Claims
- 1. In a process for the simultaneous absorption and oxidation of hydrogen sulfide to sulfur, comprising the steps of scrubbing in a scrubbing stage a gas consisting essentially of a sour gas containing H.sub.2 S with an aqueous, alkaline scrubbing solution containing pentavalent vanadium as the oxidizing agent, wherein the hydrogen sulfide is absorbed by the scrubbing agent and oxidized by pentavalent vanadium to elemental sulfur with reduction of the pentavalent vanadium to tetravalent vanadium, and then in a regeneration stage, separate from the scrubbing stage, regenerating the thus-reduced scrubbing solution in the presence of a promoter by reoxidation of the tetravalent vanadium gas to pentavalent vanadium with a gas containing molecular oxygen, the improvement wherein the scrubbing solution consists essentially of sodium carbonate, vanadium, and an amine promoter.
- 2. A process according to claim 1, wherein the promoter is either a soluble salt of an aminocarboxylic acid or an amine having no carboxyl groups.
- 3. A process according to claim 1, wherein sodium thiocyanate is present in the scrubbing solution in sufficient amounts to prevent the formation of sodium thiosulfate therein.
- 4. A process according to claim 2, wherein sodium thiocyanate is present in the scrubbing solution in sufficient amounts to prevent the formation of sodium thiosulfate therein.
- 5. A process according to claim 1, wherein the promoter is an alkylamine or an alkanolamine.
- 6. A process according to claim 1, wherein the promoter is at least one of diethylamine, butylamine, triethylenetetramine, hexamethylenediamine, or N,N'-bis(3-aminopropyl)ethylenediamine.
- 7. A process according to claim 1, wherein the promoter is at least one of mono-, di- , or triethanolamine, dimethylethanolamine, methyldiethanolamine, dimethylaminopropanol, 2(2-aminoethoxy)ethanol, or methylaminoethanol.
- 8. A process according to claim 1, wherein the promoter is diethanolamine.
- 9. A process according to claim 1, wherein the promoter is at least one of aminoacetic acid, imido-bis-acetic acid or aminopropionic acid.
- 10. A process according to claim 1, wherein the promoter is employed in a concentration of 10-100 g/l.
- 11. A process according to claim 1, wherein the promoter is employed in a concentration of 30-50 g/l.
- 12. A process according to claim 1, wherein the promoter is a mixture of classes of compounds other than a mixture of amines having no carboxyl groups with amines having carboxyl groups.
- 13. A process according to claim 1, wherein the scrubbing liquid contains anthraquinone disulfonic acid and said promoter functions as a complexing agent.
- 14. An alkaline scrubbing solution for the scrubbing of gases containing H.sub.2 S, said solution consisting essentially of sodium carbonate, vanadium, sodium thiocyanate and at least one soluble salt of an amino carboxylic acid selected from the group consisting of aminoacetic acid, imido-bis-acetic acid, and aminopropionic acid.
- 15. An alkaline scrubbing solution for the scrubbing of gases containing H.sub.2 S, said solution consisting essentially of sodium carbonate, vanadium, sodium thiocyanate and at least one soluble salt of an amino carboxylic acid selected from the group consisting of aminoacetic acid, imido-bis-acetic acid, and aminopropionic acid and at least one amine selected from the group consisting of monoethanolamine, diethanolamine, triethanolamine, dimethylethanolamine, methyldiethanolamine, methylaminoethanol, dimethylaminopropanol and 2(2-aminoethoxy)ethanol.
- 16. A scrubbing solution according to claim 15, wherein the amine is diethanolamine.
Priority Claims (1)
Number |
Date |
Country |
Kind |
3239602 |
Oct 1982 |
DEX |
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CROSS-REFERENCE TO RELATED APPLICATION
This application is a continuation-in-part of application Ser. No. 455,703, filed Jan. 5, 1983, and now abandoned.
US Referenced Citations (3)
Number |
Name |
Date |
Kind |
4036942 |
Sibeud et al. |
Jul 1977 |
|
4283379 |
Fenton et al. |
Aug 1981 |
|
4374104 |
Primach |
Feb 1983 |
|
Foreign Referenced Citations (1)
Number |
Date |
Country |
1488659 |
Oct 1977 |
GBX |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
455703 |
Jan 1983 |
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