Claims
- 1. A method for the preparation of an alkenyl ester of a carboxylic acid represented by the general formula
- R.sup.1 COOR.sup.3
- wherein R.sup.1 is a hydrogen atom or a substituted or unsubstituted aliphatic or aromatic monovalent hydrocarbon group and R.sup.3 is an alkenyl group, which comprises: subjecting a carboxylic acid represented by the general formula
- R.sup.1 COOH
- wherein R.sup.1 is the same as defined above to transesterification reaction in the liquid phase with an ester compound represented by the general formula
- R.sub.2 COOR.sup.3
- wherein R.sup.2 is a hydrogen atom or a substituted or unsubstituted monovalent hydrocarbon group which is different from R.sup.1 above and R.sup.3 is the same as defined above; carrying out said transesterification reaction in the presence of a binary catalyst system comprising a main catalyst of a palladium compound in an amount from about 0.001 to about 0.5 parts by weight remaining as adsorbed on a solid catalyst carrier and a co-catalyst consisting of a combination of an alkali metal compound in an amount from about 1 to about 15 parts by weight and a copper (II) compound in amount from about 0.001 to about 1.0 part by weight, all per 100 parts by weight of the total amount of said carboxylic acid and said ester compound, the weight ratio of said copper (II) compound to said alkali metal compound being in the range from about 0.001 to about 0.5; from about 0.001 to about 0.5 parts by weight of said alkali metal compound being an alkali metal bromide, and from about 0.001 to about 0.5 parts by weight of said copper (II) compound being copper (II) bromide.
- 2. A method as claimed in claim 1, wherein said alkali metal compound consists of said alkali metal bromide plus an alkali metal compound which is more soluble in said carboxylic acid and ester compound than said alkali metal bromide.
- 3. The method as claimed in claim 1 wherein said palladium compound and said cocatalyst remain adsorbed on a solid catalyst carrier.
- 4. The method as claimed in claim 1 wherein said transesterification reaction is carried out in an atmosphere of oxygen or an oxygen-containing gas.
Priority Claims (2)
Number |
Date |
Country |
Kind |
52-122882 |
Oct 1977 |
JPX |
|
52-156928 |
Dec 1977 |
JPX |
|
BACKGROUND OF THE INVENTION
This application is a continuation-in-part of our copending application bearing Ser. No. 928,710 and filed on July 27, 1978, now abandoned.
US Referenced Citations (4)
Non-Patent Literature Citations (3)
Entry |
Smidt, J. et al., Angewandte Chemie, vol. 74, pp. 93-101, (1962). |
Smidt, J., Chemistry & Industry, (London) pp. 54-61, (1962). |
Sabel, A., Chemisches Berichte, vol. 102, pp. 2939-2949, (1969). |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
928710 |
Jul 1978 |
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