Method of forming a hydroform

Abstract
A reinforced hydroform member having an outer structural member reinforced by a structural foam supported by the outer structural member. The structural foam extends along at least a portion of the length of the outer structural member. The structural foam is a heat-activated epoxy-based resin. As the foam is heated, it expands and adheres to adjacent surfaces. The preferred structural foam material is commercially available from L&L Products of Romeo, Mich. under the designation L5206, L5207, L5208, or L5209.
Description
FIELD OF THE INVENTION

The present invention relates generally to a heat-activated foam reinforced structural member. More particularly, the invention relates to a structural foam reinforced hydroform structures, wherein the structural foam becomes chemically active and expands upon heating.


BACKGROUND OF THE INVENTION

Traditionally, hydroforming techniques are used to draw and shape metal tubes. Conventional hydroforming techniques often involve two steps: (1) placing the desired bends in the tube and (2) forming the tube to the desired configuration. Step 2 usually requires placing a tubular member having an open bore in a mold and pinching off the ends of the tube. A pressurized liquid is injected into the open bore, causing the tube to stretch and expand out against the mold.


The advantage of the hydroforming process is that it allows formation of relatively long tubular structures having a seamless perimeter. This process eliminates the cost of welding or machining operations often used to shape the part in the desired configuration. As a result, a hydroform oftentimes has a high length to diameter ratio. For instance, a hydroform structure may have a length in excess of 15′ and a diameter ranging from approximately ¾ to more than 12″. It is not unusual for a hydroform structure to exceed the length of other tubular members, such as torsion bars or tubular bars, formed using other processes.


Additionally, hydroforms are complex structural shapes that typically include bends and contour changes. Often the number of bends and contour changes in a hydroformed bar are greater and more complex than those found in torsion bars or other tubular structures formed using different techniques.


Hydroform structures typically have a constant wall thickness prior to forming, and thus tend to develop weak spots at the site of bends or changes in contour, as well as at certain locations along a long tubular section. Thus, hydroform sections are generally reinforced to improve their structural stiffness and strength.


Traditional ways of reinforcing tubular structures such as hydroforms include sliding a metal sleeve inside the tube and welding the reinforcing member in place. However, because the hydroform often includes one or more bends or one or more changes in contour, it is often difficult to insert the sleeve into the hydroform at the site of weak spots. Other techniques include reinforcing the hydroform from the outside by welding the sleeve onto the outside of the hydroform. However, hydroforms are often used in applications having very close tolerances, resulting in little or no clearance for an externally placed reinforcing member.


Additionally, in many operations the weight of the tubular member is critical and must be kept low as possible. Thus, the use of an external sleeve adds unwanted weight to the tubular assembly. Finally, the welding operation tends to be labor intensive, time consuming and inexact, increasing the cost of forming the hydroform member and producing parts that have questionable reliability.


Consequently, there is needed a device and method for reinforcing the weak areas of hydroform tubes without significantly increasing the weight and manufacturing complexity.


SUMMARY OF THE INVENTION

The invention relates to a reinforced hydroform member. In one embodiment, the hydroform member includes an outer structural member having an open bore; and a structural foam supported by the outer structural member. The foam extends along at least a portion of the length of the outer structural member, and may fill at least a portion of the length of the bore.


The structural foam is generally and preferably a heat-activated epoxy-based resin. As the foam is heated, it expands and adheres to adjacent surfaces. The preferred structural foam material is commercially available from L&L Products of Romeo, Mich. under the designation L5206, L5207, L5208, or L5209.


In an alternative embodiment, the hydroform member includes an inner structural member having an open section, wherein the inner structural member is received in the bore of the outer structural member. The outer structural member and the inner structural member are fabricated of metal, and the structural foam extends along at least a portion of the length of the inner structural member and the outer structural member.


In still another embodiment, the reinforced hydroform includes an outer elongated tubular bar having a open center; an elongated inner tubular bar having an open bore coextensive therewith such that the inner tubular bar is received in the open center of the outer tubular bar so as to extend concentrically therewith; and a structural foam supported by the outer surface of the inner tubular bar, wherein the structural foam extends along at least a portion of the length of the inner structural member.


The reinforced hydroform may be formed by (1) providing an outer structural member having an open bore; (2) reinforcing the outer structural member by applying a structural foam thereto; (3) reshaping the outer structural member, causing the exterior surface of the outer structural member to assume a desired configuration; and (4) heating the structural foam to a temperature sufficient to cause the structural foam to expand and adhere to adjacent surfaces.


Where the hydroform includes a inner structural member, the method of forming the reinforced hydroform further includes the step of providing an inner structural member that is received in the open bore of the outer structural member so as to form a structural assembly. The structural assembly is reinforced by applying the structural foam thereto.





BRIEF DESCRIPTION OF THE DRAWINGS

The features and inventive aspects of the present invention will become more apparent upon reading the following detailed description, claims and drawings, of which the following is a brief description:



FIG. 1 is a perspective view of an automobile, showing a portion of the automobile frame reinforced by the hydroform member.



FIG. 2 is a perspective view showing a reinforced hydroform tube formed in accordance with the teachings of the present invention.



FIG. 3 is a section view of the hydroform tube described in FIG. 2, showing the position of the foam in the uncured state.



FIG. 4 is a section view of the hydroform tube described in FIG. 2, showing the position of the foam in the cured state.



FIG. 5 is a side section view showing the hydroform tube described in FIG. 2.





DESCRIPTION OF THE PREFERRED EMBODIMENT


FIG. 1 shows a reinforced hydroform member 10 formed in accordance with the teachings of the present invention. The hydroform member 10 imparts increased strength or stiffness to a structural member, and, thus, may be used in a variety of applications. For instance, the reinforced hydroform member 10 may be used as part of the frame system for automobiles or building structures.


The hydroform member 10 includes an outer metal tube 12 and an inner concentric tube 14. The outer tube 12 includes an open center and preferably has a seamless outer perimeter. Although FIG. 2 shows the tube 12 as having a circular cross-section and an open center, other geometric configurations having a continuous perimeter and an open portion therein may be used to form the tube 12. In the preferred embodiment, the outer tube 12 is fabricated of steel. However, it will be appreciated that other materials capable of plastic deformation may be used.


The physical dimensions of the outer tube 12 will vary depending on the intended use of the hydroform member 10. Where the hydroform member 10 is used as part of an automobile framing system, the outer tube 12 may have a length in excess of 15′ and an inner diameter typically ranging from approximately ¾″ to 12″. For an outer tube 12 having these dimensions, the outer tube 12 has a constant wall thickness prior to any deformation. The wall thickness of tube chosen will vary depending on the function and structure of the element being reinforced.


The inner tube 14 is received in the open center of the outer tube 12. Preferably, the inner tube 14 is concentrically received in the open center of the outer tube 12, and extends axially along the length of the outer tube 12 such that each end of the inner tube 14 is substantially flush with the respective ends of the outer tube 12.


In the preferred embodiment, the inner tube 14 has an open center and a seamless outer perimeter. Although FIG. 2 shows the tube 14 as having a circular cross-section and an open center, other geometric configurations having a continuous perimeter and an open portion therein may be used to form the tube 14. The preferred material from which to fabricate the inner tube 14 is steel. However, other materials capable of plastic deformation, particularly aluminum, may be used.


The physical dimensions of the inner tube 14 will vary depending on the intended use of the hydroform member 10. Where the hydroform member 10 is used as part of an automobile framing system, the inner tube 14 may have a length in excess of 15′. The inner diameter typically has a value ranging between approximately 1″ and 12″ and a constant wall thickness generally having a specific value ranging between 0.030″ and 0.30″.


As best seen in FIG. 2, the inner tube 14 supports a reinforcing structural foam 16 along at least a portion of the outer perimeter thereof. The primary purpose of the structural foam 16 is to increase the structural strength and stiffness of the components being reinforced. Typically, the structural foam 16 is applied to a carrier in the areas where reinforcement is needed. When dealing with hydroforms, the areas generally needing reinforcement are locations where the surface bends or changes contour. In the preferred embodiment, the structural foam 16 increases the compressive strength, bending strength, and structural stiffness of the hydroform 10 without adding significantly to the overall weight of the hydroform 10.


The structural foam 16 is preferably heat-activated and expands and cures upon heating, typically by a foaming and cross-linking reactions. The structural foam 16 is generally applied to the tube 14 in a solid or semi-solid state. The structural foam 16 may be applied to the outer perimeter of the tube 14 in a fluid state using commonly known injection techniques, wherein the structural foam 16 is heated to a temperature that permits the structural foam 16 to flow slightly. Upon cooling the structural foam 16 hardens and adheres to the outer surface of the tube 14. Alternatively, the structural foam 16 may be applied to the tube 14 as precast pellets, which are heated slightly to permit the pellets to bond to the outer surface of the tube 14. At this stage, the structural foam 16 is heated just enough to cause the structural foam 16 to flow slightly, but not enough to cause the structural foam 16 to thermally expand. Additionally, the structural foam may also be applied by heat bonding/thermoforming and by co-extrusion. Note that other expandable sheet materials can be used, such as, without limitation, an encapsulated mixture of materials that, when activated by temperature, pressure, chemically, or other by other ambient conditions, will expand.


The structural foam 16 is an epoxy-based material, but may include an ethylene copolymer or terpolymer, such as with an alpha-olefin. As a copolymer or terpolymer, the molecule is composed of two or three different monomers, i.e., small molecules with high chemical reactivity that are capable of linking up with similar molecules.


A number of epoxy-based structural reinforcing foams are known in the art and may also be used to produce the structural foam 16. A typical structural foam includes a polymeric base material, such as an epoxy resin or ethylene-based polymer which, when compounded with appropriate ingredients (typically a blowing agent and perhaps a curing agent and filler), expands and cures in a reliable and predictable manner upon the application of heat or another activation stimulus. The resulting material has a low density and sufficient stiffness to impart desired rigidity to a supported article. From a chemical standpoint for a thermally-activated material, the structural foam 16 is usually initially processed as a thermoplastic material before curing. After curing, the structural foam 16 typically becomes a thermoset material.


An example of a preferred structural foam 16 formulation is an epoxy-based material that may include an ethylene copolymer or terpolymer that is commercially available from L&L Products of Romeo, Mich., under the designations L5206,L5207, L5208 and L5209. One advantage of the preferred structural foam materials 16 over prior art materials is the preferred materials can be processed in several ways. The preferred materials can be processed by injection molding, extrusion or with a mini-applicator extruder. This enables the creation of part designs that exceed the capability of most prior art materials.


While the preferred materials for fabricating the structural foam 16 have been disclosed, the structural foam 16 can be formed of other materials provided that the material selected is heat-activated or otherwise activated by an ambient condition (e.g. moisture, pressure, time or the like) and expands in a predictable and reliable manner under appropriate conditions for the selected application. One such material is the epoxy based resin disclosed in U.S. patent application Ser. No. 09/268,810, the teachings of which are incorporated herein by reference, filed with the United States Patent and Trademark Office on Mar. 8, 1999 by the assignee of this application. Some other possible materials include, but are not limited to, polyolefin materials, copolymers and terpolymers with at least one monomer type an alpha-olefin, phenol/formaldehyde materials, phenoxy materials, and polyurethane materials with high glass transition temperatures. See also U.S. Pat. Nos. 5,766,719; 5,755,486; 5,575,526; 5,932,680 (incorporated herein by reference). In general, the desired characteristics of the structural foam 16 include high stiffness, high strength, high glass transition temperature (typically greater than 70 degrees Celsius), and good corrosion and humidity resistance properties.


In applications where a heat activated, thermally expanding material is employed, an important consideration involved with the selection and formulation of the material comprising the structural foam 16 is the temperature at which a material reaction or expansion, and possibly curing, will take place. For instance, in most applications, it is undesirable for the material to be active at room temperature or otherwise at the ambient temperature in a production line environment. More typically, the structural foam 16 becomes reactive at higher processing temperatures, such as those encountered in an automobile assembly plant, when the foam 16 is processed along with the automobile components at elevated temperatures or at higher applied energy levels. While temperatures encountered in an automobile assembly body shop may be in the range of 148.89° C. to 204.44° C. (300° F. to 400° F.), body and paint shop applications are commonly about 93.33° C. (215° F.) or slightly higher. If needed, blowing agents can be incorporated into the composition to cause expansion at different temperatures outside the above ranges.


Generally, prior art expandable foams have a range of expansion ranging from approximately 0 to over 1000 percent. The level of expansion of the structural foam 16 may be increased to as high as 1500 percent or more, but is typically between 0% and 300%.


The hydroform member 10 may be used in a variety of applications where structural reinforcement is desired. The hydroform member 10 has particular application in those instances where the overall weight of the structure being reinforced is a critical factor. For instance, the hydroform member may be used to increase the structural strength of aircraft frames, marine vehicles, automobile frames, building structures or other similar objects. In the embodiment disclosed the hydroform member 10 is used as part of an automobile frame to reinforce selected areas of the automobile frame.


As best illustrated in FIG. 1, the hydroform member 10 is coupled to the frame portion of an automobile frame assembly. The frame portion to be reinforced by the hydroform member 10 is illustrated by the phantom lines. It will be appreciated that the hydroform 10 may be used to reinforce other areas of an automobile frame.


Method of Forming the Hydroform 10

The method of forming the hydroform member 10 includes applying the structural foam 16 to the outer perimeter of the inner tube 14. The structural foam 16 is applied to the inner tube 14 using the techniques previously discussed.


The inner tube 14 is then received in the open center of the outer tube 12. The tube assembly 12, 14 is reshaped to include any desired bends, twists or contour changes. One particular method in which the tube assembly 12, 14 could be deformed is by first inserting the inner tube 14 into the outer tube 12 to be hydroformed and then bending the outer tube 12 to lock the inner tube 14 into place. After completion of the bending process, the tube assembly 12, 14 is placed in a mold and each end of the tube assembly 12, 14 is sealed using known techniques. For instance, an end cap (not shown) is inserted over each end of the tubular members 12, 14, and one end of a kick bolt (not shown) is coupled to one of the end caps and the other end to a fluid source under pressure.


Next, a hydroforming process is employed to reshape and to stretch the tubular assembly 12, 14 to the desired configuration. It will be appreciated that hydroforming, sometimes referred to as fluid forming or rubber diaphragm forming, is a known process for drawing and shaping metal components. The hydroforming process explained herein is for illustrative purposes only, and it will be appreciated that other hydroforming techniques may be used.


The hydroforming process employed in practicing this invention includes injecting a liquid under pressure into the open center of the tube 14 through the end cap. The fluid pressure causes the tube assembly 12, 14 to expand outwardly, bringing the exterior of the tube 12 into contact with the mold into which the tube assembly 12, 14 has been placed. Consequently, the exterior of the outer tube 12 is forced to assume the shape of the mold. The inner tube 14 can also be drawn during the hydroforming operation at locations wherein the outer tube 12 is also drawn. In other words, the inner tube 14 can be deformed in the same manner as the outer tube 12, whether through the initial bending process or through the subsequent drawing process that occurs during hydroforming. Once the hydroforming process is completed, the kick bolt (not shown) is removed.


Finally, after hydroforming the tube assembly 12, 14, the strength and stiffness of the hydroform 10 is increased by curing the structural foam 16. To cure the structural foam 16, the structural foam 16 is heated to a temperature sufficient to permit the structural foam 16 to expand and adhere to the inner surface of the outer tube 12. As the structural foam 16 is heated, it becomes chemically active and expands, forming a bond with the adjacent structure, the inner surface of the tube 12. The characteristics of the foam 16 can be provided by a separate adhesive layer in between the structural foam 16 and the inner surface of the tube 16, or it can be obtained from the formulation of the foam 16 itself.


During the curing cycle, the structural foam 16 is heated to a temperature higher than the temperature used during application of the foam material 16 to the tube 14. This higher temperature causes activation of the expansion and curing properties of the structural foam 16 by initiating chemical decomposition of the blowing agent and curing agent additives. FIG. 4 illustrates the position of the structural foam 16 after the curing cycle. As shown, the structural foam 16 adheres to the inner surface of tube 12 and the outer surface of tube 14. After the curing process, the end caps (not shown) are removed.


Upon cooling, the structural foam 16 stiffens and resists deformation during handling. Preferably, for cost and weight considerations, the structural foam 16 does not extend throughout the entire length of the tube assembly 12, 14. However, it will be appreciated that the structural foam 16 could be applied to the inner tube 14 so as to expand the entire length of the tubular assembly 12, 14.


Alternatively, the structural foam 16 may be applied to the tubular assembly 12, 14 using an extruder or injection process, wherein molten structural foam 16 is dispensed into key sections of the member to be reinforced. In this manner, the molten structural foam material 16 flows into the cavity to be reinforced. Another method for applying the structural foam 16 to the tubular assembly 12, 14 includes using structural foam 16 pellets. The pellets are inserted into the cavity between the tubes 12, 14 and cured as described above.


Preferably, the structural foam 16 is applied to the assembly 12, 14 at the location to be reinforced, which is generally at bends or locations where the surface contour changes. However, it will be appreciated that the structural foam 16 may be applied to the entire length of the hydroform 10 if desired.


The application of the structural foam 16 to the tube 14, increases the structural strength and stiffness of the tube 14. As a result, the overall structural strength and stiffness of the hydroform 10 is increased.


There are a variety of configurations that may be employed to fabricate a hydroform member 10. For instance, the hydroform 10 need not be fabricated as a tubular assembly but may comprise any configuration having a continuous perimeter and an open section therein. The disclosed embodiment is given to illustrate the invention. However, it is not intended to limit the scope and spirit of the invention. Therefore, the invention should be limited only by the appended claims.

Claims
  • 1. A method for forming a hydroform, comprising: providing a first tubular structure having an outer surface;disposing an adhesive structural material upon the outer surface with an applicator wherein the adhesive structural material includes epoxy;providing a second tubular structure having an inner surface defining a bore;hydroforming the first tubular structure while the adhesive structural material is located upon the outer surface thereby forming a hydroformed contour of the first tubular structure with the adhesive structural material located upon the contour; andadhering the adhesive structural material to the inner surface of the second tubular structure.
  • 2. A method as in claim 1 wherein the step of hydroforming occurs while at least a portion the first tubular structure and the adhesive structural material are located within the open bore of the second tubular structure.
  • 3. A method as in claim 1 wherein the adhesive structural material is epoxy-based.
  • 4. A method as in claim 1 wherein the second tubular structure is metal.
  • 5. A method as in claim 4 wherein the second tubular structure is formed of aluminum or steel.
  • 6. A method as in claim 1 further comprising: assembling the first tubular structure to a vehicle as a portion of a frame of the vehicle.
  • 7. A method as in claim 1 wherein the adhesive structural material is activated for curing at a temperature in the range of about 148.89° C. to about 204.44° C.
  • 8. A method as in claim 1 wherein the adhering step is performed prior to the step of hydroforming.
  • 9. A method as in claim 1 wherein the hydroforming includes injecting a liquid under pressure into the bore such that an outer surface of the first structure assumes a shape of a mold.
  • 10. A method for forming a hydroform, comprising: providing a first structure having an inner surface defining an open bore;providing a second structure having an outer surface;positioning an adhesive structural material within the open bore of the first structure between the inner surface defining the bore and the outer surface of the second structure;hydroforming the first structure and second structure while at least a portion of the structural material is located in the open bore wherein the hydroforming includes injecting a liquid under pressure into the bore such that an outer surface of the first structure assumes a shape of a mold; andadhering the adhesive structural material to the inner surface defining the bore and to the outer surface of the second structure.
  • 11. A method as in claim 10 wherein the first structure is tubular.
  • 12. A method as in claim 10 wherein the second structure is tubular.
  • 13. A method as in claim 10 wherein the step of positioning the adhesive structural material within the open bore of the first structure includes disposing the adhesive structural material upon the outer surface of the second structure.
  • 14. A method as in claim 10 wherein the adhesive structural material is expandable at a temperature greater than a glass transition temperature of the adhesive structural material.
  • 15. A method as in claim 10 wherein the adhesive structural is epoxy-based.
  • 16. A method as in claim 10 wherein the second structure is metal.
  • 17. A method as in claim 16 wherein the second structure is formed of aluminum or steel.
  • 18. A method as in claim 10 further comprising: assembling the first structure to a vehicle as a portion of a frame of the vehicle.
  • 19. A method as in claim 10 wherein the adhesive structural material is activated for curing at a temperature in the range of about 148.89°0 C. to about 204.44° C.
  • 20. A method as in claim 10 wherein the adhering step is performed prior to the step of hydroforming.
  • 21. A method for forming a reinforced hydroform automotive vehicle frame structure, comprising: providing an outer elongated metal tubular structure having an inner surface defining an open bore;providing an inner elongated metal tubular structure having an outer surface;applying an adhesive structural material to at least one of the inner surface defining the open bore and the outer surface of the inner tubular structure;introducing the adhesive structural material within a space defined between the inner surface of the outer tubular structure and the outer surface of the inner tubular structure; andhydroforming the outer tubular structure and the inner tubular structure with the adhesive structural material therebetween to form the automotive vehicle frame structure and for forming a first hydroformed contour in the inner tube and a second hydroformed contour in the outer tube wherein the first hydroformed contour is adjacent to and corresponding with the second hydroform contour and at least a portion of the expandable material is located between the first hydroformed contour and the second hydroformed; andbonding the adhesive structural material to at least one of the tubular structures wherein the bonding is performed prior to the step of hydroforming;wherein the hydroforming includes injecting a liquid under pressure into the bore such that an outer surface of the outer structure assumes a shape of a mold; andwherein the adhesive structural material is epoxy based.
  • 22. A method as in claim 21 wherein the adhesive structural material is expandable at a temperature greater than a glass transition temperature of the adhesive structural material.
  • 23. A method as in claim 21 wherein the outer tubular structure is formed of aluminum or steel.
  • 24. A method as in claim 21 further comprising: assembling the outer tubular structure to a vehicle as a portion of a frame of the vehicle.
Parent Case Info

This application is a continuation of and claim the benefit of the filing date of application Ser. No. 09/459,756 filed on Dec. 10, 1999, now U.S. Pat. No. 6,668,457.

US Referenced Citations (228)
Number Name Date Kind
1814677 Fennema Jul 1931 A
3025596 Ward et al. Mar 1962 A
3054636 Wessells III Sep 1962 A
3123170 Bryant Mar 1964 A
3400182 Kolt Sep 1968 A
3493257 Fitzgerald et al. Feb 1970 A
3615974 Graff Oct 1971 A
3649375 Venkatesan Mar 1972 A
3665968 DePutter May 1972 A
3746387 Schwenk Jul 1973 A
3757559 Welsh Sep 1973 A
3868796 Bush Mar 1975 A
3890108 Welsh Jun 1975 A
4019301 Fox Apr 1977 A
4029128 Yamagishi Jun 1977 A
4082825 Puterbaugh Apr 1978 A
4083384 Horne et al. Apr 1978 A
4090734 Inami et al. May 1978 A
4238540 Yates et al. Dec 1980 A
4378395 Asoshina et al. Mar 1983 A
4397490 Evans et al. Aug 1983 A
4440434 Celli Apr 1984 A
4457555 Draper Jul 1984 A
4463870 Coburn, Jr. et al. Aug 1984 A
4559274 Kloppe et al. Dec 1985 A
4598857 Matsui Jul 1986 A
4610836 Wycech Sep 1986 A
4613177 Loren et al. Sep 1986 A
4695343 Wycech Sep 1987 A
4705716 Tang Nov 1987 A
4732806 Wycech Mar 1988 A
4751249 Wycech Jun 1988 A
4762352 Enomoto Aug 1988 A
4769391 Wycech Sep 1988 A
4803108 Leuchten et al. Feb 1989 A
4810548 Ligon, Sr. et al. Mar 1989 A
4813690 Coburn, Jr. Mar 1989 A
4836516 Wycech Jun 1989 A
4853270 Wycech Aug 1989 A
4861097 Wycech Aug 1989 A
4864711 Yokota Sep 1989 A
4898630 Kitoh et al. Feb 1990 A
4901395 Semrau Feb 1990 A
4901500 Wycech Feb 1990 A
4908930 Wycech Mar 1990 A
4917435 Bonnett et al. Apr 1990 A
4922596 Wycech May 1990 A
4923902 Wycech May 1990 A
4946737 Lindeman et al. Aug 1990 A
4978562 Wycech Dec 1990 A
4984406 Friesen Jan 1991 A
4989913 Moore, III Feb 1991 A
4995545 Wycech Feb 1991 A
5040803 Cieslik et al. Aug 1991 A
5072952 Irrgeher et al. Dec 1991 A
5102188 Yamane Apr 1992 A
5122398 Seiler et al. Jun 1992 A
5124186 Wycech Jun 1992 A
5194199 Thum Mar 1993 A
5209541 Janotik May 1993 A
5213391 Takagi May 1993 A
5255487 Wieting et al. Oct 1993 A
5266133 Hanley et al. Nov 1993 A
5338080 Janotik et al. Aug 1994 A
5344208 Bien et al. Sep 1994 A
5358397 Ligon et al. Oct 1994 A
5373027 Hanley et al. Dec 1994 A
5382397 Turner, Jr. Jan 1995 A
5395135 Lim et al. Mar 1995 A
5474721 Stevens Dec 1995 A
5475911 Wells et al. Dec 1995 A
5506025 Otto et al. Apr 1996 A
5560672 Lim et al. Oct 1996 A
5575526 Wycech Nov 1996 A
5577784 Nelson Nov 1996 A
5580120 Nees et al. Dec 1996 A
5642914 Takabatake Jul 1997 A
5648401 Czaplicki et al. Jul 1997 A
5649400 Miwa Jul 1997 A
5652039 Tremain et al. Jul 1997 A
5660116 Dannawi et al. Aug 1997 A
5707098 Uchida et al. Jan 1998 A
5720092 Ni et al. Feb 1998 A
5725272 Jones Mar 1998 A
5731069 Delle Donne et al. Mar 1998 A
5755486 Wycech May 1998 A
5766719 Rimkus Jun 1998 A
5785376 Nees et al. Jul 1998 A
5786394 Slaven Jul 1998 A
5803533 Schulz et al. Sep 1998 A
5804608 Nakazato et al. Sep 1998 A
5806915 Takabatake Sep 1998 A
5806919 Davies Sep 1998 A
5819408 Catlin Oct 1998 A
5839777 Vlahovic Nov 1998 A
5851626 McCorry et al. Dec 1998 A
5855094 Baudisch et al. Jan 1999 A
5866052 Muramatsu Feb 1999 A
5871849 Lepine Feb 1999 A
5878784 Sales et al. Mar 1999 A
5884960 Wycech Mar 1999 A
5885494 Venkataraman et al. Mar 1999 A
5885688 McLaughlin Mar 1999 A
5888600 Wycech Mar 1999 A
5888642 Meteer et al. Mar 1999 A
5894071 Merz et al. Apr 1999 A
5901528 Richardson May 1999 A
5901752 Lundman May 1999 A
5902656 Hwang May 1999 A
5904024 Miwa May 1999 A
5931474 Chang et al. Aug 1999 A
5932680 Heider Aug 1999 A
5934737 Abouzahr Aug 1999 A
5941597 Horiuchi et al. Aug 1999 A
5984389 Nuber Nov 1999 A
5985435 Czaplicki et al. Nov 1999 A
5988734 Longo et al. Nov 1999 A
5992923 Wycech Nov 1999 A
5994422 Born et al. Nov 1999 A
6003274 Wycech Dec 1999 A
6004425 Born et al. Dec 1999 A
6006484 Geissbuhler Dec 1999 A
6009913 Kojima et al. Jan 2000 A
6016603 Marando et al. Jan 2000 A
6022066 Tremblay et al. Feb 2000 A
6033300 Schneider Mar 2000 A
6050630 Hochet Apr 2000 A
6053210 Chapman et al. Apr 2000 A
6058673 Wycech May 2000 A
6059342 Kawai et al. May 2000 A
6068424 Wycech May 2000 A
6073991 Naert Jun 2000 A
6077884 Hess et al. Jun 2000 A
6079180 Wycech Jun 2000 A
6082811 Yoshida Jul 2000 A
6090232 Seeliger et al. Jul 2000 A
6092864 Wycech et al. Jul 2000 A
6094798 Seeliger et al. Aug 2000 A
6096403 Wycech et al. Aug 2000 A
6096791 Born et al. Aug 2000 A
6099948 Paver, Jr. Aug 2000 A
6102379 Ponslet et al. Aug 2000 A
6102473 Steininger et al. Aug 2000 A
6103341 Barz et al. Aug 2000 A
6103784 Hilborn et al. Aug 2000 A
6110982 Russick et al. Aug 2000 A
6129410 Kosaraju et al. Oct 2000 A
6131897 Barz et al. Oct 2000 A
6135542 Emmelmann et al. Oct 2000 A
6146565 Keller Nov 2000 A
6148581 Separautzki Nov 2000 A
6149227 Wycech Nov 2000 A
6150428 Hanley, IV et al. Nov 2000 A
6152260 Eipper et al. Nov 2000 A
6153709 Xiao et al. Nov 2000 A
6165588 Wycech Dec 2000 A
6168226 Wycech Jan 2001 B1
6174932 Pachl et al. Jan 2001 B1
6183013 Mackenzie et al. Feb 2001 B1
6189953 Wycech Feb 2001 B1
6196621 VanAssche et al. Mar 2001 B1
6197403 Brown et al. Mar 2001 B1
6199940 Hopton et al. Mar 2001 B1
6216509 Lotspaih et al. Apr 2001 B1
6232433 Narayan May 2001 B1
6233826 Wycech May 2001 B1
6237304 Wycech May 2001 B1
6247287 Takabatake Jun 2001 B1
6253524 Hopton et al. Jul 2001 B1
6254488 Hill Jul 2001 B1
6263635 Czaplicki Jul 2001 B1
6270600 Wycech Aug 2001 B1
6272809 Wycech Aug 2001 B1
6276105 Wycech Aug 2001 B1
6276740 Mellor et al. Aug 2001 B1
6277898 Pachl et al. Aug 2001 B1
6281260 Hanley, IV et al. Aug 2001 B1
6287666 Wycech Sep 2001 B1
6296298 Barz Oct 2001 B1
6303672 Papalos et al. Oct 2001 B1
6305136 Hopton et al. Oct 2001 B1
6308412 Christofaro et al. Oct 2001 B1
6311452 Barz et al. Nov 2001 B1
6315938 Jandali Nov 2001 B1
6319964 Blank et al. Nov 2001 B1
6321793 Czaplicki et al. Nov 2001 B1
6332731 Wycech Dec 2001 B1
6341467 Wycech Jan 2002 B1
6348513 Hilborn et al. Feb 2002 B1
6358584 Czaplicki Mar 2002 B1
6368438 Chang et al. Apr 2002 B1
6372334 Wycech Apr 2002 B1
D457120 Broccardo et al. May 2002 S
6382635 Fitzgerald May 2002 B1
6383610 Barz et al. May 2002 B1
6389775 Steiner et al. May 2002 B1
6406078 Wycech Jun 2002 B1
6408515 Durand Jun 2002 B1
6413611 Roberts et al. Jul 2002 B1
6419305 Larsen Jul 2002 B1
6422575 Czaplicki et al. Jul 2002 B1
6435601 Takahara Aug 2002 B2
6467834 Barz et al. Oct 2002 B1
6471285 Czaplicki et al. Oct 2002 B1
6474722 Barz Nov 2002 B2
6474723 Czaplicki et al. Nov 2002 B2
6482486 Czaplicki et al. Nov 2002 B1
6486256 Tabutton et al. Nov 2002 B1
6502821 Schneider Jan 2003 B2
6561571 Brennecke May 2003 B1
6619727 Barz et al. Sep 2003 B1
6620501 Kassa et al. Sep 2003 B1
6634698 Kleino Oct 2003 B2
6641208 Czaplicki et al. Nov 2003 B2
6668457 Czaplicki Dec 2003 B1
6682818 Czaplicki et al. Jan 2004 B2
6692347 Schneider Feb 2004 B1
6729425 Schneider et al. May 2004 B2
6851232 Schwegler Feb 2005 B1
6928736 Czaplicki et al. Aug 2005 B2
20020053179 Wycech May 2002 A1
20020054988 Wycech May 2002 A1
20020066254 Ebbinghaus Jun 2002 A1
20020074827 Fitzgerald et al. Jun 2002 A1
20030001469 Hankins et al. Jan 2003 A1
20030050352 Guenther et al. Mar 2003 A1
20040074150 Wycech Apr 2004 A1
20040084141 Czaplicki May 2004 A1
Foreign Referenced Citations (105)
Number Date Country
2919046 May 1979 DE
3627725 Feb 1988 DE
90 11 147.8 Sep 1990 DE
40 28 895 Feb 1992 DE
42 27 393 Mar 1993 DE
93 20 333.0 Jun 1994 DE
19632275 Aug 1996 DE
19635734 Apr 1997 DE
196 44 047 May 1998 DE
196 48 164 May 1998 DE
198 12 288 May 1999 DE
19753658 Jun 1999 DE
29904705 Jun 1999 DE
198 56 255 Jan 2000 DE
198 58 903 Jun 2000 DE
0 061 131 Aug 1986 EP
0 236 291 Sep 1987 EP
0 414 302 Feb 1991 EP
0 611 778 Jan 1994 EP
0679501 Nov 1995 EP
0 697 956 Dec 1996 EP
0 775 721 May 1997 EP
0707695 Jun 1998 EP
0863358 Sep 1998 EP
0 891 918 Jan 1999 EP
0 893 331 Jan 1999 EP
0 893 332 Jan 1999 EP
0 893 332 Jan 1999 EP
0 453 777 Oct 1999 EP
1 122 156 Aug 2001 EP
1 362 683 Nov 2003 EP
1 362 769 Nov 2003 EP
1 366 960 Dec 2003 EP
1 484 162 Dec 2004 EP
1 508 508 Feb 2005 EP
1 555 191 Jul 2005 EP
61 118 211 Jun 1986 JP
01 069 309 Mar 1989 JP
01 164 867 Jun 1989 JP
02 206 537 Aug 1990 JP
5-38992 Feb 1993 JP
2001191947 Jul 2001 JP
02001191949 Jul 2001 JP
WO8701978 Apr 1987 WO
WO8906595 Jul 1989 WO
WO 9305103 Sep 1992 WO
WO 9502144 Jan 1995 WO
WO 9532110 May 1995 WO
WO9702967 Jan 1997 WO
WO9743501 Nov 1997 WO
WO9802689 Jan 1998 WO
WO9821060 May 1998 WO
WO9850221 May 1998 WO
WO9836944 Aug 1998 WO
WO9908865 Feb 1999 WO
WO9920516 Apr 1999 WO
WO9928575 Jun 1999 WO
WO9936243 Jul 1999 WO
WO9939882 Aug 1999 WO
WO9941468 Aug 1999 WO
WO9948746 Sep 1999 WO
WO9950057 Oct 1999 WO
WO 9961216 Dec 1999 WO
WO 9961236 Dec 1999 WO
WO9961237 Dec 1999 WO
WO9961281 Dec 1999 WO
WO9961289 Dec 1999 WO
WO9961719 Dec 1999 WO
WO 9964287 Dec 1999 WO
WO0003894 Jan 2000 WO
WO0012571 Mar 2000 WO
WO0013876 Mar 2000 WO
WO0013958 Mar 2000 WO
WO 0017000 Mar 2000 WO
WO9912595 Mar 2000 WO
WO0012595 Apr 2000 WO
WO0020483 Apr 2000 WO
WO0022024 Apr 2000 WO
WO0027920 May 2000 WO
WO0037230 Jun 2000 WO
WO0037239 Jun 2000 WO
WO0037241 Jun 2000 WO
WO0037242 Jun 2000 WO
WO0037243 Jun 2000 WO
WO0037302 Jun 2000 WO
WO 0037302 Jun 2000 WO
WO0037554 Jun 2000 WO
WO0038863 Jul 2000 WO
WO0039232 Jul 2000 WO
WO0040629 Jul 2000 WO
WO0041051 Jul 2000 WO
WO0041916 Jul 2000 WO
WO0043253 Jul 2000 WO
WO0043254 Jul 2000 WO
WO0046017 Aug 2000 WO
WO0046461 Aug 2000 WO
WO0052086 Sep 2000 WO
WO0055444 Sep 2000 WO
WO 0068041 Nov 2000 WO
WO0154936 Aug 2001 WO
WO0156845 Aug 2001 WO
WO0157130 Aug 2001 WO
WO0171225 Sep 2001 WO
WO0183206 Nov 2001 WO
WO 03042024 May 2003 WO
Related Publications (1)
Number Date Country
20040084141 A1 May 2004 US
Continuations (1)
Number Date Country
Parent 09459756 Dec 1999 US
Child 10696314 US