The present disclosure is concerned with a method of gluing a first metal part to another part such as a second metal part, where at least a surface portion of the first metal part is treated with laser pulses to activate the outer metal surface prior to applying an adhesive.
It is known to prepare a surface portion of a first metal part intended for being glued to another part with laser pulses to remove contaminants on the surface of the metal surface and to activate the metal surface so that a glue will better adhere to the metal surface. Document EP 3 792 323 A1 generally describes such a gluing method.
There is a general desire to improve a gluing method comprising the treatment of a metal surface with laser pulses, specifically to improve such a gluing method with respect to the resulting purity of the activated metal surface and to improve the endurance of the adhesive connection.
In accordance with at least one aspect a method of gluing a first metal part to another part is proposed that includes the steps of (a) providing a first metal part such as a steel part, and another part such as a second metal part, (b) treating a surface portion of the first metal part intended for being glued to the other part with laser pulses so that a surface layer of the first metal part across the surface portion is removed, preferably by ablation, (c) while applying laser pulses to the surface portion of the first metal part also applying a pressurized air or gas stream to the surface portion, (d) applying an adhesive to at least the surface portion of the first metal part and/or to a surface of the other part, and (e) gluing the first metal part and the other part together.
In accordance with at least one aspect a method of manufacturing a personal care device including the step of gluing a steel shaft into a metal cap, the method comprising the steps of (a) providing the steel shaft and the metal cap sized to receive at least a tip region of the steel shaft, (b) treating a surface portion of the steel shaft intended for being glued to the metal cap with laser pulses so that a surface layer from the steel shaft across the surface portion is removed, preferably by ablation, (c) while treating the surface portion of the steel shaft with the laser pulses also applying a pressurized air or gas stream to the surface portion, (d) treating at least a portion of an inner surface of the metal cap intended for being glued to the respective surface portion of the steel shaft with laser pulses, (e) applying an adhesive to the surface portion of the steel shaft and/or to the portion of the inner surface of the metal cap, and (f) fitting the metal cap onto the steel shaft and curing of the adhesive.
The present disclosure will be further elucidated by a detailed description of example embodiments and with reference to figures. In the FIGS.
While it has been contemplated to perform laser pulse treatment of metal surfaces under a suction hood or a more locally provided exhaustion system to remove metal vapors, i.e., small metal particles created in the laser pulse-induced ablation process and to avoid that metal vapor containing air pollutes the environment, it was found that even a strong exhaustion system is not able to reliably remove metal vapor or particulate metal material from a treatment volume, where treatment volume means at least the volume around a surface portion of a first metal part that is being treated with laser pulses and that typically gets polluted with metal vapor. The metal particles and/or metal ions of the metal vapor thus can eventually redeposit on the just ablated metal surface, which leads to reduction in the purity of the ablated metal surface and thus to a reduced adherence of glue to the re-contaminated metal surface. It was found that such redeposition, while basically relevant for all metal surfaces, becomes specifically troublesome for steel surfaces, which is believed to be due to the chromium content of steel.
In accordance with the present disclosure, a pressurized air or gas stream is directed to the surface portion of the first metal part that is being treated with laser pulses, e.g., to the surface portion where surface areas are ablated by laser pulses. The pressurized air or gas stream tends to carry away the metal vapor and the particulate metal matter that become ejected into the surroundings, i.e., into the treatment volume, from the treated surface portion by the effects of the ablating laser pulses, which, depending on the pulse length and the applied energy may be considered as causing sublimation and melting of surface layers. Due to the sudden sublimation and melting, atoms and particulate matter in the micrometer and sub-micrometer range is catapulted into the treatment volume around the surface portion being treated. The gaseous and particulate components may create a plasma that shields the surface portion being treated by laser pulses and some of the laser energy may become absorbed by the plasma and thus the ablation process may become diminished. Further, the particulate matter may impact onto the ablated surface again and may then cause recontamination of the activated metal surface. It was found that recontamination in general and for a first metal part made of steel specifically recontamination comprising chromium causes loosely adhering recontamination areas that may cause breaking points for the glue being applied to the ablated surface. It was identified that the application of a pressurized air or gas stream to the treated surface portion can considerably improve the resulting purity of the ablated surface portion and the probability that metal particles become deposited on the ablated metal surface is reduced as the metal particles are carried away by the pressurized air or gas stream. The glued together parts endure much higher stress then glued together part where no pressurized air or gas stream was applied, which is discussed below.
An “air or gas stream” in accordance with present disclosure means a stream of regular air or a stream of an inert gas such as nitrogen and/or argon and mixtures of air and purified inert gases may be considered as well.
While in the present disclosure the term “adhesive” shall mean all adhesives that are suitable for gluing a first metal to another part, specifically a second metal part, one example adhesive is DELO DUPOPDX CR8016 available from company DELO Industrie Klebstoffe GmbH & Co. KGaA, Windach, Germany.
With hindsight it may sound obvious to apply a pressurized air or gas stream to a currently being laser-ablated metal surface, but it indeed was a lengthy process to understand the lack of expected adherence between the finally glued together parts when a pressurized air or gas stream was not applied. This was specifically the case as such lack of expected adherence only showed up for a small fraction of glued metal parts in the practical example that is exemplified further below in
Various parameters of the air or gas stream were investigated with respect to the quality of the ability of the air stream to carry away the metal vapor and/or particulate matter around the surface portion being treated, i.e., from the treatment volume, and to thus reduce the recontamination of the just activated metal surface. Air or gas stream parameters that were investigated are the following: velocity of the air or gas at the surface portion being treated, velocity of the air or gas at the outlet of a pressure nozzle, distance of the pressure nozzle to the surface portion being treated, amount of air or gas delivered by the pressure nozzle (also known as air flow volume), shape of the pressure nozzle, and orientation and/or position of the pressure nozzle relative to the treated surface portion. These air or gas stream parameters are discussed in more detail in the following.
Metal particles created in the laser pulse-induced ablation process tend to have velocities that can extend into the sonic and supersonic range, where it is understood that the speed of sound is 343 m/s in air at 20 degrees Celsius.
It was found that a velocity of the pressurized air or gas stream at the surface portion being treated with a laser being in the range of the velocity of the particulate matter in the treatment volume may cause a more prominent reduction of recontamination than velocities being higher or much lower. A velocity of the pressurized air or gas stream at the surface portion being treated in a range of between 80 m/s and 400 m/s has been found to be effective.
The pressurized air or gas stream or jet is typically delivered by a pressurized air or gas delivery system, e.g., a compressed air or gas reservoir. The pressurized air or gas stream is typically exiting the pressurized air or gas delivery system via a pressure nozzle. It was also found that a velocity of the pressurized air or gas delivery system at the pressure nozzle may be in a range of between 100 m/s and 700 m/s. The pressurized air or gas may have a compression in the range of between 1 bar to 6 bar (these values mean the compression above atmospheric pressure), where the compression may preferably be in a range of between 2 bar and 5 bar. The pressurized air or gas stream may be directed towards the surface portion of the first metal part that is being treated with laser pulses. It was found that a pressure nozzle having an exit shape, i.e., the shape of the air or gas outlet, so that the pressurized air or gas stream impinging onto the surface portion being treated has about a cross-sectional shape that follows the shape of the surface portion tends to lead to improved adhesion results. It is believed that this can be assigned to a more constant static pressure of the pressurized air or gas stream over the surface portion being treated. Specifically, the static pressure of the pressurized air or gas stream over at least 50% of the surface portion is not deviating from a mean static pressure value in the at least 50% of the surface portion by more than about ±20%, preferably by more than about ±15%. The surface portion being treated may specifically relate to the length of a laser pulse line. It can be assumed that the surface portion being treated has a certain area that may be covered by abutting or slightly overlapping laser pulses. E.g., a single laser pulse may be circular and may have a diameter of 50 μm and a pulse length in the nanosecond to femtosecond range. The pulses may be applied at a frequency of 400 kHz. The pulses along a laser line of pulses may then have a center-to-center distance of 20 μm. A line of pulses having a length of 10 mm can thus be applied in 1/800 second. That means that an area of 1.6 mm2 can be treated within a second (ignoring any time that is needed to turn the laser beam, which is typically done by mirrors). That means that the surface region being treated has a length extension that is defined by the laser line length. As mentioned, it seems to be beneficial to use a pressurized air or gas stream that covers the full length of the laser line. The pressurized air or gas stream may also cover the width of the total surface portion to be treated, but in order to limit the need for pressurized air or gas one can also limit the width of the pressurized air or gas stream and then either the pressurized air or gas stream may be arranged to follow the laser in width direction or the first metal part may be moved to keep the currently being treated surface portion inside the cross-section of the pressurized air or gas stream. In case that the first metal part has a total surface portion to be treated that extends circumferentially around the first metal part, the first metal part may be rotated so that the currently being treated surface portion stays within the cross-section of the pressurized air or gas stream. The width of the pressurized air or gas stream may then be chosen to be larger than the width of the rotating first metal part so that the pressurized air or gas stream can carry metal vapor and particulate matter around the first metal part where the pressurized air or gas stream together with the carried along metal vapor and particulate matter is eventually exhausted by an exhaustion system.
It was found that it is sensible to place the pressure nozzle having an air or gas outlet at a distance to the surface portion being treated in the range of between 4 mm and 20 mm, preferably in a range of between 8 mm and 16 mm, where the distance is measured between a central point of the air or gas outlet and a central point of the surface portion. It may be sensible to try to place the pressure nozzle as close to the first metal part as possible as the velocity of the pressurized air or gas stream reduces the longer the distance is. The pressure nozzle cannot be placed in the laser path but can be placed at any side with respect to the surface portion being treated, where it may be preferred to place it underneath or above the surface portion being treated, where underneath or above shall mean with respect to the line of laser pulses that is applied onto the surface portion.
In case that the total surface area to be treated with laser pulses is curved, e.g., if the total surface area is a surface of a metal shaft that circumferentially extends around the shaft, either the laser may be moved around the first metal part or the first metal part may be moved, e.g., rotated. That implies that the pressurized air or gas stream does not need to cover the complete total surface area that is intended to be treated with laser pulses but that it is sufficient to have the pressurized air or gas stream impinge onto the surface portion that is currently being treated. That means that in case the currently being treated surface portion is longer in one direction than in a perpendicular direction, then the nozzle may have an essentially oval or generally elongated shape, where the long axis of the oval or elongated shape may coincide with the longer extension of the currently being treated surface portion.
The exhaustion system, e.g., a double horn exhaustion system enveloping the treatment area, may have a suction power in a range of between 500 l/min to 3000 l/min, i.e., a suction power that may be higher and even considerably higher than the air flow provided by the pressurized air or gas stream.
In a practical example, the first metal part is a steel shaft of a personal care device, and the other part is a second metal part, namely a metal cap. The steel shaft may be treated by laser pulses on a total surface area that may circumferentially extend around the steel shaft. In addition to the laser pretreatment, the first metal part in general may be pre-treated first by another method such as plasma pretreatment to immobilize volatile organic compounds on the surface of the metal part. Specifically, a turned and polished metal shaft may still comprise volatile organic compounds on its surface and their immobilization prior to the activation of the metal surface by laser ablation supports keeping the activated surface portion free from contamination. This is of course true for all first metal parts independent from a realization as a steel shaft. The steel shaft may be made from a standard stainless steel and may thus comprise a certain percentage of chromium, e.g., more than 10.5% by weight. The metal cap may as well be made from a standard stainless steel, specifically in a deep drawing process as is generally known in the art. While an inner surface portion of the metal cap may also be pretreated prior to gluing, e.g., by a plasma pretreatment and/or by a laser pretreatment, this should not be considered mandatory. As is exemplified in the description with respect to
Generally, it is referred to document EP 3 792 323 A1, which shall be incorporated herein by reference, with respect to details of a metal gluing process comprising femtosecond laser pulse pre-treatment and an optional plasma pretreatment.
Table 1 below lists the relevant values for an ultra-fast laser pulse pre-treatment as one example and some ranges are provided that are considered as sensible, even though the below table shall not exclude values outside of the proposed ranges to be used as well. Overall, the values may be varied to some extent if the light fluence stays within the proposed range. It is reiterated that the herein proposed application of a pressurized air or gas stream is also sensible for longer or even shorter laser pulse lengths.
A qualitative test method was developed to investigate the strength of the adhesive connection between the first metal part and the other part and was specifically used to test the strength of the adhesive connection between the steel shaft and the metal cap. In this test method a hammer was pivotably mounted at an end of its shaft and the hammer was deflected until a predetermined stopper had been reached and then the hammer was released, became accelerated by gravitation, and hit the metal cap/steel shaft element. Between each stroke the metal cap/steel shaft element was rotated around its longitudinal axis by about 20 to 30 degrees. Metal cap/steel shaft elements manufactured with the described method but without the additionally applied pressurized air or gas stream withheld up to about 110 hammer strokes from a sample size of 30 and those metal cap/steel shaft elements made with the applied pressurized air or gas stream withheld at least about 200 hammer strokes from a sample size of 30. In these hammering tests it was also found that for the metal cap/steel shaft elements made without the pressurized air or gas stream the breakage typically appeared at the border between the adhesive and the steel, i.e., once the metal cap could be separated from the steel shaft with a manual force, essentially no adhesive residues adhered to the steel shaft. In contrast, for the metal cap/steel shaft elements made with the pressurized air or gas stream, the breakage typically occurred within the adhesive, i.e., adhesive residues remained on the steel shaft once the metal cap could be separated from the steel shaft using a manual force. This showed that the surface adhesion between the adhesive and the steel surface was considerably improved when applying a pressurized air or gas stream in the manufacturing method.
It is believed that the effect of the pressurized air or gas stream will also be present for other laser pulse lengths above femtosecond laser pulses, e.g., for picosecond or nanosecond laser pulses and also for attosecond laser pulses.
The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.”
Every document cited herein, including any cross referenced or related patent or application and any patent application or patent to which this application claims priority or benefit thereof, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
Number | Date | Country | Kind |
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22173033.6 | May 2022 | EP | regional |