To optimize the ratio of oxygen produced to on-board mass, it has been proposed to use high-performance adsorbents, in particular faujasite-type zeolites modified by digestion or having a high degree of lithium exchange, such as those described in document EP-A-0 297 542 or EP-A-461 478In practice, the high-performance adsorbents of this type are used with an intake mixture temperature close to room temperature, below 40° C.
On-board systems for generating an oxygen-rich gas mixture, commonly called OBOGS (on-board oxygen generating systems), have been known for several decades for supplying the pilots of military warplanes with oxygen and are beginning to be fitted into civil transport aircraft, as disclosed in document FR-A-2 823 180 in the name of the Applicant.
To optimize the ratio of oxygen produced to on-board mass, it has been proposed to use high-performance adsorbents, in particular faujasite-type zeolites modified by digestion or having a high degree of lithium exchange, such as those described in document EP-A-0 297 542 or EP-A-461 478. In practice, the high-performance adsobents of this type are used with an intake mixture temperature close to room temperature close to room temperature, below 40° C.
The present invention relates to a method of supplying occupants of an aircraft with an oxygen-rich mixture by air separation in a pressure swing adsorption (PSA) system.
The Applicant has found that, in on-board applications, which are necessarily compact and have high flow rates, by optimizing the PSA process it is possible to operate at higher temperatures without, however, reducing performance.
Thus, the subject of the invention is a method comprising, in one cycle, a high-pressure adsorption/production phase and a low-pressure desorption/regeneration phase, employing a high-performance adsorbent having a particle size not exceeding 0.8 mm, the duration of the cycle not exceeding 10 seconds, and the feed air is introduced at a temperature between 50 and 90° C., typically between 60 and 80° C. and advantageously between 60 and 70° C.
For a further understanding of the nature and objects for the present invention, reference should be made to the following detailed description, taken in conjunction with the accompanying drawing, in which like elements are given the same or analogous reference numbers and wherein:
The present invention relates to a method of supplying occupants of an aircraft with an oxygen-rich gas mixture by air separation in a pressure swing adsorption (PSA) system.
According to more particular features of the invention:
The Applicant has found that with such adsorption temperatures the kinetics are improved, this being significant in the case of OBOGS, and the yield is also improved.
Moreover, the hot feed air makes it possible to moderate the thermal profiles in the adsorbent beds.
Finally, since the on-board separation systems are fed with compressed air coming from a compression stage of an aircraft engine with a temperature generally above 150° C., the process according to the invention makes it possible to considerably reduce the size of the exchangers for cooling the feed air, and therefore to save weight and space.
Recognizable in
The gas transfer chain is completed by an inlet mass flow meter 9, an outlet mass flow meter 10, an inlet temperature sensor 11, an inlet pressure sensor 12, an outlet pressure sensor 13 and an oxygen content analyzer 14, these various sensors, connected to a control system (not shown), allowing the flow rates and the pressures along the chain to be adjusted.
In one particular embodiment suitable for supplying commercial aircraft passengers, an oxygen supply subassembly typically comprises two twinned adsorbers 2 operating in alternating cycles and using, as adsorbent, an LiX zeolite having an Si/Al ratio between1 and 1.25 and exchanged to more than 92% with lithium cations. The intake pressure is about 3 bar for a desorption pressure of about 0.5 bar. The flow rate of the intake air is between 3400 and 3500 Nl/min. The temperature of the intake air is between 60 and 65° C. and the cycle time is 2×4 seconds.
Although the invention has been described in relation to particular embodiments, it is not limited thereby but is capable of modifications and of variants that will become apparent to those skilled in the art within the context of the claims hereinbelow.
It will be understood that many additional changes in the details, materials, steps and arrangement of parts, which have been herein described in order to explain the nature of the invention, may be made by those skilled in the art within the principle and scope of the invention as expressed in the appended claims. Thus, the present invention is not intended to be limited to the specific embodiments in the examples given above.
Number | Date | Country | Kind |
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02 16122 | Dec 2002 | FR | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/FR03/50156 | 12/8/2003 | WO | 00 | 6/14/2005 |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2004/056451 | 7/8/2004 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
4194891 | Earls et al. | Mar 1980 | A |
4406675 | Dangieri et al. | Sep 1983 | A |
Number | Date | Country |
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0 297 542 | Jan 1989 | EP |
0 461 478 | Dec 1991 | EP |
0 486 926 | May 1992 | EP |
1 245 266 | Oct 2002 | EP |
2 823 180 | Mar 2004 | FR |
Number | Date | Country | |
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20060117950 A1 | Jun 2006 | US |