Claims
- 1. A method for operation of an electrolytic bath in an electrolytic cell comprising an anode electrode and a cathode electrode opposing the anode electrode; said method comprising:
- a. providing two diaphragms arranged between said electrodes; said two diaphragms defining an intermediate chamber between said electrodes; a first one of said diaphragms and said cathode electrode defining a cathode chamber; a second one of said diaphragms and said anode electrode defining an anode chamber;
- b. wherein said first diaphragm is a cation selectively permeable membrane;
- c. circulating different kinds of electrolyte solutions respectively to the anode chamber, the cathode chamber, and the intermediate chamber, characterized in that the cathode chamber solution which is circulatorily supplied into the cathode chamber has a salt containing an ammonium ion and a sodium ion as cations, and a sulfuric ion as anion, and being free from any nitric ions, said ions functioning as electrolytes, for maintaining basic electrical conductivity of said cathode chamber solution;
- d. maintaining the pH of the cathode chamber solution at 8.5 to 10.5;
- e. circulating an electrolyte solution containing a divalent ferrous ion component to said intermediate chamber;
- f. supplying electric current between the anode and the cathode while circulatorily supplying the different kinds of electrolyte solutions respectively into the anode, cathode, and intermediate chambers, causing any divalent ferrous ion component dissolved in the electrolyte solution circulatorily supplied into the intermediate chamber to be selectively electrophoresed toward the cathode;
- g. contacting the divalent ferrous ion with the cathode chamber solution to produce triiron tetroxide (Fe.sub.3 O.sub.4); and
- h. separating triiron tetroxide from said cathode chamber solution.
- 2. The method for the operation of an electrolytic bath according to claim 1, further including controlling hydrogen ion concentration in the cathode chamber solution by adding to the circulated cathode chamber solution constituents comprising a free acid selected from the group consisting of sulfuric acid, hydrochloric acid, and phosphoric acid, and a soluble free alkaline agent solution; and adjusting the addition of said added constituents to control the hydrogen ion concentration in the cathode chamber solution; and controlling the amount of the ferrous ion component separated by migration to the cathode chamber by said addition adjustment.
- 3. The method for the operation of an electrolytic bath according to claim 1, further comprising adding to the circulated cathode chamber solution, an organic chelating agent which selectively reacts with the divalent ferrous ion component separated by migration to the cathode chamber solution; and controlling the amount of the separated ferrous ion component by the amount of said added agent; and maintaining said separated divalent ferrous ion component in a soluble ionized state.
- 4. A method for operation of an electrolytic bath in an electrolytic cell comprising an anode electrode and a cathode electrode opposing the anode electrode; said method comprising:
- a. providing two diaphragms arranged between said electrodes; said two diaphragms defining an intermediate chamber between said electrodes; a first one of said diaphragms and said cathode electrode defining a cathode chamber; a second one of said diaphragms and said anode electrode defining an anode chamber;
- b. wherein said first diaphragm is a cation selectively permeable membrane;
- c. circulating different kinds of electrolyte solutions respectively to the anode chamber, the cathode chamber, and the intermediate chamber, characterized in that the cathode chamber solution which is circulatorily supplied into the cathode chamber has a regulator which maintains alkalinity of the cathode chamber solution by decomposing itself in response to electrolysis, said regulator comprising at least one selected from the group consisting of an ammonium salt, a urea carbonate, and a carboxylate;
- d. maintaining the pH of the cathode chamber solution at 8.5 to 10.5;
- e. circulating an electrolyte solution containing a divalent ferrous ion component to said intermediate chamber;
- f. supplying electric current between the anode and the cathode while circulatorily supplying the different kinds of electrolyte solutions respectively into the anode, cathode, and intermediate chambers, causing any divalent ferrous ion component dissolved in the electrolyte solution circulatorily supplied into the intermediate chamber to be selectively electrophoresed toward the cathode;
- g. contacting the divalent ferrous ion with the cathode chamber solution to produce triiron tetroxide (Fe.sub.3 O.sub.4); and
- h. separating triiron tetroxide from said cathode chamber solution.
- 5. The method for operation of an electrolytic bath according to claim 4, further comprising adding to the circulated cathode chamber solution constituents comprising a free-acid containing sulfuric acid and a soluble free alkaline agent solution; and adjusting the addition of said added constituents to control the pH of the cathode chamber solution; and controlling the amount of the metal ion components separated by migration to the cathode chamber by said addition adjustment; and maintaining said separated metal ion component in a solubilized state.
- 6. The method for the operation of an electrolytic bath according to claim 4, further comprising adding to the circulated cathode chamber solution, an organic chelating agent which selectively reacts with the divalent ferrous ion component separated by migration to the cathode chamber solution; and controlling the amount of the separated ferrous ion component by the amount of said added agent; and maintaining said separated divalent ferrous ion component in a soluble ionized state.
Priority Claims (1)
Number |
Date |
Country |
Kind |
4-221856 |
Aug 1992 |
JPX |
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Parent Case Info
This is a continuation of application Ser. No. 08/107,290 filed on Aug. 16, 1993, now abandoned.
US Referenced Citations (4)
Number |
Name |
Date |
Kind |
3394068 |
Calmon et al. |
Jul 1968 |
|
4008076 |
Junghanss et al. |
Feb 1977 |
|
4234393 |
Hepworth et al. |
Nov 1980 |
|
4948489 |
Greenberg |
Aug 1990 |
|
Foreign Referenced Citations (5)
Number |
Date |
Country |
0623339 |
Jul 1961 |
CAX |
75882 |
Jul 1983 |
EPX |
507006 |
Oct 1992 |
EPX |
2404558 |
Mar 1978 |
DEX |
3618769 |
Jul 1987 |
DEX |
Continuations (1)
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Number |
Date |
Country |
Parent |
107290 |
Aug 1993 |
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