1. Field of the Invention
The present invention relates to rotating electric machines such as synchronous machines. It also relates to double-fed machines, applications in asynchronous static current converter cascades, external pole machines and synchronous flux machines, as well as to alternating current machines intended primarily as generators in a power station for generating electric power. The invention particularly relates to the stator in such machines and a method for fixing the windings, as well as cooling the stator teeth and the insulated electric conductor constituting the stator winding.
2. Discussion of the Background
Similar machines have conventionally been designed for voltages in the range 15-30 kV, and 30 kV has normally been considered to be an upper limit. This generally means that a generator must be connected to the power network via a transformer which steps up the voltage to the level of the power network, which is in the range of approximately 130-400 kV. The present invention is intended primarily for use with high voltages. High voltages shall be understood here to mean voltages in excess of 10 kV. A typical operating range for the machine according to the invention may be voltages from 36 kV up to 800 kV. The invention is secondarily intended for use in the stated technical area at voltages below 36 kV.
Two different air-cooled systems exist for conventional cooling: radial cooling where the air passes the rotor through the hub and radial channels in the rotor, and axial cooling where the air is blown into the pole gaps by axial fans. The stator is divided into radial air ducts created by (often straight) spacers that are welded in place. Due to the poor thermal conductivity axially through the stator laminations the air ducts must be frequently repeated. The drawback with air-cooling is that the ventilation losses are considerable and that, because of the ventilation ducts, the stator becomes longer. Furthermore, particularly with said high-voltage generators with long teeth, the ventilation ducts may also weaken the structure mechanically.
Axial liquid cooling, e.g. water-cooling, through cooling tubes, e.g. of metal, in the stator yoke has been known for some time. One drawback is that eddy currents are induced in metal tubes if they are present in a magnetic flux varying with time, thus leading to certain power losses when used in an electric machine.
The object of the present invention is to provide a method for mounting a cooling tube in a cooling tube channel, and also a rotating electric machine having cooling tubes mounted using this method in conjunction with direct cooling of the stator and particularly the stator teeth in such a machine.
Another object of the invention is to eliminate ventilation ducts, thereby resulting in shorter and stronger stators, at the same time as ensuring that the magnetic flux in the stator teeth is disturbed as little as possible by said cooling. The object is also to achieve a higher degree of efficiency.
A further object of the invention is to achieve a steady fixing of the cables in the stator slots by these cooling tubes.
The above-mentioned object is achieved by the method and the arrangement in accordance with the invention having the features described herein.
By using high-voltage insulated electric conductors with solid insulation similar to that used in cables for transmitting electric power (e.g. XLPE-cables) the voltage of the machine can be increased to such levels that it can be connected directly to the power network without an intermediate transformer. The conventional transformer can thus be eliminated. The concept generally requires the slots in which the cables are placed in the stator to be deeper than with conventional technology (thicker insulation due to higher voltage and more turns in the winding). This means that the distribution of losses differs from that in a conventional machine, which in turn entails new problems in cooling the stator, for instance, and particularly the stator teeth.
The insulated conductor or high-voltage cable used in the present invention is flexible and is of the type described in more detail in WO 97/45919 and WO 97/45847. The insulated conductor or cable is described further in WO 97/45918, WO 97/45930 and WO 97/45931.
Thus, in the device in accordance with the invention the windings are preferably of a type corresponding to cables having solid, extruded insulation, like, those currently used for power distribution, such as XLPE-cables or cables with EPR-insulation. Such a cable has an inner conductor composed of one or more strand parts, an inner semiconducting layer surrounding the conductor, a solid insulating layer surrounding this and an outer semiconducting layer surrounding the insulating layer. Such cables are flexible, which is an important property in this context since the technology for the device according to the invention is based primarily on winding systems in which the winding is formed from conductors which are bent during assembly. The flexibility of a XLPE-cable normally corresponds to a radius of curvature of approximately 20 cm for a cable 30 mm in diameter, and a radius of curvature of approximately 65 cm for a cable 80 mm in diameter. In the present application the term “flexible” is used to indicate that the winding is flexible down to a radius of curvature in the order of four times the cable diameter, preferably eight to twelve times the cable diameter.
The winding should be constructed to retain its properties even when it is bent and when it is subjected to thermal or mechanical stress during operation. It is vital that the layers retain their adhesion to each other in this context. The material properties of the layers are decisive here, particularly their elasticity and relative coefficients of thermal expansion. In a XLPE-cable, for instance, the insulating layer is made of cross-linked, low-density polyethylene, and the semiconducting layers are made of polyethylene with soot and metal particles mixed in. Changes in volume as a result of temperature fluctuations are completely absorbed as changes in radius in the cable and, thanks to the comparatively slight difference between the coefficients of thermal expansion in the layers in relation to the elasticity of these materials, the radial expansion can take place without the adhesion between the layers being lost.
The material combinations stated above should be considered only as examples. Other combinations fulfilling the conditions specified and also the condition of being semiconducting, i.e. having a resistivity within the range of 10-106 ohm-cm, e.g. 1-500 ohm-cm, or 10-200 ohm-cm, naturally also fall within the scope of the invention.
The inner and outer semiconducting layers may be of the same basic material but with particles of conducting material such as soot or metal powder mixed in.
The mechanical properties of these materials, particularly their coefficients of thermal expansion, are affected relatively little by whether soot or metal powder is mixed in or not—at least in the proportions required to achieve the conductivity necessary according to the invention. The insulating layer and the semiconducting layers thus have substantially the same coefficients of thermal expansion.
Ethylene-vinyl-acetate copolymer/nitrile rubber, butylymp polyethylene, ethylene-acrylate-copolymers and ethylene-ethyl-acrylate copolymers may also constitute suitable polymers for the semiconducting layers.
Even when different types of material are used as base in the various layers, it is desirable for their coefficients of thermal expansion to be substantially the same. This is the case with the combination of the materials listed above.
The materials listed above have relatively good elasticity, with an E-modulus of E<500 MPa, preferably <200 MPa. The elasticity is sufficient for any minor differences between the coefficients of thermal expansion for the materials in the layers to be absorbed in the radial direction of the elasticity so that no cracks or other damage appear and so that the layers are not released from each other. The material in the layers is elastic, and the adhesion between the layers is at least of the same magnitude as in the weakest of the materials.
The conductivity of the two semiconducting layers is sufficient to substantially equalize the potential along each layer. The conductivity of the outer semiconducting layer is sufficiently large to contain the electrical field in the cable, but at the same time sufficiently small not to give rise to significant losses due to currents induced in the longitudinal direction of the layer.
Thus, each of the two semiconducting layers essentially constitutes one equipotential surface, and the winding composed of these layers will substantially enclose the electrical field within it.
There is, of course, nothing to prevent one or more additional semiconducting layers being arranged in the insulating layer.
The invention relates to a method for fixing the cable in a high-voltage generator by a pre-shaped triangular tube of XLPE that during operation is to also used for cooling the windings and the tooth section of the stator core. At the assembly, the pre-shaped tube is inserted into the triangular space between cables and tooth. The shape of the tube should provide enough clearance to permit easy insertion of the tube. When the tube is in place, it is heated to a temperature of 125-130°C. at which it may be shaped. Moreover, an over-pressure is applied to the inside of the tube in order to press the tube against the cables and the slot wall. Both heating and pressurizing of the tube are achieved by heating and pressurizing a pressure medium, causing the tube to soften and expand, whereby its outer periphery assumes a shape fitting against cables and slot wall. While retaining the overpressure, the tube is then cooled by exchanging the warm pressure medium against a cold pressure medium, e.g. cold water, which fills the expanded tube and causes it to solidify and permanently assume this expanded shape. The tube will now act as an elastic element, absorbing the thermal expansion of the cables during operation. The tube is also used as a cooling tube during operation, the overpressure of the cooling medium providing a steadying pressure on the cables. This pressure against cables and the slot wall improves the heat transfer as well. The tubes are placed against one of the slot walls in every or every other cable interspace.
The invention also relates to a rotating electric machine provided with cooling tubes that can also fix the position of the cable that are mounted by this method.
The machine has axially running cooling tubes made of a dielectric material, e.g. a polymer, and drawn through the triangular cable interspaces in the stator teeth. The tubes are expanded in the interspaces so that good heat transfer occurs when coolant is circulated in the tubes. The tubes run in the stator yoke and in the stator teeth along the entire axial length of the stator and, if necessary, they can be spliced in the stator teeth.
Polymer cooling tubes are non-conducting and the risk of short-circuiting is therefore eliminated, nor can eddy currents occur in them. Polymer cooling tubes can also be bent cold and drawn through several cooling tube channels without splicing, which is a great advantage.
Polymer cooling tubes can be produced from many materials, such as polyethylene, polypropene, polybutene, polyvinylidene fluoride, polytetrafluoroethylene, as well as filled and reinforced elastomers. Of these materials, polyethylene with high density, HDPE, is preferred since its thermal conductivity increases with increased density. If the polyethylene is cross-linked, which can be achieved by splitting a peroxide, silane cross-linking or radiation patterning, its ability to withstand pressure at increased temperature is enhanced, at the same time as the risk of voltage corrosion disappears. Cross-linked polyethylene, e.g. XLPE tubing from Wirsbo bruks AB, is used, for instance, for water pipes.
In a method and a device in accordance with the invention, the windings are preferably of a type corresponding to cables having solid, extruded insulation, like those currently used for power distribution, such as XLPE-cables or cables with EPR-insulation. Such a cable has an inner conductor composed of one or more strand parts, an inner semiconducting layer surrounding the conductor, a solid insulating layer surrounding this and an cuter semiconducting layer surrounding the insulating layer. Such cables are flexible, which is an important property in this context since the technology for the device according to the invention is based primarily on winding systems in which the winding is drawn back and forth in a plurality of turns, i.e. without being spliced at the coil ends as required when the winding in the core consists of rigid conductors. The flexibility of a XLPE-cable normally corresponds to a radius of curvature of approximately 20 cm for a cable 30 mm in diameter, and a radius of curvature of approximately 65 cm for a cable 80 mm in diameter. In the present application the term “flexible” is used to indicate that the winding is flexible down to a radius of curvature in the order of eight to twenty-five times the cable diameter.
The winding should be constructed to retain its properties even when it is bent and when it is subjected to thermal stress during operation. It is vital that the layers retain their adhesion to each other in this context. The material properties of the layers are decisive here, particularly their elasticity and relative coefficients of thermal expansion. In a XLPE-cable, for instance, the insulating layer is made of cross-linked, low-density polyethylene, and the semiconducting layers are made of polyethylene with soot and metal particles mixed in. Changes in volume as a result of temperature fluctuations are completely absorbed as changes in radius in the cable and, thanks to the comparatively slight difference between the coefficients of thermal expansion in the layers in relation to the elasticity of these materials, the radial expansion can take place without the adhesion between the layers being lost.
The material combinations stated above should be considered only as examples. Other combinations fulfilling the conditions specified and also the condition of being semiconducting, i.e. having a conductivity within the range of 1-105 ohm-cm, and being insulating respectively, i.e. with a conductivity less than 105 ohm-cm.
For example, the insulating layer may be made of a solid thermoplastic material such as low density polyethylene (LDPE), high density polyethylene (HDPE), polypropylene (PP), polybutylene (PB), polymethyl-pentene (PMP), cross-linked materials such as cross-linked polyethylene (XLPE), or rubber such as ethylene-propylene rubber (EPR) or silicone rubber.
The inner and outer semiconducting layers may be of the same basic material but with particles of conducting material such as soot or metal powder mixed in.
The mechanical properties of these materials, particularly their coefficients of thermal expansion, are affected relatively little by whether soot or metal powder is mixed in or not. The insulating layer and the semiconducting layers thus have substantially the same coefficients of thermal expansion.
Ethylene-vinyl-acetate copolymer/nitrile rubber, butylymp polyethylene, ethylene-acrylate-copolymers and ethylene-ethyl-acrylate copolymers may also constitute suitable polymers for the semiconducting layers.
Even when different types of material are used as base in the various layers, it is desirable for their coefficients of thermal expansion to be substantially the same. This is the case with the combination of the materials listed above.
The materials listed above have an elasticity which is sufficient to absorb minor differences between the coefficients of thermal expansion for the materials in the layers in the radial direction of the elasticity, so that no cracks or other damage appear, and so that the layers are not released from each other.
The conductivity of the two semiconducting layers is sufficient to substantially equalize the potential along each layer. At the same time, the conductivity is so small that the outer semiconducting layer has sufficient resistivity to contain the electrical field in the cable.
Thus, each of the two semiconducting layers essentially constitutes one equipotential surface, and the winding composed of these layers will substantially enclose the electrical field within it.
There is, of course, nothing to prevent one or more additional semiconducting layers being arranged in the insulating layer.
The invention will now be described in more detail with reference designations as in the accompanying drawings.
In large conventional machines the stator frame 2 often has a welded steel plate construction. In large machines the stator core 3, also known as the laminated core, is normally made of 0.35 mm core sheet, divided into stacks having an axial length of approximately 50 mm and separated from each other by partitions forming ventilation ducts 5 mm wide. However, in the machine described the ventilation ducts have been eliminated. In large machines each laminated stack is formed by placing sheet metal segments 9, punched to a suitable size, together to form a first layer, each subsequent layer being laid crosswise to form a complete laminated part of a stator core 3. The parts and partitions are held together by pressure brackets 10 which are pressed against pressure rings, fingers or segments, not shown. Only two pressure brackets are shown in FIG. 1.
The tube member 24 is inserted into the space 23 and a pressure medium is heated pressurizing the tube member 24 which will soften and expand, its outer periphery assuming the shape of the restricting area of space 23 delimited by the cable parts second semiconducting layer 15 and the flat side 22 of the stator tooth slot 20, whereafter, maintaining a constant pressure, the warm pressure medium is substituted by a cold pressure medium filling the expanded tube member 24 and causing it to solidify and permanently assuming this expanded shape. It is possible to use the same pressure medium, though at different temperatures. In that case, the temperature of the warm pressure medium will be higher than the softening temperature of the tube member while the temperature of the cold pressure medium will keep below the softening temperature of the tube member. In order to prevent expansion of the free parts of the tube member, i.e. the parts situated outside the stator, these parts are provided with an expansion guard before the pressurization of the cooling tube is started.
Each tube member 24 is made of a dielectric material, e.g. a polymer, preferably XLPE, in order to prevent electric contact with the plate of the stator tooth 4 or with the second semiconducting layer 15 of the cable parts 18.
During expansion the wall thickness of tube member 24 is reduced. The tube member 24 is allowed to expand until 50% of its original wall thickness G remains. The wall thickness and other properties of the tube member are chosen in order to ensure that, after being expanded, the remaining wall thickness is sufficient to completely fill out the space between the outer periphery of the tube member and the second semiconducting layer 15 of the cable parts and the flat side 22 of the stator tooth slot respectively. The material of the tube member is determined with respect to factors like coefficient of thermal conductivity, coefficient of linear expansion as well as hot forming property.
Although the described embodiment relates to a triangular cable interspace, other forms of interspaces are possible, e.g. the cables may be arranged at a larger radial distance thereby forming a hour-glass-shaped interspace in which a pre-shaped cooling tube/fixing means of hour-glass shape may be arranged according to the present invention. It is also possible that the tube member prior to being expanded presents a different cross section than the space itself, e.g. an elliptic cross section, but that the tube member has a wall thickness allowing sufficient expansion.
Number | Date | Country | Kind |
---|---|---|---|
9704380 | Nov 1997 | SE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/SE98/02162 | 11/27/1998 | WO | 00 | 8/22/2000 |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO99/31781 | 6/24/1999 | WO | A |
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4918835 | Wcislo et al. | Apr 1990 | A |
4924342 | Lee | May 1990 | A |
4926079 | Niemela et al. | May 1990 | A |
4942326 | Butler, III et al. | Jul 1990 | A |
4949001 | Campbell | Aug 1990 | A |
4982147 | Lauw | Jan 1991 | A |
4994952 | Silva et al. | Feb 1991 | A |
4997995 | Simmons et al. | Mar 1991 | A |
5012125 | Conway | Apr 1991 | A |
5030813 | Stanisz | Jul 1991 | A |
5036165 | Elton et al. | Jul 1991 | A |
5036238 | Tajima | Jul 1991 | A |
5066881 | Elton et al. | Nov 1991 | A |
5067046 | Elton et al. | Nov 1991 | A |
5083360 | Valencic et al. | Jan 1992 | A |
5086246 | Dymond et al. | Feb 1992 | A |
5091609 | Swada et al. | Feb 1992 | A |
5094703 | Takaoka et al. | Mar 1992 | A |
5095175 | Yoshida et al. | Mar 1992 | A |
5097241 | Smith et al. | Mar 1992 | A |
5097591 | Wcislo et al. | Mar 1992 | A |
5111095 | Hendershot | May 1992 | A |
5124607 | Rieber et al. | Jun 1992 | A |
5136459 | Fararooy | Aug 1992 | A |
5140290 | Dersch | Aug 1992 | A |
5153460 | Bovino et al. | Oct 1992 | A |
5168662 | Nakamura et al. | Dec 1992 | A |
5171941 | Shimizu et al. | Dec 1992 | A |
5175396 | Emery et al. | Dec 1992 | A |
5182537 | Thuis | Jan 1993 | A |
5187428 | Hutchison et al. | Feb 1993 | A |
5231249 | Kimura et al. | Jul 1993 | A |
5235488 | Koch | Aug 1993 | A |
5246783 | Spenadel et al. | Sep 1993 | A |
5264778 | Kimmel et al. | Nov 1993 | A |
5287262 | Klein | Feb 1994 | A |
5293146 | Aosaki et al. | Mar 1994 | A |
5304883 | Denk | Apr 1994 | A |
5305961 | Errard et al. | Apr 1994 | A |
5321308 | Johncock | Jun 1994 | A |
5323330 | Asplund et al. | Jun 1994 | A |
5325008 | Grant | Jun 1994 | A |
5325259 | Paulsson | Jun 1994 | A |
5327637 | Britenbach et al. | Jul 1994 | A |
5341281 | Skibinski | Aug 1994 | A |
5343139 | Gyugyi et al. | Aug 1994 | A |
5355046 | Weigelt | Oct 1994 | A |
5365132 | Hann et al. | Nov 1994 | A |
5387890 | Estop et al. | Feb 1995 | A |
5397513 | Steketee, Jr. | Mar 1995 | A |
5399941 | Grothaus et al. | Mar 1995 | A |
5400005 | Bobry | Mar 1995 | A |
5408169 | Jeanneret | Apr 1995 | A |
5449861 | Fujino et al. | Sep 1995 | A |
5452170 | Ohde et al. | Sep 1995 | A |
5468916 | Litenas et al. | Nov 1995 | A |
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5500632 | Halser, III | Mar 1996 | A |
5510942 | Bock et al. | Apr 1996 | A |
5530307 | Horst | Jun 1996 | A |
5533658 | Benedict et al. | Jul 1996 | A |
5534754 | Poumey | Jul 1996 | A |
5545853 | Hildreth | Aug 1996 | A |
5550410 | Titus | Aug 1996 | A |
5583387 | Takeuchi et al. | Dec 1996 | A |
5587126 | Steketee, Jr. | Dec 1996 | A |
5598137 | Alber et al. | Jan 1997 | A |
5607320 | Wright | Mar 1997 | A |
5612510 | Hildreth | Mar 1997 | A |
5663605 | Evans et al. | Sep 1997 | A |
5672926 | Brandes et al. | Sep 1997 | A |
5689223 | Demarmels et al. | Nov 1997 | A |
5807447 | Forrest | Sep 1998 | A |
5834699 | Buck et al. | Nov 1998 | A |
Number | Date | Country |
---|---|---|
399790 | Jul 1995 | AT |
565063 | Feb 1957 | BE |
391071 | Apr 1965 | CH |
266037 | Oct 1965 | CH |
534448 | Feb 1973 | CH |
539328 | Jul 1973 | CH |
646403 | Feb 1979 | CH |
657482 | Aug 1986 | CH |
1189322 | Oct 1986 | CH |
40414 | Aug 1887 | DE |
277012 | Jul 1914 | DE |
336418 | Jun 1920 | DE |
372390 | Mar 1923 | DE |
386561 | Dec 1923 | DE |
387973 | Jan 1924 | DE |
406371 | Nov 1924 | DE |
425551 | Feb 1926 | DE |
426793 | Mar 1926 | DE |
432169 | Jul 1926 | DE |
433749 | Sep 1926 | DE |
435608 | Oct 1926 | DE |
435609 | Oct 1926 | DE |
441717 | Mar 1927 | DE |
443011 | Apr 1927 | DE |
460124 | May 1928 | DE |
482506 | Sep 1929 | DE |
501181 | Jul 1930 | DE |
523047 | Apr 1931 | DE |
568508 | Jan 1933 | DE |
572030 | Mar 1933 | DE |
584639 | Sep 1933 | DE |
586121 | Oct 1933 | DE |
604972 | Nov 1934 | DE |
629301 | Apr 1936 | DE |
673545 | Mar 1939 | DE |
719009 | Mar 1942 | DE |
846583 | Aug 1952 | DE |
875227 | Apr 1953 | DE |
975999 | Jan 1963 | DE |
1465719 | May 1969 | DE |
1807391 | May 1970 | DE |
2050674 | May 1971 | DE |
1638176 | Jun 1971 | DE |
2155371 | May 1973 | DE |
2400698 | Jul 1975 | DE |
2520511 | Nov 1976 | DE |
2656389 | Jun 1978 | DE |
2721905 | Nov 1978 | DE |
137164 | Aug 1979 | DE |
138840 | Nov 1979 | DE |
2824951 | Dec 1979 | DE |
2835386 | Feb 1980 | DE |
2839517 | Mar 1980 | DE |
2854520 | Jun 1980 | DE |
3009102 | Sep 1980 | DE |
2913697 | Oct 1980 | DE |
2920478 | Dec 1980 | DE |
3028777 | Mar 1981 | DE |
2939004 | Apr 1981 | DE |
3006382 | Aug 1981 | DE |
3008818 | Sep 1981 | DE |
209313 | Apr 1984 | DE |
3305225 | Aug 1984 | DE |
3309051 | Sep 1984 | DE |
3441311 | May 1986 | DE |
3543106 | Jun 1987 | DE |
2917717 | Aug 1987 | DE |
3612112 | Oct 1987 | DE |
3726346 | Feb 1989 | DE |
3925337 | Feb 1991 | DE |
4023903 | Nov 1991 | DE |
4022476 | Jan 1992 | DE |
4233558 | Mar 1994 | DE |
4402184 | Aug 1995 | DE |
4409794 | Aug 1995 | DE |
4412761 | Oct 1995 | DE |
4420322 | Dec 1995 | DE |
19620906 | Jan 1996 | DE |
4438186 | May 1996 | DE |
19020222 | Mar 1997 | DE |
19547229 | Jun 1997 | DE |
468827 | Jul 1997 | DE |
134022 | Dec 2001 | DE |
049104 | Apr 1982 | EP |
0493704 | Apr 1982 | EP |
0056580 | Jul 1982 | EP |
078908 | May 1983 | EP |
0120154 | Oct 1984 | EP |
0130124 | Jan 1985 | EP |
0142813 | May 1985 | EP |
0155405 | Sep 1985 | EP |
0102513 | Jan 1986 | EP |
0174783 | Mar 1986 | EP |
0185788 | Jul 1986 | EP |
0277358 | Aug 1986 | EP |
0234521 | Sep 1987 | EP |
0244069 | Nov 1987 | EP |
0246377 | Nov 1987 | EP |
0265868 | May 1988 | EP |
0274691 | Jul 1988 | EP |
0280759 | Sep 1988 | EP |
0282876 | Sep 1988 | EP |
0309096 | Mar 1989 | EP |
0314860 | May 1989 | EP |
0316911 | May 1989 | EP |
0317248 | May 1989 | EP |
0335430 | Oct 1989 | EP |
0342554 | Nov 1989 | EP |
0221404 | May 1990 | EP |
0375101 | Jun 1990 | EP |
0406437 | Jan 1991 | EP |
0439410 | Jul 1991 | EP |
0440865 | Aug 1991 | EP |
0469155 | Feb 1992 | EP |
0490705 | Jun 1992 | EP |
0503817 | Sep 1992 | EP |
0571155 | Nov 1993 | EP |
0620570 | Oct 1994 | EP |
0620630 | Oct 1994 | EP |
0642027 | Mar 1995 | EP |
0671632 | Sep 1995 | EP |
0676777 | Oct 1995 | EP |
0677915 | Oct 1995 | EP |
0684679 | Nov 1995 | EP |
0684682 | Nov 1995 | EP |
0695019 | Jan 1996 | EP |
0732787 | Sep 1996 | EP |
0738034 | Oct 1996 | EP |
0739087 | Oct 1996 | EP |
0740315 | Oct 1996 | EP |
0749190 | Dec 1996 | EP |
0751605 | Jan 1997 | EP |
0739087 | Mar 1997 | EP |
0749193 | Mar 1997 | EP |
0780926 | Jun 1997 | EP |
0802542 | Oct 1997 | EP |
0913912 | May 1999 | EP |
805544 | Apr 1936 | FR |
841351 | Jan 1938 | FR |
847899 | Dec 1938 | FR |
916959 | Dec 1946 | FR |
1011924 | Apr 1949 | FR |
1126975 | Mar 1955 | FR |
1238795 | Jul 1959 | FR |
2108171 | May 1972 | FR |
2251938 | Jun 1975 | FR |
2305879 | Oct 1976 | FR |
2376542 | Jul 1978 | FR |
2467502 | Apr 1981 | FR |
2481531 | Oct 1981 | FR |
2556146 | Jun 1985 | FR |
2594271 | Aug 1987 | FR |
2708157 | Jan 1995 | FR |
123906 | Mar 1919 | GB |
268271 | Mar 1927 | GB |
293861 | Nov 1928 | GB |
292999 | Apr 1929 | GB |
319313 | Jul 1929 | GB |
518993 | Mar 1940 | GB |
537609 | Jun 1941 | GB |
540456 | Oct 1941 | GB |
589071 | Jun 1947 | GB |
666883 | Feb 1952 | GB |
685416 | Jan 1953 | GB |
702892 | Jan 1954 | GB |
715226 | Sep 1954 | GB |
723457 | Feb 1955 | GB |
739962 | Nov 1955 | GB |
763761 | Dec 1956 | GB |
805721 | Dec 1958 | GB |
827600 | Feb 1960 | GB |
854728 | Nov 1960 | GB |
870583 | Jun 1961 | GB |
913386 | Dec 1962 | GB |
965741 | Aug 1964 | GB |
992249 | May 1965 | GB |
1024583 | Mar 1966 | GB |
1053337 | Dec 1966 | GB |
1059123 | Feb 1967 | GB |
1103098 | Feb 1968 | GB |
1103099 | Feb 1968 | GB |
1117401 | Jun 1968 | GB |
1135242 | Dec 1968 | GB |
1147049 | Apr 1969 | GB |
1157885 | Jul 1969 | GB |
1174659 | Dec 1969 | GB |
1236082 | Jun 1971 | GB |
1268770 | Mar 1972 | GB |
1319257 | Jun 1973 | GB |
1322433 | Jul 1973 | GB |
1340983 | Dec 1973 | GB |
1341050 | Dec 1973 | GB |
1365191 | Aug 1974 | GB |
1395152 | May 1975 | GB |
1424982 | Feb 1976 | GB |
1426594 | Mar 1976 | GB |
1438610 | Jun 1976 | GB |
1445284 | Aug 1976 | GB |
1479904 | Jul 1977 | GB |
1493163 | Nov 1977 | GB |
1502938 | Mar 1978 | GB |
1525745 | Sep 1978 | GB |
2000625 | Jan 1979 | GB |
1548633 | Jul 1979 | GB |
2046142 | Nov 1979 | GB |
2022327 | Dec 1979 | GB |
2025150 | Jan 1980 | GB |
2034101 | May 1980 | GB |
1574796 | Sep 1980 | GB |
2070341 | Sep 1981 | GB |
2070470 | Sep 1981 | GB |
2071433 | Sep 1981 | GB |
2081523 | Feb 1982 | GB |
2099635 | Dec 1982 | GB |
2105925 | Mar 1983 | GB |
2106306 | Apr 1983 | GB |
2106721 | Apr 1983 | GB |
2136214 | Sep 1984 | GB |
2140195 | Nov 1984 | GB |
2150153 | Jun 1985 | GB |
2268337 | Jan 1994 | GB |
2273819 | Jun 1994 | GB |
2283133 | Apr 1995 | GB |
2289992 | Dec 1995 | GB |
2308490 | Jun 1997 | GB |
2332557 | Jun 1999 | GB |
175494 | Nov 1981 | HU |
60206121 | Mar 1959 | JP |
57043529 | Aug 1980 | JP |
57126117 | May 1982 | JP |
59076156 | Oct 1982 | JP |
59159642 | Feb 1983 | JP |
6264964 | Sep 1985 | JP |
1129737 | May 1989 | JP |
62320631 | Jun 1989 | JP |
2017474 | Jan 1990 | JP |
3245748 | Feb 1990 | JP |
4179107 | Nov 1990 | JP |
318253 | Jan 1991 | JP |
424909 | Jan 1992 | JP |
5290947 | Apr 1992 | JP |
6196343 | Dec 1992 | JP |
6233442 | Feb 1993 | JP |
6325629 | May 1993 | JP |
7057951 | Aug 1993 | JP |
7264789 | Mar 1994 | JP |
8167332 | Dec 1994 | JP |
7161270 | Jun 1995 | JP |
8264039 | Nov 1995 | JP |
9200989 | Jan 1996 | JP |
8036952 | Feb 1996 | JP |
8167360 | Jun 1996 | JP |
67199 | Mar 1972 | LU |
90308 | Sep 1937 | SE |
305899 | Nov 1968 | SE |
255156 | Feb 1969 | SE |
341428 | Dec 1971 | SE |
453236 | Jan 1982 | SE |
457792 | Jun 1987 | SE |
502417 | Dec 1993 | SE |
792302 | Jan 1971 | SU |
425268 | Sep 1974 | SU |
1019553 | Jan 1980 | SU |
694939 | Jan 1982 | SU |
955369 | Aug 1983 | SU |
1511810 | May 1987 | SU |
WO8202617 | Aug 1982 | WO |
WO8502302 | May 1985 | WO |
WO9011389 | Oct 1990 | WO |
WO9012409 | Oct 1990 | WO |
PCTDE 9000279 | Nov 1990 | WO |
WO9101059 | Jan 1991 | WO |
WO9101585 | Feb 1991 | WO |
WO9107807 | Mar 1991 | WO |
PCT SE 9100077 | Apr 1991 | WO |
WO9109442 | Jun 1991 | WO |
WO 9111841 | Aug 1991 | WO |
WO8115862 | Oct 1991 | WO |
WO 9115755 | Oct 1991 | WO |
WO9201328 | Jan 1992 | WO |
WO9203870 | Mar 1992 | WO |
WO9321681 | Oct 1993 | WO |
WO9406194 | Mar 1994 | WO |
WO9518058 | Jul 1995 | WO |
WO9522153 | Aug 1995 | WO |
WO9524049 | Sep 1995 | WO |
WO9622606 | Jul 1996 | WO |
WO9622607 | Jul 1996 | WO |
PCTCN 9600010 | Oct 1996 | WO |
WO9630144 | Oct 1996 | WO |
WO9710640 | Mar 1997 | WO |
WO9711831 | Apr 1997 | WO |
WO9716881 | May 1997 | WO |
WO 9729494 | Aug 1997 | WO |
WO9745288 | Dec 1997 | WO |
WO9745847 | Dec 1997 | WO |
WO9745848 | Dec 1997 | WO |
WO9745906 | Dec 1997 | WO |
WO9745907 | Dec 1997 | WO |
WO 9745908 | Dec 1997 | WO |
WO9745912 | Dec 1997 | WO |
WO9745914 | Dec 1997 | WO |
WO9745915 | Dec 1997 | WO |
WO9745916 | Dec 1997 | WO |
WO9745918 | Dec 1997 | WO |
WO9745919 | Dec 1997 | WO |
WO9745920 | Dec 1997 | WO |
WO9745921 | Dec 1997 | WO |
WO9745922 | Dec 1997 | WO |
WO9745923 | Dec 1997 | WO |
WO9745924 | Dec 1997 | WO |
WO9745925 | Dec 1997 | WO |
WO9745926 | Dec 1997 | WO |
WO9745927 | Dec 1997 | WO |
WO9745928 | Dec 1997 | WO |
WO9745929 | Dec 1997 | WO |
WO9745930 | Dec 1997 | WO |
WO9745931 | Dec 1997 | WO |
WO9745932 | Dec 1997 | WO |
WO9745933 | Dec 1997 | WO |
WO9745934 | Dec 1997 | WO |
WO9745935 | Dec 1997 | WO |
WO9745936 | Dec 1997 | WO |
WO9745937 | Dec 1997 | WO |
WO9745938 | Dec 1997 | WO |
WO9745939 | Dec 1997 | WO |
WO9747067 | Dec 1997 | WO |
WO9820595 | May 1998 | WO |
WO9820596 | May 1998 | WO |
WO9820597 | May 1998 | WO |
WO 9820598 | May 1998 | WO |
WO9820600 | May 1998 | WO |
WO 9820602 | May 1998 | WO |
WO9821385 | May 1998 | WO |
PCTFR 9800468 | Jun 1998 | WO |
WO9827634 | Jun 1998 | WO |
WO9827635 | Jun 1998 | WO |
WO9827636 | Jun 1998 | WO |
WO9829927 | Jul 1998 | WO |
WO9829928 | Jul 1998 | WO |
WO9829929 | Jul 1998 | WO |
WO9829930 | Jul 1998 | WO |
WO9829931 | Jul 1998 | WO |
WO9829932 | Jul 1998 | WO |
WO9833731 | Aug 1998 | WO |
WO9833736 | Aug 1998 | WO |
WO9833737 | Aug 1998 | WO |
WO9834238 | Aug 1998 | WO |
WO 9834239 | Aug 1998 | WO |
WO9834240 | Aug 1998 | WO |
WO9834241 | Aug 1998 | WO |
WO9834242 | Aug 1998 | WO |
WO9834243 | Aug 1998 | WO |
WO9834244 | Aug 1998 | WO |
WO9834245 | Aug 1998 | WO |
WO9834246 | Aug 1998 | WO |
WO9834247 | Aug 1998 | WO |
WO9834248 | Aug 1998 | WO |
WO9834249 | Aug 1998 | WO |
WO9834250 | Aug 1998 | WO |
WO9834309 | Aug 1998 | WO |
WO9834312 | Aug 1998 | WO |
WO9834315 | Aug 1998 | WO |
WO9834321 | Aug 1998 | WO |
WO9834322 | Aug 1998 | WO |
WO9834323 | Aug 1998 | WO |
WO9834325 | Aug 1998 | WO |
WO9834326 | Aug 1998 | WO |
WO9834327 | Aug 1998 | WO |
WO9834328 | Aug 1998 | WO |
WO9834329 | Aug 1998 | WO |
WO9834330 | Aug 1998 | WO |
WO9834331 | Aug 1998 | WO |
WO 9840627 | Sep 1998 | WO |
WO 9843336 | Oct 1998 | WO |
WO9917309 | Apr 1999 | WO |
WO9917311 | Apr 1999 | WO |
WO9917312 | Apr 1999 | WO |
WO9917313 | Apr 1999 | WO |
WO9917314 | Apr 1999 | WO |
WO9917315 | Apr 1999 | WO |
WO9917316 | Apr 1999 | WO |
WO9917422 | Apr 1999 | WO |
WO9917424 | Apr 1999 | WO |
WO9917425 | Apr 1999 | WO |
WO9917426 | Apr 1999 | WO |
WO9917427 | Apr 1999 | WO |
WO9917428 | Apr 1999 | WO |
WO9917429 | Apr 1999 | WO |
WO9917432 | Apr 1999 | WO |
WO9917433 | Apr 1999 | WO |
WO9919963 | Apr 1999 | WO |
WO9919969 | Apr 1999 | WO |
WO9919970 | Apr 1999 | WO |
PCTSE 9802148 | Jun 1999 | WO |
WO9927546 | Jun 1999 | WO |
WO9928919 | Jun 1999 | WO |
WO9928921 | Jun 1999 | WO |
WO 9928922 | Jun 1999 | WO |
WO9928923 | Jun 1999 | WO |
WO9928924 | Jun 1999 | WO |
WO9928925 | Jun 1999 | WO |
WO9928926 | Jun 1999 | WO |
WO9928927 | Jun 1999 | WO |
WO9928928 | Jun 1999 | WO |
WO9928929 | Jun 1999 | WO |
WO9928930 | Jun 1999 | WO |
WO9928931 | Jun 1999 | WO |
WO9928934 | Jun 1999 | WO |
WO9928994 | Jun 1999 | WO |
WO9929005 | Jun 1999 | WO |
WO 9929005 | Jun 1999 | WO |
WO9929008 | Jun 1999 | WO |
WO9929011 | Jun 1999 | WO |
WO9929012 | Jun 1999 | WO |
WO9929013 | Jun 1999 | WO |
WO9929014 | Jun 1999 | WO |
WO9929015 | Jun 1999 | WO |
WO9929016 | Jun 1999 | WO |
WO9929017 | Jun 1999 | WO |
WO9929018 | Jun 1999 | WO |
WO9929019 | Jun 1999 | WO |
WO9929020 | Jun 1999 | WO |
WO9929021 | Jun 1999 | WO |
WO9929022 | Jun 1999 | WO |
WO 9929023 | Jun 1999 | WO |
WO9929024 | Jun 1999 | WO |
WO 9929025 | Jun 1999 | WO |
WO9929026 | Jun 1999 | WO |
WO9929029 | Jun 1999 | WO |
WO9929034 | Jun 1999 | WO |