Claims
- 1. A method for renewing a fuel cell (hydrogen gas generator) having a magnesium anode which has been depleted by galvanic action into magnesium hydroxide precipitate and an electrolytic solution, the method comprising:
- A. removing the precipitate and the electrolytic solution from a fuel cell,
- B. drying the precipitate to produce a dried precipitate,
- C. washing the dried precipitate with water to remove impurities and to produce a washed precipitate,
- D. adding water to the washed precipitate to form a slurry,
- E. reacting the slurry with hydrochloric acid means to form magnesium chloride brine,
- F. filtering the magnesium chloride brine to remove solid impurities and produce filtered magnesium chloride brine,
- G. drying this filtered magnesium chloride brine to produce dried magnesium chloride,
- H. heating the dried magnesium chloride to a molten state, so as to produce molten magnesium chloride,
- I. disassociating the molten magnesium chloride by electrolysis to produce magnesium metal in highly pure form and chloride gas,
- J. forming the magnesium metal into fuel cell anodes,
- K. installing these anodes in depleted fuel cells so as to re-energize the depleted fuel cells.
- 2. A method for renewing magnesium hydroxide precipitate produced by the depletion of a magnesium anode in a fuel cell which generates hydrogen gas used to power a vehicle, said method comprising: p1 A. removing the depleted magnesium anode and the magnesium hydroxide precipitate, from the fuel cell,
- B. drying the magnesium hydroxide precipitate to produce a dried magnesium hydroxide precipitate,
- C. washing the dried magnesium hydroxide precipitate to produce washed magnesium hydroxide precipitate,
- D. draining off excess water from the washed magnesium hydroxide precipitate to produce a slurry of magnesium hydroxide,
- E. reacting the magnesium hydroxide slurry with hydrochloric acid to form magnesium chloride brine,
- F. filtering the magnesium chloride brine to remove solids and produce filtered magnesium chloride brine,
- G. drying the magnesium chloride brine to obtain magnesium chloride granules,
- H. heating the magnesium chloride granules to produce molten magnesium chloride,
- I. applying an electrical current to the molten magnesium chloride, causing the magnesium chloride to disassociate into magnesium metal and chlorine gas,
- J. casting the molten magnesium into magnesium anodes,
- K. installing the magnesium anodes in depleted fuel cells,
- L. mixing the chlorine gas with hydrogen gas to produce a gas mixture,
- M. igniting and burning the gas mixture to produce hydrogen chloride gas,
- N. reacting the hydrogen chloride gas with water to produce hydrochloric acid,
- O. recycling the hydrochloric acid for reacting in step E,
- P. increasing the temperature of a heat transfer fluid by concentrating solar energy on the heat transfer fluid,
- Q. using the heat transfer fluid means to provide heat energy to dry the brine of Step G,
- R. using heat transfer fluid means to provide the energy to drive a turbine/generator means,
- S. driving the generator from the turbine to produce electrical power,
- T. applying the electrical power to the molten magnesium chloride of step I.
- 3. A method for renewing a fuel cell (hydrogen gas generator) having a magnesium anode which has been depleted by galvanic action and used to power a
- A. removing magnesium hydroxide precipitate from a depleted fuel cell,
- B. drying the magnesium hydroxide precipitate to produce dried magnesium hydroxide precipitate,
- C. washing the dried magnesium hydroxide precipitate and draining the water to produce a magnesium hydroxide slurry,
- D. reacting the magnesium hydroxide slurry with hydrochloric acid to produce magnesium chloride brine,
- E. filtering the magnesium chloride brine to remove solid impurities and produce filtered magnesium chloride brine,
- F. drying the magnesium chloride brine to produce magnesium chloride granules,
- G. heating the magnesium chloride granules to produce molten magnesium chloride,
- H. disassociating the molten magnesium chloride granules by electrolysis to produce magnesium metal and chlorine gas,
- I. forming the magnesium metal into magnesium anodes,
- J. installing the magnesium anodes into depleted fuel cells so as to renew and re-energize these fuel cells,
- K. recycling the chlorine gas of Step H by:
- mixing the chlorine gas with hydrogen gas to produce a gas mixture,
- burning the gas mixture to produce hydrogen chloride gas,
- reacting the hydrogen gas with water to produce hydrochloric acid,
- reacting the hydrochloric acid with the magnesium hydroxide slurry of step D,
- L. producing heat and generating electrical power by:
- increasing the temperature of a heat transfer fluid by receiving and concentrating the energy from the sun onto the transfer fluid,
- transferring heat from the heat transfer fluid means to the magnesium chloride brine of Step F,
- using heat from the heat transfer fluid means to provide energy to drive a turbine/generator means and thus to produce electrical power,
- applying the electrical power to the molten magnesium chloride of step H.
- 4. The method of claim 1 wherein the filtered magnesium chloride brine is dried by evaporative means.
- 5. The method of claim 1 wherein the filtered magnesium chloride brine is spray dried.
- 6. The method of claim 2 wherein the filtered magnesium chloride brine is dried by evaporative means.
- 7. The method of claim 2 wherein the filtered magnesium chloride brine is spray dried.
- 8. The method of claim 2 wherein the heat transfer fluid means transforms water in a boiler into steam and this steam drives the turbine/generator means.
- 9. The method of claim 2 wherein the heat transfer fluid means provides the energy to operate a hydride-dehydride-hydrogen (HDH) system wherein the pressurized hydrogen gas produced drives the turbine/generator means.
- 10. The method of claim 3 wherein the filtered magnesium chloride brine is dried by evaporative means.
- 11. The method of claim 3 wherein the filtered magnesium chloride brine is spray dried.
- 12. The method of claim 3 wherein the heat transfer fluid means transforms water in a boiler into steam and this steam drives the turbine/generator means.
- 13. The method of claim 3 wherein the heat transfer fluid means provides the energy to operate a hydride-dehydride-hydrogen (HDH) system wherein the pressurized hydrogen gas produced drives the turbine/generator means.
Parent Case Info
This is a divisional of copending application Ser. No. 07/809,303 filed on Dec. 17, 1991, now U.S. Pat. No. 5,228,529.
US Referenced Citations (3)
Divisions (1)
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Number |
Date |
Country |
Parent |
809303 |
Dec 1991 |
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