Patent Application
20230250308
This invention relates to methods for protecting wood products outdoors or in a damp environment from damage due to water and, more particularly, to methods of applying protective micro-films of polyethylene-vinyl acetate to surfaces of wooden products maintained outdoors or exposed to damp environments.
When exposed to humidity, wood can absorb water moisture, and resulting differential expansion and contraction between portions of the boards can cause damage to the wood. Absorption of water into wood deteriorates and rots wood and accelerates growth of and damage by wood-destroying mold and fungus. Visqueen or polyethylene plastic sheets on the ground, poured concrete, pack-filled dirt, or other expensive methods fail to regulate moisture content in lumber structures. Failure to regulate moisture in wood weakens wood strength, causing subfloor warping and deflecting or sagging joists. Lumber structures outdoors, in damp environments, or associated with building foundations have been difficult to protect from moisture because they are exposed to dampness or extreme outdoor weather conditions.
It is known to apply an aqueous formulation of polyvinylidene chloride to a surface of wood, inside buildings, to form plastic films thereon to protect the wood from moisture inside the buildings (see U.S. Patent Application No. 20160145457). However, these formulations have not been useful outside of buildings to adequately protect wood from moisture, for example, on wood fences, roof shingles, siding, and in crawl spaces of building foundations because the plastic films formed by these formulations are not sufficiently durable outside of buildings, in damp environments, or during exposure to extreme weather conditions. In addition, polyvinyl chlorides and polyvinylidene chloride form dioxins when combusted, for example, in accidental fires or during disposal by incineration. Dioxins are potent carcinogens, and it is preferable not to use chloride containing plastic polymers on wood products.
Application of a liquid spray that forms a plastic film of strong bonding strength on the surface of exterior wood, outside of a building or in a damp environment, providing strong durability and a strong barrier to absorption of moisture, and not producing toxic byproducts, such as dioxins, would provide an improvement over existing methods for preventing moisture damage to wood products exposed to damp or outdoor weather conditions.
This invention provides a method of treating a surface of wood to inhibit the uptake of moisture into the wood. The method includes providing an aqueous formulation comprising one or more non-chloride, film forming, long-chain polymers in water at 2-99 weight percent, spraying the aqueous formulation on the surface of the wood, and allowing the aqueous formulation to dry and form a micro-film on the surface of the wood. The one or more long-chain polymer is, preferably, polyethylene-vinyl acetate. The wood can be exterior wood outdoors (outside of a building or shelter) and may include wood products such as fences, shingles, and siding, and floor framing systems having joists, subflooring, and girder beams in crawl spaces. The wood can also be spirit barrels which need to be maintained in a damp environment. The micro-film contains no detectable volatile organic compounds. A clear coloring agent may be added to the aqueous formulation and the micro-film may remain clear so that the surface of the wood is visible through the film for inspection. An antimicrobial may be added to the aqueous formulation to stabilize and preserve the micro-film. The micro-film maintains the moisture content in the wood at 16 percent or less.
An advantage of the present invention is that it provides a simple, rapid, and relatively easy method of inhibiting moisture damage to wood products.
Another advantage is a colored micro-film that is clear and allows for continued inspection of a wood surface.
Another advantage is that the micro-film does not rub off, get diluted with water, or become damaged by workers and pets who may come into contact with micro-film treated wood.
Another advantage is a micro-film that has a water vapor permeation rate of only 0.48 g per m2 per day compared to 5 g for polyvinyl chloride and 1 g for polyvinylidene chloride.
Another advantage is a micro-film that protects wood exposed to dampness or extreme weather conditions.
While the following description details the preferred embodiments of the present invention, it is to be understood that the invention is not limited in its application to the details of arrangement of the parts or steps of the methods disclosed herein, since the invention is capable of other embodiments and of being practiced in various ways.
This invention provides a method of treating the surface of wood by applying a micro-film to the surface of wood products such as fences, singles, and siding, wood in crawl spaces of the foundations of buildings, and spirit barrels which are required to be maintained in a damp environment. The method produces protection of the wood from damage caused by moisture and provides an easy and quick way of protecting wood in spaces that are difficult to reach or access in crawl spaces of building foundations. The sealant is a long-chain waterborne polymer wax, polymer oil sealant, or a polymer adhesive that protects the entire floor framing system including joists, subflooring, girder beams, sill plate and rim band. The micro-film automatically controls the correct moisture balance for wood to achieve strength, resist environmental issues, and control warp, deflection, deterioration and rot of joists and subfloor materials that make up a building's structural floor and wall framing systems.
Wood is a porous and fibrous structural tissue found in the trunks, stems and roots of trees and other woody plants. It is an organic material, a natural composite of cellulose fibers that are strong in tension and embedded in a matrix of lignin that resists compression. Wood includes, for example, hardwood and softwood lumber directly cut from trees, as well as engineered wood composites made from strands, particles, fibers or veneers of wood. Examples of wood composites include, but are not limited to, plywood, oriented strand board (OSB), medium-density fiberboard (MDF), particle boards, and the like. Exemplary woods include hardwood species such as ash, alder, birch, cherry, mahogany, maple, oak, poplar, teak, hickory and walnut, and softwood species such as cedar, fir, pine and redwood. The wood can be cut or formed into a wide variety of shapes for use as a structural or a building material, or for fences, shingles, and siding and other outdoor wood products.
An aqueous formulation of one or more film forming, non-volatile, non-chloride containing, long-chain polymers may be produced by methods well known in art. The aqueous film forming formulation preferably includes from about 2 to 99 percent by weight (wt %) of the non-chloride containing long-chain polymer component in water, based on the total weight of the aqueous film forming formulation. A preferred non-chloride-containing long-chain polymer is polyethylene vinyl acetate (PEVA). Another preferred non-chloride containing long-chain polymer is polyurethane. These non-chloride-containing long-chain polymers can be used individually or in combination in the aqueous formulation. In combination in the aqueous formulation, preferably, PEVA is 60-70 wt % and polyurethane are 20-26 wt %.
Typical performance enhancing additives may be added as desired to the aqueous formulation such as surface-active agents, pigments, colorants, dyes, surfactants, dispersants, defoamers, thickeners, heat stabilizers, leveling agents, coalescents, biocides, mildewcides, anti-cratering agents, curing indicators, plasticizers, fillers, sedimentation inhibitors, ultraviolet light absorbers, optical brighteners, and the like at about less than 5 wt % of the total formulation.
A film stabilizer, preservative, and antimicrobial, such as zinc oxide, zinc borate, copper salts, or disodium tetraborate can be added to the aqueous formulation. Zinc oxide suppresses bacterial and mold growth in the micro-film and keeps the aqueous formulation stable when the aqueous formulation is sprayed and contacts the surface of wood. These stabilizing agents are added to the aqueous formulation up to 2 wt %.
A colorant or dye may be added to the aqueous formulation to color the wood surface in any desired color for identification and certification of application. The micro-film produced by the aqueous formulation may be clear and the colorant or dye may be clear so that the surface of the wood remains visible through the micro-film allowing termite inspection. A preferred clear colorant is Permelon Orange obtained from Standard Colors, High Point, N.C. The colorant or dye is added to the aqueous formulation up to 2 wt %.
The aqueous formulation described above can be applied on the surface of wood using any suitable procedure such as brush coating, spray coating, roll coating, curtain coating, vacuum coating fan, sock coating and the like. Spraying is a preferred application method.
If desired, the surface of the wood may be cleaned and prepared for application of the disclosed aqueous formulation using methods well known in the art. The coating composition may be applied in one or more layers, with each layer preferably being applied in an amount sufficient to provide complete coverage and a continuous coating. However, one coat is preferred at a wet coating thicknesses of about 1 to 5 mils (about 0.03 mm to about 0.1 mm). The wet coating is allowed to dry and form a micro-film that is non-toxic and without any detectable volatile organic compounds. The micro-film does not rub off, or get diluted with water, or become damaged by workers and pets who may come into contact with the micro-film.
The effectiveness of the aqueous film forming formulation of this invention can be tested using a FLIR MR 160 Imaging Moisture Meter (https://www.flir.com/instruments/moisture-restoration). Typically, readings of more than 16% moisture content (absorption), season after season, can weaken structural lumber, leading to deterioration, infestation of wood destroying organisms, and interior damage costing tens of thousands of dollars to repair. Actual moisture content meter readings show that common Visqueen or polyethylene plastic on the ground, poured concrete and pack-filled dirt or other expensive methods show failure to regulate moisture content adequately, causing weaker wood strength, subfloor warping and deflecting or sagging joists.
To demonstrate the effectiveness of the aqueous film forming formulation of this invention, the formulation was sprayed on a surface of wood in a crawl space. The moisture content of the wood before applying the aqueous film forming formulation was measured with a FLIR meter and was 19.3%. 72 hours after applying the aqueous film forming formulation the moisture content of the wood was again measured and was reduced to 11.1%.
The aqueous film forming formulation of this invention can also be applied to the surface of wood products used outdoors such as fence boards, shingles, and siding, including cement fiber siding, and to the surfaces of spirit (i.e., wine, whisky) barrels which are maintained in a damp environment. A damp environment is defined as 60% to 80% relative humidity (www.corriganhumidity.com/wine-room/#:˜:text=Experts%20agree%20that%2050%25%20RH). The aqueous film forming formulation can be applied to these wood products by the methods disclosed herein. A matting agent, for example silica matting agents, may be added to the aqueous film forming formulation to reduce surface gloss. An alcohol liquid dye, preferably, may be added to the aqueous film forming formulation to produce a desired color on the surface of the wood. The micro-film on the surface of the wood products produces a pesticide effect, inhibiting infestation by insects, such as termites and the like.
The aqueous film forming formulation can be applied to the surfaces of spirits barrels by the methods disclosed herein. The formulation will penetrate and form a micro-film on the surfaces of the wood portions and will also form a film on the metal portions. The micro-film coating will preserve the spirits barrel and will seal the stave joints, barrel chime, and barrel croze. The micro-film coating will inhibit leaching of the contents from the spirits barrel, will inhibit drying of the spirits barrel, and inhibit evaporation of water and alcohol 10%-20% from the spirits barrel. The micro-film will also prevent rusting of the metal parts of the spirits barrel and inhibit infestation of insects such as the lead cable borer beetle.
The foregoing description has been limited to specific embodiments of this invention. It will be apparent, however, that variations and modifications may be made by those skilled in the art to the disclosed embodiments of the invention, with the attainment of some or all of its advantages and without departing from the spirit and scope of the present invention. For example, The aqueous film forming formulation may be applied to any wood surface in any location. Any type of liquid tint, powder pigment, or other additive clear coloring materials may be used to achieve any desired color of the resulting micro-film formed on the wood surface.
It will be understood that various changes in the details of the method and materials which have been described and illustrated above in order to explain the nature of this invention may be made by those skilled in the art without departing from the principle and scope of the invention as recited in the following claims.
This application claims priority to earlier filed U.S. Nonprovisional patent application Ser. No. 17/460,557, filed Aug. 30, 2021, which claims the benefit of U.S. Nonprovisional patent application Ser. No. 16/517,964, filed on Jul. 22, 2019, which claims the benefit of U.S. Provisional Patent Application 62/765,334, filed on Aug. 22, 2018, the contents of which are herein incorporated by reference in their entirety.
| Number | Date | Country | |
|---|---|---|---|
| 62765334 | Aug 2018 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 16517964 | Jul 2019 | US |
| Child | 17460557 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 17460557 | Aug 2021 | US |
| Child | 18133890 | US |
