Patent Application
20160237545
This application claims priority to French Patent Application No. 1551179, filed Feb. 13, 2015, the entire content of which is incorporated herein by reference in its entirety.
The invention relates to a method of fabricating parts out of nitrided low-alloy steel and also to decarburized low-alloy steel parts suitable for being subjected to nitriding treatment.
Low-alloy steels that are intended to be subjected to nitriding typically present a carbon content lying in the range 0.20% to 0.45% that serves to impart its mechanical properties to the core of the base material after heat treatment.
The surface properties of the steel, such as hardness, may be conferred by nitriding treatment, which consists in diffusing nitrogen into the ferritic phase and which causes submicroscopic nitrides to be precipitated from nitride-forming elements such as Cr, V, Mo, and Al that are present in solid solution in the treated steel.
Concretely, in a nitriding treatment, the steel may be treated at a temperature of about 500° C. with ammonia, which decomposes into cracked ammonia and reacts simultaneously with the iron of the steel. The ammonia causes a surface layer to be formed that is constituted by iron nitrides, referred to as a “compound” layer, from which nitrogen atoms diffuse towards the core of the part in order to form the diffusion layer.
For a low-alloy steel having nitride-forming elements, it is possible to observe two layers after nitriding: the compound layer at the surface constituted by iron nitrides, and the diffusion layer in which submicroscopic nitride precipitates are dispersed that lead to the increase in hardness that is observed in the nitrided layer.
The depth of the nitrided layer may vary, depending on nitriding conditions and on the intended applications, in the range 0.05 millimeters (mm) to 1 mm.
Nevertheless, nitriding treatment remains treatment that is relatively lengthy to perform.
It would be desirable to further improve the surface properties of nitriding layers and to reduce the time required for nitriding treatment.
There thus exists a need to improve the surface properties, in particular the hardness, of nitrided layers formed at the surface of low-alloy steel parts.
There also exists a need to accelerate the apparent speed of treatment for nitriding low-alloy steel parts, i.e. for reducing the time needed to obtain a significant increase in hardness to a given depth, e.g. an increases of at least 200 on the Vicker's hardness scale (HV) compared with the hardness so the steel in the core.
To this end, in a first aspect, the invention proposes a method of fabricating a nitrided low-alloy steel part, the method comprising the following steps:
a) decarburizing the surface of a low-alloy steel part including at least one alloying element that is both nitride-forming and carbide-forming in order to obtain a decarburized part presenting a carbon-depleted surface layer of thickness less than or equal to 1.5 mm, the minimum content of carbon by weight in the carbon-depleted surface layer being less than or equal to 70% of the carbon content by weight in the core of the decarburized part;
b) treating the decarburized part with quenching treatment followed by annealing treatment; and
c) nitriding the carbon-depleted surface layer in order to obtain a nitrided low-alloy steel part, step c) being performed after step b).
The term “low-alloy steel” should be understood as meaning a steel in which no alloying element is present at a content by weight of greater than 5.00%. In other words, in a low-alloy steel, each of the chemical elements, other than iron, is present at a content by weight that is less than or equal to 5.00%.
The term “alloying element that is both nitride-forming and carbide-forming” should be understood as meaning an alloying element that is present in the steel in the form of a carbide prior to step c) and that is suitable for forming a nitride during step c). As examples of alloying elements that are both nitride-forming and carbide-forming, mention may be made for example of the following elements: Cr, Mo, and V.
The carbon content by weight in the core of the part does not vary during step a). In other words, the surface decarburizing that is performed during step a) affects carbon content only in the surface layer of the part and not in its core.
It is possible for the carbon content by weight to vary as a function of depth within the carbon-depleted surface layer. Thus, the term “minimum carbon content by weight in the carbon-depleted surface layer” should be understood as the minimum value that is reached by the carbon content by weight on moving depthwise through the carbon-depleted surface layer parallel to the gradient of carbon content by weight.
By way of example, the carbon content by weight may be measured with a Castaing microprobe by using the procedure set out in the standard ASTM E1019. The carbon content by weight in the core of the decarburized part (corresponding to that of the part prior to decarburizing) may for example lie in the range 0.20% to 0.45%.
In an embodiment of the invention, the minimum carbon content by weight in the carbon-depleted surface layer is less than or equal to 70% of the carbon content by weight in the core of the decarburized part. In other words, the minimum content of carbon by weight in the carbon-depleted surface layer is less than or equal to 0.70×(carbon content by weight in the core of the decarburized part).
The inventors have found that the layer obtained by nitriding does not present optimum properties if carbon is present in too great a quantity in the surface layer of the part prior to nitriding treatment. Under such circumstances, there is a high content of carbides in the surface layer prior to nitriding, and this can constitute a problem.
The nitrides obtained by nitrogen taking the place of carbon in the carbides (in situ precipitation of nitrides) during the nitriding treatment have a hardening potential that is smaller than that of nitrides that are obtained by precipitation from nitride-forming elements that were initially present in solid solution in the ferritic matrix. Furthermore, during nitriding, the carbon that was initially present in the carbides of the surface layer can be released and can diffuse upstream from the nitrogen diffusion front. The carbon that is released in this way can precipitate in the form of cementite networks at the grain boundaries, and can thus degrade the mechanical properties of the nitrided layer.
Thus, an aspect of the invention is based on performing decarburizing treatment of the surface of the part prior to the nitriding treatment in order to reduce the quantity of carbides present at the surface of the part, and thus be unaffected by the above-mentioned undesirable effects of carbon, while conserving good properties in the core of the part away from the surface layer. The decarburizing treatment performed during step a) makes it possible to obtain a surface layer of chemical composition that is optimized for receiving the nitriding treatment as a result of at least some of the carbides being eliminated by the decarburizing treatment, which carbides contribute during nitriding to forming networks of carbides/carbonitrides that are harmful for the mechanical strength of the nitriding layer.
An aspect of the invention beneficially makes it possible to increase the surface hardness of the nitrided part significantly and to obtain compression stress fields that are more intense, thereby enabling the fatigue strength of the steel part as treated in this way to be considerably improved. In particular, the aspect of the invention makes it possible to reduce or even to eliminate the quantity of embrittling cementite networks. In addition, the aspect of the invention makes it possible to increase the apparent speed of nitriding significantly because of the reduction in the quantity of surface carbon in the part, thereby leading to nitrogen having a greater contribution to the hardening mechanism. Thus, compared with the situation in which step a) is not performed prior to nitriding, parts treated by the method of an aspect of the invention present greater hardness in the nitriding layer for identical nitrogen content, which amounts to the speed of nitriding apparently accelerating (nitriding takes place as though more nitrogen were present at a given depth in parts that have been treated by the method of an aspect of the invention).
An aspect of the invention thus makes it possible quickly to obtain nitrided layers that are deep, e.g. having a depth of 0.7 mm. The increase in the apparent speed of nitriding also beneficially makes it possible to limit the relaxation of residual stresses in the nitriding layer because it is possible to reduce the time of exposure to the nitriding temperature.
The intermediate quenching and annealing step serves to confer its properties on the base steel. In one implementation, quenching (cooling) may be performed from the decarburizing temperature, after which annealing is then performed. In a variant, it is possible to begin by cooling the decarburized part, e.g. down to ambient temperature (20° C.), and then to perform austenitization and, after austenitization, to perform quenching treatment followed by annealing treatment.
In an implementation, the minimum content of carbon by weight in the carbon-depleted surface layer may be less than or equal to 60% of the carbon content by weight in the core of the decarburized part. In other words, the minimum content of carbon by weight in the carbon-depleted surface layer may be less than or equal to 0.6×(carbon content by weight in the core of the decarburized part).
Nitriding may be performed under conventional conditions using any type of nitriding method known to the person skilled in the art. The atmosphere, temperature, and time settings are defined as a function of the base steel and of the looked-for characteristics.
In an implementation, the thickness of the carbon-depleted surface layer may lie in the range 0.3 mm to 1.5 mm.
In an implementation, the minimum content of carbon by weight in the carbon-depleted surface layer may be greater than or equal to 0.05%.
The presence of such a minimum carbon content in the carbon-depleted surface layer serves beneficially to provide a significant increase in the surface hardness of the part after nitriding.
By way of example, the treated low-alloy steel part may be made of 32CrMoV13, 35CrMo4, 15CrMoV6, or X38CrMoV5 steel. The treated low-alloy steel part may, in an embodiment, be made of 32CrMoV13 steel.
In an implementation, it is possible during step a) to treat the low-alloy steel part with an oxidizing atmosphere containing water vapor while imposing a temperature lying in the range 850° C. to 1000° C., the oxidizing atmosphere having a dew point temperature lying in the range −40° C. to +20° C., e.g. lying in the range −10° C. to +10° C., e.g. in the range −4° C. to +4° C.
In a variant, in step a), it is possible to treat the low-alloy steel part with air at a temperature of 950° C. in order to perform the desired decarburizing.
In an implementation, it is possible, prior to step c), to perform a step of machining the carbon-depleted surface layer.
Performing such a machining step is beneficial since it makes it possible to eliminate the non-desirable oxidized layer that may form during decarburizing. This oxidized layer may typically have a thickness that is less than or equal to a few hundredths of a millimeter. There exist other ways of reducing the quantity of surface oxides in the decarburized part, and it is thus possible for example to subject the decarburized part to treatment in a reducing atmosphere, e.g. including H2, prior to step c).
The step of machining the carbon-depleted surface layer may be performed before and/or after step b).
In an implementation, it is possible, after step c), to perform a step of machining the nitrided layer formed during step c).
Performing such a machining step may make it possible to eliminate the compound layer that is formed during the nitriding treatment, with only the diffusion layer that is formed during this treatment being conserved.
In an implementation, it is possible to seek to obtain a carbon-depleted surface layer after performing step a) only in one or a plurality of predefined zones of the surface of the part. Under such circumstances, it is possible, by way of example, to coat the surface of the low-alloy steel part prior to step a) with a mask in order to perform decarburizing only in one or a plurality of predefined zones of the surface of the part as defined by the mask. By way of example, it is thus possible to deposit a varnish that forms an oxygen barrier on the surface of the part, with the zone(s) on which the varnish has not been deposited being for decarburizing during step a).
It is also possible, prior to step c), to eliminate a portion of the carbon-depleted surface layer in order to retain it in only one or a plurality of predefined zones of the surface of the part.
An aspect of the present invention also provides a decarburized low-alloy steel part including at least one alloying element that is both nitride-forming and carbide-forming, presenting a carbon-depleted surface layer of thickness less than or equal to 1.5 mm that is to be subjected to nitriding, the minimum carbon content by weight in the carbon-depleted surface layer being less than or equal to 70% of the carbon content by weight in the core of the decarburized part.
Such a part corresponds to an intermediate product obtained by performing above-described step a) prior to performing the nitriding step c).
In an embodiment, the carbon-depleted surface layer may present a thickness lying in the range 0.3 mm to 1.5 mm.
In an embodiment, the low-alloy steel may be 32CrMoV13 steel.
The various characteristics described above for the method of an aspect of the invention relating to the carbon-depleted surface layer and to the low-alloy steel used also apply to the aspect of the invention relating to the part.
Other characteristics and advantages of the invention appear from the following description made with reference to the accompanying drawings, in which:
In both situations, the part presents at its surface both chromium 1 in solid solution and chromium-enriched carbides 2 referred to as chromium carbides. In its carbon-depleted surface layer 3, the decarburized part includes a quantity of chromium carbide 2 that is smaller than that of the non-decarburized part. The low-alloy steel can enable a martensitic, bainitic/martensitic, or a bainitic structure to be obtained in the carbon-depleted surface layer after quenching. During nitriding, the part may be treated, by way of example, by means of a stream of gas comprising ammonia.
As mentioned above, chromium nitrides 4 can confer lower hardness to the nitrided layer than chromium nitrides 6. The nitrided layer obtained when the part has previously been decarburized thus beneficially presents better hardness because it has a smaller proportion of chromium nitrides 4.
Furthermore, and as shown in
A 32CrMoV13 type nitriding steel in the annealed state was initially decarburized by treatment in an oxidizing atmosphere containing water vapor and presenting a dew point of +4° C. at a temperature of 950° C. for 6 hours.
Following this decarburizing treatment, oil quenching was performed and then annealing treatment was performed at a temperature of 635° C. for 4 hours under an atmosphere of N2+10% H2. A second oil quench was performed after the annealing treatment.
Nitriding under an atmosphere made up of 50% NH3, 37.5% H2, and 12.5% N2 at a temperature of 520° C. for a duration lying in the range 101 hours to 113 hours was performed.
A 32CrMoV13 type nitriding steel in the annealed state was treated under the same conditions as in Example 1. The only difference lay in the fact that decarburizing was performed at a temperature of 980° C. and not at 950° C.
A 32CrMoV13 type nitriding steel in the annealed state was initially decarburized by treatment with an oxidizing atmosphere containing water vapor and presenting a dew point of 0° C. at a temperature of 950° C. for 6 hours.
After this decarburizing treatment, oil quenching was performed followed by annealing treatment at a temperature of 635° C. for 4 hours under an atmosphere of N2+10% H2. A second oil quench was performed after the annealing treatment.
Nitriding under an atmosphere made up of 50% NH3, 37.5% H2, and 12.5% N2 at a temperature of 550° C. for a duration of 55 hours was performed.
The term “including/comprising a” should be understood as “including/comprising at least one”.
The term “lying in the range . . . to . . . ” or “going from . . . to . . . ” should be understood as including the limits.
| Number | Date | Country | Kind |
|---|---|---|---|
| 1551179 | Feb 2015 | FR | national |
