The present invention relates to a method for fabricating a light emitter. It also relates to the emitter obtained by such a method.
The field of the invention is more particularly but non-limitatively that of miniaturized light emitters such as a “multi-chip” emitter with micrometric light-emitting diodes, for applications such as optical spectroscopy or multispectral lighting.
The concept of a light emitter such as a “multi-chip” LED has existed since the 2000s but is utilized exclusively by the lighting industry.
The challenges facing the lighting industry involve colorimetry and photometry: their aim is to obtain maximum flux, often expressed as lumen, and to optimize the colorimetric rendering in order to obtain white light of the best possible quality, based on the Colorimetric Rendering Index.
The lighting market requires a maximum flux given in lumen. Thus the “multi-chip” emitters existing on the market maximize the density of sources (or “chips”, typically micro LEDs) in the lamp in order to have greater light intensity, and specific collector optics are designed. This is the case in particular of patent US 20120068198 filed by Cree in 2011. The key points of this patent concern the design of the positioning of the sources in order to maximize the density of sources. The design is created so as to optimize the performance and obtain good colorimetric rendering.
In lighting, high-power sources are usually used, thus there are numerous heat problems to be resolved. The design of the supports or the methods is often based on optimization of the heat dissipation. Patent US 20110198628 shows each source directly bonded to the metal base for optimum heat dissipation, the design being created so as to optimize the internal reflections and thus the final flux by using a carefully designed PCB (Printed Circuit Board). Minimization of the distance between the sources in order to have better cover among the sources is also mentioned.
Maximization of the density of sources on the surface of a “multi-chip” emitter is thus an essential feature for a person skilled in the art for these different examples of “multi-chip” emitters.
The purpose of the invention is to propose a method for fabricating a light emitter that is capable of appealing to markets other than that of lighting, in particular scientific markets such as for absorption spectroscopy or fluorescence spectroscopy, lighting for microscopy or for endoscopy, or also communication via visible light (LiFi).
This objective is achieved with a method for fabricating a light emitter comprising several separate light sources and a support common to all the sources, each source being arranged in order to emit a light beam at a wavelength called working wavelength, characterized in that it comprises:
Each source can be fixed onto the support at its previously determined position so that the sources are distributed along the fixing direction in order of increasing working wavelength. For the fixing step, each source can be fixed onto the support along the fixing direction at its previously determined position, so that all the sources considered as a whole are distributed along the fixing direction in order of increasing working wavelength.
The fixing can comprise fixing sources on at least two parallel fixing axes extending along the fixing direction. Among all the sources, two sources having adjacent positions along the fixing direction are preferably not fixed on the same fixing axis. In the case of several fixing axes:
The optical assembly can comprise an optical system having a lateral chromatic aberration, the positions of the sources corresponding to an off-axis use of the optical system. Alternatively, the optical assembly can comprise a diffraction grating.
Fixing each source can comprise holding the source with a suction tip, and placing the source on the support by means of the suction tip. The support can be covered with glue before placing each source, and each source can be placed on the glue.
The emitter can comprise an electronic controller of the sources, arranged in order to control each source independently of the other sources.
The method according to the invention can comprise, after fixing, associating the emitter with the multiplexer at its placement considered during the determination of the positions of the sources.
Each source is preferably quasi-monochromatic.
Each source can comprise (preferably can consist of) a light-emitting diode.
The support can be integral with an electronic chip equipped with connecting pins arranged in order to fix the chip onto an electronic circuit board.
The optical assembly can comprise a lens and/or a prism and/or a diffraction grating.
According to yet another aspect of the invention, an emitter is proposed obtained by a fabricating method according to the invention, or an emitter plus multiplexer assembly obtained by a fabricating method according to the invention.
A light emitter according to the invention is therefore proposed (preferably an assembly of this emitter plus a multiplexer comprising an optical assembly having chromatic dispersion properties), said emitter comprising several separate light sources and a support common to all the sources, each source being arranged in order to emit a light beam at a wavelength called a working wavelength, each source having a position on the support along a fixing direction (defined as a function of optical properties of the spectral multiplexer, of the working wavelength of this source and of a placement of the emitter with respect to the multiplexer in the case of the emitter+multiplexer assembly, so that the optical assembly is arranged in order to bring the light beams of the sources spatially closer together by means of its chromatic dispersion properties and so that the multiplexer spatially superimposes said light beams).
The sources are preferably distributed along the fixing direction in order of increasing working wavelength. All the sources taken as a whole are preferably distributed along the fixing direction in order of increasing working wavelength.
The sources can be distributed on at least two parallel fixing axes extending along the fixing direction. Among all the sources, two sources having adjacent positions along the fixing direction are preferably not fixed on the same fixing axis. In the case of several fixing axes:
The emitter can comprise an electronic controller of the sources, arranged in order to control each source independently of the other sources.
Each source is preferably quasi-monochromatic.
Each source can comprise (preferably can consist of) a light-emitting diode.
The support can be firmly fixed to an electronic chip equipped with connecting pins arranged in order to fix the chip onto an electronic circuit board.
In the case of the emitter+multiplexer assembly:
Other advantages and characteristics of the invention will become apparent on reading the detailed description of embodiments which are in no way limitative, and from the following attached diagrams:
As these embodiments are in no way limitative, variants of the invention can be considered in particular comprising only a selection of the characteristics described hereinafter, in isolation from the other characteristics described (even if this selection is isolated within a phrase containing these other characteristics), if this selection of characteristics is sufficient to confer a technical advantage or to differentiate the invention with respect to the state of the art. This selection comprises at least one, preferably functional, characteristic without structural details, or with only a part of the structural details if this part alone is sufficient to confer a technical advantage or to differentiate the invention with respect to the state of the prior art.
An emitter 1 according to the invention such as described hereinafter comprises N different light sources, N being a natural number greater than or equal to 2 (preferably greater than or equal to 3, preferably greater than or equal to 10).
Each light source Si (with i an integer, i=1 to N) is arranged in order to emit a light beam comprising one or more wavelengths including a wavelength λi called working wavelength.
Each light source emits its working wavelength in the visible spectrum (between 340 nm and 800 nm).
There will be described firstly, with reference to
Reference will be made to the light intensity Ii(λ), respectively Ii+1(λ), of two quasi-monochromatic light sources at the wavelengths λi, respectively λi+1. Each spectrum Ii(λ), respectively Ii+1(λ), has the form of a bell-shaped curve (for example gaussian) having a peak at the wavelength called the working wavelength λi, respectively λi+1. This peak has a relatively small full width at half maximum with respect to the working wavelength.
Thus, a first light source Si has a bell-shaped emission spectrum with:
Similarly, a second light source Si+1 has a bell-shaped emission spectrum with:
It can therefore be considered that the light sources Si and Si+1 are quasi-monochromatic, because:
Each source has a working wavelength different from the working wavelength of the other sources.
Each source Si emits its working wavelength λi, at a light intensity Ii(λi) at least ten times (preferably 100 times) greater with respect to the other sources, i.e.: Ii(λi)≧10 Ik(λi) with i an integer i=1 to N; and with k an integer k=1 to N but k≠i (preferably Ii(λi)≧100 Ik(λi)).
Preferably, the working wavelength of each source is not emitted by the other sources.
Provision can also be made for the use of other polychromatic sources having other shapes of spectrum. According to the invention, as a function of the position of the light source, only a portion of its spectrum centred on a wavelength called a working or emission wavelength will be utilized. A polychromatic source can thus be used, provided that its spectrum has a high intensity at this working wavelength.
Each light source comprises (preferably consists of) a light-emitting diode (LED). The use of light-emitting diodes makes it possible to reduce the risk of failure, as LEDs are light sources that have a longer service life than the light sources usually used in devices such as a spectrometer, like incandescent or discharge sources. Moreover, LEDs have the advantage of being small and low cost.
Each source comprises or is a light-emitting diode of encapsulated type. This means that each individual source comprises in this case at least one light-emitting diode or “LED chip” that emits light and is placed in a housing making it possible on the one hand, to dissipate the heat given off by each chip when it emits (thus ensuring a constant temperature for example using a Pelletier module as is conventionally done), and, on the other hand, to supply electrical power (in particular electric current) to each chip for its operation. The housing is thus generally constituted by a heat-resistant and electrically insulating material such as for example an epoxide polymer such as epoxy resin, or a ceramic.
Thus, each source is designed to operate at a given temperature and at a given electrical current.
Determining each position according to the invention is carried out within this hypothesis of given temperature and of given electrical current, which thus corresponds to the point of optimal operation. However, it will be noted that variations of 1 or 2 nanometers of wavelength are in any case not serious for an LED comprising a spectrum having a full width at half maximum of around ten nanometers, in particular when an optical assembly 6 is used comprising a prism 51 (second embodiment described hereinafter) or an optical system 25 used off-axis and having a lateral chromatic aberration (first embodiment described hereinafter) that does not select a reduced portion of this spectrum but transmits the entire spectrum of each light beam emitted by each source and passing through this optical assembly 6.
The housing generally comprises two metal pins that are connected to the support 2 respectively at an anode and at a cathode. It is possible to have:
Each source (“LED chip”) has a planar, light-emitting surface (preferably lambertian) extending parallel to a plane (and is arranged in order to emit its beam preferably in a mean direction perpendicular to this plane), so that the thickness of this source is defined perpendicularly to this plane and the diameter of this source is defined as the minimum diameter of a circle contained within this plane and able to surround this source. The diameter of each source is preferably less than 1 millimetre, more preferentially less than 300 micrometres.
By “position” Xi of a source Si, is meant, quite naturally for a person skilled in the art, the position of a fixed reference point for all the sources. This is preferably the position of the centre (or barycentre) of the part (or of the surface viewed from above) that generates light for each source or of the position of the upper left corner of each source, etc. This position is defined with respect to an origin X=0, arbitrarily defined. Sources will be discussed hereinafter that are in the shape of a rectangle, rhombus or square, and the position of each source will be considered to be the position of the centre of the rectangle, rhombus or square formed by each source.
Similarly, when different sources are considered that are aligned, fixed, distributed, etc. on different axes (13, 14, 15, and/or 40), reference is made to the alignment, fixing, distribution, etc. of this fixed reference point (centre, barycentre, corner, angle, etc.) of each source on these different axes (13, 14, 15, and/or 40).
A description will be given hereinafter of two embodiments of the method according to the invention for fabricating a light emitter 1 according to the invention, this light emitter 1 comprising the different, separate light sources Si (i an integer, i=1 to N) previously described and a planar support 2 common to all the sources. A first embodiment will be a fabricating method comprising measurements of the positions of the sources. A second embodiment will be a fabricating method comprising calculations of the positions of the sources. In these two embodiments, the fabricating method according to the invention comprises:
The determination step is implemented by technical means (measurement means, typically a detector and an optional filter, or calculation means).
The emitter 1 thus obtained is arranged so that, once associated with the multiplexer 4, the multiplexer 4 implements spectral multiplexing of the beams emitted by the sources S1 to SN. By “spectral multiplexing” is meant the spatial combination of several light beams, each contributing to the final spectral composition of a light beam 26 having parallel rays, called a “collimated” light beam 26. The multiplexed light beam 26 is thus a polychromatic light beam, since it comprises several mixed wavelengths λ1 to λN.
The term “chromatic dispersion” according to the invention includes the chromatic aberrations.
A chromatic aberration of an optical assembly 6 (comprising or consisting of for example an optical system 25 or a prism 51 such as described hereinafter) is a variation of the position of the focal point of an incident light beam collimated on this optical assembly 6 then passing through this optical assembly 6, as a function of the wavelength of this light beam.
A lateral chromatic aberration of an optical assembly 6 (comprising or consisting of for example an optical system 25 such as described hereinafter) is a variation of the lateral position (i.e. perpendicularly to the optical axis A1 of the optical system 25) of the focal point of an incident light beam collimated on this optical assembly 6 then passing through this optical assembly 6, as a function of the wavelength of this light beam.
The propagation of a light beam emitted by each light source S1 to SN takes place in free space from said source to the optical assembly 6. “Free space” denotes any spatial medium of the signal pathway: air, inter-sidereal space, vacuum, etc, as opposed to a material transport medium, such as optical fibre or wired or coaxial transmission lines. Thus there is no coupling between the light beam emitted by a light source and a waveguide. There is no coupling known as “fibre-to-LED” such as may exist in the prior art. According to the invention, energy loss is thus minimal. The light beams are effectively mixed, and the intensity of the superimposed beam 26 is high. Moreover, this feature offers greater freedom of positioning of the light sources S1 to SN which reduces the cost of production according to the invention and enables mass production. Indeed, a coupling action between an optical fibre and a source for each of the sources is not required.
There will now be described, with reference to
In the first embodiment of emitter 1 according to the invention, the optical assembly 6 comprises at least one optical system 25 used off-axis and having a lateral chromatic aberration. This lateral chromatic aberration forms the chromatic dispersion property according to the invention.
The off-axis use accentuates, or even causes the appearance of, lateral spatial dispersion of the wavelengths. This can also be referred to as chromaticism of apparent magnitude.
The cost of such an optical system 25 is generally low because, intrinsically, any optical system used off-axis has lateral chromatic aberration, if it is not specifically corrected for this aberration by means of solutions known in optical design.
The light sources S1 to SN can be placed respectively at the foci of the optical system 25 corresponding to the wavelengths λ1 to λN, so that their light beams are multiplexed at the output of the optical system 25.
The optical system 25 is said to be “used off-axis”, i.e. off its optical axis A1. In other words, an incident light beam, convergent at the object focus of the optical system, does not leave this optical system parallel to the optical axis A1 of said system. Thus, the foci of the optical system 25 corresponding to different wavelengths λ1 to λN are sufficiently separated to be able to place the corresponding light sources S1 to SN at the site of these foci. In this way, the spectral multiplexing is precisely and automatically carried out by the aberrant optical system 25 used off-axis.
In this first embodiment of a fabricating method according to the invention, the step of determining the position of each source S1 to SN is carried out by a measurement.
The multiplexer 4 consists of the optical assembly 6.
The optical assembly 6 comprises (and even consists of) the off-axis optical system 25, i.e. in this example a thick biconcave lens 25 having an optical axis A1 the chromatic aberrations of which are used. The lens 25 has foci F1 to FN corresponding to the wavelengths λ1 to λN. Due to the lateral chromatic aberration, these foci are different and separated, aligned along a straight line secant with the optical axis A1 of the lens 25.
The optical assembly 6 thus comprises an optical system (the lens 25 in this particular case) having a lateral chromatic aberration, the determined positions of the sources S1 to SN corresponding to an off-axis use of the optical system.
A detector 8 is used which has the same shape (here, planar) as the support 2. The detector 8 is arranged in order to detect a light beam focused thereon, and to determine a position of the focal point of this beam on the detection surface of this detector 8.
The detector 8 is typically an array detector (CCD (“Charge-Coupled Device”) camera or PDA (“Photo Diode Array”) detector or PMT (“Photo Multiplier Tube”) array or not (for example a PSD (for “Position Sensitive Detector”) diode.
The placement 5 of the emitter 1 with respect to the multiplexer 4, considered for determining the positions of the sources S1 to SN corresponds to a distance 7 between:
the apex of the concave surface 9 of the lens 25 oriented towards the support 2, and
the support 2 this support 2 being planar and positioned perpendicularly to the axis A1 of the lens 25.
In order to measure the position Xi, along the fixing direction 3, of each source Si, the detector 8 is positioned at this placement 5 with respect to the multiplexer 4, i.e. in this example:
at the distance 7 previously considered, but this time between the apex of the concave face 9 of the lens 25 oriented towards the detector 8 and the detector 8, since the detector 8 replaces the support 2, and
Finally, the other face 10 of the lens 25 is then illuminated by a collimated beam 27 of white light, corresponding to a use off-axis A1 of the lens 25.
Furthermore:
Thus the position Xi of the source Si is determined as the position of the focal point detected by the detector 8.
This procedure is carried out for each source, changing the filter 18 for each source.
The position 18a is very clearly preferred. In fact, the filter 18 is generally optimized and operates best at a given incidence (normal incidence in the case of
In a variant, the filter 18 can be dispensed with by replacing the while beam 27 with a monochromatic beam 27 at the working wavelength λi of the source Si for which it is sought to determine the position Xi, and by thus changing the monochromatic wavelength of the beam 27 for each source Si.
There will now be described, with reference to
In this second embodiment of the fabricating method according to the invention, the step of determining the position of each source S1 to SN is carried out by a calculation.
In this second embodiment of emitter 1 according to the invention, the optical assembly 6 comprises an achromatic doublet 55 and a prism 51 the chromatic dispersion properties (more precisely the chromatic aberration properties) of which are used.
This chromatic aberration forms the chromatic dispersion property according to the invention in this embodiment.
In order to determine the position of each of the sources S1 to SN, it is necessary to investigate the response of the multiplexer in the “reverse direction of use”, i.e. to investigate the chromatic dispersion of a white collimated beam.
In the optical assembly 6:
the prism 51 converts a collimated white beam 27 into a multitude of collimated monochromatic beams 28 the directions of which depend on their wavelengths, and
the doublet 55 focuses the collimated beams 28 in its focal plane as a function of their direction (but not of their wavelength).
As shown in
where:
θ0 is the angle of incidence of the ray
n is the optical index of the prism 51 (function of the wavelength of the ray λ); for example,
α is the angle at the apex of the prism.
With reference to
X=F′·tan(θ)
F′ is the focal length of the doublet 55
X is the height in the focal plane
θ is the angle of the collimated beam
Unlike a simple lens, the focal length of the achromatic doublet 55 is quasi-independent of λ. In order to reduce the focal length and/or increase the aperture a triplet may be preferred.
Thus, the position Xi(λi) of the source Si of working wavelength λi (with i an integer i=1 to N) is determined by calculating it according to the formula:
and λref is the wavelength for which the origin of positions (X(λref)=0) is arbitrarily set.
This step of determination by calculation is implemented by technical means, more precisely by calculation means. The calculation means typically comprise a processor, typically an analogue and/or digital electronic circuit, and/or a microprocessor and/or a computer central processing unit.
This step of determination by calculation could be completed by an optical design step: radiometric optimization. This calculation step consists of simulating the source+optical system assembly in the sense of actual operation so as to optimize the collimated white exit beam by slight modifications of the position of the sources as well as of the radii of curvature, thicknesses and/or positions of the optics of the multiplexer.
The table below shows an example for an SF11 glass prism, for α=60°, for θ0=θWhite=68.5°, for F′=35 mm, for δref=δ(λref)=62.3° and for N=15.
There will now be described, with reference to
After having determined the positions of the sources S1 to SN, the fabricating method according to the invention shown comprises fixing each source S1 to SN, along the fixing direction 3, onto the support 2 at its previously determined position X1 to XN, so that the sources S1 to SN are distributed along the fixing direction 3 in order of increasing working wavelength λ1 to λN and according to the law or the properties of chromatic dispersion of the spectral multiplexer.
It is noted that according to the invention it is not simply sought to put the sources S1 to SN closer to one another: the spacing between the sources S1 to SN must comply with the law of chromatic dispersion of the optical assembly 6 for which it is designed.
The support 2 is a planar surface firmly fixed to an electronic chip 11 equipped with connecting pins 12 arranged in order to fix the chip 11 onto an electronic circuit board and to make it possible to supply each source S1 to SN independently with electricity.
The support 2 is covered with glue before placing each source S1 to SN. According to the chosen method of electrical supply, either conductive glue or insulating glue is used.
In order to fix each source Si onto the support 2, this source is held by a suction tip, and the source Si is placed on the support 2 (more precisely in contact with the glue) by the suction tip, at its previously determined position Xi. During placement, the projection of the tip over the plane of the support 2 remains fixed, and the support 2 is mounted on a piezoelectric displacement stage and is mobile so as to place the source Si at its correct, previously determined position Xi.
An additional baking step is implemented in order to set the glue permanently.
With reference to
Thus, the space requirement of the sources S1 to SN is reduced by “superimposing” them on the axis X by means of an offset in the Y direction.
It is noted that the emitter 1 according to the invention, obtained by a fabricating method according to the invention, is particularly appropriate in that it comprises sources S1 to SN on at least two (preferably at least three, preferably three) parallel fixing axes 13, 14, 15 extending along the fixing direction 3.
Among the sources S1 to SN, there are pairs of two sources (for example S10 and S11, or S11 and S12, or S12 and S13, or S13 and S14, or S14 and S15) having adjacent positions along the fixing direction 3 (i.e. without a third source having an intermediate position along the fixing direction 3 comprised between the positions of these two sources along the fixing direction 3) but which are not fixed on the same fixing axis 13, 14, 15.
It is noted that the sources S1 to SN comprise two sets:
a first set of sources S1 to S9, and
a second set of sources S10 to S15 the working wavelengths λ10 to λ15 of which are greater than all the working wavelengths λ1 to λ9 of the sources of the first set.
All the sources of the second set belong to a pair of two sources (for example S0 and S11, or S11 and S12, or S12 and S13, or S13 and S14, or S14 and S15) having adjacent positions along the fixing direction 3 but which are not fixed on the same fixing axis 13, 14, 15.
Each source is linked to an anode 16 and to a cathode 17 (typically by gold wire bonding).
As has just been described, the emitter 1 comprises the support 2 and the sources S1 to SN.
The emitter 1 can moreover comprise the chip 11 firmly fixed to the support 2.
The emitter can moreover comprise control electronics (not shown), arranged in order to control each source independently of the other sources. Typically, this control electronics is an electronic circuit board (printed circuit) on which the chip 11 is fixed.
Moreover, the fabricating method according to the invention can comprise, as shown in
For example, in the case of the first embodiment of an emitter according to the invention shown in
at the distance 7, with respect to the lens 25, considered for determining the position X1 to XN of each source S1 to SN
with the inclination of the support 2 (for example perpendicular), with respect to the axis A1, considered for determining the position X1 to XN of each source S1 to SN,
assuming that the intersection of the support 2 and the axis A1 corresponds to a position reference value Xref (for example Xref=0) considered for determining the position X1 to XN of each source S1 to SN.
Similarly, in the case of the second embodiment of an emitter according to the invention shown in
at the focal length F′, with respect to the doublet 55, considered for determining the position X1 to XN of each source S1 to SN
with the inclination of the support 2 (a priori perpendicular), with respect to the optical axis A2 of the doublet 55, considered for determining the position X1 to XN of each source S1 to SN,
assuming that the intersection of the support 2 and the optical axis of the doublet 55 corresponds to a position reference value Xref (for example Xref=0 in the case of the fifteen values calculated in the preceding table) considered for determining the position X1 to XN of each source S1 to SN.
With reference to
With reference to
the first fixing axis 13 corresponds to a first working wavelength range (300 to 580 nm) of the sources S1 to S8 distributed on this axis 13, and
the second fixing axis 14 corresponds to a second working wavelength range (620 to 860 nm) of the sources S9 to S15 distributed on this axis 14, so that there is no intersection between these two working wavelength ranges, but that the sources of the first working wavelength range (300 to 580 nm) and the sources of the second working wavelength range (620 to 860 nm) are situated one after another (perpendicularly to the direction 3). Thus, all the sources S1 to S15 considered as a whole are not distributed along the fixing direction 3 in order of increasing working wavelength λ1 to λ15.
It is therefore noted that:
On the other hand, unlike the case in
The case of
It is possible that all of the sources taken as a whole are not distributed along the fixing direction 3 in order of increasing working wavelength. This is the case in particular, with reference to
Unlike the case in
With reference to
so as to compensate for the longitudinal chromatic aberrations of the spectral multiplexer. It is particularly appropriate to have as patterns a step 43, 44, 45 for each fixing axis 13, 14, 15, each step 43, 44, 45 having a different elevation from the other steps along a normal 46 to the plane 36 of the support 2. In the case of
Of course, the invention is not limited to the examples which have just been described and numerous adjustments can be made to these examples without exceeding the scope of the invention.
Of course, the various characteristics, forms, variants and embodiments of the invention can be combined together in various combinations insofar as they are not incompatible or mutually exclusive. In particular, all the previously described variants and embodiments can be combined together.
For example, it is possible to use the first embodiment of the method according to the invention (measurement) for fabricating the second embodiment of an emitter according to the invention.
Similarly, it is possible to use the second embodiment of the method according to the invention (calculation) for fabricating the first embodiment of an emitter according to the invention.
Moreover, the second embodiment of the method according to the invention (calculation) can be based on a calculation in which the calculation steps, implemented by technical means, are based on a theoretical model or on a digital simulation model.
Finally, the first or the second embodiment of the method according to the invention (measurement or calculation) can be used to fabricate numerous other example embodiments of an emitter according to the invention. It will be noted for example that the prism 51 can be replaced or combined with a diffraction grating, the chromatic dispersion properties of which can also be used.
For example, the first or the second embodiment of the method according to the invention (measurement or calculation) can be used to fabricate a variant of the second embodiment of an emitter according to the invention (
Number | Date | Country | Kind |
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1357872 | Aug 2013 | FR | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2014/066854 | 8/5/2014 | WO | 00 |