Claims
- 1. A method of producing a silazane containing at least two Si--N groups which comprises
- (a) providing a precursor containing at least one Si--N group, catalytically cleaving an Si--N bond in the presence of a metal catalyst capable of activating Si--N bonds, such cleavage being carried out in the presence of hydrogen or a hydrogen donor, and reacting the cleavage product to produce the desired silazane, or
- (b) providing one or more reactants which provide an Si--H group and an --NH group and causing reaction to occur between Si--H and --NH groups in the presence of a catalyst capable of activating Si--H and Si--N groups, such reaction resulting in formation of an Si--N group.
- 2. The method of claim 1 wherein the reaction is conducted under conditions to cause the initial product or products to undergo further reaction to provide other products.
- 3. The method of claim 2 wherein the reaction products are controllable by the choice and/or amount of catalyst.
- 4. The method of claim 2 wherein the reaction products are controllable by choice of temperature.
- 5. The method of claim 2 wherein the reaction products are controllable by the choice of solvent.
- 6. The method of claim 1 wherein the initial reaction product or products are the result of reaction of type (a) or of type (b) and further reaction of type (b) or type (a) is caused to ensue.
- 7. The method of claim 2 wherein the reaction is caused to proceed to the point of producing oligomeric or polymeric polysilazanes which are viscous liquids or solids at room temperature.
- 8. The method of claim 1 wherein the reaction is initially of type (a).
- 9. The method of claim 8 wherein the precursor is a cyclic silazane and the initial reaction product is a cleavage product resulting from cleavage of an Si--N group in the ring.
- 10. The method of claim 9 wherein further reaction of the initial product or products is caused to take place and such further reaction may be of type (a) or type (b) or both.
- 11. The method of claim 8 wherein the precursor is a linear silazane and the initial reaction product is a cleavage product resulting from cleavage of an Si--N group in the linear silazane.
- 12. The method of claim 11 wherein further reaction of the initial product or products is caused to take place and such further reaction may be of type (a) or type (b) or both.
- 13. The method of claim 1 wherein the reaction is initially of type (b).
- 14. The method of claim 13 wherein the Si--H group and the N--H group are present in different compounds.
- 15. The method of claim 13 wherein the Si--H and N--H groups are present in the same compound.
- 16. The method of claim 14 or claim 15 wherein further reaction of the initial product or products is caused to take place and such further reaction may be of type (a) or type (b) or both.
- 17. A method of preparing polysilazanes having the repeating structure I
- --Si--N-- I
- which comprises:
- (a) providing a starting material having the structure II in its molecule
- --Si--A II
- in which A is hydrogen, N< or Si--, structure II being part of a linear structure or part of a cyclic structure
- (b) providing a catalyst which is effective to activate Si--H, Si--N and/or Si--Si bonds, and
- (c) reacting the starting material in the presence of such catalyst with (1) hydrogen where A is nitrogen and structure II is part of a cyclic silazane or (2) with H--X--H in other cases, X being selected from the group ##STR20## R being hydrogen or an organic group or a silyl group (d) thereby forming a polymer having the repeating unit
- --Si--N--
- 18. The method of claim 17 wherein R is hydrogen or a hydrocarbon group.
- 19. The method of claim 17 wherein the catalyst is a homogeneous catalyst.
- 20. The method of claim 19 wherein the catalyst is a metal complex.
- 21. The method of claim 20 wherein the catalyst is a metal carbonyl cluster.
- 22. The method of claim 17 wherein the catalyst is a heterogeneous catalyst.
- 23. The method of claim 17 wherein the reaction is carried out in an organic solvent at a temperature of about 78.degree. to 250.degree. C.
- 24. The method of claim 17 wherein the starting material is a linear or cyclic silazane and it is reacted with hydrogen.
- 25. The method of claim 17 wherein the starting material is a linear or cyclic silazane and it is reacted with H--X--H.
- 26. The method of claim 25 wherein H--X--H is ammonia.
- 27. The method of claim 25 wherein H--X--H is a primary amine.
- 28. The method of claim 25 wherein H--X--H is hydrazine or a substituted hydrazine.
- 29. The method of claim 17 wherein the starting material is a cyclic compound containing an Si--Si bond in the ring and it is reacted with H--X--H.
CROSS REFERENCE TO RELATED APPLICATION
This application is a continuation-in-part of copending United States application Ser. No. 06/727,415, filed Apr. 26, 1985, now U.S. Pat. No. 4,612,383, entitled "METHOD OF PRODUCING POLYSILAZANES."
PCT Information
Filing Document |
Filing Date |
Country |
Kind |
102e Date |
371c Date |
PCT/US86/00458 |
3/4/1986 |
|
|
3/4/1986 |
3/4/1986 |
Publishing Document |
Publishing Date |
Country |
Kind |
WO86/06377 |
11/6/1986 |
|
|
US Referenced Citations (24)
Non-Patent Literature Citations (8)
Entry |
Blum and Laine, Organometallics 5: 2081 (1986). |
Fink, Walter, Helv. Chim. Acta 49:1408 (1966). |
Kono and Ojima, Organic Preparations and Procedures Int. 5 (3): 135-139 (1973). |
Kruger and Rochow, J. Polymer Sc. 2A: 3179:3189 (1964). |
Legrow et al., "Ceramics from Hydridopolysilazane", Mat. Res. Soc. Symp. Proc. 73: 553-558 (Apr. 1986). |
Sommer and Citron, J. Org. Chem. 32: 2470-2472 (1967). |
Zoeckler and Laine, J. Org. Chem. 48:2539-2543 (1983). |
Chem. Abs. 102: 224838s. |
Continuation in Parts (1)
|
Number |
Date |
Country |
Parent |
727415 |
Apr 1985 |
|