Method for producing steel fibers

Abstract
A method of making steel fibers, preferably for use as a concrete additive, and for the supply thereof in making steel fiber concrete, characterized in that to form the steel fibers (2) first a sheet-metal strip (1) is notched either on one face or both faces so as to form steel-fiber wires (4) that are initially connected together by webs (5), and that further, for subsequently converting the webs (5) into thin easily mutually separable separation webs forming separation surfaces that are fracture-rough and low in burring upon separation, the steel-fiber strip is subjected to a flexing process in which each web (5) is subjected to multiple bending deformations about its longitudinal axis in such a way that incipient cracks are produced at the webs (5) due to fatigue fracture and thus the separation webs are produced.
Description
TECHNICAL FIELD

The invention concerns a method of making steel fibers, preferably for use as a concrete additive, and for the supply thereof in making steel fiber concrete. It has proven to be advantageous in many areas of use to add steel fibers to concrete instead of or in addition to the usual structural steel mats, where in particular the formation of microcracks in the new concrete is prevented. In addition the simple processing affords enormous labor savings and gives the concrete a longer service life. Depending on the application it is also possible to achieve higher tensile and flex strength as well as a higher load-bearing capacity.


BACKGROUND

Nonetheless making the steel fibers is complicated and expensive as they have to be either milled, cut as sheet-metal fibers from sheeting or strips, stamped and shaped, or shaped, bent and cut to length in the form of wire fibers individually or in packets.


SUMMARY

The object of the invention is to provide a method of the kind set forth in the introduction of this specification, which permits simple and inexpensive production of steel fibers.


According to the invention that object is achieved in that to form the steel fibers first a sheet-metal strip is notched either on one face or both faces so as to form steel-fiber wires that are initially connected together by webs, and that further, for subsequently converting the webs into thin easily mutually separable separation webs forming separation surfaces that are fracture-rough and low in burring upon separation, the steel-fiber strip is subjected to a flexing process in which each web is subjected to multiple bending deformations about its longitudinal axis in such a way that incipient cracks are produced at the webs due to fatigue fracture and thus the separation webs are produced.


The advantage achieved by the invention is essentially that a sheet-metal strip is used as the starting material for the steel fibers, so that not only is an advantageous starting material available, but in addition shaping of a multiplicity of steel-fiber wires can be done.


In that respect in accordance with the invention as a further advantage there is the possibility of the steel-fiber wires in the notching operation being provided with anchor formations formed by interruptions in the notching operation. Those anchor formations thus represent local cross-sectional enlargements due to upsetting in the notching operation and relative to the notched cross-section of the steel fibers. Those interruptions can be provided relative to the notching projections in the rolling tool so that making steel-fiber wires with anchor formations is possible in one working step, with positioning of the anchor formations at the ends of the steel fibers being particularly effective.


In accordance with a first embodiment of the invention the method is performed in such a way that the steel-fiber wires are shaped to extend transversely to the longitudinal direction of the sheet-metal strip.


In that respect in a further advantageous configuration there is the possibility that the steel-fiber wire strip provided with anchor formations after the notching operation and extending over the entire width of the sheet-metal strip is subdivided by separating blades forming two or more steel-fiber strips.


In that respect it is further advantageous if the subdivision forming a plurality of steel-fiber strips is carried out prior to the flexing process.


In a further procedure it is recommended that the steel-fiber strips after the flexing process pass through a shaping roller for shaping the steel fibers (crooked ends, upset ends, wave shape and so forth) to correspond to the intended use.


Finally this procedure involves the possibility of the steel-fiber strips being wound up after complete manufacture thereof. When the steel-fiber strip is in the form of a coil, a large amount of steel fibers are in ordered relationship and can be easily and quickly separated and made available in a compact and readily transportable fashion for transport to the position of use thereof. Therefore the invention further provides that separation of the steel-fiber strips to form steel fibers is carried out at the location of concrete preparation. In that way it is possible to dispense with equipment and measures with which nowadays “clumping” (lump formation of steel fibers in the concrete) is to be avoided. It will be appreciated that it is also possible for the separation operation to be performed in the production line if that is desirable or necessary.


In an alternative configuration of the invention however the steel-fiber wires can also be shaped to extend longitudinally of the sheet-metal strip.


In that respect after the flexing process optionally the upper face and/or the lower face of the strip can be easily roughened by knurling, in which case however that is also possible in comparable fashion in respect of the above-described alternative with steel-fiber wires extending transversely to the longitudinal direction of the sheet-metal strip. That makes it possible to achieve better adhesion in the concrete.


After those method steps the steel-fiber strip could optionally be wound into a coil and the subsequent method steps could then be implemented at the location of concrete preparation with a suitable piece of equipment.


In that respect the method further provides that then the steel-fiber wires oriented longitudinally of the strip are separated from each other.


In the further course of the method after their separation the steel-fiber wires are subjected by a shaping tool to a shaping operation corresponding to the intended use. That can involve producing a crooked shape of the steel-fiber ends, a wave-shaped configuration extending longitudinally, or the like.


Finally in this procedure the steel-fiber wires after shaping thereof are cut to the desired length so that the individual steel fibers are ready for use for the further application thereof.


Notching of the sheet-metal strip is advantageously effected in a V-shape, so that a notch apex angle W should be between 30° and 120°. In that respect a notch apex angle W of about 60° has proven to be particularly advantageous.


The thickness of the web should advantageously be 20% to 95% of the thickness of the strip.


In accordance with the invention the depth of the V-shaped notches is advantageously so selected that it corresponds to the strength of the sheet-metal strip and the intended use of the steel fibers.


In addition it has proven to be advantageous in accordance with the invention if the flexing process includes multiple bending deformation to one side of the plane of the steel-fiber strip, until incipient fatigue-fracture cracks form in the webs at the notch bottoms. Alternatively the flexing process can also include multiple bending deformation to both sides of the plane of the steel-fiber strip, until incipient fatigue-fracture cracks form at the webs at the notch bottoms.


In that respect the flexing process can take place in such a way that multiple bending deformation of the webs is done through equal angles in each case. Depending on the respective situation of use and material nature instead however it may also be more advantageous if the multiple bending deformation of the webs is done to one or both sides through increasing or also decreasing angles.


Preferably, multiple bending deformation of the webs should be effected at an angle less than the notch angle.


To completely separate the steel-fiber wires from each other the separation web can be broken by slight, oppositely directed deflection of immediately juxtaposed steel-fiber wires. More specifically in the case of steel fibers that extend transversely to the strip direction, the separation web can be severed in a separation apparatus like a zip fastener and thus the steel fibers can be individually separated while, in the case of the steel-fiber wires that extend longitudinally of the strip, the separation operation is carried out by shaping rollers by slight, oppositely directed deflection of immediately adjacent steel-fiber wires and thereafter the steel fiber is shaped and cut to length.


Preferably semifinished material of metal in strip form is used as the starting material.


With regard to the apparatus the object of the invention is attained by a steel-fiber strip of metal that has a plurality of mutually parallel steel-fiber wires connected together by webs and produced in accordance with at least one of the preceding method claims, characterized in that semifinished material in strip form is used as starting material and for forming the steel-fiber wires is notched on one face or on both faces and in the notching operation is provided with anchor formations, the webs being converted by multiple bending deformations by a flexing process to provide thin, easily separable separation webs that form low-burring and fracture-rough separation surfaces upon separation and that have fatigue fractures or incipient fatigue-fracture cracks and the steel-fiber wires and the steel-fiber strips are subjected to a shaping operation, steel fibers suitable as an additive to concrete being formed in the separation operation of the steel-fiber strips or the steel-fiber wire strips.


Incipient fatigue-fracture cracks are produced at the notch bottoms by the flexing process so that the webs are weakened. The remaining web residues—referred to as separation webs—can be very thin because they are at the neutral fiber of the bending operation; the steel-fiber wires can thus be later easily separated from each other into individual fibers.


Here high-quality steel-based or iron-based materials in all strength states that are standard on the market are provided as the metallic starting material. If the intended use requires it, the metallic starting material can also be coated in the form of metal strips, in particular galvanized or copper-plated steel strip. It is desirable in that respect in particular that the metallic material involved is materials with which—if required—particularly high strength values can also be achieved by rolling, for the respective group of materials.


Finally the invention concerns a steel fiber produced in accordance with the above-described method. It is characterized in that it is formed from semifinished material in strip form that is used as the starting material and that, for forming steel-fiber wires that are initially still connected together by webs, is notched on one face or on both faces and is provided with anchor formations in the notching operation, the webs being converted by multiple bending deformations by a flexing process to provide thin separation webs that form easily mutually separable separation surfaces that have low burring, are fracture-rough upon separation, and have a fatigue fracture. In that way that steel fiber forms a completely novel type of steel fiber.


In that respect it is desirable if the steel fiber is of a shape suitable for addition to concrete.





BRIEF DESCRIPTION OF THE DRAWINGS

The invention is described in greater detail hereinafter by means of embodiments by way of example illustrated in the drawing in which:



FIG. 1 is a diagrammatic view of the procedure according to the invention in a first embodiment with a steel-fiber wire extending transversely of the strip direction,



FIG. 2 shows a view corresponding to FIG. 1 of the procedure in an alternative configuration, with a steel-fiber wire extending longitudinally of the strip direction,



FIG. 3 shows a detail view of the notching roll, shown in developed form,



FIG. 4 shows a cross section through a notched strip of which only part is shown and that is intended for making the steel-fiber strip or steel-fiber wire strip, with notching already done,



FIG. 5 shows the notched strip subjected to flexing and intended for making the steel-fiber strip or the steel-fiber wire strip when bent, in FIG. 5a for steel-fiber wires extending longitudinally of the strip direction and in FIG. 5b for steel-fiber wires extending transversely of the strip direction,



FIG. 6 shows a system for severing the separation webs of the steel-fiber strip or steel-fiber wire strip,



FIG. 7 shows an only partial view in section through the wire strip at a notch,



FIG. 8 shows a separation apparatus for separating the steel fibers,



FIG. 9 shows different views of an individual steel fiber,



FIG. 10 shows a different configuration of individual steel fibers, and



FIG. 11 shows a steel fiber with an end cross-sectional enlargement in comparison with the cross-section of the steel fiber.





DETAILED DESCRIPTION

The method diagrammatically shown in the drawing, in particular in FIGS. 1 and 2, serves for making steel fibers 2 that are preferably used as a concrete additive. For that purpose, for forming the steel fibers 2, first a sheet-metal strip 1 is notched either on one face or on both faces between rollers 3, thereby forming steel-fiber wires 4 having anchor formations 7. Here, the steel-fiber wires 4 are to start with still connected together by webs 5, as can be seen from FIG. 4.


For subsequently converting the webs 5 to make thin, easily mutually separable separation webs that, when separated, form low-burring and fracture-rough separation surfaces, the steel-fiber strip formed by the steel-fiber wires 4 is flexed such that each web 5 is subjected to multiple flexings about its longitudinal axis as indicated in the drawing at 6. This way the regions of the webs 5 are formed with incipient cracks, due to fatigue fracture, and the separation webs are produced. Moreover, incipient scratching of the surface is done between the notches so that fatigue fracture is also triggered there to extend the bases of the notches.


During notching the steel-fiber wires 4 can also be provided with anchor formations 7 in the form of cross-sectional enlargements relative to the steel fiber cross-section, as can be seen from FIGS. 3 and 9. They serve for better anchoring the steel fibers 2 in the concrete and can be positioned at the appropriate location, corresponding to the intended use. In FIG. 9 the flexing fracture surface is also shown at 15.


In the configuration of the invention shown in FIG. 1 the steel-fiber wires 4 extend transversely to the longitudinal direction of the sheet-metal strip 1. Depending on the desired length of the steel fibers 2 they can either extend over the entire width of the sheet-metal strip 1; it is however also possible to provide separating blades 8 that subdivide the steel-fiber wire strip 1 into two or more steel-fiber substrips. That subdivision of the steel-fiber wire strip is desirably done prior to the flexing process.


After the flexing process the steel-fiber wire strip or strips pass through a shaping roller 9 that imparts to the steel fibers 4 a shape corresponding to the later intended use. As shown in FIG. 10 the ends of the steel fibers 2 can be for example of a crooked configuration; similarly the steel fibers 2 can be converted into a wavy shaped or shaped in some other suitable fashion. In particular the shape of the steel fiber ends can be altered, more specifically in the nature of an enlargement, as indicated in FIG. 11. That enlargement or thickening leads to particularly effective anchoring in the concrete.


After complete manufacture, the steel-fiber strips are wound into a coil so that they can be transported to the later position of use easily and in a space-saving fashion.


The step of separating the steel-fiber strips to obtain steel fibers 2 is thus carried out only at the location of concrete preparation, and for that purpose an individual separator as shown in FIG. 8 can be used. This is a high-speed toothed wheel 10 that separates the individual steel fibers 2. This further gives the advantage that, when the step of separating the steel fibers from one another is done at the concrete preparation location, the individual steel fibers 2 can be more homogeneously introduced into the concrete while otherwise—if the steel fibers 2 are supplied in already separated form—they have a tendency to “clumping” and thus result possibly in irregular distribution in the concrete.


There is however also the possibility of the steel-fiber wires 4 extending longitudinally of the sheet-metal strip 1, as shown diagrammatically in FIG. 2. In principle the procedure here is very similar; in addition here there is a further pair of rollers 11 that, after the flexing procedure, optionally roughen up the upper and/or the lower face of the strip 1 by knurling. That however is in principle also possible in the first variant of the operating procedure, in a similar form.


Here however, following the flexing process, the steel-fiber wires 4 extending longitudinally of the strip are separated from each other at 12. After that separation the shaping operation is then again done by means of a special shaping tool 13 which imparts to the steel fibers 2 the shaping required for the later use.


After that shaping operation the steel-fiber wires 4 are cut to the desired length for example by rotary shears 14 so that the steel fibers 2 can be packaged in separated condition and taken to the later location of use. The steel-fiber wire strip can also be wound up into a coil after the flexing process and the operation of separating the steel fibers can then be carried out by a suitable piece of equipment that separates, shapes and cuts them to length, at the location of concrete preparation.


Notching the sheet-metal strip 1 is effected in a V-shape, the notch angle W being between 30° and 120°, a notch angle W of about 60° being preferred.


The thickness of the initially remaining web 5 is in this case usually 20% to 95% of the thickness of the strip 1.


In accordance with the invention the depth of the V-shaped notches is advantageously so selected that it corresponds to the strength and purpose of use of the steel fibers.


The flexing process can take place in different ways; thus it is first conceivable that only multiple flexing deformation to one side relative to the plane of the steel-fiber strip 1 is done until fatigue fracture occurs at the webs 5. Equally however the flexing process can also entail multiple flexing deformation to both sides with respect to the plane of the steel-fiber strip, in which case the multiple flexing deformation of the webs 5 can either be done by identical angular amounts or however through increasing or decreasing angles. Details in that respect are also to be found in particular in FIGS. 5a and 5b.


In any event multiple flexing deformation of the webs 5 should be at an angle which is less than the notch angle W.


The separation webs in the case of the longitudinally oriented steel fibers are then broken locally transversely relative to the strip 1 by slight, oppositely directed deflection of immediately adjacent steel-fiber wires, which can be carried out by suitable shaping rollers and is shown in FIG. 6. In the case of transversely extending steel fibers, the separation operation is done in the separator (FIG. 8) as the last method step.


Usually the starting material used is semifinished metal in strip form, in which case in particular high-quality steel- or iron-based materials in all strength standard on the market are recommended. Insofar as particular purposes of use make it necessary it is also possible for that purpose to use coated metal strips, in particular galvanized or copper-plated steel strip. In any event the metallic material preferably is a material with which particularly high strength values can also be achieved by rolling, for the particular material group.


Finally a steel fiber produced in accordance with the above-described method is also the subject of the invention. It is formed from semifinished material in strip form as the starting material, and, to produce steel-fiber wires 4 that are initially connected together by webs 5, is notched on one or both faces. In the notching operation they are provided with anchor formations. The anchor formations are regions of larger cross-section of the steel fibers, which have been left by the notching operation by virtue of a suitable tool configuration and which are even still somewhat upset in the notching operation. The anchor formations are preferably positioned at the ends of the steel fibers, in that respect there also being the possibility of transversely extending steel fibers also being notched such that their transverse ends are also upset.


The webs 5 are subjected to incipient cracking on both faces due to fatigue fracture by virtue of multiple bending deformations by a flexing process and the web residue—the separation web—is later separated practically without deformation so that the separation surfaces have a low degree of burring and are fracture-rough.


The upper face and the lower face of the steel fibers can also be knurled and in addition the steel fiber can be provided with a shape suitable for addition to concrete and the intended use.

Claims
  • 1. A method of making steel fibers for use as a concrete additive, and for the supply thereof in making steel fiber concrete, the method comprising the steps of: to form the steel fibers, first notching a sheet-metal strip on one face or both faces so as to form steel-fiber wires that are initially connected together by webs, andthereafter, for converting the webs into thin easily mutually separable separation webs forming separation surfaces that are fracture-rough and low in burring upon separation, flexing the steel-fiber strip by subjecting each web to multiple bending deformations about its longitudinal axis, wherein the strip is alternated between an inclined position and a declined position with respect to the lateral width of the strip as the strip is subjected to the multiple bending deformations and in such a way that incipient cracks are produced at the webs due to fatigue fracture and thus the separation webs are produced.
  • 2. The method according to claim 1, wherein in the notching operation the steel-fiber wires are provided with anchor formations formed by interruptions in the notching operation.
  • 3. The method according to claim 1 wherein the steel-fiber wires are formed transversely to the longitudinal direction of the sheet-metal strip.
  • 4. The method according to claim 1 wherein the steel-fiber wire strip, which after the notching operation extends over the entire width of the sheet-metal strip, is subdivided by separation blades into two or more steel-fiber substrips.
  • 5. The method according to claim 4, wherein the steel-fiber wire strip is subdivided prior to the flexing process.
  • 6. The method according to claim 1 further comprising: passing the steel-fiber strips through a shaping roller.
  • 7. The method according to claim 1 wherein the steel-fiber wires are formed longitudinally of the sheet-metal strip.
  • 8. The method according to claim 1, wherein the steel-fiber wires oriented longitudinally of the strip are separated from each other.
  • 9. The method according to claim 1 further comprising: separating the steel-fiber strip in the separation web; andshaping after the steel-fiber wires with a shaping tool.
  • 10. The method according to claim 1 wherein the notching produces notches of V-shape.
  • 11. The method according to claim 10, wherein a notch angle is between 30° and 120°.
  • 12. The method according to claim 1, wherein the thickness of the webs is 20% to 95% of the thickness of the strip.
  • 13. The method according to claim 1, wherein the flexing process includes multiple bending deformation to one side of a plane of the steel-fiber strip until fatigue fracture at the webs.
  • 14. The method according to claim 1 wherein the flexing process includes multiple bending deformation to both sides of a plane of the steel-fiber strip until incipient fatigue fracture cracks occur at the webs.
  • 15. The method according to claim 14, wherein the multiple bending deformation of the webs is done through an angle less than the notch angle.
  • 16. The method according to claim 1 wherein the separation webs are locally broken by slight oppositely directed deflection of immediately adjacent steel-fiber wires.
  • 17. A steel-fiber strip or steel-fiber wire strip of metal having a plurality of parallel steel-fiber wires connected together by webs and produced in accordance with claim 1, wherein semifinished material in strip form is used as starting material and that, for forming steel-fiber wires initially still connected together by webs, is notched on one face or on both faces and in the notching operation is provided with anchor formations, wherein the webs are converted by multiple bending deformations by means of a flexing process to form thin easily separable separation webs that form low-burring and fracture-rough separation surfaces upon separation and that have fatigue fractures, and the steel-fiber wires and the steel-fiber strips are subjected to a shaping operation such that steel fibers suitable as an additive to concrete are formed in the individual separation operation of the steel fibers from the steel-fiber strip or the steel-fiber wire strip.
  • 18. The steel-fiber strip or steel-fiber wire strip according to claim 17, wherein the starting material includes at least one of galvanized steel and copper-plated steel.
  • 19. The steel-fiber strip or steel-fiber wire strip according to claim 17, wherein the metallic starting material is a material with which particularly high strength values can also be achieved by rolling for the respective material.
  • 20. The steel fiber strip or steel fiber wire strip of claim 17, wherein the separation web includes a substantially burr-free wire when separated from an adjacent steel fiber strip.
Priority Claims (1)
Number Date Country Kind
10-2008-034-250 U Jul 2008 DE national
US Referenced Citations (54)
Number Name Date Kind
867090 Wolf Sep 1907 A
872127 Havemeyer Nov 1907 A
928430 Dudley Jul 1909 A
931185 Dudley Aug 1909 A
931322 Lindau Aug 1909 A
939962 Jenks Nov 1909 A
982682 Johnson Jan 1911 A
984283 Maxwell Feb 1911 A
1023149 Havemeyer Apr 1912 A
1076439 McKibbin Oct 1913 A
1147603 Boyer Jul 1915 A
1164477 Dale et al. Dec 1915 A
1280046 Kuhne Sep 1918 A
1364182 Conkling Jan 1921 A
1423163 Simpson Jul 1922 A
1477378 Ohlson et al. Dec 1923 A
1635658 Boardman Jul 1927 A
2053375 Nicholas Sep 1936 A
2216869 Yoder et al. Oct 1940 A
2347904 Greulich May 1944 A
2635493 Schumacher Apr 1953 A
2659950 West Nov 1953 A
2775151 Schumacher Dec 1956 A
2948084 Shockey Aug 1960 A
3092470 Ripling Jun 1963 A
3170279 Dubini Feb 1965 A
3214877 Akin Nov 1965 A
3628710 Stehle Dec 1971 A
3953953 Marsden May 1976 A
4008597 Bartram et al. Feb 1977 A
4011109 Golland et al. Mar 1977 A
4066165 Ruskin Jan 1978 A
4109500 Franek Aug 1978 A
4137686 Kern Feb 1979 A
4155238 Rogers May 1979 A
4267985 Rogers May 1981 A
4305187 Iwamura et al. Dec 1981 A
4804585 Tani et al. Feb 1989 A
4883713 Destree et al. Nov 1989 A
4960649 Takata et al. Oct 1990 A
5039366 Strattman Aug 1991 A
5215830 Cinti Jun 1993 A
5451471 Over et al. Sep 1995 A
5477721 Barnes Dec 1995 A
5989713 Naaman Nov 1999 A
6060163 Naaman May 2000 A
6235108 Lambrechts May 2001 B1
7316849 Boegel et al. Jan 2008 B2
20030152738 Boegel et al. Aug 2003 A1
20060121241 Bonds Jun 2006 A1
20070050960 Stuhlbacher et al. Mar 2007 A1
20070261354 Chang Nov 2007 A1
20100129678 Stahl May 2010 A1
20110212343 Stahl Sep 2011 A1
Foreign Referenced Citations (37)
Number Date Country
287820 Jun 1913 DE
540837 Dec 1931 DE
805711 May 1951 DE
1627152 Dec 1970 DE
1930914 Dec 1970 DE
2651126 May 1977 DE
9000846 Jun 1991 DE
0098825 Jan 1984 EP
0392039 Oct 1990 EP
0529105 Mar 1993 EP
0608013 Jul 1994 EP
0861948 Sep 1998 EP
1356887 Oct 2003 EP
1375773 Jan 2004 EP
1623774 Feb 2006 EP
1840291 Oct 2007 EP
1382445 Dec 1964 FR
537553 Jun 1941 GB
664170 Jan 1949 GB
1247943 Sep 1971 GB
2053754 Feb 1981 GB
212747 Oct 1996 HU
57094403 Jun 1982 JP
58032529 Feb 1983 JP
58143910 Aug 1983 JP
61125719 Jun 1986 JP
61067502 May 1989 JP
H1034253 Feb 1998 JP
471164 May 1975 SU
2008135002 Nov 2008 WO
2011018063 Feb 2011 WO
2011018064 Feb 2011 WO
2011041995 Apr 2011 WO
2012031577 Mar 2012 WO
2013029595 Mar 2013 WO
2013050013 Apr 2013 WO
2013071912 May 2013 WO
Non-Patent Literature Citations (16)
Entry
JP 57094403 A—English abstract.
EP 0098825A1—English translation.
EP 1356887—English abstract.
HU 212747—Claims as granted in English.
HU 212747—Abstract.
JP H1034253 A—English translation.
JP 60167502—Abstract.
JP 58032529—Abstract.
SU 471164 A1—machine translation.
EP 0392039 A—Abstract.
US4011109A English counterparts to DE 2651126 A.
DE 1627152 A—English abstract.
DE 9000846—machine translation.
International Search Report for PCT Application No. PCT/DE2009/000736 dated Jan. 28, 2010.
International Preliminary Report on Patentability for PCT Application No. PCT/DE2009/000736 dated Jan. 25, 2011.
International Preliminary Report on Patentability in International Application No. PCT/DE2008/000224, dated Nov. 10, 2009.
Related Publications (1)
Number Date Country
20150202670 A1 Jul 2015 US
Continuations (1)
Number Date Country
Parent 13002734 US
Child 14631297 US