Claims
- 1. A method for removing sulfur compounds from coal-derived gases produced from the gasification of coal containing sulfur in a gasifier having a gasification zone, a combustion zone and an ash zone, comprising the steps of introducing a mixture of particulate coal and a calcium compound into the gasifier, heating the coal particulates in the gasifier to a temperature adequate to form a coal-derived gaseous mixture containing sulfur compounds including hydrogen sulfide, conveying the gaseous mixture through a bed containing particulate absorbent from zinc ferrite, iron oxide, or combinations thereof for absorbing sulfur compounds including the hydrogen sulfide from the gaseous mixture, thereafter contact the particulate absorbent containing absorbed hydrogen sulfide with a stream of air or oxygen and steam for regenerating the absorbent by converting the hydrogen sulfide to sulfur dioxide, conveying a stream containing steam and the sulfur dioxide resulting from the regeneration of absorbent into the gasifier for contact and reaction with said calcium compound within the gasifier to form therewith a solid sulfur-calcium compound, and removing the sulfur-calcium compound from said gasifier.
- 2. A method for removing sulfur compounds from coal-derived gases as claimed in claim 1, wherein the gaseous mixture conveyed through said bed of particulate absorbent is at a temperature in the range of about 1,000.degree. to 1,200.degree. F. entering said bed of particulate absorbent and in the range of about 1,000.degree. to 1,500.degree. F. exiting said bed of particulate absorbent.
- 3. A method for removing sulfur compounds from coal-derived gases as claimed in claim 1, wherein the bed of particulate absorbent is periodically contacted with the stream of air or oxygen and steam for regenerating the absorbent.
- 4. A method for removing sulfur compounds from coal-derived gases as claimed in claim 3, including the step of coupling in parallel a plurality of beds of particulate absorbent to said gasifier, wherein the step of conveying the gaseous mixture through a bed of particulate absorbent is provided at only one of said plurality of beds at any given time.
- 5. A method for removing sulfur compounds from coal-derived gases as claimed in claim 4, wherein the step of contacting the bed of particulate absorbent with the stream of air or oxygen and steam is provided at another one of said plurality of beds of particulate absorbent distinct from the bed of solid absorbent through which the gaseous mixture is being conveyed.
- 6. A method for removing sulfur compounds from coal-derived gases as claimed in claim 1, wherein said bed of particulate absorbent is a circulating bed with different portions thereof being subjected to the gaseous mixture containing the sulfur compounds and the stream of air or oxygen and steam for concurrently absorbing the sulfur compounds in the particulate absorbent and regenerating the particulate absorbent.
Parent Case Info
This is a continuation of application Ser. No. 850,301, filed Apr. 10, 1986, now abandoned.
US Referenced Citations (11)
Foreign Referenced Citations (1)
Number |
Date |
Country |
928461 |
Jun 1963 |
GBX |
Continuations (1)
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Number |
Date |
Country |
Parent |
850301 |
Apr 1986 |
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