This invention relates generally to the field of treating tailings especially wet tailings of the sort that might contain some clay particles, some water and some other contaminants such as hydrocarbons, heavy metals or the like. Most particularly this invention relates to treating persistent tailings that are accumulated as waste by-products from mining or other industrial processes. An example of a process which creates such tailings is for example, the extraction of hydrocarbons from oil sands with hot water such as is used in the Clarke process.
Oil or tar sands are a source of hydrocarbons, which is commonly called bitumen, which can be recovered, and then reformed into a synthetic crude or Syncrude™. At present some of such hydrocarbons are recovered through a process known as surface mining. To obtain Syncrude™, the hydrocarbons must be first separated from the natural base or matrix in which it is found. This matrix includes sands, clays, silts, minerals and other materials, such as heavy metals. Typically the matrix is lifted by large shovels into dump trucks and trucked to a separation facility. The most common separation step used on surface mined oil sands is the hot water separation process which uses hot water to separate out the hydrocarbons from the sand and clay matrix. However, the separation is not perfect and a liquid waste is produced as a by-product which may include small amounts of hydrocarbons, heavy metals and other waste materials, but is mostly a stable colloidal mixture of water and clay, sand and other materials. One form of this waste liquid is called Mature Fine Tailings (MFT) and is collected in onsite reservoirs called tailings ponds. Unfortunately, MFT is a very persistent material that is not easy to treat or to dry out.
Oil extraction has been carried out for many years on the vast reserves of oil that exists in Alberta, Canada. It is estimated that 750,000,000 m3 of MFT have been produced. Some estimates show that 550 km2 of land has been disturbed by surface mining, yet only 267 ha (less than 0.5%) has received certification as being reclaimed. Even this small area was not mined, nor used for associated processing operations, but was only used for the storage of overburden.
The MFT ponds present three environmental and economic issues: water and pollution management, sterilization of potentially productive ore located below the ponds and delays in reclamation of the water in the tailings itself. Although concentrations vary, MFT can typically comprise 50 to 70% water. This high water content forms, in combination with the naturally occurring clays, a thixotropic liquid. This liquid is quite stable and persistent and has been historically collected in large holding ponds. Very little has been done to treat the MFT that has been created and so it continues to build up in ever larger holding ponds. As development of the oil sands accelerates and more and more production is brought on line, more and more MFT will be produced.
What is desired is a way to deal with the MFT that has been and will be generated, to permit land reclamation, a way to release captured water in an environmentally responsible way and to provide access to the productive ore located beneath such ponds. Further the presence of ever larger amounts of wastes to contain presents storage problems and concerns about leaching and the like of the liquids from existing storage facilities either into the ground water or into surface runoff such as streams and the like. What is desired is a way to stabilize the MFT to remove the water and to increase its load bearing capacity so it can be buried and the land reclaimed and remediated above it. Recently the AER (Alberta Energy Regulator) has indicated that there will be deadlines imposed to resolve the tailings issue.
MFT represent a mixture of days (illite, montmorillonite and kaolinite), water and residual bitumen resulting from the processing of oil sands. In some cases MFT may also be undergoing intrinsic biodegradation. The biodegradation process may create a frothy mixture, further compounding the difficulty in consolidating this material. These days, most particularly, sodium montmorillonite found in MFT are expansive; i.e., volumetric changes of as much as 30% can occur between wetting and drying. It is estimated that between 40 and 200 years are required for these days to sufficiently consolidate to allow for reclamation of tailings ponds, if left to their own devices. Such delays will result in unacceptably large volumes of MFT, and protracted periods of time before reclamation can take place unless a way to effect disposal and reclamation is found.
It is known that the application of an electrical field to a dielectric material results in certain electro-kinetic phenomena, including electro-osmosis, the movement of water from an anode to a cathode; electrophoresis, the movement of ions in the water to oppositely charged electrodes and electrostriction, a result of the application of an electrical field that results in mechanical work which deforms the dielectric material. Electro-osmosis has been used to dewater solid or consolidated day soils for construction projects to improve load bearing capacity. Electrophoresis has been used in many industries, such as the pharmaceutical industry and ceramics industry to produce high grade separations. Electrostriction has been used on a small scale to create high density ceramics. In an electrical resistance heating treatment at Fargo, N. Dak. (Smith et al., 2006)a, where the applied electric field ranged between 0.46 to 0.8 volt/cm, an electro osmotic phenomenon was observed with AC current. Examples of applications of electrical fields in various circumstances can be found in the following prior patents. aSmith, G. J., J. von Hatten, and C. Thomas (2006) Monitoring Soil Consolidation during Electrical Resistivity Heating. Proceedings of the Fifth International Conference on Remediation of Chlorinated and Recalcitrant Compounds. May 22-25, 2006, Monterey, Calif.,
The application of electrical current to treat oil sands tailings has also been tried, as shown in U.S. Pat. No. 4,501,648. However, this teaches a small device with a tracked moving immersed electrode onto which is deposited clay solids. The electrode is moved out of contact with the liquid and then the solids are scraped off the electrode. A chemical pre-treatment step is required to achieve the desired deposition rate on the immersed electrode. While interesting, this invention is too small scale and expensive to be practical for MFT treatment and requires a chemical pre-treatment step which adds to the cost. What is desired is a better way to deal with vast volumes of MFT that now exist and will continue to be created by ongoing operations.
Our own prior patent Canadian Patent No. 2,736,675 teaches using an electro treating process to encourage the water to separate from the clay and to therefore speed up the reclamation process. However what is required is an apparatus and a process whereby the electrical field can be applied in an efficient and sensible manner to economically treat the liquid wastes such as MFT to recover and reuse the trapped water, to free up storage capacity and generally mitigate harmful environmental effects.
The present invention provides a configuration of electrodes and a staged treatment plan whereby the MFT may be treated in an economical and efficient way. In particular the present invention teaches that rather than using electrodes spread out to form a regularly spaced treatment grid to evenly treat large areas or volumes of tailings as in the prior art, the electrodes may be placed in the MFT to be treated generally towards the edges of a predetermined three dimensional space or volume to create an electrical field to generate a geotechnical structure within the volume having one or more of a desired width, length, thickness, position, porosity and strength. In one embodiment the geotechnical structure can be made by positioning the electrodes to create an electrical field in which the current is generally parallel to the direction of gravitation forces. Provided the current is passed between the electrodes in the correct direction the use of horizontal electrodes may encourage the electromotive forces to be acting on the solid particles in the same direction as gravity to enhance the consolidation of the solids into the geotechnical structure. In another embodiment the electromotive forces may be acting in a direction opposite to gravity to create a geotechnical structure in the form of, for example, a consolidated skin or top layer on a tailings pond. In another embodiment the electromotive forces might be generally orthogonal to the direction of gravity to create a geotechnical structure in the nature of a side wall for a containment structure to reinforce a side slope of a containment pond. In any case, the use of disposable electrodes may allow the electrodes to be abandoned, in the consolidated solids which form the geotechnical structure, and to thereby avoid the cost of recovering and reclaiming the electrodes. As well the abandoned electrodes may add structural integrity as a form of reinforcing of the geotechnical structure created by the consolidated solids. In another embodiment the present invention may allow consolidation to create geotechnical structures consisting of a number of layers, with one layer building upon the next with the simple expedient of placing a further electrode spaced from the old electrode pair which then becomes part of a new electrode pair to generate a new consolidating layer. In some cases these layers may be consolidated sufficiently to be impervious, for example to act as a tailings pond lining. In other cases the layers may be required to have a specific bearing strength to allow for further non electro treating consolidation.
Thus the present invention comprehends that various geotechnical structures may be formed including bottom layers, top layers and side wall structures according to the present invention.
According to a preferred aspect of the invention therefore there may be provided a method of electro treating tailings to cause a separation of at least some water from said tailings and a consolidation and compaction of at least some solid particles, said method comprising:
According to another aspect the present invention provides a method of electro treating oil sands tailings to cause a separation of at least some water from said tailings and a consolidation and compaction of the remaining solid material, said method comprising:
Reference will now be made by way of example only to preferred embodiments of the invention by reference to the following drawings in which:
In this description the term geotechnical structure means a structure made in situ from fines or clay solids or other dewatered solids extracted from a tailings pond. In this sense a structure is a deposit of solids which is organized according to a containment or treatment plan and may comprise generally horizontal, inclined or vertical structures. In particular such a geotechnical structure may preferably have been consolidated by an electro treat, such as by means of an AC current with a DC offset as described in one or more of our prior patents including Canadian Patent No. 2,736,675, Canadian Patent Application No. 2,758,872 published on Oct. 7, 2012 and Canadian Patent Application No. 2,782,949 published on Jan. 9, 2014. Although other types of consolidating forces can be used to create consolidated soils from tailings it is believed that the AC current with a DC off set is able to provide good results at a reasonable cost. As well, the use of such an electro treat allows for the creation of a geotechnical structure around the electrode, which in turn means that the electrodes may be placed in a position to create a geotechnical structure of a predetermined size, shape and location, and may be developed to a desired strength based on the treatment time and the strength of the electrical field. The present invention comprehends that the treatment time and intensity can be set for a specific strength and function desired from the design purpose of the geotechnical structure as explained in more detail below.
Also shown in
In terms of field intensity the intensity of the AC treatment can be applied in a range of 0.5 V/cm to 1.5 V/cm and most preferable is in a range of 0.75 V/cm to 1.25 V/cm. AC treatment is preferable at a low frequency (10 Hz or lower). The DC offset can also be applied in a range amount of 0.25 V/cm to 0.75 V/cm. The present invention comprehends a range of treatment intensities the specifics of which will depend upon the properties of the tailings to be treated, including the water content and the nature of the solids within the tailings. As well the treatment duration can be varied to allow a geotechnical structure of a specific size and strength to be created.
According to one aspect of the present invention if the horizontal electrodes are lined up one above the other then they will create an electric field between them that is essentially parallel to the gravitation field.
The denser layer 44 at the bottom of the containment structure 20 may be one form of a geotechnical structure formed according to the present invention. For example, depending upon the treatment time the solid dewatered layer 44 may be consolidated to a degree whereby the dewatered layer is essentially impervious to water seepage.
The present invention comprehends that the expressed water 52 may be removed from the containment structure 20 and treated to make it suitable for re-use or for disposal into the environment. Assuming that no fresh waste has been added the tailings pond level may have subsided due to the removal of water and the consolidation of solids as shown as level 45 which is lower than level 21. The present invention may be used to free the water from the tailings mixture and enable the water to be removed and treated and reused or disposed of. Once the water is expressed from the thixotropic material it can be processed in conventional water purification processes and ideally recycled back into the main hot water extraction process again. It will be appreciated that the present invention comprehends repeating the steps outlined in
In another embodiment of the present invention the horizontal electrodes are used to create an electrical field which directs the solids in a direction other than in the direction of gravity. In this case the present invention comprehends that a geotechnical structure may be formed by a local consolidation of the solids adjacent to the anodes. As such the present invention comprehends positioning the anodes in a location where the geotechnical structure is to be positioned.
By way of example,
In this arrangement the solids may be encouraged by the electro-treating process to consolidate around the anode part of the frame and as a result may provide a geotechnical structure in any desired location within the tailings pond. In one embodiment a layer at a top of the tailings pond may be created. This is because the frame electrode can be supported in place for example towards a top of the tailings fluid. It may be supported by floats, or other anchoring elements secured to the shore or with supports from the bottom of the pond as the case may be. In some cases the solids collecting around the vertical anode may act as structural elements, in the nature of columns. However this is dependent on the intensity and duration of treatment provided and is not considered an essential element.
In this aspect of the invention by positioning the frame element at or near the top of the pond, a geotechnical structure in the form of a surface load bearing layer may be formed which layer may facilitate further consolidation of the tailings below through more conventional means. Preferably the top layer is consolidated enough to be impervious to the tailings and load bearing.
In the frame electrode arrangements as shown in
In a further embodiment of the present invention the electrodes can be positioned to establish a geotechnical structure where it is most desired. For example, in certain situations the containment pond may have side walls which are simple earth berms or earth dikes. In cases where too much water is placed within the berms or dikes, or where there has been erosion of the like of the dike wall this in turn can threaten to spill the contents of the containment structure into the surrounding land. In some cases there may be erosion from the inside as the watery tailings act on the inside wall of the earth dike or berm. In such cases the only strategy may be to try to add wall thickness to the outside of the dike, but this may also be constrained by the presence of geological features such as river banks, streams or the like. Often the tailings ponds are an accumulation of materials which are harmful to the environment and thus are not to be released into the surrounding lands and waterways under any circumstances, let alone in a catastrophic wave as a result of the dike failure. What is desired is a way to rebuild the inside wall of the dike structure.
According to the present invention the method of creating a geotechnical structure in a preferred location can be used to shore up or thicken walls of confinement structures such as dike walls by the application of the electro-treat to the tailings itself. For example, as shown in
Various modifications and alterations are possible within the broad scope of the invention, some of which have been discussed above and other which will be apparent to those skilled in the art, for example the configuration of the frame electrode may vary and the amount and duration of the electro treat can also vary depending upon the end properties of the geotechnical structure that is desired. What is considered important is the realization that the electro treating of tailings can do more than dewater the tailings; it can be used to create desirable geotechnical structures where no such structures could previously be positioned. The techniques of the invention described above can also be combined, for example, a top layer can be formed and the side walls reinforced or a bottom layer made to prevent the top loading from expressing water through the sides and bottom of the pond, where that would be a risk based on the characteristics of the containment structure.
Number | Date | Country | Kind |
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2865400 | Sep 2014 | CA | national |
Filing Document | Filing Date | Country | Kind |
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PCT/CA2015/000505 | 9/25/2015 | WO | 00 |