The invention relates to a solid oxide fuel cell utilizing an integrated sensor.
The statements in this section merely provide background information related to the present disclosure and may not constitute prior art. Solid oxide fuel cells create an electromotive force across an electrolyte by reacting a fuel, typically hydrogen, at an anode disposed on a first side of the electrolyte, and an oxidant, typically oxygen at a cathode disposed on a second side of the electrolyte. Solid oxide fuel cells can operate utilizing an onboard fuel that is reformed prior to utilization within the fuel cell. Using an onboard fuel is advantageous in that the onboard fuel is easy to transport and in that the reformation process can be utilized to preheat the fuel cell to operate at the fuel cell at desired operating temperatures.
Solid oxide fuel cell systems can control an oxygen-to-fuel ratio at the fuel reforming reactor to efficiently reform the onboard fuel and to prevent coking Typically, fluid flow sensors provide feedback so that air and fuel flow rates can be controlled. However, the fluid flow sensors undesirably raise the cost of the fuel cell system and the fluid flow sensors do not measure air and fuel in close proximity to the solid oxide fuel cell, thereby limiting the precision of control systems utilizing traditional fluid flow sensors.
Therefore, fuel cells with improved sensing methods and components are needed.
It should be understood that the appended drawings are not necessarily to scale, presenting a somewhat simplified representation of various preferred features illustrative of the basic principles of the invention. The specific design features of the fuel cell as disclosed herein will be determined in part by the particular intended application and use environment. Certain features of the illustrated embodiments have been enlarged or distorted relative to others for visualization and clear explanation. In particular, thin features may be thickened, for example, for clarity of illustration.
A method for controlling a fuel cell system is described in accordance with exemplary embodiments. The fuel cell system includes an air actuator, a fuel actuator, and a fuel cell. The fuel cell includes an anode, a cathode, and an electrolyte. The method includes measuring an open circuit voltage of the fuel cell. The method further includes determining an air actuator control signal based on the open circuit voltage of the fuel cell. The method further includes controlling the air actuator based on the air actuator control signal. The method further includes determining a fuel actuator control signal based on the open circuit voltage of the fuel cell. The method further includes controlling the fuel actuator based on the fuel actuator control signal.
Described herein are various embodiments of a fuel cell system and methods for controlling a fuel cell system based on an open circuit voltage of a fuel cell. The fuel cell systems described herein include fuel cell stacks, wherein the open circuit voltage can be detected by a control circuit continuously monitoring one or more cells providing an open circuit voltage level. In an exemplary embodiment, one or more fuel cells can be dedicated to open circuit voltage sensing throughout the life of the fuel cell system. In alternate designs, a control system can command a fuel cell stack so that a fuel cell can be utilized for providing electrical power during certain time periods and can be utilized for open circuit voltage sensing during other time periods.
The disclosure presents an exemplary fuel cell system 10 utilizing exemplary control schemes. However, it is to be understood that aspects of the control schemes and strategies described herein can be applied to systems utilizing other types of sensors and other types of actuators. Alternate control schemes may substitute an actuator described herein for another type of actuator, while being within the scope and spirit of the disclosure. For example, one or more of a pump, a valve, or a blower may be substituted for the blowers and valves described herein. The term (‘actuator,’) as used herein, refers to a component that a control system 20 can command to affect operation of the fuel cell system 10 by modifying, for example, a fluid flow rate or a power attribute.
The current collection system 36 is electrically connected to the sensing cell 34 through an anode current collector and a cathode current collector that route current away from the sensing cell 34 without interconnecting the sensing cell 34 with other fuel cell tubes 32. Since the sensing cell 34 is detecting open circuit voltage and not configured to route substantial levels of electric current from the sensing cell 34, the sensing cell 34 can include much less current conduction material then each one of the fuel cell tubes 32. In an exemplary fuel cell stack 30, the fuel cells tubes 32 are arranged in a series connection to produce DC power at a voltage which is a sum of the potential of the individual fuel cells. Alternatively, fuel cell electrodes can be connected in parallel or in a combination with some electrodes connected in series and some electrodes in parallel.
The fuel cell tubes 32 and the sensing cell 34 each comprise a substantially similar construction and each include the active portion 38 having an inner anode layer, an exterior cathode layer, and an electrolyte disposed therebetween. The active portion 38 utilizes air and fuel to generate electromotive force across the electrolyte, thereby motivating electric current.
In an exemplary embodiment, the fuel cell tubes 32 and the sensing cell 34 are advantageously relatively light in weight, and provide good power density to mass ratios. Exemplary tubes comprise a 1 mm-20 mm diameter tube. Thin, lightweight tubes are also advantageous in that the tubes hold less heat, allowing the fuel cell to be heated rapidly. Other material combinations for the anode, electrolyte and cathode, as well as other cross section geometries (triangular, square, polygonal, etc.) will be readily apparent to those skilled in the art given the benefit of this disclosure.
In general, the anode layer and the cathode layer are formed of porous materials capable of functioning as an electrical conductor and capable of facilitating the appropriate reactions. The porosity of these materials allows dual directional flow of gases (e.g., to admit the fuel or oxidant gases and permit exit of the byproduct gases). In an exemplary embodiment, the anode comprises a conductive metal such as nickel, disposed within a ceramic skeleton, such as yttria-stabilized zirconia. The cathode layer comprises a conductive material chemically stable in an oxidizing environment. In an exemplary embodiment, the cathode layer comprises a perovskite material and specifically lanthanum strontium cobalt ferrite. In an alternative exemplary embodiment, the cathode layer comprises lanthanum strontium manganite (LSM).
The electrolyte layer comprises a dense layer substantially preventing molecular transport, therethrough. Exemplary materials for the electrolyte layer include zirconium-based materials and cerium-based materials such as yttria-stabilized zirconia and gadolinium doped ceria, and can further include various other dopants and modifiers to affect ion conducting properties.
Each of the fuel cell tubes 32 further include a fuel feed tube (not shown) and a fuel reforming reactor (not shown) disposed therein. The fuel reforming reactors are disposed within fuel feed tubes and the fuel feed tubes are disposed within each of the fuel cell tubes 32 and within the sensing cell, such that each fuel reforming reactor is positioned upstream from (as defined by flow of fuel gas) and proximate to active portions 38 of the fuel cell tubes 32 and of the sensing cell 34. The fuel reforming reactor reforms hydrocarbon fuel to hydrogen by catalyzing a partial oxidizing reaction between the hydrocarbon and oxygen. In an exemplary embodiment, the fuel reforming reactor comprises a supported catalyst. The supported catalysts includes very fine scale catalyst particles supported on a substrate. The catalyst can comprise, for example, particles of a suitable metal such as platinum or other noble metals such as palladium, rhodium, iridium, osmium, or their alloys and the substrate can comprise oxides (such as aluminum oxide), carbides, and nitrides.
Referring to
The control system 20 comprises a microprocessor configured to execute a set of control algorithms comprising resident program instructions and calibrations stored in storage mediums to provide the respective control functions. The control system 20 can monitor input signals from sensors disposed throughout the fuel cell systems 10, 10′ some of which are described in detail herein below and can execute algorithms in response to the monitored input signals to execute routines to control power flows and component operations of the fuel cell systems 10, 10′.
The control system 20 detects a current level (‘CURRENT_FUELCELL_MEASURED’) and a voltage level (‘VOLT_FUELLCELL_MEASURED’), and an open circuit voltage level (OCV_MEASURED) from the fuel cell stack 30. In an exemplary embodiment, a current level from the sensing cell 34 is measured to provide the open circuit voltage level. In an alternate embodiment open circuit voltages can be provided by fuel cells of the fuel cell stack during operating conditions when power is not being drawn from the fuel cell stack 30 by the power board 22.
The power board 22 provides voltage conversion between the fuel cell stack 30 voltage and the primary system voltage and the level of current the power board draws from the fuel cell stack 30 can be adjusted by commands (CURRENTDRAW_POWERBOARD) from the control system 20. Further, the control system 20 monitors a temperature (‘TEMPERATURE_POWERBOARD’) from temperature sensor (not shown) of power board 22.
The power bus 24 comprises an electrically conductive network configured to route power from the energy conversion devices (the rechargeable battery 28 and the fuel cell stack 30) to the face plate 32. The face plate 82 comprises a plurality of power ports for connecting external devices to the fuel cell systems 10, 10′.
The exemplary rechargeable battery 28 is a rechargeable battery configured to receive power from the power bus 24 and to discharge power to the power bus 24. The rechargeable battery 28 can comprise any of several rechargeable battery technologies including, for example, nickel-cadmium, nickel-metal hydride, lithium-ion, and lithium-sulfur technologies. In alternative embodiments, other reversibly energy storage technologies such as ultra-capacitors can be utilized in addition to or instead of the rechargeable battery 28. Further, in alternate embodiments, multiple energy storage devices can be utilized within fuel cell systems 10, 10′. The control system 20 receives information from internal sensors within the battery 28 monitoring battery state of charge (‘BATTERY_SOC’) and temperatures (‘TEMPERATURE_BATTERY’) at varied locations of the battery 28.
The fuel tank 49 contains a fuel for use by the fuel cell stack 30. Exemplary fuels include a wide range of hydrocarbon fuels. In an exemplary embodiment, the fuel comprises an alkane fuel and specifically, propane fuel. In alternative embodiments, the fuel can comprise one or more other types of alkane fuel, for example, methane, ethane, propane, butane, pentane, hexane, heptane, octane, and the like, and can include non-linear alkane isomers. Further, other types of hydrocarbon fuel, such as partially and fully saturated hydrocarbons, and oxygenated hydrocarbons, such as alcohols and glycols, can be utilized as fuel that can be converted to electrical energy by the fuel cell stack 30. The fuel also can include mixtures comprising combinations of various component fuel molecules examples of which include gasoline blends, liquefied natural gas, JP-8 fuel and diesel fuel.
Other signals monitored by the control system 20 include fuel flow rate (‘FLOWRATE_FUEL’) from the fuel flow rate sensor 54 (fuel cell system 10), an anode air flow rate (‘FLOWRATE_ANODEAIR’) from anode air flow rate sensor 52 (fuel cell system 10), a reactor temperature (‘TEMPERATURE_REACTOR’) from a temperature sensor 50 proximate fuel reforming reactors of the fuel cell stack 30, and an interconnect temperature (‘TEMPERATURE_INTERCONNECT’) from a temperature sensor 51 disposed proximate interconnect members of the fuel cell stack 30. The control system 20 is configured to provide signals to send commands to component actuators of the fuel cell stack 30. The signals include a fuel valve position (‘POSITION_FUELVALVE’), an anode air blower power level (‘POWER_ANODEBLOWER’), a coil power level (‘POWER_COIL’), and a cathode air blower power level (‘POWER_CATHODEBLOWER’).
The cathode air blower 46 moves ambient air through the recuperator 45 and into the fuel cell stack 30 and an exhaust fan (not shown) pulls exhaust gases (‘EXHAUST’) away from the fuel cell stack 30. The fuel valve 44 controls fuel flow from the fuel tank 49 into the fuel cell stack 30 and the anode air blower 43 moves ambient air into the fuel cell stack 30, wherein the ambient air and fuel are combined and reacted within the fuel reforming reactors. The coil 48 comprises a resistant heating coil 48 that can heat fuel and air that pass through the fuel cell stack 30 to combust the air and fuel.
Referring to
At base control start step 101, the control system 20 initializes the control scheme 100. The control system 20 receives reactor temperature measurements (102) from the temperature sensor 50 (TEMPERATURE_REACTOR) and utilizes the reactor temperature measurements to calculate a desired open circuit voltage range (104) between a minimum desired open circuit voltage (‘OCV_MIN’) and a maximum desired open circuit voltage (‘OCV_MAX’) correlating to a desired fuel-to-air ratio lower limit and a desired fuel-to-air ratio upper limit, respectively. Further, the open circuit voltage level measured from the fuel cell 30 (106) is compared to the minimum desired open circuit voltage level (‘OCV_MIN’) (step 108). If the open circuit voltage is greater than the minimum desired open circuit voltage, the control system 20 proceeds to step 112. If the open circuit voltage is not greater than the minimum desired open circuit voltage, the control system proceeds to step 110.
At step 110, the control system 20 increases the target fuel flow rate by commanding the fuel valve 44 to increase fuel flow rate therethrough, and control system 20 subsequently returns to the base control start 101.
At step 112, the control system 20 determines whether the open circuit voltage is less than the maximum desired open circuit voltage. If the open circuit voltage is less than the maximum desired open circuit voltage, the control system 20 proceeds to the current draw control scheme 130. If the measure open circuit voltage is not less than the maximum desired open circuit voltage, the control system proceeds to step 114.
The power draw control scheme 140 (
At step 134, the control system 20 determines a minimum voltage based on the electric current level of the fuel cell stack 30. At step 136, the control system 20 determines whether the voltage level of the fuel cell stack 30 is greater than the minimum voltage. If the voltage level of the fuel cell stack 30 is greater than the minimum voltage, the control system 20 proceeds to step 138, and the electric current level of the fuel cell stack 30 and then returns to base start 101. If the measured voltage is not greater than the minimum voltage, the control system 20 proceeds to step 140.
At step 140, the control system 20 determines whether the fuel flow rate based on the fuel valve is less than a maximum fuel flow rate (‘FUEL_VALVE_MAX’). If the fuel flow rate is less than a maximum fuel flow rate, the control system 20 will step up the air flow rate 142 and subsequently return to base start 101. If the control system 20 determines the fuel flow rate is not less than the maximum fuel flow rate, the control system 20 will set the desired current level to the current level of the fuel cell stack 30 and the control system 20 returns to the base start 101.
It is to be noted that although fuel flow rate is checked by the control system 20 at step 140, air flow rate is modified by the control system 20 at step 142, wherein fuel flow rate can thereby be modified in the next control loop after the control system 20 returns to base start 101.
At step 114, the control system 20 determines fuel flow rate is at an initial fuel value by determining whether the fuel valve position is equal to an initial valve position value (‘FUEL_VALVE_INITIAL’). If the fuel flow rate is at the initial fuel flow rate value, the control system 20 proceeds to step 116. If the fuel flow rate is not at the initial fuel flow rate value, the control system proceeds to step 118. At step, 116, the control system reinitializes the fuel flow rate and an anode air flow rate and then returns to initialization step 101. The initial fuel flow rate and the initial anode air flow rate provide fuel and air flow rates that are below the desired fuel-to-air ratio range, but provide a fuel-to-air ratio that contributes to stable operation of the fuel cell stack 30, wherein the fuel and air can be tuned from the initial fuel flow rate and initial air flow rate, respectively, to provide a desired fuel-to-air ratio.
At step 118, the control system 20 generates a signal indicating a system fault and enters a system shutdown mode (120).
Referring to
The portion 186 of graph 170 in
Referring to
The exemplary embodiments shown in the figures and described above illustrate, but do not limit, the claimed invention. It should be understood that there is no intention to limit the invention to the specific form disclosed; rather, the invention is to cover all modifications, alternative constructions, and equivalents falling within the spirit and scope of the invention as defined in the claims. Therefore, the foregoing description should not be construed to limit the scope of the invention.
This application claims priority to Provisional Application 61/181,781 filed on May 28, 2009 the entire contents of which are hereby incorporated by reference, herein.
Number | Date | Country | |
---|---|---|---|
61181781 | May 2009 | US |