Claims
- 1. A method of separating gases, comprising flowing gases to be separated past or through a particulate composite material with a carbon matrix and selectively adsorbing a portion of said gases to be separated into said material to separate the selectively adsorbed portion of gases from the gases to be separated wherein said material includes an essentially carbon microporous phase having a microporous volume between 0.1 and 1 cm.sup.3 /g, associated with an amorphous mineral dispersed phase essentially containing a mineral oxide selected from the group consisting of silicon, aluminum, titanium and magnesium oxides, said mineral dispersed phase being disposed on the carbon phase to a thickness of less than 10 nm.
- 2. A method according to claim 1, wherein the amorphous mineral dispersed phase represents 0.1 to 10% by weight of the composite material.
- 3. A method according to claim 1 wherein the amorphous mineral dispersed phase represents 0.5 to 5% by weight of the composite material.
- 4. A method according to claim 1, wherein the amorphous mineral dispersed phase essentially contains amorphous silica.
- 5. A method according to claim 1, wherein the particles of the composite material have sizes of the order of 0.5 to 5 mm.
- 6. A method according to claim 1, wherein the method separates gases from air.
- 7. A method according to claim 1, wherein the selectively adsorbed portion of gases are selected from the group consisting of nitrogen, oxygen and argon.
- 8. A method according to claim 1, wherein said material is prepared by a process comprising contacting an essentially carbon microporous particulate matrix with a volatile gaseous precursor, said precursor comprising silicon, aluminum, titanium or magnesium, and heat treating the matrix to decompose the precursor on the matrix in situ at the temperature of decomposition of the volatile precursor and form said material.
- 9. The method according to claim 1, wherein the gases are separated by Pressure Swing Adsorption.
Priority Claims (1)
Number |
Date |
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Kind |
90 09090 |
Jul 1990 |
FRX |
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Parent Case Info
This is a division of application No. 07/725,469 filed Jul. 3, 1991, now U.S. Pat. No. 5,294,585.
US Referenced Citations (10)
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Entry |
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Divisions (1)
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Number |
Date |
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Parent |
725469 |
Jul 1991 |
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