Method for reducing nitrogen oxide emissions of a recovery boiler, and a recovery boiler

Information

  • Patent Application
  • 20070295249
  • Publication Number
    20070295249
  • Date Filed
    June 20, 2007
    17 years ago
  • Date Published
    December 27, 2007
    16 years ago
Abstract
A method for reducing nitrogen oxides of a recovery boiler, and a recovery boiler, where the furnace of the recovery boiler is supplied with primary air from primary air nozzles, black liquor from liquor nozzles, secondary air from secondary air nozzles above the primary air nozzles but still below the liquor nozzles, tertiary air from tertiary air nozzles above the liquor nozzles, and quaternary air from quaternary air nozzles above the tertiary air nozzles. Black liquor is supplied to the furnace from first liquor nozzles and second liquor nozzles, which liquor nozzles are arranged substantially on the same level with respect to the height of the furnace, and the droplet size of liquor fed from the second liquor nozzles is substantially smaller than the droplet size of liquor fed from the first liquor nozzles.
Description

BRIEF DESCRIPTION OF THE DRAWINGS

In the following, the invention will be described in more detail with reference to the appended drawings, in which



FIG. 1 shows schematically the furnace of a recovery boiler, seen from the side,



FIG. 2 shows an embodiment for placing the first and second liquor nozzles according to the invention on the walls of the furnace of the recovery boiler, and



FIG. 3 shows another embodiment for placing the first and second liquor nozzles according to the invention on the walls of the furnace of the recovery boiler.





DETAILED DESCRIPTION OF THE INVENTION


FIG. 1 shows a recovery boiler 1 according to the invention, comprising a furnace 2 with a char bed 3 on its bottom. The char bed 3 is formed when black liquor is fed in the form of droplets from liquor spray nozzles 6a into the furnace 2. When entering the furnace, the liquor is dried, part of it is pyrolyzed, and part becomes coke. As a result of the combustion of the coke, smelt is formed which accumulates on the bottom of the furnace and is led from there to a smelt dissolving tank and into a chemical recovery plant.


In order to burn the liquor so that the resulting flue gases contain as little nitrogen oxides as possible, combustion air is fed into the furnace from nozzles placed at several different levels with respect to the height of the furnace. Primary air nozzles 4 are placed closest to the bottom of the furnace, at a distance from it. Secondary air nozzles 5 are placed above the primary air nozzles 4 but still below the liquor nozzles 6a and 6b in the height direction of the furnace. As can be seen from the figure, the secondary air 5 is divided into two parts to be fed from different levels into the furnace 2. Part of the secondary air is fed into the furnace 2 via so-called lower secondary air nozzles 5a, and the rest is fed into the furnace 2 via upper secondary air nozzles 5b. Above the secondary air nozzles 5, liquor nozzles 6a and 6b are provided for feeding liquor into the furnace. Above the liquor nozzles, tertiary air nozzles 7 are provided for feeding tertiary air into the furnace. Above the tertiary air nozzles, quaternary air nozzles 8 are provided for feeding quaternary air into the furnace.


By feeding the combustion air from different levels into the furnace 2, different combustion zones are formed in the furnace, whereby the quantity of combustion air to be fed into them can be adjusted. Approximately at the level of the primary air nozzles 4 there is a reducing zone A with substoichiometric, reducing conditions. Into this zone, air is fed from the primary air nozzles 4. The combustion of coke formed of liquor takes place here. Approximately at the level of the secondary air nozzles 5, or slightly above them but still underneath the liquor nozzles 6a and 6b, there is a combustion zone B where the air coefficient is slightly greater than 1. The purpose of this zone is to secure the complete combustion of the liquor. Air is fed from the secondary air nozzles 5 into the combustion zone B.


Approximately at the level of the tertiary air nozzles 7 or slightly above them there is an afterburning zone C with substoichiometric, reducing conditions. Combustion air is fed from the tertiary air nozzles 7 into the afterburning zone C. Uppermost in the furnace 2 there is a burning-out zone D which is placed approximately at the level of the quaternary air nozzles 8 or above them. Combustion air is fed from the quaternary air nozzles 8 into the burning-out zone. The zone D has an air coefficient well above 1, and its purpose is the afterburning of pyrolysis gases still left in the furnace by means of excess air.


Black liquor is fed into the furnace from one level so that two combustion zones are generated. The first and second liquor nozzles 6a and 6b are provided between the secondary air nozzles 5 and the tertiary air nozzles 7. The liquor nozzles 6a and 6b are placed substantially on the same level with respect to the height of the furnace. There are two different types of liquor nozzles, producing liquor droplets of different sizes. The larger liquor droplets fed from the first liquor nozzles 6a fly downwards, and the liquor and the pyrolysis gases formed thereof are burnt in the reducing zone A and the combustion zone B prevailing underneath the liquor nozzles 6a and 6b.


The second nozzles 6b produce a liquor jet consisting of liquor droplets that are are substantially smaller than the liquor droplets generated by the first nozzles 6a. The liquor droplets generated by the second liquor nozzles 6b and the pyrolysis gases formed of them are burnt in the afterburning zone C and the burning-out zone D prevailing at the level of the liquor nozzles and higher than them.


The first liquor nozzles may be spoon-shaped nozzles that are commonly used and which generate liquor droplets in the size of some millimetres. The aim is that the formed droplets fall downwards, dry on their way down and are burnt as low down as possible in the furnace.


The second liquor nozzles are nozzles which are capable of generating substantially smaller liquor droplets than the first liquor nozzles. The size of the liquor droplets is some hundreds of microns. The droplet size is adjusted such that the liquor to be fed from the second nozzles forms a “liquor cloud” in the centre of the boiler, at the level of the liquor nozzles or slightly above them. However, the droplet size is adjusted to be so large that the droplets travel to the centre of the cross-sectional area of the boiler. A carrier gas can be utilized for feeding the liquor. The second liquor nozzles may be, for example, nozzles provided with a carrier gas channel surrounding the liquor channel in the nozzle and thereby forming a curtain of gas around the liquor. The carrier gas improves the penetrability of the liquor in the centre of the furnace and prevents the formation of a liquor cloud in the vicinity of the walls of the furnace.


If necessary, the liquor to be fed from the second nozzles can be heated or treated to make the formation of small droplets easier. However, the liquor to be fed from the nozzles is the same liquor as the liquor fed from the first nozzles.


The first and the second liquor nozzles can be arranged in different ways to the walls 9 of the furnace. FIG. 2 shows an embodiment for their placement. The first nozzles 6a are placed symmetrically so that three nozzles are provided on each wall. The second nozzles 6b are placed at the corners of the furnace 2. In the embodiment of FIG. 3, two first nozzles 6a are provided on each wall 9. On each wall 9, the second nozzles 6b are placed between the first nozzles 6a, substantially in the center of the wall of the furnace. Naturally, the number and placement of the first and second liquor nozzles with respect to the walls of the furnace may vary from the examples shown in FIGS. 2 and 3.


The invention is not intended to be limited to the embodiments presented as examples above, but the invention is intended to be applied widely within the scope of the inventive idea as defined in the appended claims.

Claims
  • 1. A method for reducing nitrogen oxide emissions of a recovery boiler, in which method the furnace of the soda recover boiler is supplied with primary air from primary air nozzles to the lower part of the furnace,black liquor from liquor nozzles,secondary air from secondary air nozzles, which secondary air is supplied above the primary air nozzles but still underneath the liquor nozzles,tertiary air from tertiary air nozzles, which tertiary air is supplied above the liquor nozzles,quaternary air from quaternary air nozzles, which quaternary air is supplied above the tertiary air nozzles,
  • 2. The method according to claim 1, wherein the liquor fed from the first liquor nozzles and the pyrolysis gases formed thereof are burnt in a reducing zone and a combustion zone prevailing underneath the liquor nozzles.
  • 3. The method according to claim 2, wherein combustion air is fed into the reducing zone from the primary air nozzles so that substoichiometric, reducing conditions prevail in the reducing zone.
  • 4. The method according to claim 2, wherein combustion air is fed into the combustion zone from the secondary air nozzles so that excess air conditions prevail in the combustion zone.
  • 5. The method according to claim 1, wherein the liquor fed from the second liquor nozzles and the pyrolysis gases formed thereof are burnt in an afterburning zone and a burning-out zone prevailing above the second liquor nozzles.
  • 6. The method according to claim 5, wherein combustion air is fed into the afterburning zone from tertiary air nozzles so that substoichiometric, reducing conditions prevail in the afterburning zone.
  • 7. The method according to claim 6, wherein the temperature in the afterburning zone is about 950 to 1500° C., preferably about 1050 to 1400° C.
  • 8. The method according to claim 5, wherein combustion air is fed into the burning-out zone from the quaternary air nozzles so that excess air conditions prevail in the burning-out zone.
  • 9. The method according to claim 8, wherein the temperature in the burning-out zone is about 950 to 1200° C., preferably about 950 to 1050° C.
  • 10. The method according to claim 1, wherein black liquor is fed into the furnace from the first liquor nozzles and the second liquor nozzles which are arranged symmetrically with respect to the walls of the furnace.
  • 11. The method according to claim 10, wherein black liquor is fed into the furnace from the first liquor nozzles and the second liquor nozzles, the first liquor nozzles being arranged symmetrically on the walls of the furnace and the second liquor nozzles being arranged in the corners of the furnace.
  • 12. The method according to claim 10, wherein black liquor is fed into the furnace from the first liquor nozzles and the second liquor nozzles, the second liquor nozzles being arranged between the first liquor nozzles on the walls of the furnace.
  • 13. The method according to claim 1, wherein black liquor is fed into the furnace from the first liquor nozzles and the second liquor nozzles, the black liquor being supplied from the same liquor tank.
  • 14. A recovery boiler comprising a furnace,primary air nozzles for feeding primary air to the lower part of the furnace,liquor nozzles for feeding black liquor to the furnace,secondary air nozzles for feeding secondary air into the furnace, the secondary air nozzles being placed above the primary air nozzles but still below the liquor nozzles with respect to the height of the furnace,tertiary air nozzles for feeding tertiary air into the furnace, the tertiary air nozzles being placed above the liquor nozzles,quaternary air nozzles for feeding quaternary air into the furnace, the quaternary air nozzles being placed above the tertiary air nozzles,
  • 15. The recovery boiler according to claim 14, wherein below the liquor nozzles, the furnace is provided with a reducing zone and a combustion zone, in which zones the liquor fed from the first liquor nozzles and the pyrolysis gases formed thereof are arranged to be burnt.
  • 16. The recovery boiler according to claim 15, wherein the primary air nozzles are arranged to feed combustion air into the reducing zone.
  • 17. The recovery boiler according to claim 15, wherein the secondary air nozzles are arranged to feed combustion air into the combustion zone.
  • 18. The recovery boiler according to claim 14, wherein above the liquor nozzles, the furnace is provided with an afterburning zone and a burning-out zone, in which the liquor fed from the second liquor nozzles and the pyrolysis gases formed thereof are arranged to be burnt.
  • 19. The recovery boiler according to claim 18, wherein the tertiary air nozzles are arranged to feed combustion air into the afterburning zone.
  • 20. The recovery boiler according to claim 19, wherein the temperature in the afterburning zone is about 950 to 1500° C., preferably about 1050 to 1400° C.
  • 21. The recovery boiler according to claim 18, wherein the quaternary air nozzles are arranged to feed combustion air into the burning-out zone.
  • 22. The recovery boiler according to claim 21, wherein the temperature in the burning-out zone is about 950 to 1200° C., preferably about 950 to 1050° C.
  • 23. The recovery boiler according to claim 14, wherein the first and the second liquor nozzles are arranged symmetrically with respect to the walls of the furnace.
  • 24. The recovery boiler according to claim 23, wherein the first liquor nozzles are arranged symmetrically on the walls of the furnace and the second liquor nozzles are arranged in the corners of the furnace.
  • 25. The recovery boiler according to claim 23, wherein the second liquor nozzles are arranged between the first liquor nozzles on the walls of the furnace.
  • 26. The recovery boiler according to claim 14, wherein the black liquor fed from the first liquor nozzles and the second liquor nozzles into the furnace is supplied from the same liquor tank.
Priority Claims (1)
Number Date Country Kind
20065429 Jun 2006 FI national