Method of conducting an absorption or desorption reaction between a gas and a solid

Abstract

Method of conducting an absorption or desorption reaction between a gas and a solid in which the reaction medium is formed using a powdery solid having a compaction between 5 and 60% of the optimum compaction of the reaction without graphite.

Description

The present invention relates to a method of conducting an absorption or desorption reaction between a gas and a solid, this solid being formed by a salt or a mixture of salts capable of reacting with the gas while giving an absorption reaction or conversely a desorption reaction, these reactions taking place in the presence of expanded graphite. The principle of these reactions between a gas and a solid is described for example in the French Pat. No. 2 547 512: "Method of implementing a gas-solid reaction" or else in the French Pat. No. 2 548 340: "Three phase heat pump" or else in the French patent application No. 85 08408 filed on June 4, 1985: "Thermochemical heat storage and destorage method and device".

Furthermore, the absorption or desorption reaction kinetics have been studied as a function of the initial condition of the salts. In particular, the article published in the review Physique Appliquee 18 (1983) pages 107 to 112 of February 1983 entitled: "Optimisation des densites energetiques de systeme stockage chimique basee sur des reactions solide gaz renversables" describes a study of the variation of the energy density of the reaction as a function of the initial compaction of the salt, this reaction being carried out in the absence of any compound similar to expanded graphite. Such compaction is expressed in moles of anhydrous salt per m.sup.3. The curve published on page 109 of this publication shows that, for each reaction studied, there exists a compaction value for which the energy density, expressed in kWh per m.sup.3 is maximum. In the rest of the text, this value will be called optimum compaction of the reaction without graphite.

An object of the present invention is to provide a method which makes it possible to conduct a reaction of the above type in the presence of expanded graphite, the reagent formed by one or more salts being present in the reaction medium in powdery form, said reaction having optimum power.

For that, the invention provides a method of conducting an absorption or desorption reaction between a gas and a solid, said solid being formed by one or more salts in powdery form, in the presence of expanded graphite, in which method the reaction medium comprises between 0--not included--and 60% by weight of expanded graphite, characterized in that, in order to form the reaction medium, a powdery solid is used having a compaction between 5 and 60% of the optimum compaction of the reaction without graphite.

In preferred embodiments of the invention, the percentage of expanded graphite is between 20 and 25% included by weight and the packing of the salt is chosen in a range between 20 and 60% of the optimum compaction; for a graphite percentage between 25 excluded and 35% included, the compaction of the salt is chosen between 15 and 55% of the maximum value; for a graphite percentage between 35 excluded and 40% included, the compaction of the salt is chosen between 15 and 50% of the optimum value; for a graphite percentage between 40 excluded and 45% included, the compaction of the salt is chosen between 10 and 50% of the optimum value; for a graphite percentage between 45 excluded and 50% included, the compaction of the salt is chosen between 10 and 45% of the optimum value; and finally for a graphite percentage between 50 excluded and 60% included, the compaction of the salt is chosen between 5 and 40% of the optimum value.

In another embodiment of the invention, the solid powdery compound is formed by a salt or a mixture of salts, itself formed by a compound of a halogen chosen from Cs, Br, I, F and an element chosen from: Li, Na, K, Rb, Be, Mg, Ca, Sr, Ba, Mn, Fe, Co, Ni, Cu, Ag, Au, Zn, Cd, Hg, Sn, Pb, Cr, Sb.

But also, this salt or these mixtures of salts may be chosen from: NH.sub.4 Cl, NH.sub.4 Br, NH.sub.4 I, NH.sub.4 NO.sub.3, Sr(ClO.sub.4)2, Ba(ClO.sub.4).sub.2, Fe.sub.2 (SO.sub.4).sub.3, NiSO.sub.4, CuSO.sub.4, Ag(ClO.sub.4), AgNO.sub.3, ZnSO.sub.4.

But other characteristics and advantages of the invention will appear more clearly from the following description, given by way of non limitative illustration with reference to the accompanying figures in which:

FIG. 1 shows the variation of the energy density as a function of the compaction of the salt for a reaction without expanded graphite,

FIG. 2 shows the variation of the mean power as a function of the compaction of the salt and the expanded graphite mixture.

The variation of the energy density, which is shown in FIG. 1, is taken from the above mentioned publication and published in the review Physique Appliquee, and clearly shows that the energy density is maximum for a very specific value of the compaction of the salt, this compaction being designated Topt in this FIG. 1.

In FIG. 2, the variation of the mean power has been shown as a function of the compaction of the mixture, namely of the reaction medium comprising the salt or salts and expanded graphite.

It will be noted that the energy density passes through a maximum which is between two values Tm and TM, these values corresponding to a certain percentage of the Topt value shown in FIG. 1.

By way of illustration, the values will be given below of the measurements made for a reaction using calcium chloride and methylamine, which reaction was conducted in the presence of expanded graphite.

For a weighted rate of 25% of expanded graphite, the compaction optimum, for optimum power, is situated at about 244 kg of mixture per m.sup.3, i.e. 183 kg of anhydrous salt (calcium chloride) per m.sup.3, which corresponds to compaction of the salt equal to 45% of the Topt value defined as being the optimum compaction of the reaction without graphite. For a rate of 35% of expanded graphite, the compaction optimum is situated at 186 kg of mixture per m.sup.3, which corresponds to compaction equal to 35% of the optimum compaction such as defined above. Using the experimental curves similar to FIG. 2, it can be readily determined that compaction optimum is situated between:--20 and 60% of the optimum compaction in the presence of 25% graphite and between 15 and 55% in the presence of 35% graphite.

Similarly, it can be verified that for a reaction using lithium chloride in the presence of methylamine, the optimum, for 40% expanded graphite, is situated at a value of 86 kg of salt per m.sup.3, which corresponds for equilibrium between 2 and 3 moles of methylamine, to 40% of the optimum compaction.

In the following tables the compaction ranges have been shown for simultaneously optimizing the power and the energy density, these ranges being drawn up for different percentages of expanded graphite and for a whole series of equilibriums with ammonia and a whole series of equilibriums of different salts with methylamine.

In these tables, in the first column the nature of the salt has been shown, in the second column the equilibrium concerned between the salt and the gas molecules, in the third column the minimum and maximum weight values of anhydrous salt expressed in kg per m.sup.3, corresponding to 25% of expanded graphite, whereas the last three columns contain indications of the compaction minimum and maximum for 35%, 50% and 60% of expanded graphite. The first series of tables concerns the reactions conducted in the presence of ammonia whereas the second series concerns reactions conducted in the presence of methylamine.

__________________________________________________________________________ With NH.sub.3Salts Equilibrium 25% 35% 50% 60%__________________________________________________________________________LiCl 0-1 180/560 130/510 90/420 40/370 1-2 120/360 90/330 60/270 30/240 2-3 80/270 60/250 40/200 20/180 3-4 70/210 50/200 30/160 10/140 4-5 50/180 40/160 20/130 10/120LiBr 0-1 340/1040 250/950 170/780 80/690 1-2 230/690 170/640 110/520 50/460 2-3 170/520 130/480 80/390 40/350 3-4 140/420 100/380 70/310 30/280 4-5 120/350 80/320 50/260 20/230LiI 0-1 460/1390 340/1270 230/1040 110/930 1-2 320/970 240/890 160/730 80/650 2-3 240/740 180/680 120/560 60/500 3-4 200/600 150/550 100/450 50/400 4-5 160/510 120/460 80/380 40/340 5-5,5 150/470 110/430 70/350 30/320NaCl 0-2,5 130/390 90/360 60/300 30/260 2,5-5 70/230 50/210 30/180 20/160NaBr 0-5,25 120/380 90/350 60/280 30/250NaI 0-4 210/640 150/580 100/480 50/430 4-4,5 190/590 140/540 90/440 40/390 4,5-6 150/470 110/430 70/350 30/310KI 0-4 210/650 160/600 100/490 50/430 4-6 160/490 120/450 80/370 40/330RbBr 0-3 260/800 190/730 130/600 60/530RbI 0-6 200/610 150/560 100/460 50/410NH.sub.4 Cl 0-3 90/290 70/270 40/220 20/200NH.sub.4 Br 0-1 290/900 220/830 140/680 70/600 1-5 110/360 80/330 50/270 20/240or 1-4 130/420 100/380 60/320 30/280 4-6 100/310 70/290 50/230 20/210NH.sub.4 I 0-1 350/1050 260/970 170/790 80/700 1-2 260/810 200/740 130/610 60/540 2-3 210/660 160/600 100/490 50/440 3-5 150/480 110/440 70/360 30/320 5-6 130/420 100/390 60/320 30/280NH.sub.4 NO.sub.3 0-0,5 270/820 200/750 130/610 60/550BeCl.sub.2 0-2 170/520 120/480 80/390 40/350 2-4 110/340 80/310 50/260 20/230 4-6 80/250 60/230 40/190 20/170 6-12 40/140 30/130 20/110 10/100BeBr.sub.2 0-4 220/680 160/620 110/510 50/460 4-6 160/510 120/470 80/380 40/340 6-10 110/340 80/310 50/260 20/230BeI.sub.2 0-4 320/980 240/900 160/740 80/650 4-6 240/750 180/690 120/560 60/500 6-13 130/410 100/380 60/310 30/270MgCl.sub.2 0-1 280/870 210/790 140/650 70/580 1-2 210/630 150/580 100/470 50/420 2-4 130/410 100/370 60/310 30/270 4-6 90/300 70/280 40/230 20/200MgBr.sub.2 0-1 490/1480 370/1360 240/1110 120/990 1-2 370/1110 270/1020 180/830 90/740 2-6 180/550 130/510 90/420 40/370MgI.sub.2 0-1 630/1900 470/1740 310/1430 150/1270 1-2 490/1480 370/1350 240/1110 120/990 2-6 260/780 190/720 130/590 60/520CaCl.sub.2 0-1 280/870 210/800 140/650 70/580 1-2 210/660 160/600 100/490 50/440 2-4 170/530 130/480 80/400 40/350 4-8 100/330 80/300 50/240 20/220CaBr.sub.2 0-1 470/1420 350/1300 230/1060 110/950 1-2 360/1090 270/1000 180/820 90/730 2-6 180/570 140/530 90/430 40/380 6-8 150/460 110/420 70/350 30/310CaI.sub.2 0-1 590/1780 440/1630 290/1330 140/1190 1-2 470/1420 350/1300 230/1060 110/950 2-3 390/1180 290/1080 190/890 90/790 3-6 260/780 190/720 130/590 60/520SrCl.sub.2 0-1 410/1240 300/1130 200/930 100/830 1-8 140/430 100/400 70/320 30/290or 0-8SrBr.sub.2 0-1 590/1770 440/1630 290/1330 140/1180 1-2 450/1360 340/1250 220/1020 110/910 2-6 240/710 170/650 110/530 50/480 6-8 190/570 140/530 90/430 40/380SrI.sub.2 0-1 680/2050 510/1880 340/1540 170/1370 1-2 540/1640 400/1500 270/1230 130/1090 2-6 300/910 220/830 150/680 70/610 6-8 240/740 180/680 120/560 60/500Sr(ClO.sub.4).sub.2 0-2 400/1220 300/1120 200/920 100/810 2-6 230/710 170/650 110/540 50/480 6-7 210/650 160/590 100/490 50/430BaCl.sub.2 0-8 190/590 140/540 90/440 40/390BaBr.sub.2 0-1 680/2040 510/1870 340/1530 170/1360 1-2 520/1590 390/1450 260/1190 130/1060 2-4 360/1100 270/1010 180/820 90/730 4-8 220/680 160/620 110/510 50/450BaI.sub.2 0-2 610/1860 460/1710 300/1400 150/1240 2-4 440/1330 330/1220 220/1000 110/890 4-6 340/1040 250/950 170/780 80/690 6-8 280/850 210/780 140/640 70/570 8-9 250/780 190/710 120/590 60/520Ba(ClO.sub.4).sub.2 0-5 290/880 210/800 140/660 70/590 5-6 260/790 190/730 130/590 60/530MnCl.sub.2 0-0,5 450/1380 340/1270 220/1040 110/920 0,5-1 370/1120 270/1030 180/840 90/750 1-2 300/910 220/830 150/680 70/610 2-6 150/460 110/420 70/350 30/310MnBr.sub.2 0-1 650/1960 490/1800 320/1470 160/1310 1-2 430/1300 320/1190 210/980 100/870 2-6 240/730 180/670 120/550 60/490MnI.sub.2 0-2 550/1650 410/1520 270/1240 130/1100 2-6 310/940 230/870 150/710 70/630FeCl.sub.2 0-1 380/1170 290/1070 190/880 90/780 1-2 280/840 210/770 140/630 70/560 2- 6 150/480 110/440 70/360 40/320FeBr.sub.2 0-1 600/1810 450/1660 300/1360 150/1210 1-2 440/1340 330/1230 220/1000 110/890 2-6 240/740 180/680 120/560 60/500FeI.sub.2 0-2 570/1710 420/1570 280/1290 140/1140 2-6 300/930 230/850 150/700 70/620Fe.sub.2 (SO.sub.4).sub.3 0-3 390/1180 290/1080 190/880 90/790 3-6 280/860 210/790 140/650 70/570 6-12 180/560 140/510 90/420 40/370CoCl.sub.2 0-1 400/1220 300/1120 200/920 100/820 1-2 290/880 210/800 140/660 70/590 2-6 160/500 120/460 80/380 40/340CoBr.sub.2 0-1 620/1880 470/1730 310/1410 150/1260 1-2 460/1390 340/1270 230/1040 110/920 2-6 250/770 190/710 120/580 60/510CoI.sub.2 0-2 590/1780 440/1630 290/1340 140/1190 2-6 310/950 230/870 150/720 70/640NiCl.sub.2 0-1 420/1260 310/1160 210/950 100/840 1-2 290/900 220/820 140/670 70/600 2-6 130/420 100/380 60/310 30/280 6-7 120/370 90/340 60/280 30/250 7-9 90/300 70/270 50/230 20/200 9-10 90/270 60/250 40/210 20/180NiBr.sub.2 0-1 640/1930 480/1770 320/1450 160/1290 1-2 460/1410 350/1290 230/1060 110/940 2-6 220/680 160/620 110/510 50/450NiI.sub.2 0-2 600/1810 450/1660 300/1360 150/1210 2-6 300/920 220/840 150/690 70/610NiSO.sub.4 0-1 460/1380 340/1270 230/1040 110/920 1-2 330/1010 250/920 160/760 80/670 2-6 160/480 120/440 80/360 40/320CuCl 0-0,5 540/1630 400/1490 270/1220 130/1090 0,5-1 400/1210 300/1110 200/910 100/810 1-1,5 320/970 240/890 160/730 80/650 1,5-3 190/600 140/550 90/450 50/400CuBr 0-1 530/1600 390/1460 260/1200 130/1070 1-1,5 430/1300 320/1200 210/970 100/860 1,5-3 270/830 200/760 130/620 60/550CuI 0-0,5 820/2460 610/2260 400/1850 200/1640 0,5-1 640/1940 480/1780 320/1450 160/1290 1-1,5 530/1600 390/1460 260/1200 130/1070 1,5-2 450/1360 330/1250 220/1020 110/910 2-3 340/1050 260/960 170/790 80/700CuCl.sub.2 0-2 290/900 220/820 140/680 70/600 2-3.sup.1 /3 210/660 160/600 100/490 50/440 3.sup.1 /3-5 160/490 120/450 80/370 40/330CuBr.sub.2 0-2 450/1380 340/1270 220/1040 110/920 2-3.sup.1 /3 340/1030 250/940 170/770 80/690 3.sup.1 /3-5 250/780 190/710 120/590 60/520CuSO.sub.4 0-1 450/1380 340/1270 230/1040 110/920 1-2 330/1010 250/930 160/760 80/680 2-4 220/660 160/610 110/500 50/440 4-5 180/570 140/520 90/430 40/380AgCl 0-1 560/1690 420/1550 280/1270 140/1130 1-1,5 450/1360 330/1240 220/1020 110/900 1,5-3 280/850 210/780 140/640 70/570AgBr 0-1 690/2080 510/1910 340/1560 170/1390 1-1,5 560/1690 420/1550 280/1270 140/1130 1,5-3 350/1080 260/990 170/810 90/720AgI 0-0,5 900/2730 680/2500 450/2050 220/1820 0,5-1 730/2190 540/2010 360/1650 180/1460 1-1,5 610/1840 450/1680 300/1380 150/1220Ag(ClO.sub.4) 0-2 330/1000 250/920 160/750 80/670 2-3 270/840 200/770 130/630 60/560AgNO.sub.3 0-2 370/1140 280/1050 190/860 90/760AuCl 0-1 820/2470 610/2260 410/1850 200/1640 1-2 560/1710 420/1560 280/1280 140/1140 2-6 250/770 190/700 120/580 60/510AuBr 0-1 910/2760 680/2530 450/2070 230/1840 1-2 640/1950 480/1780 320/1460 160/1300 2-3 500/1500 370/1380 250/1130 120/1000 3-4 400/1220 300/1120 200/920 100/820 4-6 290/890 220/820 140/670 70/600AuI 0-1 1000/3020 750/2770 500/2260 250/2010 1-2 720/2170 540/1990 360/1630 180/1450 2-3 560/1690 420/1550 280/1270 140/1130 3-6 330/1020 250/940 170/770 80/680ZnCl.sub.2 0-1 370/1140 280/1040 180/860 90/760 1-2 280/840 210/770 140/630 70/560 2-4 180/560 130/510 90/420 40/370 4-6 170/520 120/470 80/390 40/350ZnBr.sub.2 0-1 570/1720 420/1580 280/1290 140/1150 1-2 430/1300 320/1190 210/980 100/870 2-4 290/880 210/810 140/660 70/590 4-5 270/810 200/750 130/610 60/540 5-6 260/790 190/720 130/590 60/530ZnI.sub.2 0-1 680/2070 510/1900 340/1550 170/1380 1-2 540/1630 400/1490 270/1220 130/1090 2-4 370/1140 280/1050 190/860 90/760 4-6 320/970 240/890 160/730 80/650ZnSO.sub.4 0-0,5 550/1670 410/1530 270/1250 130/1110 0,5-1 450/1370 340/1260 230/1030 110/920 1-2 330/1010 250/930 160/760 80/680 2-3 260/800 200/740 130/600 60/540 3-4 220/670 160/610 110/500 50/440 4-5 180/570 140/520 90/430 40/380CdCl.sub.2 0-1 580/1740 430/1600 290/1310 140/1160 1-2 450/1360 330/1250 220/1020 110/910 2-4 280/870 210/800 140/660 70/580 4-6 210/650 160/600 100/490 50/440CdBr.sub.2 0-1 750/2270 560/2080 370/1700 180/1510 1-2 590/1790 440/1640 290/1340 140/1200 2-6 300/910 220/830 150/680 70/610CdI.sub.2 0-2 660/2000 500/1840 330/1500 160/1340 2-6 360/1090 270/1000 180/820 90/730HgCl.sub.2 0-1,5 840/2530 630/2320 420/1900 210/1690 1,5-2 610/1860 460/1710 300/1400 150/1240 2-8 210/650 160/600 100/490 50/440HgBr.sub.2 0-2 790/2380 590/2180 390/1790 190/1590 2- 8 270/830 200/760 130/630 60/560HgI.sub.2 0-.sup.4 /3 860/2600 640/2380 430/1950 210/1730 .sup.4 /3-2 830/2490 620/2280 410/1870 200/1660 2-6 400/1230 300/1130 200/920 100/820HgF.sub.2 0-2 730/2220 550/2030 360/1670 180/1480SnCl.sub.2 0-4 250/770 190/700 120/580 60/510 4-9 130/420 100/380 60/310 30/280SnBr.sub.2 0-1 690/2100 520/1930 350/1580 170/1400 1-2 530/1600 390/1460 260/1200 130/1070 2-3 420/1290 320/1180 210/970 100/860 3-5 300/930 230/850 150/700 70/620 5-9 190/600 140/550 90/450 40/400SnI.sub.2 0-1 770/2340 580/2140 380/1760 190/1560 1-2 610/1850 460/1700 300/1390 150/1240 2-3 500/1530 380/1410 250/1150 120/1020 3-5 370/1140 280/1050 180/860 90/760 5-9 250/760 180/690 120/570 60/500 9-10 230/700 170/640 110/520 50/470PbCl.sub.2 0-1 760/2300 570/2110 380/1720 190/1530 1-1,5 650/1960 480/1790 320/1470 160/1310 1,5-2 560/1710 420/1560 280/1280 140/1140 2-3,25 420/1290 320/1180 210/970 100/860 3,25-8 220/670 160/620 110/510 50/450PbBr.sub.2 0-1 910/2740 680/2520 450/2060 220/1830 1-2 690/2090 520/1920 340/1570 170/1390 2-3 560/1690 420/1550 280/1270 140/1130 3-5,5 370/1140 280/1040 180/860 90/760 5,5- 8 280/860 210/790 140/650 70/580PbI.sub.2 0-0,5 1050/3170 790/2900 520/2380 260/2110 0,5-1 920/2770 690/2540 460/2080 230/1850 1-2 730/2210 550/2030 360/1660 180/1480 2-5 450/1380 340/1270 220/1040 110/920 5-8 330/1000 250/920 160/750 80/670CrCl.sub.2 0-6 150/460 110/420 70/350 30/310CrBr.sub.2 0-6 230/700 170/640 110/530 50/470CrI.sub.2 0-6 270/840 200/770 130/630 60/560SbF.sub.3 0-1 600/1810 450/1660 300/1360 150/1210 1-2 450/1360 330/1250 220/1020 110/910 2-3 360/1090 270/1000 180/820 90/730 3-4 250/760 180/700 120/570 60/510 4-6 180/560 130/520 90/420 40/380__________________________________________________________________________ ______________________________________ Equi- With CH.sub.3 NH.sub.2Salts librium 25% 35% 50% 60%______________________________________LiCl 0-1 120/380 90/350 60/290 30/260 1-2 80/250 60/230 40/190 20/170 2-3 30/120 20/110 10/90 10/80 3-4 30/110 20/100 10/90 10/80MgCl.sub.2 0-2 140/430 100/390 70/320 30/290 2-4 80/250 60/230 40/190 20/170 4-8 40/140 30/130 20/110 10/100CaCl.sub.2 0-1 220/680 160/620 110/510 50/460 1-2 150/460 110/430 70/350 30/310 2-4 90/280 70/260 40/210 20/190 4-6 80/250 60/230 40/190 20/170SrCl.sub.2 0-5/3 240/740 180/680 120/550 60/490 5/3-3 160/500 120/460 80/380 40/330MnCl.sub.2 0-1 280/850 210/780 140/640 70/570 1-2 180/560 130/510 90/420 40/380 2-6 100/310 70/290 50/230 20/210FeCl.sub.2 0-5 90/280 60/260 40/210 20/190CoCl.sub.2 0-4 110/350 80/320 50/260 20/230 4-6 80/250 60/230 40/190 20/170NiCl.sub.2 0-4 110/350 80/320 50/270 20/240 4-6 80/250 60/230 40/190 20/170CuCl.sub.2 0-4 110/360 80/330 50/270 30/240ZnCl.sub.2 0-2 190/590 140/540 90/440 40/390 2-4 150/460 110/420 70/350 30/310 4-6 120/380 90/350 60/290 30/260LiBr 0-1 240/730 180/670 120/550 60/490 1-2 140/440 110/410 70/330 30/300 2-3 100/320 70/290 50/240 20/210 3-4 80/250 60/230 40/190 20/170 4-5 60/210 50/190 30/160 10/140MnBr.sub.2 0-4 180/550 130/510 90/410 40/370 4-6 130/400 90/360 60/300 30/270FeBr.sub.2 0-5 150/470 110/430 70/350 30/310COBr.sub.2 0-6 130/410 100/370 60/310 30/270NiBr.sub.2 0-6 130/410 100/380 60/310 30/270CuBr.sub.2 0-4 190/590 140/540 90/440 40/390ZnBr.sub.2 0-5 150/470 110/440 70/360 30/320CdBr.sub.2 0-3 280/850 210/780 140/640 70/570LiI 0-0,25 600/1810 450/1660 300/1360 150/1210 0,25-0,5 470/1430 350/1310 230/1080 110/960 0,5-1 330/1010 250/930 160/760 80/680 1-2 210/640 150/590 100/480 50/430 2-3 150/470 110/430 70/350 30/310 3-3,5 130/410 100/380 60/310 30/280MnI.sub.2 0-6 180/550 130/500 90/410 40/370FeI.sub.2 0-5 210/640 150/590 100/480 50/430CoI.sub.2 0-4 250/780 190/720 120/590 60/520 4-6 180/560 140/520 90/420 40/380NiI.sub.2 0-6 180/570 140/520 90/430 40/380ZnI.sub.2 0-5 210/640 150/590 100/480 50/430CdI.sub.2 0-3 350/1080 260/990 170/810 80/720NiSO.sub.4 0-3 170/510 120/470 80/390 40/340 3-4,5 120/370 90/340 60/280 30/250 4,5-5,5 100/310 70/290 50/240 20/210 5,5-8 70/230 50/210 30/170 10/150Fe.sub.2 (SO.sub.4).sub.3 0-7 170/530 130/490 80/400 40/350 7-12 110/350 80/320 50/270 20/240ZnSO.sub.4 0-3 170/530 130/480 80/400 40/350 3-3,12 160/510 120/470 80/380 40/340 3,12-3,5 150/470 110/430 70/350 30/310 3,5-4,25 130/400 100/370 60/300 30/270______________________________________

Obviously, additional modifications and variations of the present invention are possible in light of the above teachings. It is therefore to be understood that within the scope of the appended claims, the invention may be practiced otherwise than as specifically described herein.

Claims

1. A method of conducting an absorption or desorption reaction between a gas and a solid, said solid being formed by one or more salts in powdery form, in the presence of expanded graphite, in which method the reaction medium comprises expanded graphite in a positive amount up to 60% by weight, characterized in that, in order to form the reaction medium, a powdery solid is used having a compaction between 5 and 60% of the optimum compaction of the reaction without graphite, wherein said optimum compaction is the compaction value for which the energy density is a maximum for the reaction without graphite.

2. Method according to claim 1, in which the percentage of expanded graphite is between 20 and 25% included by weight, characterized in that the compaction of the salt is chosen in a range between 20 and 60% of the optimum compaction.

3. Method according to claim 1, in which the percentage of expanded graphite is between 25 excluded and 35% included by weight, characterized in that compaction of the salt is chosen between 15 and 55% of the optimum compaction.

4. Method according to claim 1, in which the percentage of expanded graphite is between 35 excluded and 40% included, characterized in that compaction of the salt is chosen between 15 and 50% of the optimum compaction.

5. Method according to claim 1, in which the percentage of expanded graphite is between 40 excluded and 45% included by weight, characterized in that compaction of the salt is chosen between 10 and 50% of the optimum compaction.

6. Method according to claim 1, in which the percentage of expanded graphite is between 45 excluded and 50% included by weight, characterized in that compaction of the salt is chosen between 10 and 45% of the optimum compaction.

7. Method according to claim 1, in which the expanded graphite percentage is between 50 excluded and 60% by weight, characterized in that compaction of the salt is chosen in a range between 5 and 40% of the optimum compaction.