The present disclosure is concerned with a method of gluing a metal part to another part and which method in particular comprises a pre-treatment of the surface portion of the metal part to be glued to another part by applying laser pulses.
It is known that a surface portion of a metal part that shall be glued to another part can be pretreated to enable a more durable adhesive bond. Such pretreatment may be cleaning of the metal surface with an alcoholic liquid, e.g. isopropanol. It may alternatively be ablating a surface layer of the metal surface, which surface layer comprises contaminants such as volatile organic compounds, e.g. oil, and a reaction layer that together deteriorate the durability adhesive joint.
DE102009017492A1 generally discusses a pretreatment of a metal surface intended for being glued to another metal surface by means of nanosecond or picosecond laser pulses, e.g. with laser pulses having a length in the range between one and several hundred picoseconds.
It was found that such adhesive bonds, in particular if they are exposed to repeating mechanical stress and/or certain aggressive chemicals such as essential oils, do not always show the needed durability. Such described repeating mechanical load and/or aggressive chemical environment may occur, e.g., for personal care devices such as electric toothbrushes.
It is thus an object of the present invention to provide a method for gluing a metal part to another part that results in improved durability of the adhesive connection, in particular where the adhesive connection is subjected to a repeating load and/or where the adhesive connection becomes exposed to a wet environment comprising essential oils.
In accordance with one aspect a method is provided for gluing a metal part to another part, the metal part and the other part in particular intended for being used in a personal care device such as an electric toothbrush, wherein the method comprises the steps of providing a metal part, in particular a steel part, and another part, in particular another metal part; treating a surface portion of the metal part intended for being glued to the other part with ultra-fast laser pulses having a pulse length in the femtosecond range, in particular in the range of between 1 to 990 femtoseconds, so that a surface layer of the metal surface is removed; applying an adhesive to the treated surface of the metal part or to a surface of the other part; and gluing the metal part and the other part together.
In accordance with one aspect, a method is provided for manufacturing a personal care device, the method comprising the step of gluing a steel shaft into a metal cap, the method further comprising the steps of: providing the steel shaft and the metal cap sized to receive at least a tip region of the steel shaft; treating a surface portion of the steel shaft intended for being glued to the other part with ultra-fast laser pulses having a pulse length in the femtosecond range, in particular in the range of between 1 to 990 femtoseconds, so that a surface layer from the metal surface is removed; treating at least a portion of an inner surface of the metal cap intended for being bonded with the respective surface portion of the steel shaft with fast or ultra-fast laser pulses; applying an adhesive to the treated surface portion of at least one of the steel shaft and the metal cap; and fitting the metal cap onto the steel shaft and curing of the adhesive.
In the context of the present description, “personal care” shall mean the nurture (or care) of the skin and of its adnexa (i.e. hairs and nails) and of the teeth and the oral cavity (including the tongue, the gums etc.), where the aim is on the one hand the prevention of illnesses and the maintenance and strengthening of health (“care”) and on the other hand the cosmetic treatment and improvement of the appearance of the skin and its adnexa or of the teeth and the oral cavity. It shall include the maintenance and strengthening of wellbeing. This includes skin care, hair care, and oral care as well as nail care. This further includes grooming activities such as beard care, shaving, and depilation. A “personal care device” thus means any device for performing such nurturing or grooming activity, e.g. (cosmetic) skin treatment devices such as skin massage devices or skin brushes; wet razors (with or without electronic or electric components such as a vibration device); electric shavers or trimmers; electric epilators; and oral care devices such as manual or electric toothbrushes, (electric) flossers, (electric) irrigators, (electric) tongue cleaners, or (electric) gum massagers. This shall not exclude that the proposed personal care device may have a more pronounced benefit in one or several of these nurturing or device areas than in one or several other of these areas.
In accordance with the present description, a metal part that shall be adhesively bonded with another part, in particular another metal part, is pretreated with ultra-fast laser pulses in the femtosecond range. It had been found that femtosecond laser pulses ablate contaminant and oxide layers (together forming the “surface layer”) from the metal surface while the creation of heat affected zones is reduced, which provides a high wettability of the then activated metal surface so that an adhesive applied on the pre-treated surface will easily spread and contact the whole pretreated surface.
The herein described method of gluing a first metal part to another part had been identified by investigating improvements of adhesive metal bonding technologies in particular with a view on improved durability under recurring mechanical stress and alternatively or additionally with a view on a chemically relatively aggressive environment that in particular comprises essential oils or alcohols, such as would occur during use of a personal care device like an electric toothbrush. E.g. drive shaft parts that are coupled with a replaceable functional head to drive the functional head into motion typically have to endure cyclic load (i.e. repeating load) and may also get exposed to a saliva-toothpaste mixture (most toothpastes comprise one or several essential oils). Particularly suitable method steps were identified that individually tend to provide an improvement of the mentioned durability of the adhesive bond and that tend to show further improvement of the durability when used in combination. The surface purity (i.e. the pure active metal surface without contaminants and without passivation layers) is in particular of relevance if steel shall be bonded by means of an epoxy resin. It was found that chemical activity of the surface is in particular of high relevance in the presence of volatile organic compounds.
For example, it is known to clean metal surfaces with laser pulses, but it had so far not been reported to make use of laser pulses in the femtosecond range, i.e. laser pulses as short as 1 femtosecond to 999 femtoseconds, in particular in the range of below 990 fs, and further in particular in the range of below 950 fs, further in particular in the range of below 940 fs or 930 fs or 920 fs or 910 fs. A pulse length of about 900 fs may be considered. A lower range limit may be set to 50 fs or 100 fs or 200 fs or 300 fs or 400 fs or 500 fs or 600 fs or 700 fs or 800 fs. This shall not exclude any value in between the given examples. The ultra-fast laser pulses in the femtosecond range tend to sublimate the irradiated material due to the fast deposition of energy in the material. In contrast to longer laser pulses applying the same energy, where the material heats and melts, where so-called heat affected zones (HAZ) are generated, the femtosecond pulses lead to a different material ablation process with a reduced generation of observable HAZ. It is believed that this has a positive influence on the durability of the adhesive connection between the metal surface and the adhesive.
It has further been found that a metal part that may be used in a personal hygiene device may be contaminated with volatile organic compounds such as oil. While it is usually believed that pre-treatment of a metal surface with a laser ablation technique is sufficient to lay open an active metal surface for further bonding/gluing, it was found that the strongly increased wettability of such a pre-treated metal surface, in particular if pre-treated with ultra-fast laser pulses, leads to a wetting of the activated surface by volatile organic compounds present on the non-pre-treated surface portions adjoining the pre-treated surface portion in a short timeframe. Such fast contamination of the activated metal surface with volatile organic compounds leads to a problematic decrease of the long-term durability of the adhesive connection.
In contrast to known metal-surface pre-treatment techniques that involve only one treatment step, an additional pre-treatment with an air-pressure plasma is additionally proposed, which plasma pre-treatment in particular is performed prior to the laser pre-treatment. In particular, the plasma pre-treatment covers surface portions of the metal part that are adjoining the surface portion that will be pre-treated by laser ablation so that the volatile organic compounds on these later adjoining surface portions that are not removed become immobilized and cannot easily migrate to the laser pre-treated surface portion. The plasma pre-treatment cleans the surface on the one hand and on the other hand immobilizes remaining volatile organic compounds, e.g., by polymerizing and cracking of oil-based contaminants.
Thus, while the laser-pretreatment removes to some extent the active surface layer that remains after plasma cleaning, the plasma-pre-treatment at least reduces the contamination of the laser treated surface with remaining volatile organic compounds if the plasma pre-treatment has covered a surface area larger than the surface portion that is treated by ultra-fast laser pulses. As plasma pre-treatment and laser ablation pre-treatment have so far only be used in isolation and combination of both had been considered as economically inefficient and non-synergistic. The combination of both processes in the manner as discussed is considered a relevant and unusual step in accordance with the present disclosure. The immobilization of volatile organic compounds outside of the area that is pre-treated with femtosecond laser pulses by plasma treatment increased the durability of the adhesive connection under the mentioned circumstances even beyond the durability of only femtosecond laser pulse pre-treatment.
For sake of completeness, it is mentioned that also the other part, in particular if the other part is a metal part as well, may as well be treated by a combination of a preceding plasma pre-treatment and a subsequent laser pulse pre-treatment.
The metal part that is pre-treated with ultra-fast laser pulses may comprise a cylindrical section having an outer cylindrical surface that shall be pre-treated. E.g. the metal part may be a drive shaft of a motor that shall be used in a personal care device such as an electric toothbrush. In order to pre-treat the outer cylindrical surface of the metal part, the metal part may be rotated around the center axis of the cylindrical section. By way of example, it is assumed that the cylindrical section has a diameter of 3 mm and a height of 10 mm. The circumference of the cylindrical section is then 9.42 mm. A laser pulse having a diameter of 50 μm may be used so that by applying 250 overlapping parallel lines of laser pulses in length direction, the outer cylindrical surface of the example cylindrical section can be completely covered (the laser pulses would have a distance of about 37.7 μm in circumferential direction).
The laser pulses may be applied at a frequency of about 400 kHz and with a laser feed speed of 8000 mm/s. Laser pulses applied in length direction will then have a distance of 20 μm. Due to the overlap in length direction and also in circumferential direction, the total overlap of the laser pulse is about 70%. In the present example, a rotation of the cylindrical section around its length axis may be done at about 180 rotations/minute during the laser pre-treatment, which means that the laser beam having a feed speed of 8,000 mm/s generates laser treated lines on the metal part having a distance of about the 37.7 μm as previously mentioned.
In order to counteract the rotation of the cylindrical section, the laser may be scanned along a path that is not straight but that has a sand-clock type of shape, where the long extension of the sand-clock may be 10 mm or more in the present example and the small extension may be about 37 μm. If the laser were scanned long a straight line up and down, the laser ablation lines would follow a serrated path on the rotating cylinder section, which would cause a very strong overlap of the laser pulses at the respective tips of the serrated line. Counteracting the rotational motion by the sand-clock type path and moving the laser spot by the about 37 μm at the turning points essentially leads to straight and parallel laser ablation lines on the rotating cylindrical section.
In some embodiments, the cylindrical section of the pre-treated metal part represents an end portion of the metal part. The laser beam may then be scanned beyond the end of the cylindrical section, which longer way (e.g. in the example beyond the 10 mm) is then to be considered for the small distance motion, which would then be somewhat larger than the mentioned 37 μm. It is noted that the values discussed herein are just provided as an example and that the treated metal part may have any other geometry.
The energy applied per laser pulse may be set to 50 μJ, which means an average power of the laser of 20 W at a pulse frequency of 400 kHz. Generally, a Nd: YAG USPL laser may be used, which has a wavelength of 1030 nm. This shall not exclude that a laser source may be used having any other wavelength, in particular a wavelength in the range of between 930 nm and 1064 nm.
The application of ultra-fast laser pulses in essentially partially overlapping and essentially parallel lines leads to the formation of laser induced periodic surface structures (LIPSS). The laser may be linearly polarized. The LIPSS may have a spatial period of about the wavelength of the laser light (in the example thus a spatial period of about 1 μm). It is believed that these LIPSS tend to improve the durability of the adhesive bond that will form between the metal surface and the adhesive.
Table 1 lists the relevant values for the ultra-fast laser pulse pre-treatment and some ranges are provided that are considered as sensible, even though the below table shall not exclude that values outside of the proposed ranges can be used as well. Overall, the values may be varied rather to some extent as long as the light fluence stays within the proposed range.
In some embodiments, the metal part is a metal shaft, in particular a steel shaft, that is glued into a metal cap as other part. In this bonding process, a further element may be fixed in the metal cap, where the further element may be a permanent magnet such as a permanent magnet disk.
Generally, a primer such as a silane primer may be applied to the surface of the metal part (and additionally also to the surface of the other part) after the surface treatment with laser pulses, e.g. DELO SACO SIL E® available from company DELO Industrie Klebstoffe GmbH & Co. KGaA, Windach, Germany.
In the schematic depiction of
In
In the schematic depiction of
A portion of the previously plasma-treated surface of the metal part 10 is not treated with laser pulses, namely surface portions 12 and 13 that are adjoining the surface portion 11 that is treated with laser pulses. Surface portions 12 and 13 may comprise immobilized volatile organic compounds 14 and an activation due to the plasma treatment. As was already explained, this pre-treatment sequence as explained with reference to
In the schematic depiction of
The schematic depiction of
The schematic depiction of
It can be seen that the treatment of the shaft surface with femtosecond laser pulses (a pulse length of 900 fs was used) improved the durability well above the durability obtained with nanosecond laser pulse treatment. The additional pre-treatment with a plasma as explained with respect to
The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.”
Every document cited herein, including any cross referenced or related patent or application and any patent application or patent to which this application claims priority or benefit thereof, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
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