Patent Application
20100181041
The invention pertains to a method for production of precision castings by centrifugal casting. The method in particular pertains to the production of precision castings made of titanium or alloys containing large amounts of titanium, e.g. titanium aluminides.
Especially titanium aluminides are considered an optimum material in various areas of application because of their low density, relatively high-temperature, specific strength relative to nickel superalloys, and corrosion resistance. However, materials with a narrow range between solidus and liquidus temperature, like TiAl or pure titanium grade 2, are very difficult to shape, the only practical method for forming them is to cast them.
When casting such materials one is encountered with further problems like an unusual high amount of shrinkage of the intermetallic phase (y-TiAl) during solidification resulting in the formation of shrinkholes, voids, pores, etc. in castings. This makes it usually necessary to reprocess the casting by expensive high-pressure compaction (HIP method).
Further, when casting such materials in molds having a complicated geometry, like shrouded tubine blades, the casting frequently shows damages shows damages like cracks, e.g. hot tears, or even torn off blade shrouds. These are strain induced damages corresponding to a rapid shrinkage during the solidification process.
An object of the present invention is it to avoid the disadvantages in the art. It is an aim of the present invention to provide a method allowing a production of castings having less pores, shrinkholes, voids and the like, thereby avoiding an expensive reprocessing by high-pressure compaction. A further aim of the present invention is to provide a method by which castings having a complicated geometry can be produced without strain induced damages.
This object is solved by the features of independent claims 1 and 22. Advantageous embodiments of the invention are described by the features of claims 2 to 21 and claims 23 to 41.
In accordance with the present invention there is provided a method for production of precision castings by centrifugal casting, comprising the following steps:
In the sense of the present invention under a “crucible” there is in general understood a container which has sufficient heat resistance to take up a metallic melt without being damaged and without undergoing reactions with the metal melt. A “crucible” in the sense of the present invention may have any suitable shape. In particular it may have a cylindrical shape the bottom of which has a rounded concave shape. However, a “crucible” in the sense of the present invention may also be formed as a ring-like channel. Suitable materials for the production of a crucible are alumina, Y2O3, magnesia, silica glass, graphite and the like.
The proposed method differs from conventional method in particular in that there is exerted a pressure on the melt after the mold has completely been filled.—The pressure is exerted on the melt until a predetermined cooling-temperature in a range of 1300° C. to 800° C. has been reached. The predetermined cooling-temperature depends on the used metal alloy. The predetermined cooling-temperature is advantageously selected to be lower than a brittle-ductile transition temperature of the used alloy. Under the term “brittle-ductile transition temperature” there is understood a temperature at which the bonds of an intermetallic phase change from metal bonds to atomic bonds. At temperatures above the brittleductile transition temperature intermetallic phases are bond by metal bonds. At such temperatures intermetallic phases are ductile. At a temperature below the brittle-ductile transition temperature intermetallic phases change their properties and become brittle. The predetermined cooling-temperature can be choosen to be for example 20° C. to 200° C. lower than the brittle-ductile transition temperature.
The amount of the pressure which is exerted on the melt after the mold is completely filled corresponds to the centrifugal force acting on the melt at the moment when the mold is completely filled times a factor of 1.0 to 5.0. The centrifugal force depends on the rotational speed of the rotor, the first radius at which the mold is distanced from the axis and the mass of the melt. Under the term “first radius” there is understood the distance between the axis and an inlet opening of the mold. According to the invention the pressure to be exerted on the melt is the centrifugal force at the precise moment of completely filling of the mold times a factor which is selected from a range of 1.0 to 5.0. From this relation one can calculate a suitable pressure to be exerted on the melt for molds being placed at a different first radius from the axis as well as for any mass of metal melt which is taken up in the mold. As can be seen from the above relation the pressure being exerted upon the melt after the mold is completely filled may be higher than during the time when the mold is being filled. According to an embodiment the pressure may be increased after the mold has been filled, preferably at a constant rate, for a predetermined period and afterwards there may be exerted a constant pressure on the melt. The predetermined period may be in the range of 1 to 25 seconds, preferably 5 to 20 seconds. The period of the constant pressure may be in range of 1 to 6 minutes, preferably of 4 to 6 minutes.
When reaching the predetermined cooling-temperature the pressure is relieved so that in maximum the atmospheric pressure is acting upon the melt.
By the proposed exerting of a pressure on the solidifying melt being hotter than the predetermined cooling-temperature a formation of pores, voids, shrinkholes and the like in the castings can be significantly reduced. It is in particular not necessary to reprocess the casting by high-pressure compaction. A particular advantage is that a formation of strain induced damages can be avoided even when producing castings with a complicated geometry, like shrouded turbine blades and vane clusters.
According to an embodiment of the invention the crucible is accommodated in the rotor at a second radial distance from, the axis, the second radial distance being smaller than the first radial distance. The second radial distance may be calculated from an outlet opening of the crucible to the axis. Usually, the second radial distance is larger than a diameter of the crucible. If the crucible and the associated mold are both accommodated eccentrically with respect to the axis of the rotor it is possible to create higher centrifugal forces acting upon the melt at comparable rotating speeds. Thereby the mold can rapidly be filled and the formation of cold runs can be avoided. This further improves the quality of the casting in that less pores, voids or shrinkholes are created.
It is possible to create the melt in the crucible while the rotor is standing, i.e. while the rotor is not rotating. In this case the melt can be created by inductively heating an ingot within the crucible. It is also possible to heat the ingot or to support the heating of the ingot by microwaves. By the proposed heating methods an ingot can be melt within several minutes.
According to a further advantageous feature the mold is preheated before step lit. c. The temperature of said preheating may be in the range of 50° C. to 1100° C., preferably in the range of 850° C. to 1100° C. Such a preheating temperature is in particular useful when producing turbine blades. For example for the production of turbo charger wheels it has been proofed to be advantageous to use a temperature for said preheating in the range of 50° C. to 250° C. It has to be understood that the preheating temperature of the mold depends from the geometry of the casting and has to be determined for each geometry.
The preheating of the mold can take place for example in a furnace from which the mold is transferred into the rotor before a centrifugal casting takes place. However, it is also possible to preheat the mold by suitable heating device being provided at the centrifugal casting device, in particular at the rotor. By preheating the mold an undesirable quenching of the melt being forced into the mold can be avoided. Surface quality of the casting can be improved. By preheating the mold in particular an undesirable reaction of the melt with the mold material can be counteracted.
According to a further advantageous feature the predetermined cooling-temperature is in a range of 1050° C. to 800° C. Predetermined cooling-temperatures selected from this range are usually lower than the brittle-ductile transition temperature of titanium aluminides. When choosing a cooling-temperature from the proposed range and exerting a pressure upon the melt until the choosen predetermined cooling-temperature is reached castings made of titanium aluminides can be produced with an excellent quality.
The pressure can be exerted upon the melt in different manners. According to a simple embodiment the pressure is exerted upon the melt by rotating the rotor. In this case the pressure is created by centrifugal forces acting upon the melt. However, it is also possible to exert the pressure upon melt for example by pressurised gas. In this case as gas there may be used preferably an inert gas like Argon or the like.
According to a further embodiment of the invention during steps lit. c to lit. e the melt is under vacuum or shield gas. In particular the use of vacuum is advantageous as therewith a formation of gas-filled pores and an oxidation of the metal, in particular of titan aluminides, can be avoided. It has been proven appropriate to use a vacuum of 10−1 to 10−2 bar in order to avoid the formation of in particular gas-filled pores.
According to a further embodiment the solidifying melt is cooled down after step lit. e to room temperature at a cooling-rate of 50° C. to 150° C. per hour. Such a cooling-rate can be realised by the use of molds having suitable thermal isolation properties. Molds without suitable thermal isolation properties may be placed in a furnace which is preheated upon a temperature which is in the range of the predetermined cooling-temperature. After transferring the mold into the furnace it may be cooled down by controlling the heating elements of the furnace so that the aforementioned cooling-rate is realised within the furnace. The proposed controlled cooling down of the mold also counteracts the formation of hot tears in the casting.
The proposed method is in particular well suited for producing castings from a metal melt consisting of a titanium alloy. The titanium alloy advantageously comprises Ti and Al as main constituents. A suitable composition (in at. %) of a γ-TiAl based alloy may be summarised as follows:
Ti45-52 at. %Al45-48 at. % X11-3 at. %X22-4 at. %X31 at. %,
where
For example, the titanium alloy may contain 30 to 45 wt. % Al, 1.5 to 6 wt. % Nb and as balance Ti as well as unavoidable impurities. The titanium alloy may further contain one or more of the further constituents: 0.5 to 3.0 wt. % Mn, 0.1 to 0.5 wt. % B, 1.5 to 3.5 wt. % Cr. Further, the titanium alloy may contain O in an amount of 0 to 1000 ppm, C in an amount of 0 to 1000 ppm, preferably 800 to 1200 ppm, Ni in an amount of 100 to 1000 ppm and N in an amount of 0 to 1000 ppm.
According to a further embodiment of the invention the melt is heated up during step lit. b to a temperature which is 50° C. to 150° C. higher than the melting temperature of the metal. By this measure the heat energy of the melt is increased. When using such a superheated melt in particular an undesirable formation of cold runs in molds for castings having thick wall sections, i.e. sections with a thickness in the range of 0.5 mm, can be avoided.
According to an alternative solution of the object in step lit. b the metal melt is poured into the crucible. This allows a production of larger quantities of metal melt. If in the rotor there is accommodated a multitude of molds, a multitude of castings can be produced simultaneously.
According to an advantageous embodiment the melt may be poured into the crucible while the rotor is rotating. By this measure the melt being poured into the crucible can be accelerated rapidly and can be forced with a high speed into the mold. Consequently, the mold is filled with the melt being at a relatively high temperature which in turn guaranties a certain mobility of the melt and therefore the pressure being exerted upon the melt during step lit. d can effectively be used to cold runs and to reduce pores.
It has been proven appropriate that the crucible has the form of a ring-shaped channel being centrally accommodated in the rotor, the outer circumference of which having a second radial distance from the axis, the second distance being smaller than the first radial distance. According to this feature the melt is poured into a ring-shaped channel at a radial distance with respect to the axis. Consequently, the centrifugal force acting upon the melt and therefore the velocity by which the melt is transferred into the mold can be increased by this measure.
With respect to further embodiments of the alternative method reference is made to the above transcription of the embodiments regarding the method. The features described there can be also embodiments of the alternative method.
Embodiments of the invention are now described in detail with reference to the accompanied figures:
a shows a first plot of the rotational speed of a rotor over the time and
b shows a second plot of the rotational speed of a rotor over the time.
Nearby the outer end of each arm 2 there is provided a first crucible 6 made of a heat resistant material, e.g. silica glass or the like. The first crucible 6 is mounted at a bottom of the arm 2, preferably in a gas-tight manner.
The first crucible 6 is surrounded by an induction-coil 7 which can be moved in an essentially vertical direction. In an lower position (not shown here) of the induction-coil 7 it does not surround the first crucible 6 so that the first crucible 6 can be rotated with the rotor 1 around the axis A. Within the first crucible 6 there is accommodated a second crucible 8 having a outlet opening 9 which is placed opposite to the inlet opening 5 of the mold 4.
The second crucible 8 is made of a heat-resistant material, e.g. alumina, Y2O3, graphite or the like. According to a preferred embodiment of the invention the second crucible 8 is made of alumina, magnesia or the like. There may be provided a third crucible (not shown here) made of graphite which may be placed within the second crucible 8. By the use of the third crucible an inductive melting of an ingot taken up therein can be accelerated.
Opposite to a bottom of the second crucible 8 there is provided a window 10 through which by means of a camera 11 the melting of the ingot may be observed.
A hollow shaft 12 extending vertically from the rotor 1 may be driven by an electric motor (not shown here).
In an embodiment of the invention there is provided a vacuum source, e.g. a vacuum pump or the like, which is connected by means of a conventional sealing with the hollow shaft 12 to create within the rotor 1, which is designed in this case in a gas-tight manner, a vacuum.
In a second embodiment of the invention the rotor 1 may have breakthroughs 13. The rotor 1 may be surrounded by a gas-tight housing 14. The vacuum source may be connected to the gas-tight housing 14 to create therein and thereby also within the rotor 1 a vacuum.
In another embodiment of the invention there is provided instead of a vacuum source a source of a shield gas, e.g. Ar or the like, by which the hollow structure surrounded by the rotor 1 may be flooded during the centrifugal casting process.
As can be seen from
It has to be understood that the rotor 1 may comprise more than two arms 2, e.g. 4, 6, 8 or more arms. The rotor 1 may also be disk-shaped.
According to a further embodiment within the rotor 1 there may also be accommodated a first and a second crucible which are formed like ring-channels. These ring like channels again may be made for example of a heat-resistant ceramic like silica-glass, alumina, graphite and the like. One or more ingots taken up in the second crucible, which is formed as a ring-channel, may be again heated by an induction-coil, which surrounds an inner and an outer diameter of the first crucible, which is as well formed like a ring-channel and which accommodates the second ring-channel like crucible.
The second ring-channel like crucible may have several outlet openings. Vis-á-vis each outlet opening there is accommodated in a radial direction a corresponding mold with their inlet opening.
The fourth crucible 16 is arranged centrically with respect to the axis A. A lid 17 having a centrically arranged opening 18 covers the fourth crucible 16. A fifth crucible 19 may be connected via a tube 20 with the opening 18 so that a melt can be poured from the fifth crucible 19 through the opening 18 into the fourth crucible 16.
By using the first device a precision casting may be produced as follows:
A titanium aluminide ingot is placed in the second crucible 8. The respective titanium aluminide alloy may have e.g. one of the following compositions:
a) 31 wt. % Al, 5 wt. % Nb, 1.5 wt. % Mn, 0.3 wt. % B and as balance Ti as well as unavoidable impurities;
b) 43 wt. % Al, 2 wt. % Nb and as balance Ti as well as unavoidable impurities;
c) 33 wt. % Al, 5 wt. % Nb, 2.5 wt. % Cr and as balance Ti as well as unavoidable impurities.
A mold which may be made of a ceramic being lined at there interior contact surface with Y2O3 is preheated in a furnace up to a temperature of around 1000° C. Suitable materials for the production of a mold are for example disclosed in the WO 2005/039803 A2.
The mold 4 being preheated to a temperature of around 1000° C. is mounted at the arm 2 and then covered with the piston 3 which is mounted in a gas-tight manner at the arm 2. In dependency on the number of arms 2 provided at the rotor 1 a multitude of molds 4 can be mounted at the rotor 1.
The ingot is then melt by inducing currents with the induction-coil 7. When the melt has reached a temperature in the range of 1400° C. to 1700° C., preferably in the range of 1450° C. to 1650° C., the rotor 1 is accelerated within 0.5 to 2.0 seconds, preferably within less than 1.5 seconds, upon rotational speed of 110 to 260 rpm, preferably with 100 to 160 rpm. The second radius r2 is in this case chosen to be 300 to 400 mm, preferably around 350 mm. The melt is forced by centrifugal forces from the second crucible 8 into the mold 4.
Afterwards the mold 4 has been filled with melt the rotor 1 is furtheron rotated at a rotational speed of 110 to 260 rpm, preferably of at least 160 rpm, for at least 60 seconds, preferably for 120 to 300 seconds. During the further rotation of the rotor 1 the rotational speed may be increased at a constant rate, e.g. from initial rotational speed selected from a range of 110 to 160 rpm to a rotational speed selected from a range of 180 to 260 rpm when the solidifying melt in the mold 4 has reached predetermined cooling-temperature in the range of 1300° C. to 1100° C.
The temperature of the solidifying melt in the mold 4 may be determined by conventional temperature measuring techniques using for example a thermocouple. The temperature values measured therewith may be corrected in accordance with a suitable algorithm in a conventional manner.
When the rotation of the rotor 1 has been stopped the mold 4 is demounted from the arm 2 and then placed in the furnace which is preheated on a temperature of around 1000° C. The mold 4 is then cooled down within the furnace with a rate of 50° C. to 100° C. per hour.
According to an embodiment of the aforementioned method the rotor 1 may be evacuated before melting the ingot within the second crucible 8. The vacuum within the rotor 1 may be in the range of 10−1 to 10−2 bar. Alternatively the rotor 1 may be flooded with shield gas, for example Ar before melting the ingot.
By use of the second device precision castings by centrifugal casting can be produced as follows:
Molds 4 are preheated in a similar manner as described above in a furnace up to a temperature of 1000° C. and then placed in suitable holding devices provided within the rotor 1.
The rotor 1 is accelerated upon a rotational speed in the range of 110 to 260 rpm. As soon as the melt has reached a predetermined temperature in the range of 1450° C. to 1650° C. the melt taken up in the fifth crucible 19 is poured into the fourth crucible 16. The melt is than forced through the outlet openings 9 provided at the fourth crucible 16 in the molds 4 which are located vis-á-vis.
Afterwards, the rotor 1 is furtheron rotated as described above. After stopping the rotation the molds 4 are demounted from the rotor 1 and cooled down as described above.
a and 3b show plots of the rotational speed of the rotor above the time. In
When using the first device an ingot is melt within the second crucible 8. As soon as predetermined temperature of the melt has been reached the rotor 1 is accelerated within less then one second up to a rotational speed of around 140 rpm. Observations have shown that the melt is completely forced into the mold one second after starting the rotation of the rotor 1. As can be seen from
When using the second device shown in
By the proposed exerting of a centrifugal force on the solidifying melt in particular the formation of hot tears can be successfully be avoided. In the production of castings made from titan aluminides it has been proven to be advantageous to stop the exerting of the centrifugal force after the solidifying melt has reached a temperature which is lower than the brittle-ductile transition temperature of the material. Further, it is advantageous to increase the centrifugal force after the mold has completely being filled at the time when the melt is hot and mobile.
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/EP2006/010191 | 10/23/2006 | WO | 00 | 5/8/2009 |
