Claims
- 1. A method for hetero-epitaxial growth of crystalline silicon carbide or crystalline diamond film on a substrate comprising a substrate material, said method comprising the steps of:
- a) providing sources for generating a flux of said substrate material and carbon in a reaction chamber evacuated to a predetermined pressure;
- b) depositing under hetero-epitaxial growth conditions a compositionally-graded intermediate layer including said substrate material and carbon on said substrate, wherein the composition of a lower surface of said compositionally-graded intermediate layer in contact with said substrate is substantially that of the substrate material and the composition of an upper surface thereof is substantially that of said crystalline silicon carbide or crystalline diamond film and wherein the carbon content increases in a direction away from said substrate, said hetero-epitaxial growth conditions allowing said substrate material and carbon to migrate; and
- c) depositing said crystalline silicon carbide or crystalline diamond film on said compositionally-graded intermediate layer.
- 2. The method of claim 1 wherein said substrate material is silicon.
- 3. The method of claim 1 wherein carbon and said substrate material at a top surface of said compositionally-graded intermediate layer are in a ratio in the range of 0.9 to 1.1.
- 4. The method of claim 1 wherein said compositionally-graded intermediate layer is deposited by:
- a) providing an evaporation source of said substrate material; and
- b) independently controlling the relative fluxes of said substrate material and carbon to co-deposit said compositionally-graded intermediate layer.
- 5. The method of claim 1 wherein said source of carbon is a predissociated hydrocarbon gas.
- 6. The method of claim 4 wherein said source of carbon is a carbon particle flux.
- 7. The method of claim 6 wherein said carbon particle flux is ionized.
- 8. The method of claim 4 wherein said substrate material is silicon.
- 9. The method of claim 8 wherein said source of carbon is a predissociated hydrocarbon gas.
- 10. The method of claim 8 wherein said source of carbon is a carbon particle flux.
- 11. The method of claim 10 wherein said carbon particle flux is ionized.
- 12. The method of claim 1 wherein said compositionally-graded intermediate layer is deposited by:
- a) providing a first source for evaporating the substrate material;
- b) providing an ion source for producing a flux of carbon including ionic carbon; and
- c) independently co-depositing said substrate material and carbon onto said substrate by independently controlling the relative fluxes of said substrate material and carbon to form said compositionally-graded intermediate layer.
- 13. The method of claim 12 wherein said silicon carbide or crystalline diamond film is formed by utilizing said ion source for depositing at least ionized carbon species.
Priority Claims (1)
Number |
Date |
Country |
Kind |
2-173463 |
Jun 1990 |
JPX |
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Parent Case Info
This is a continuation of application Ser. No. 07/724,383 filed on Jun. 28, 1991, now abandoned.
US Referenced Citations (10)
Foreign Referenced Citations (1)
Number |
Date |
Country |
63-224225 |
Sep 1988 |
JPX |
Continuations (1)
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Number |
Date |
Country |
Parent |
724383 |
Jun 1991 |
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