrinkle is prevented from occurring in the separators.
Note that the present embodiment has described an example in which the slit position P1 is provided on the roller 77. However, the present invention is not limited to such a configuration. The slit position P1 can be, like the position L5 shown in
An angle θ4 formed by (i) a straight line via which the center of the roller 77 is connected to the slit position P1 and (ii) a straight line via which the center of the roller is connected to the detachment position P3 is approximately 90 degrees.
In a case where the slit position P1 and the detachment position P2 or P3 are provided on an identical roller, a distance between the slit position P1 and the detachment position P2 is short, as compared with a case where the detachment position P2 or P3 is provided on a roller on a downstream side of the roller on which the slit position P1 is provided. A short distance between the slit position P1 and the detachment position P2 results in a short distance of conveyance of the plurality of separators 12a, into which the separator original sheet 12b is slit at the slit position P1, being conveyed while being adjacent to each other. Therefore, for example, it is possible to prevent any one of the plurality of separators 12a from being conveyed while skewing and overlapping adjacent one of the plurality of separators 12a.
(Method of Slitting Heat-Resistant Layer)
In a case where the heat-resistant layer 4 (
(Upper Winding-Off Method and Lower Winding-Off Method)
A method of winding off the separator original sheet from the core 53 to the route U is referred to as an upper winding-off method, whereas a method of winding off the separator original sheet from the core 53 to the route L is referred to as a lower winding-off method. It is assumed that the separator original sheet is slit while being wound off by the upper winding-off method and the resultant separators (products) are wound up by an upper winding method. In this case, the separator original sheet wound around the core 53 is identical to the separators wound around the respective plurality of cores 81a and 81b in that the same surface faces outside. However, in a case where the separator original sheet is slit while being wound off by the lower winding-off method and the separators (products) are wound up by the upper winding method, the separator original sheet wound around the core 53 is different from the separators wound around the respective plurality of cores 81a and 81b in that different surfaces face outside.
A method for producing a separator in accordance with an aspect of the present invention includes: (a) slitting, in a direction in which a separator original sheet is conveyed, the separator original sheet into a plurality of separators; and (b) detaching, from a roller which the plurality of separators obtained through slitting in the step (a) first contact, one or more of the plurality of separators and another one or more of the plurality of separators at different positions provided on the roller in a circumferential direction of the roller.
Note here that the “separator original sheet” means a broad separator which has not been slit. The “direction in which a separator original sheet is conveyed” corresponds to a lengthwise direction (MD: Machine Direction) of the separator original sheet, and corresponds to a direction in which a subject to be produced is conveyed in the steps of producing the separator.
According to this feature, one or more of the plurality of separators and another one or more of the plurality of separators are detached from the roller at different positions provided on the roller in a circumferential direction of the roller. This decreases a distance from the slit position to the detachment position, as compared to the arrangement in which the detachment position is provided on a roller on a downstream side of a roller which the separators obtained through slitting first contact. This causes a short distance of conveyance of the plurality of separators, into which the separator original sheet is slit at the slit position, being conveyed while being adjacent to each other. Therefore, it is possible to prevent any one of the plurality of separators from being conveyed while skewing and overlapping adjacent one of the plurality of separators 12a.
The method for producing a separator in accordance with an aspect of the present invention is preferably arranged such that in the step (a), the separator original sheet is slit at a portion where the separator original sheet is in contact with the roller.
According to the above arrangement, the separator original sheet is slit at the portion where the separator original sheet is in contact with the roller. That is, the separator original sheet is slit in a state where the separator original sheet is held on the roller. This (i) causes behavior of the separator original sheet to be stable at the portion at which the separator original sheet is slit and (ii) accordingly allows acting of an unnecessary force on the slit part to be suppressed. It is therefore possible to prevent occurrence of a tear in an unexpected direction of such a separator.
The method for producing a separator in accordance with an aspect of the present invention is preferably arranged such that in the step (a), the separator original sheet is slit by a slitting blade provided on a side of the separator original sheet which side is opposite to a side on which the roller is provided; and the roller has a groove at a position corresponding to the slitting blade.
According to the above arrangement, the grove is formed at the position corresponding to the slitting blade. It is therefore possible to avoid a situation in which an edge of the slitting blade is in contact with the roller, and possible to suppress occurrence of wear on the edge and production of a chip.
The method for producing a separator in accordance with an aspect of the present invention is preferably arranged such that the one or more of the plurality of separators and the another one or more of the plurality of separators are detached, from the roller, on a downstream side of a position at which the separator original sheet is slit in the step (a).
According to the above arrangement, in a case where a detachment position at which the plurality of separators are detached and a slit position at which the separator original sheet is slit are the same position, a force caused by vibration acts on the plurality of separators being detached in the different directions, while the separator original sheet is being slit. This causes the plurality of separators being detached to be unstable and may cause a tear in an unexpected direction of the plurality of separators. However, according to the above arrangement, it is possible to reduce such a risk.
The method for producing a separator in accordance with an aspect of the present invention is preferably arranged such that the one or more of the plurality of separators and the another one or more of the plurality of separators are separated upward and downward, respectively, and wound up by respective first and second rolling sections which are provided one above the other.
The method for producing a separator in accordance with an aspect of the present invention is preferably arranged such that a heat-resistant layer is formed on one surface of the separator original sheet; and in the step (a), the one surface of the separator original sheet is in contact with the roller, and the separator original sheet is slit by a slitting blade provided on a side of the other surface of the separator original sheet on which surface no heat-resistant layer is formed.
A method for slitting a separator original sheet in accordance with an aspect of the present invention includes the steps of: (a) slitting, in a direction in which a separator original sheet is conveyed, the separator original sheet into a plurality of separators; and (b) detaching, from a roller which the plurality of separators obtained through slitting in the step (a) first contact, one or more of the plurality of separators and another one or more of the plurality of separators at different positions provided on the roller in a circumferential direction of the roller.
The present invention is not limited to the embodiments, but can be altered by a skilled person in the art within the scope of the claims. An embodiment derived from a proper combination of technical means each disclosed in a different embodiment is also encompassed in the technical scope of the present invention.
The present invention is applicable to a method for producing a separator for use in a lithium-ion secondary battery and to a method for slitting a separator original sheet.
Number | Date | Country | Kind |
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2014-263597 | Dec 2014 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2015/065013 | 5/26/2015 | WO | 00 |