This is a national phase entry under 35 U.S.C. §371 of International Patent Application PCT/EP2010/052765, filed Mar. 4, 2010, published in English as International Patent Publication WO 2010/102943 A1 on Sep. 16, 2010, which claims the benefit under Article 8 of the Patent Cooperation Treaty to French Patent Application Serial No. 0951543, filed Mar. 12, 2009, the entire disclosure of each of which is hereby incorporated herein by this reference.
The present invention relates to the field of multilayer semiconductor structures (also known as multilayer semiconductor wafers) produced by transferring at least one layer formed from an initial substrate onto a final substrate, the layer corresponding to the portion of initial substrate in which a plurality of microcomponents has been formed, for example.
Three-dimensional component integration technology (3D-integration) requires the transfer of one or more layers of microcomponents onto a final substrate, the final substrate itself possibly incorporating microcomponents. The transferred layer or layers include microcomponents (electronic, optoelectronic, etc., components) produced at least in part on an initial substrate, the layers then being stacked on a final substrate. Primarily because of the very small size and large numbers of microcomponents present on a single layer, each transferred layer must be positioned on the final substrate with great accuracy so that they are very closely aligned with the subjacent layer. Further, it may be necessary to carry out treatments on the layer after its transfer, for example, to form other microcomponents, in order to expose the microcomponents on the surface, to produce interconnections, etc.; the treatments also have to be carried out with great accuracy in regard to the components present in the layer.
However, the applicants have discerned that following transfer, there are circumstances where it is very difficult, if not impossible, to form additional microcomponents that are aligned with all of the microcomponents formed before the transfer.
This phenomenon of misalignment is described in relation to
As can be seen in
As can be seen in
Once it has been bonded to the final substrate 20, the geometry of the initial substrate 10 is different from that which it had initially in
This modification of the geometry of the initial substrate 10 is even more pronounced after it has been thinned (
As can be seen in
However, even when positioning tools are used, offsets occur between some of the microcomponents 11 and 12, such as the offsets Δ11, Δ44, or Δ88 indicated in
Photolithography tools include algorithms for correcting certain modes of overlay (rotation, translation, etc.) that may be applied to attempt to minimize the overlay between two steps of defining or forming the components. However, it has been observed that this misalignment is not homogeneous (i.e., cannot be reduced to elementary transformations); thus, it is not possible to correct the photolithography exposure in a general and satisfactory manner in order to obtain, for each exposed field of the wafer, a satisfactory maximum value for the overlay (for example, less than 100 nm [nanometer] or 50 nm). A correction of the parameters governing the lithography exposure for each field of the wafer is not industrially desirable, and so it is important to seek to optimize the set of parameters that might lead to overlay.
Further, when a layer of microcomponents is transferred onto a final substrate having a first layer of microcomponents, it is very important to be able to minimize the overlay between the microcomponents of each of the layers when they are to be interconnected. Under such circumstances, it is not possible to compensate for overlays existing between the microcomponents of the two layers by lithography.
The aim of the invention is to propose a solution that, during fabrication of multilayer or composite structures, can reduce the phenomenon of overlay and distortion between the microcomponents formed on one face of a first substrate and the microcomponents subsequently formed on another face of the substrate after transfer onto a second substrate.
To this end, the present invention proposes a method of producing a composite structure, comprising a step of producing a first layer of microcomponents on one face of a first substrate, the first substrate being held flush against a holding surface of a first support during production of the microcomponents, and a step of bonding the face of the first substrate comprising the layer of microcomponents onto a second substrate, the method being characterized in that during the bonding step, the first or second substrate is held flush against a holding surface of a second support that has a flatness that is less than or equal to that of the first support used during production of the microcomponents.
Thus, by holding, during bonding, one of the two substrates flush against a holding surface of a support, i.e., the surface with which the substrate is held flush, that presents at its surface a flatness that is identical to or less than that of the holding surface of the support used during formation of the microcomponents, the risks of overlay and distortion during subsequent formation of additional layers of microcomponents are substantially reduced.
By fixing the first substrate during bonding in a geometric configuration, at least in terms of bow/warp type deformations, that is similar to that presented thereby when the microcomponents are formed, it is possible to regain that geometric configuration during formation of an additional layer of microcomponents on the other face of the first substrate. Even if the first substrate has a different geometry once released following bonding, for example. due to the difference in geometry compared with the second substrate, the first substrate regains its geometry presented at the moment of bonding when the second substrate was being held flush against a support having a similar flatness to that of the flat reference support used during production of the microcomponents. In this manner, during formation of the second layer of microcomponents on the face of the first substrate opposite to that comprising the first layer of microcomponents or on the exposed face of the first layer, the reliability of the alignment of the photolithography mask with the microcomponents of the first layer or the first face of the layer and, as a result, the quality and value of the wafer are improved.
In accordance with a particular characteristic of the invention, the flatness of the holding surface of the first support is 2 μm [micrometer] or less.
In accordance with one aspect of the invention, during the bonding step, the first substrate is held flush against the second support.
In accordance with another aspect of the invention, during the bonding step, at least the first substrate is maintained at a temperature substantially equivalent (preferably by ±0.5° C. or less) to the temperature to which it is subjected during the step of producing the first layer of microcomponents.
In accordance with another aspect of the invention, during the bonding step, the first and second substrates are maintained at a substantially equivalent temperature. The temperature difference between the first and the second substrates is preferably ±0.5° C. or less.
In accordance with a particular characteristic of the invention, after the bonding step, the method comprises a step of thinning the first substrate.
In accordance with another particular characteristic of the invention, the method further comprises a step of producing a second layer of microcomponents on the face of the first substrate opposite to the face comprising the first layer of microcomponents.
Before the bonding step, the method may comprise a step of forming a layer of oxide on the face of the first substrate comprising the first layer of microcomponents.
In accordance with a particular aspect of the invention, the first substrate is constituted by an SOI type structure.
During the step of producing the first layer of microcomponents and the bonding step, it is possible to use a substrate carrier device comprising a support platen with which the first substrate is flush, the substrate carrier device being capable of holding the first substrate flush against the support platen.
The first substrate may be held flush against the support platen by suction (vacuum pump), by capillary attraction (substrate held flush against a rigid support, for example, formed from marble, and retained thereon by capillary attraction), or by an electrostatic force. The use of an electrostatic force is especially useful when vacuum bonding is to be carried out.
The present invention also provides an apparatus for wafer bonding substrates, the apparatus comprising a substrate carrier device, and being characterized in that the substrate carrier device comprises a holding surface for a substrate having a flatness of 2 micrometers or less.
In accordance with one characteristic of the bonding apparatus of the invention, the substrate carrier device is adapted to receive circular substrates (wafers) 200 mm (millimeters) or 300 mm in diameter.
In accordance with another characteristic of the bonding apparatus of the invention, the apparatus also has a treatment chamber enclosing the substrate carrier device, the treatment chamber comprising temperature control means.
Other characteristics and advantages of the invention become apparent from the following description of particular implementations of the invention given by way of non-limiting example and made with reference to the accompanying drawings, in which:
The present invention is of general application to the production of composite structures comprising at least bonding, for example, by wafer bonding, a first substrate or wafer comprising components onto a second substrate or wafer.
As described above, after bonding, the geometry of the first substrate is different from that which it had when the components thereof were being formed. As a consequence, after bonding, offsets are created in the structures of the first substrate, which causes an overlay and a distortion between the originally formed components and those formed subsequently.
In order to minimize these phenomena and to allow the subsequent production of components in alignment with those formed on the first substrate before bonding, the present invention proposes holding, during bonding, one of the two substrates on a holding surface of a support that has a flatness similar to or less than that of the support used to hold the first substrate during formation of the components. The flatness of the holding surface of the support used during bonding is preferably less than that of the support used when the components are being formed.
The holding surface of the support corresponds to the surface with which the substrate is flush, i.e., the surface of the support in contact with the substrate. Depending on the type of support used, this holding surface may be a continuous or discontinuous surface. For example, when using a support with an electrostatic or capillary attraction system to hold the substrate, the support generally has a continuous holding surface that is entirely in contact with the substrate when the substrate is flush against the support. In contrast, with a support using suction forces to hold the substrate, for example, the support may have grooves or cavities on its surface that can hold the substrate by suction through them. Under such circumstances, the holding surface of the support corresponds to the surface of the support located around the grooves or cavities, i.e., the surface in contact with the substrate when it is held flush against the support.
In the present invention, the flatness corresponds to the value of the distance between the lowest point and the highest point of the holding surface of the support. As an example, a flatness of x micrometers means that every point of the designated surface is located between two parallel planes spaced apart by x μm.
A method of producing a three-dimensional structure by transfer of a layer of microcomponents formed on an initial substrate onto a final substrate in accordance with one implementation of the invention is described below with reference to
Production of the three-dimensional structure commences by forming a first series of microcomponents 110 on the substrate of a wafer or initial substrate 100 (
The initial substrate 100 may also be constituted by a multilayer structure of another type or by a monolayer structure.
The microcomponents 110 are formed by photolithography using a mask that can define zones for forming patterns corresponding to the microcomponents 110 to be produced.
In accordance with the invention, when the microcomponents 110 are being formed by photolithography, the initial substrate 100 is held on a substrate carrier device 120. The substrate carrier device comprises a support platen 121 having a holding surface 121a with which the initial substrate 100 is held flush using an electrostatic system associated with the support platen 121. The flatness of the holding surface 121a of the support platen 121 is generally 2 micrometers (μm) or less.
After forming the microcomponents, a layer of oxide 104, for example, of SiO2, is deposited on the surface of the initial surface 100 comprising the microcomponents 110 with a view to preparing for bonding (step S2,
Next, a surface 104a of the oxide layer 104, as well as the surface 200a of a final substrate or wafer 200 formed from silicon, are prepared in order to bond them (step S3). Metal pins, for example, formed from copper, may be provided on the surface of the layer 104a and in contact with all or part of the microcomponents 110 in order to be able to bring the microcomponents 110 into contact with other microcomponents present in the final substrate. As with the initial substrate, the final substrate 200 may also comprise a layer of oxide and, optionally, metal pins on its bonding face. The treatments carried out in order to prepare the surface vary as a function of the bonding energy that is to be obtained. If a standard bonding energy is to be obtained, i.e., relatively weak bonding energy, the surface may be prepared by carrying out chemical-mechanical polishing followed by a clean. Alternatively, if a high bonding energy is to be obtained between the two substrates, preparation of the surface includes an RCA type clean (namely, a combination of SC1 treatment (NH4OH, H2O2, H2O) that is adapted to remove particles and hydrocarbons, and SC2 treatment (HCl, H2O2, H2O) that is adapted to remove metallic contaminants), plasma surface activation, and an additional clean followed by scrubbing.
In a variation, the final substrate 200 may also comprise components that are either directly formed thereon or formed during a preceding transfer step.
In accordance with the invention, during bonding, the back face of one of the two substrates is held on a holding surface of a support that has a flatness that is similar to or less than that of the support used during formation of the microcomponents, i.e., a flatness of 2 micrometers or less, preferably less than 2 micrometers. As can be seen in
As can be seen in the example described herein, it is the initial substrate on which the components have been formed that is preferably placed and held flush against the support. Under such circumstances, holding the initial substrate on the support means that bow and/or warp of the substrate can be compensated for, in particular, if it does not include a compensating layer or if the surface preparation steps have resulted in the creation of such deformations. Further, bringing the back face of a substrate into contact with the support may result in the creation of defects (scratches, particulate contamination, etc.), and so it is preferable for the back face of the initial substrate to be in contact with the support, since this will subsequently be thinned.
Once the initial substrate has been placed on and held flush against the support platen 221 of the substrate carrier device 220, the final substrate 200 is placed on the initial substrate in order to bring the surface 104a of the initial substrate into intimate contact with the face of the final substrate 200 with a view to bonding by wafer bonding (step S4). Bonding by wafer bonding is a technique that is known per se. It should be recalled that the principle of bonding by wafer bonding is based on bringing two surfaces into direct contact, i.e., without using a specific material (adhesive, wax, solder, etc.). Such an operation requires that the surfaces for bonding are sufficiently smooth, free of particles or contamination, and are sufficiently close together to allow contact to be initiated, typically at a distance of a few nanometers or less. The attractive forces between the two surfaces are then high enough to cause molecular adhesion (bonding induced by the total of the attractive forces (Van der Waals forces) of electronic interaction between atoms and molecules of the two surfaces to be bonded).
Next, bonding by wafer bonding proper is carried out by delicately pressing using a tool, for example, a stylus, on the upper face of the final substrate 200, in order to initiate propagation of a bonding wave (step S5). The point at which the tool is applied may, for example, be located at the center or at the edge of the wafer. The mechanical pressure exerted by the tool may be in the range 1 MPa [megapascal] to 33.3 MPa and is applied to a bearing surface of 1 mm2 [square millimeter] or less. The two substrates are then bonded together by wafer bonding over the whole of their surfaces in contact (bonding interface). This thereby produces a buried layer of microcomponents 110 at the bonding interface between the substrates 100 and 200.
During bonding, the temperature of the substrates is preferably controlled. To this end, the bonding apparatus may, for example, comprise a closed chamber enclosing the substrate carrier device. The temperature of the substrates may be adjusted by temperature control means belonging to the chamber (heating and/or cooling system for the atmosphere in the chamber) and/or belonging to the substrate carrier device (cooling fluid circulating in the support platen and/or heating means integrated into the support platen).
In accordance with a first aspect, the substrates 100 and 200 are maintained at a substantially similar temperature. The temperature difference between the two substrates is preferably ±0.5° C. or less.
The temperature of the substrates may be accurately controlled at a reference temperature by maintaining, in the closed chamber of the bonding apparatus, an atmosphere at a controlled temperature during the steps of preparing to bond the substrates (scrubbing, cleaning, bringing into contact, etc.) and the bonding steps. The temperature of the support platen on which bonding is carried out, as well as the fluids applied to the substrates (cleaning, scrubbing), is also controlled according to the reference temperature.
Preferably, it is also ensured that the temperature during bonding and, optionally, during the bonding preparation steps, is substantially similar (to ±0.5° C.) to the temperature at which the microcomponents 110 are formed on the initial substrate 100 held on the substrate carrier device 120 by photolithography. This prevents any effects of expansion and of generating an overlay between these various steps.
After bonding, the resulting structure undergoes a moderate heat treatment (below 500° C.) in order to increase the bonding energy between the two substrates and to allow one of them to be subsequently thinned.
As can be seen in
Thus, a composite structure 300, formed by the final substrate 200 and a layer 100a corresponding to the remaining portion of the initial substrate 100, is formed.
As can be seen in
Just as for the formation of the microcomponents 110, the composite structure 300 formed by the final substrate 200, and the layer 100a is held on a support platen 131 of a substrate carrier device 130 that is identical to the device 120, i.e., a platen having an electrostatic holding system, a holding surface 131a of which has a flatness of 2 micrometers or less. The photolithography mask is then applied to the free surface of the layer 100a.
In a variation, the three-dimensional structure is formed by a stack of layers, each layer having been transferred using the assembly method of the present invention (a first layer may already be present in the final substrate), and each layer being in alignment with the directly adjacent layers.
By means of the method of producing a composite structure of the invention, it is possible to bond the initial substrate 100 to the final substrate without deformation, or at least with a reduction in the deformations, in such a manner that significant offsets of the microcomponents 110 before and after transfer of the initial substrate 100 onto the final substrate 200 can no longer be observed. It is thus possible to limit these residual offsets to values of less than 200 nm, or even less than 100 nm, in a homogeneous manner over the entire surface of the wafer. The microcomponents 140, even of very small sizes (for example, <1 μm), can thus be formed easily in alignment with the microcomponents 110, even after transfer of the initial substrate. This means, for example, that the microcomponents present in the two layers or on two distinct faces of the same layer can be interconnected via metal connections, thereby minimizing the risks of poor interconnection.
As a consequence, the method of the present invention means that the phenomenon of overlay during transfer of a circuit layer onto another layer or onto a support substrate can be eliminated or at least reduced, and very high quality multilayer semiconductor wafers can be produced.
Number | Date | Country | Kind |
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09 51543 | Mar 2009 | FR | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP2010/052765 | 3/4/2010 | WO | 00 | 10/18/2011 |
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WO2010/102943 | 9/16/2010 | WO | A |
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