Method for purifying and producing acrylic acid

Abstract

The objective of the present invention is to provide methods of efficiently purifying and producing acrylic acid by removing solid acrylic acid polymers dissolving and existing in crude acrylic acid supplied to purifying process. The purifying method of the present invention comprises: filtrating the crude acrylic acid to obtain a filtrate at temperature from 15 to 70° C. and at liquid linear velocity of 5 m/s or less, wherein the crude acrylic acid contains an acrylic acid of 50% by mass or more; and purifying the acrylic acid from the filtrate. The producing method of the present invention comprises carrying out the purifying method.

Description

Claims

1. A method for purifying acrylic acid from a crude acrylic acid obtained by at least one of absorbing or condensing an acrylic acid-containing gas produced by catalytic vapor phase oxidation reaction, comprising: filtrating the crude acrylic acid to obtain a filtrate at temperature from 15 to 70° C. and at liquid linear velocity of 5 m/s or less, wherein the crude acrylic acid contains an acrylic acid of 50% by mass or more; andpurifying the acrylic acid from the filtrate.

2. A method for purifying acrylic acid from a crude acrylic acid obtained by at least one of absorbing or condensing an acrylic acid-containing gas produced by a catalytic vapor phase oxidation reaction, comprising: filtrating the crude acrylic acid to obtain a first filtrate at temperature over 70° C. and at liquid linear velocity of 5 m/s or less, wherein the crude acrylic acid contains an acrylic acid of 50% by mass or more;further filtrating the first filtrate to obtain a second filtrate at temperature from 15 to 70° C. and at liquid linear velocity of 5 m/s or less; andpurifying the acrylic acid from the second filtrate.

3. The method according to claim 1, wherein the purifying is carried out by as least one of distillation or crystallization.

4. The method according to claim 2, wherein the purifying is carried out by as least one of distillation or crystallization.

5. The method according to claim 1, wherein the purifying is carried out by crystallization.

6. The method according to claim 2, wherein the purifying is carried out by crystallization.

7. A method for producing acrylic acid, comprising: producing an acrylic acid-containing gas by catalytic vapor phase oxidation reaction;obtaining a crude acrylic acid containing an acrylic acid of 50% by mass or more by at least one of absorbing or condensing the acrylic acid-containing gas;filtrating the crude acrylic acid to obtain a filtrate at temperature from 15 to 70° C. and at liquid linear velocity of 5 m/s or less; andpurifying the acrylic acid from the filtrate.

8. A method for producing acrylic acid, comprising: producing an acrylic acid-containing gas by catalytic vapor phase oxidation reaction;obtaining a crude acrylic acid containing an acrylic acid of 50% by mass or more by at least one of absorbing or condensing the acrylic acid-containing gas;filtrating the crude acrylic acid to obtain a first filtrate at temperature over 70° C. and at liquid linear velocity of 5 m/s or less;further filtrating the first filtrate to obtain a second filtrate at temperature from 15 to 70° C. and at liquid linear velocity of 5 m/s or less; and purifying the acrylic acid from the second filtrate.