Not applicable.
Not applicable.
1. Field of the Invention
The invention relates to shelving and the like, e.g., countertops and table tops, including shelving which may be adapted for use with refrigerators. More particularly, the invention relates to the support surfaces of such articles which have spill containing features.
2. Background Art
Previous types of shelving have been developed for use as refrigerator and other shelves. Shelving designs exist in the prior art which include means for containing liquid spills and leaks from a container stored on a shelf, and preventing the spill from dripping from the shelf onto the floor or into other parts of a refrigerator, commonly referred to as “spill proof” shelving. For example, Kane, et al., U.S. Pat. No. 5,564,809, issued Oct. 14, 1996, discloses a shelf assembly with a shelf panel, a shelf support supporting the panel and a molded one-piece member encapsulating the edge of the shelf panel and a substantial majority of the shelf support.
Herrmann, et al., U.S. Pat. No. 5,735,589, issued Apr. 7, 1998, discloses a shelf panel for a refrigerator compartment which includes a shelf panel which is slidably supported for extension and retraction on a support, and which includes slide members which are preferably molded so as to form a rim on an the top article support surface of the shelf panel to contain liquids.
Bird, et al., U.S. Pat. No. 5,429,433, issued Jul. 4, 1995, also describes a refrigerator shelf which is adapted for containment of spills on the shelf. The shelf includes a planer shelf with a rim molded around the perimeter edge of the shelf, which projects above the top surface of the shelf to form a dam for containing liquid spills on the shelf.
Meier, et al., U.S. Pat. No. 6,120,720, issued Sep. 19, 2000, discloses a method of manufacturing a glass shelf with a plastic edge for retaining spills on the shelf. The glass shelf panel is placed in a cavity of a mold and plastic material is injected into mold cavities surrounding the glass shelf panel such that a plastic edging is formed around the perimeter of the glass shelf panel.
Additional techniques for containing spills in refrigerator shelving include the use of injection molded plastic, so as to encapsulate a support plate forming the shelf, using plastic molded parts to essentially “sandwich” a support plate between the parts, or using a silicone sealant or various other types of adhesives to form physical spill containment barriers around the perimeter of the refrigerator shelving. In addition to the foregoing, it is known to utilize formed lips or ridges on the surface of the support plate, so as to essentially provide a physical barrier as a liquid retention feature.
The present invention is a method for containing spills on shelving and the like having a support top surface, and the resulting items made in accordance with the method, by providing the support top surface with a hydrophobic surface which is arranged in a spill containment pattern and which is generally in the plane of the top surface of the support. The majority of the top surface of the support consists of one or more spill containment areas which are of a non-hydrophobic nature and which are bounded by the hydrophobic surfaces, such that spills on the surface collect in the non-hydrophobic spill containment area or areas and are prevented from spreading by the hydrophobic surfaces.
These and other objects, advantages and features of the invention will be more fully understood and appreciated by reference to the Description of the Preferred Embodiments, and the appended drawings.
Preferred embodiments of the invention will now be described with reference to the drawings, in which:
In the preferred embodiments, the term “shelving and/or the like,” or “shelf and/or the like” encompasses shelves and articles whose top surfaces serve similar functions, such as countertops and table tops. Certain embodiments are especially advantageous for use in refrigerator shelving.
In such preferred embodiments of the invention, refrigerator shelving is provided with a spill containment pattern which may consist of a hydrophobic surface in the pattern of a frame-like border, which defines the boundaries of a single spill containment area therein. The pattern may be a frame-like border which extends along the perimeter of the shelf's top surface (
A preferred embodiment shelf may be incorporated into a shelving assembly with a shelf-supporting mechanism, such as a bracket, and a shelf, which is capable of supporting articles on its top surface. The disclosure provided herein relates to the shelf portion of the assembly, which can be used with brackets of various designs, including various types of brackets as known in the art.
The shelf may consist of metal, glass, plastic, other suitable material, or a combination of any of the foregoing, and has a hydrophobic surface which is generally in the plane of the top surface of the shelf and which is arranged in a spill containment pattern to provide a spill containment feature on the top surface of the shelf as illustrated in
A hydrophobic or super hydrophobic surface treatment may be applied to the shelf's top surface to create the hydrophobic surface described herein in a variety of methods which are known in the art, and any surface coatings may be used which are known to be hydrophobic or are known to make the surface of the shelf hydrophobic. The hydrophobic surface described herein is not limited to any specific hydrophobic or super hydrophobic surface treatment, and any method of making the surface of the shelf hydrophobic may be employed.
More specifically, according to the preferred embodiments, there are several known hydrophobic compounds which may be used with any of the methods described in the prior art. Some of the commonly recognized hydrophobic compounds include: fluorocarbons; fluoroalkyl silanes; fluoroalkoxy silanes; and fluoroalkyl alkyl silanes. Any such hydrophobic compounds or a mixture thereof can be used to create the hydrophobic surfaces described herein, and other applicable hydrophobic compounds will be apparent to those skilled in the art. It is believed that tridecafluoro-1,1,2,2-tetrahydrooctyl trichlorosilane provides a good example of a suitable hydrophobic compound.
More specifically, and further in accordance with the preferred embodiments described herein, methods of creating the hydrophobic surface may include, without limitation: (1) application of a hydrophobic compound to the top surface using any known application technique such as spraying; brushing; wiping; dipping; solvent casting; flow coating; curtain coating; roller coating; spin coating; printing; screen printing; ink jet printing; vacuum coating; magnetic field-assisted cathodic sputtering; plasma deposition; plasma magnetron deposition; plasma or atmospheric CVD; powder or liquid pyrolysis; atomization or chemical vapor deposition; electrophoretic deposition; cross-linking processes; etc.; (2) roughening the surface to be made hydrophobic using various methods (sanding, etching, e.g., acid etching, applying ceramic frit to bind particles on the surface; otherwise binding particles to the surface, etc.) and then applying a hydrophobic compound to the roughened surface; (3) providing a coating of hydrophobic particles on the surface; (4) using sol-gel deposition to apply a hydrophobic compound to the surface, either on top of or within the matrix of the sol-gel; (5) applying a metal oxide primer with an integrated or separate hydrophobic compound; (6) applying a hydrophobic compound comprising a variety of molecular chain lengths to create a coating with surface irregularities; (7) adhering a thin material, such as a tape of thin glass or plastic which has been made hydrophobic to the surface; (8) applying a ceramic frit, with or without structure forming particles as in (2) above, and then applying a hydrophobic compound over the cured fit.
The hydrophobic surface treatments described herein can be cured according to a number of different methods, if curing is required by the surface preparation or the hydrophobic compound, including without limitation: heating; UV radiation; VUV radiation; electron beam irradiation; ionizing radiation; laser; IR; and thermal radiation.
One preferred embodiment of the shelf comprises a glass or tempered glass shelf which is printed, e.g., screen printed, with a ceramic frit material, over which a hydrophobic coating is applied. In accordance with various aspects of the invention, the ceramic frit material can include finely ground glass particles. These particles may be mixed with inorganic or organic pigments, so as to yield a desired color. The coated glass can then be heated to around 1150° F. This heat treatment will cause the ceramic frit to fuse to the glass surface. It is believed that this coating can be characterized as being nearly as hard and tough as the glass itself. Also, the coated glass with the ceramic frit material is durable, and resists chipping, peeling, fading, and scratching. In addition, the ceramic frit material is substantially resistant to most chemicals.
In one embodiment, the ceramic fit can include some micro-scale additive particles which will remain unmelted at the temperature at which the frit is sintered, as described for example in U.S. Pat. Nos. 4,591,530 to Lui, 6,872,441 and 6,800,354 to Baumann, and 5,324,566 and 5,437,894 to Ogawa. The frit is printed in the pattern of a frame-like border at or near the outer perimeter of the shelf's top surface. The shelf with the printed frit is then heated to a temperature above the melting point of the primary components of the frit material, but below the melting point of the glass shelf, for a time sufficient to sinter the frit so that it is bonded to the top surface of the shelf. (The time and temperature required to sinter the frit will vary based on the materials chosen for the frit.) A hydrophobic solution, such as a 1% solution of Tridecafluoro-1,1,2,2-Tetrahydrooctyl Trichloro Silane, a perfluoroalkyl alkyl silane, in hexane, is then applied to the area which has been coated with the frit using any known method such as wiping the solution onto the fit. The hydrophobic solution is then cured by heating it or exposing it to controlled humidity for a period of time. The method described herein will produce a hydrophobic surface that is in a continuous border around the perimeter of the shelf's top surface which will operate as a spill containment feature.
One advantage of using a ceramic frit material to prepare the surface of the shelf for coating with the hydrophobic solution as described herein, in addition to improving the durability of the hydrophobic surface, is that frit material is commercially available in multiple colors and can be printed in a manner which allows for the inclusion of designs, company names or logos in the surface area where the frit material is applied to the shelf.
In accordance with the preferred embodiments, the hydrophobic surface provides a spill containment surface which prevents spilled liquids from leaking off of the shelf's top surface. The hydrophobic surface repels liquids, causing them to collect in the non-hydrophobic region or regions of the shelf. The hydrophobicity of the hydrophobic surface is sufficient to repel a spilled liquid and prevent it from crossing onto or over the hydrophobic surface and therefore forces the spilled liquid to bead up or puddle up on the non-hydrophobic regions of the shelf due to the surface tension of the liquid. Thus, the hydrophobic surface is capable of containing spills without the use of a barrier lip or barrier edging used in prior art spill containment assemblies which act as a “dam” for the spilled liquid.
The reference to the fact that the hydrophobic surface is generally in the plane of the top surface of the shelf is intended to include surfaces and surface treatments, all or a portion of which may extend a small distance above the level of the top surface of the shelf which is not readily noticeable to the naked eye. For example, as described in greater detail above, the hydrophobic surface may be a hydrophobic coating, or a combination of a layer of ceramic frit and a hydrophobic coating on the ceramic fit. Such layers typically have a thickness of from about 0.001 microns to about 250 microns.
A visual perspective of situations involving liquid spillage is illustrated in
To illustrate the concepts of liquid spillage, a soda can 1010 is illustrated as being left on its side on the upper surface of the shelf panel 1006. The soda can 1010 has spilled liquid which is shown as liquid 1012 on a portion of the shelf panel 1006. The visible edge of the shelf panel 1006 located on its upper surface at the intersection of the perimeter of the plastic rim 1004 may include a sealed edge 1014. As previously described herein, the sealed edge 1014 may merely include some type of a sealing adhesive or, alternatively, a silicone material or the like. In this manner, an attempt is made to essentially provide a raised physical barrier that is sealed to the shelf panel 1006 to seal the spilled liquid 1012 from spillage off of the shelf panel 1006.
A preferred embodiment shelf assembly 1020 is illustrated in
In addition to the embodiment shown in
The hydrophobic surface arranged in a spill containment pattern in accordance with the preferred embodiments described herein eliminates the need for plastic encapsulation material to create a spill containment barrier. Accordingly, the shelves produced in accordance with the preferred embodiments described herein utilize relatively less material than prior art spill-containing shelves. Further, the shelves described herein have no need for silicone sealants to create a spill containment barrier. With the exception of the hydrophobic tape embodiment, they have no need for adhesives to create a spill containment barrier. Elimination of the need for these materials also results in relatively less use of material. Further, using the hydrophobic surfaces arranged in a spill containment pattern in accordance with the preferred embodiments eliminates the need for formed lips or ridges on the shelf's top surface, which reduces the amount of material used and the complexity of manufacturing, and, therefore, reduces the manufacturing cost.
Elimination of plastic encapsulation and sealants from the design of the shelf member also eliminates a potential source of failure or leakage since the sealants and plastic encapsulation may have cracks or crevices where they join with the shelf member in which organic or inorganic materials may become entrapped and involve a bond area to the shelf member which may eventually leak. Still further, by eliminating the space taken up by plastic encapsulation, sealants, adhesives, or formed lips and ridges, the relative amount of usable shelf space is increased on a shelf in accordance with the preferred embodiments described herein. Still further, the use of hydrophobic surfaces arranged in a spill containment pattern retains an amount of liquid comparable to that retained by prior art shelves having spill containing dam features, without the necessity of using the dams.
As earlier described herein, the hydrophobic surface arranged in a spill containment pattern in accordance with the preferred embodiments provides a spill containment feature which prevents spilled liquids from leaking off of the top surface of the shelf, and shelves in accordance with the preferred embodiments can be used in various applications, such as refrigerator shelves.
It will be apparent to those skilled in the pertinent arts that other embodiments of shelving members in accordance with the invention may be designed. That is, the principles of shelving members in accordance with the invention are not limited to the specific embodiments described herein. For example, shelf members or other support surfaces having a hydrophobic spill containment surfaces could be used in various settings, such as shelving in other settings, tables, countertops or the like, and are not limited to use as refrigerator shelves.
Further, it will be apparent to those skilled in the pertinent art that any method which may be used for creating a hydrophobic surface arranged in a spill containment pattern in substantially the same plane as the top surface of the shelf member is within the scope of the invention described herein, even if such method requires the use of multiple pieces to manufacture the shelf member. For example, a frame of hydrophobic material may be bonded to the shelf member such that it forms a continuous border which is generally in the same plane as the top surface of the shelf. Accordingly, it will be apparent to those skilled in the art that modifications and other variations of the above-described illustrative embodiments of the invention may be effected without departing from the spirit and scope of the novel concepts of the invention.
This application claims priority to U.S. provisional patent application Ser. No. 61/133,273 entitled HYDROPHOBIC SHELF, filed Jun. 27, 2008, and to U.S. provisional patent application Ser. No. 61/216,540, entitled Hydrophobic Shelf With Ceramic Frit, filed May 18, 2009.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/US2009/048775 | 6/26/2009 | WO | 00 | 3/11/2011 |
Number | Date | Country | |
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61133273 | Jun 2008 | US | |
61216540 | May 2009 | US |