This application is a National Stage of International Application No. PCT/JP2022/002030 filed Jan. 20, 2022, claiming priority based on Japanese Patent Application No. 2021-009143 filed Jan. 22, 2021.
The present invention relates to a method of installing a heat insulating block on a furnace shell, a method of manufacturing a heat insulating wall, a heat insulating wall, an industrial furnace, and a set for installing a heat insulating block.
A heat resisting concrete called a castable is conventionally used for forming a heat insulating wall over an inner face of a steel shell of a heating furnace or the like. In recent years, instead of a castable, a heat insulating material made from an inorganic fiber having fire resistance and heat insulating properties is lined in view of workability for a heat insulating wall and in view of strength of a formed heat insulating wall.
Examples of the method of forming a heat insulating wall with a heat insulating material made from an inorganic fiber include: the paper lining of stacking inorganic fiber mats in parallel to a furnace shell (face of a steel shell), and fixing the mats with studs that are provided perpendicularly to the furnace shell: the stack lining (so-called H anchoring) of stacking inorganic fiber mats perpendicularly to a furnace shell, and fixing the mats with metal fixtures that are fixed perpendicularly to the furnace shell, and rods that are fixed to these metal fixtures and that penetrate through the mats in parallel to the furnace shell; and the modular method of fitting a heat insulating block to a stud that is provided perpendicularly to a furnace shell via a fitting for fixing a heat insulating block (hereinafter may be referred to as “metal fixture for a block”): the heat insulating block is formed by making an inorganic fiber mat a block, and installing the metal fixture for a block on one face of the block (for example, Patent Literature 1).
Among them, the stack lining has advantages of fast construction, and low manufacturing costs for blocks. The stack lining leads to, however, a structure of horizontally skewering inorganic fiber mats with rods, in short, a structure of supporting inorganic fiber mats with rods at points. Thus, metal fixtures cannot sufficiently support inorganic fiber mats, which is problematic and which causes a problem of the inorganic fiber mats falling off from a furnace shell (ceiling in particular), or some space generated between the inorganic fiber mats and the furnace shell. At a construction site, the places to be horizontally skewered at inorganic fiber mats depend on a constructor. These places may be slightly different from the right places, and thus, the precision of the construction becomes poor, which is problematic.
The modular method leads to a structure of supporting inorganic fiber mats with beams on faces, which enables the inorganic fiber mats to be firmly fixed to a furnace wall. However, this method requires some time and costs for making a heat insulating block that is provided with a metal fixture, and thus, an improvement in this method in this point is demanded.
From the above, an object of the present invention is to provide a method of installing a heat insulating block on a furnace shell which enables the heat insulating block to be firmly fixed to a furnace wall but does not require much time and costs for making the heat insulating block, and which further offers good workability at a site: a method of manufacturing a heat insulating wall by this method: the heat insulating wall constructed by this method; an industrial furnace provided with this heat insulating wall; and a set for installing the heat insulating block.
As a result of their diligent studies to solve the above-described problems, the inventors of the present invention have found the following matters.
a. An inorganic fiber aggregate mat can be firmly fixed to a furnace shell by: inserting a beam of a fixture into a fold of a heat insulating block that is formed by folding up the inorganic fiber aggregate mat, so that the beam supports the inorganic fiber aggregate mat on a face.
b. The time and costs required for manufacturing a heat insulating block can be reduced by the step of making a heat insulating block which leads to a structure of not disposing a fixture in the heat insulating block and which leads to the formation of the heat insulating block and the fixture as separate bodies.
c. On a heat insulating wall made by the above-described method, the support point of a beam of a fixture at which the beam supports a heat insulating block is located outside the heat insulating block. The heat insulating wall made by the above-described method has a structure different from a conventional heat insulating wall in this point.
d. A fixture is provided with beams of different lengths: a longer beam is inserted into and installed in one heat insulating block, and thereafter a shorter beam is inserted into and installed in another heat insulating block; thereby, workability for a heat insulating wall can be improved.
e. Fixtures each provided with a beam to be inserted into one heat insulating block, and inserted into the heat insulating block in two directions, respectively, to be fixed to the furnace shell; thereby, workability for a heat insulating wall can be further improved.
Based on the above matters, the inventors of the present invention have completed the invention as follows.
[1] A method of installing a heat insulating block on a furnace shell, the method comprising: inserting a beam of a fixture into a fold of an inorganic fiber aggregate mat, the inorganic fiber aggregate mat being folded up to form a heat insulating block: and fixing the fixture and a furnace shell to each other, wherein a support point of the beam at which the beam supports the heat insulating block is outside the heat insulating block.
[2] A method of installing a heat insulating block to a furnace shell, the method comprising: preparing a heat insulating block that comprises a folded inorganic fiber aggregate mat, and a fixture that comprises a beam; inserting the beam of the fixture into a fold of the inorganic fiber aggregate mat of the heat insulating block: and fixing the fixture and a furnace shell to each other.
[3] The method according to [1] or [2], wherein the heat insulating block has at least two folds on a face thereof which is to be disposed on the furnace shell.
[4] The method according to [3], wherein the fixture comprises at least two beams, and positions of the beams correspond to positions of the folds of the heat insulating block.
[5] The method according to any one of [1] to [4], wherein the fixture comprises plural beams that are to be installed in two different heat insulating blocks, the beams including a first beam area to be installed in one of the heat insulating blocks, and a second beam area to be installed in another one of the heat insulating blocks, and the first beam area and the second beam area are different from each other in length.
[6] The method according to any one of [1] to [5], wherein every two of the heat insulating blocks which are next to each other are installed, so that a space therebetween is at least 1 mm.
[7] The method according to [6], wherein another inorganic fiber aggregate mat is inserted into the space between every two of the heat insulating blocks which are next to each other.
[8] A method of manufacturing a heat insulating wall, the method comprising: forming a heat insulating wall on a furnace shell by the method defined in any one of [1] to [7].
[9] A heat insulating wall comprising: a heat insulating block comprising an inorganic fiber aggregate mat that is folded up and that has at least two folds on a face thereof which is to be fixed to a furnace shell; and a fixture having at least two beams, wherein the beams of the fixture are inserted into the folds of the heat insulating block, and the fixture is fixed to the furnace shell, and thereby, the heat insulating block is installed on a furnace wall, and support points of the beams at which the beams support the heat insulating block are outside the heat insulating block.
[10] The heat insulating wall according to [9], wherein the fixture comprises plural beams that are installed in two different heat insulating blocks, the beams including a first beam area installed in one of the heat insulating blocks, and a second beam area installed in another one of the heat insulating blocks, and the first beam area and the second beam area are different from each other in length.
[11] The heat insulating wall according to [9] or [10], wherein a space between every two of the heat insulating blocks which are installed on the furnace shell and which are next to each other is at least 1 mm.
[12] An industrial furnace comprising the heat insulating wall defined in any one of [9] to [11].
[13] A set for installing a heat insulating block, the set comprising, as separate members: a heat insulating block comprising an inorganic fiber aggregate mat that is folded up and that has at least two folds on a face thereof which is to be fixed to a furnace wall; and a fixture having at least two beams, wherein positions of the folds of the heat insulating block and positions of the beams of the fixture correspond to each other.
[14] The set according to [13], wherein the heat insulating block is compressed in a direction of laminating the inorganic fiber aggregate mat, and is fixed with a band in a compressed state thereof.
[15] The set according to [13] or [14], wherein the fixture comprises plural beams that are to be installed in two different heat insulating blocks, the beams including a first beam area to be installed in one of the heat insulating blocks, and a second beam area to be installed in another one of the heat insulating blocks, and the first beam area and the second beam area are different from each other in length.
The method of installing a heat insulating block on a furnace shell according to the present invention enables a heat insulating block to be firmly fixed to a furnace shell, and offers good workability at a site. This method does not require much time and costs for making a heat insulating block.
Hereinafter a method of installing a heat insulating block on a furnace shell, a method of manufacturing a heat insulating wall, a heat insulating wall, an industrial furnace, and a set for installing a heat insulating block as examples according to embodiments of the present invention will be described. The scope of the present invention is not limited to the following embodiments.
Unless otherwise specified, the description of “a to b” showing a numeral range means “at least a and at most b” and also encompasses the meanings of “preferably more than a” and “preferably less than b”.
Any upper or lower limit concerning the numerical range in this description, even if being slightly beyond the numerical range specified in the present invention, shall be encompassed in equivalents of the present invention as long as offering the same operation and effect as that within the numerical range.
<Method of Installing Heat Insulating Block on Furnace Shell>
A method of installing a heat insulating block on a furnace shell according to the present invention comprises: inserting a beam of a fixture into a fold of an inorganic fiber aggregate mat of a heat insulating block: and fixing the fixture and a furnace shell to each other. Hereinafter each step will be described.
At the stage of making a heat insulating block in the method of installing a heat insulating block on a furnace shell according to the present invention, no fixture is disposed on the heat insulating block, and the heat insulating block and the fixture are made or prepared as separate bodies.
(Step of Inserting Beams 24 of Fixture 20 into Fold of Inorganic Fiber Aggregate Mat 12 of Heat Insulating Block 10)
Heat Insulating Block 10
The heat insulating block 10 is provided with the inorganic fiber aggregate mat 12 that is folded up.
Inorganic Fiber Aggregate Mat 12
An inorganic fiber forming the inorganic fiber aggregate mat 12, which forms the heat insulating block 10, is not particularly limited, but examples thereof include silica, alumina/silica, and silica-containing or alumina/silica-containing single or composite fibers of any of zirconia, spinel, titania and calcia. Among them, alumina/silica fibers, particularly polycrystalline alumina/silica fibers are particularly preferable in view of thermal resistance, fiber strength (toughness), and safety. Alumina/silica fibers each having an alumina ratio of 70 to 80 mass % and a silica ratio of 30 to 20 mass % are especially preferable.
As the inorganic fiber aggregate mat 12, a mat (needled blanket) obtained by needling-treating an aggregate of an inorganic fiber that substantially contains no fiber having a fiber diameter of 3 μm or less is preferable because safety is secured and at the same time thermal resistance and durability are improved.
The bulk density of the inorganic fiber aggregate is not particularly limited, but is preferably 85 kg/m3 to 150 kg/m3, and further preferably 90 kg/m3 to 140 kg/m3 in view of the thermal resistance and strength of the heat insulating block 10 to be formed.
The thickness of the inorganic fiber aggregate mat 12 is appropriately selected, but is preferably 10 to 30 mm, and more preferably 12.5 to 27 mm in view of workability and strength. Too small a thickness of the mat 12 causes a lot of trouble with work; and too large a thickness thereof makes it difficult to maintain the structure when the mat 12 is folded up, which are problematic.
The size of the inorganic fiber aggregate mat 12 is not particularly limited. The mat 12 can be treated by appropriately cutting a piece of a preferred size out of the mat 12 according to a site for constructing a furnace shell.
Method of Folding up Inorganic Fiber Aggregate Mat 12
The method of folding up the inorganic fiber aggregate mat 12 of the heat insulating block 10 is not particularly limited as long as a fold appears on a face of the heat insulating block 10 which is to be installed on a furnace shell (face P1 on the left back side of
In the method of folding up the inorganic fiber aggregate mat 12, the one long mat 12 may be folded in a zigzag way as shown in
The bulk density of the heat insulating block 10 is not particularly limited, but is preferably 96 kg/m3 to 160 kg/m3, and preferably 100 kg/m3 to 140 kg/m3. The inorganic fiber aggregate mat 12 used for the heat insulating block 10 may be compressed. The compression ratio is preferably at most 40%, more preferably at most 30%, further preferably at most 20%, further preferably at most 15%, and most preferably 1 to 10% in view of workability in the step of inserting the beams of the fixture described later. This can secure workability for the heat insulating block, and can also improve thermal resistance and durability. A higher compression ratio makes the bulk density of the heat insulating block 10 higher, and improves the thermal resistance of the heat insulating block 10.
The heat insulating block 10 may be sewn with, for example, an alumina rope, to be compressed, or to keep its structure. The bulk density of the heat insulating block 10 may be made to be higher by folding up to laminate the inorganic fiber aggregate mat 12, pressing, with plywood, a metal plate, or the like, both side faces to be compressed and compressing the mat 12, and fixing the mat 12 with, for example, bands 14. As described above, in the present invention, the compression ratio of the heat insulating block 10 is preferably not too high. Thus, plywood or the like disposed on both side faces to be compressed is not essential, but the compression may be kept only with the bands 14 as shown in
Plural heat insulating blocks 10 may be fixed to a furnace shell by: cutting the bands 14 after the construction to release the compression, so that the heat insulating blocks 10 are in close contact with each other.
In a conventional modular method of constructing a heat insulating wall using a heat insulating block, it is necessary to insert a beam in a space in an inorganic fiber aggregate mat, and to install a metal fixture for a block on a face of the heat insulating block which is to be installed on a furnace shell, which requires some time and costs for manufacturing the heat insulating block. In the method according to the present invention, however, no such a metal fixture is necessary for manufacturing the heat insulating block 10: the heat insulating block 10 can be formed only from the inorganic fiber aggregate mat 12 and the bands 14. Thus, plural heat insulating blocks 10 can be manufactured at low costs for a short time.
That is, in the step of making or preparing the heat insulating block 10, no beam of the fixture is inserted in the heat insulating block 10, and the heat insulating block 10 and the fixture are prepared as separate bodies.
Fixture 20
In the installation method according to the present invention, the heat insulating block 10 is installed on a furnace shell with the fixture 20, which is a separate member.
The number of the beams 24 in the fixture 20 is the same as or smaller than the number of the folds of the inorganic fiber aggregate mat 12 of the heat insulating block 10, and is preferably at least 2, and more preferably at least 4. The larger the number of the beams 24 is, the higher the strength at which the heat insulating block 10 is fixed to a furnace shell is but the poorer workability when the beams 24 are inserted into the folds of the inorganic fiber aggregate mat 12 is. Thus, the upper limit of the number of the beams 24 is preferably at most 6. The fixture 20 according to the embodiment shown in
The distances between the beams 24, W1 and W2 are dependent on the positional relationship of the folds of the inorganic fiber aggregate mat 12 of the heat insulating block 10, into which the respective beams 24 are to be inserted. For example, when the beam 24 and the beam 24 are inserted into two folds that are next to each other on the installing face P1 of the heat insulating block 10, the distance between these beam 24 and beam 24 corresponds to the thickness of two laminates of the inorganic fiber aggregate mat 12 compressed in the heat insulating block 10.
The breadths W1 and W2 between the beams 24, and the positions of the folds of the heat insulating block 10 may be adjusted by any of the following ways: selecting the thickness of the inorganic fiber aggregate mat 12, or appropriately adjusting the compression ratio of the inorganic fiber aggregate mat 12 when the heat insulating block 10 is manufactured: or making the fixture 20 by adjusting the breadths W1 and W2 between the beams 24 of the fixture 20, so that the breadths are the same as the distances between the folds in the manufactured heat insulating block 10, into which the beams 24 are to be inserted.
In the fixture 20 according to the shown embodiment, the beams 24 are disposed so as to extend from the standing piece 22B in parallel to a furnace shell. The beams 24 are installed on the standing piece 22B apart from a furnace shell by the height W3. The height W3 for the beams 24 corresponds to the thickness of the inorganic fiber aggregate mat 12 at the folded portions in the heat insulating block 10. Thus, the height W3 for the beams 24 of the fixture 20 is adjusted according to the thickness of the used inorganic fiber aggregate mat 12: or the thickness of the inorganic fiber aggregate mat 12 is selected according to the height W3 for the beams 24 of the fixture 20. A slightly lower height W3 than the mat 12 can fill a tiny space between the heat insulating block 10 and a furnace shell.
The method of installing the fixture 20 on a furnace shell will be described later. The fixture 20 shown in
In the embodiment in
The fixture 20 may have a structure of having the beams 24 on any one of the upper and lower sides of the standing piece 22B. In this case, the heat insulating block 10 is fixed with any of the fixtures 20 thereabove and therebelow. The beams 24 preferably have lengths of any ratio from ⅓ to approximately 1 of the length of the heat insulating block 10 in the direction Y1.
The piece 22C is not limited as long as having a function of preventing the other beams 24 of the other fixture 20, which is next to the fixture 20, from deforming. The position at the standing piece 22B where the piece 22C is installed is not limited as long as the piece 22C is formed at a position further from a furnace shell than positions at the standing piece 22B where the beams 24 are fixed. As shown in
Fixture 20 Having Beams of Different Lengths
As shown in
The fixture 20 according to the above-described embodiment makes it possible that: for example, a heat insulating block into which the relatively long first beam area 24A is inserted is installed on a furnace shell via the fixture 20, and thereafter, another heat insulating block is fitted to the relatively short second beam area 24B. The fixture 20 has been fixed to the furnace shell already, and thus, a space is limited, so that it is difficult to install another heat insulating block. However, the second beam area is short, which makes the second beam area easy to be inserted into the folds of another heat insulating block, which improves workability when another heat insulating block is installed. The long first beam area can also improve workability without any deterioration of the durability of the heat insulating blocks.
In this case, the length of the first beam area 24A is preferably any ratio from ⅓ to ⅔ of the length of the heat insulating block 10 in the direction Y1; and the length of the second beam area 24B is preferably any ratio from 1/10 to ⅓ of the length of the heat insulating block 10 in the direction Y1, and specifically, is preferably 30 to 90 mm. The length of the first area and the second area in total is preferably any ratio from ⅓ to ¾ of the length of the heat insulating block 10 in the direction Y1.
When another heat insulating block is fitted, marking the folded portions into which the second beam area 24B is to be inserted improves workability when the second beam area 24B is installed in another block. For the marking, any means such as a pen and a seal may be used: an oil-based pen is most preferable.
Fixture 20 Having L-shaped or T-shaped Beams
(Step of Fixing Fixture 20 and Furnace Shell to Each Other)
The heat insulating block 10 can be fixed to a furnace shell by fixing the fixture 20 to the furnace shell in addition to the above-described step of inserting the beams 24. In the method of installing the heat insulating block 10 on a furnace shell according to the present invention, the order of carrying out the above-described step of inserting the beams 24, and the step of fixing the fixture 20 to a furnace shell is not particularly limited. One may carry out the step of inserting the beams 24 first, and then, fix the fixture 20 to a furnace shell, or vice versa. In view of workability, it is preferable to carry out the step of inserting the beams 24 first to install the fixture 20 on the heat insulating block 10, and then to fix this fixture 20 to a furnace shell, in that order.
When Fixtures 20 are Fixed to Furnace Shell 30 with Studs 32
The procedures when the fixtures 20 are fixed to the furnace shell 30 with the studs 32 will be described with reference to
In the embodiment of
Next, as shown in
As the above, the heat insulating block 10A at the first tier is disposed on the furnace shell 30. Plural heat insulating blocks 10A are aligned and disposed in the width direction according to the width of the furnace shell 30 through the same procedures.
Next, as shown in
As the above, the heat insulating block 10B at the second tier is disposed on the furnace shell 30. Plural heat insulating blocks 10B are aligned and disposed in the width direction according to the width of the furnace shell 30 through the same procedures, which is the same as described above.
Heat insulating blocks 10C . . . at the third and successive tiers are also disposed through the same procedures for disposing the heat insulating block 10B at the second tier described above, so that a heat insulating wall of a desired height is manufactured on the furnace shell. The fixture 20A having the beams 24 only on one side thereof (at a vertically opposite position from the fixture 20A at the first tier) is used for the uppermost heat insulating blocks (or heat insulating blocks at an end portion) forming the heat insulating wall.
Instead of the fixtures 20B, 20C . . . , as shown in
Also in this case, the heat insulating blocks 10 may be fixed by fitting, to one stud, the hole 26 at the center portion of the main body plate 22A of one of the fixtures 20A installed on an upper one of every two heat insulating blocks 10 that are vertically next to each other, and that on a lower one thereof.
Particularly, when there is no space in the vertical direction (direction of installing the fixtures), for example, when the last one heat insulating block 10 in the uppermost direction is installed, a work space is limited, which makes it difficult to do construction as the beams 24 are inserted to the heat insulating block 10. In this case, as shown in
At this time, a sufficient space between the heat insulating blocks 10 allows the holes 26 to be fitted to the studs 32 as the positions of the holes 26 at the center portions of the main body plates 22A of the fixtures 20A are checked from the inside of a furnace, which improves workability. Further, like the fixtures 20A shown in
In this case, as shown in
When Fixtures 20 are Fixed to Furnace Shell 30 by Welding
The fixtures 20 may be fixed to the furnace shell 30 by welding. In this case, no studs 32, which are made to stand at the furnace shell 30 in advance in the above-described step, are necessary, and the fixtures 20 are directly welded to the furnace shell 30. Any welding method such as arc welding, semi-automatic welding, and TIG welding may be appropriately selected.
Cutting the bands of heat insulating blocks that align in the right-left direction and that are next to each other causes their compression to be released, so that the heat insulating blocks are arranged in close contact with each other.
<Method of Manufacturing Heat Insulating Wall>
The method of manufacturing a heat insulating wall according to the present invention is a method comprising: forming a heat insulating wall on a furnace shell by the above-described method of installing the heat insulating block 10 on a furnace wall.
The position where a heat insulating wall is formed is not particularly limited, but may be on any of a side face, a bottom face, and a ceiling inside a furnace. The method of manufacturing a heat insulating wall according to the present invention exerts a great effect when the heat insulating wall is disposed on a ceiling, on which the heat insulating wall is easy to peel off and fall off from a furnace shell due to the gravity thereof from the viewpoint that the heat insulating blocks can be firmly fixed to the furnace shell.
<Heat Insulating Wall>
A heat insulating wall according to the present invention is formed on a furnace shell by the above-descried method of installing the heat insulating block 10 on a furnace shell or method of manufacturing a heat insulating wall according to the present invention. A preferred embodiment of the heat insulating wall is a heat insulating wall comprising: the heat insulating block 10 comprising the inorganic fiber aggregate mat 12, which is folded up and which has at least two folds on a face thereof which is to be fixed to a furnace shell; and the fixture 20 having at least two beams 24, wherein the beams 24 of the fixture 20 are inserted into the folds of the heat insulating block 10, and the fixture 20 is fixed to the furnace shell, and thereby, the heat insulating block 10 is installed on a furnace wall.
The heat insulating block 10 having at least two folds, and correspondingly to this, the fixture 20 having at least two beams 24 allow the fixture 20 to hold the heat insulating block 10 in a well-balanced manner, and enable the heat insulating block 10 to be firmly fixed to a furnace shell.
(Position of Support Points of Beams 24 at which Beams 24 Support Heat Insulating Block 10)
In the heat insulating wall made according to the above-described method, support points of the beams 24 of the fixture 20 at which the beams 24 support the heat insulating block 10 are positioned outside the heat insulating block. In this point, the heat insulating wall made according to the above-described method has a structure different from a conventional heat insulating wall.
The support points will be described with reference to
As described above, in the heat insulating wall formed by the method according to the present invention, the positions of the support points of the beams 24 at which the beams 24 support the heat insulating block 10 are located outside the heat insulating block 10. Here, “located outside the heat insulating block” means “located outside the heat insulating block when looking from the inside of the furnace (upper side of the sheet)”, in short, means that the position of the heat insulating block and the positions of the support points do not overlap each other when looking from the inside of the furnace.
<Industrial Furnace>
An industrial furnace according to the present invention is provided with the above-described heat insulating wall. The industrial furnace is not particularly limited, and for example, can be used as an industrial furnace for various purposes. Particularly, in view of high thermal resistance, the industrial furnace according to the present invention can exert its effect when used as a direct heating furnace of a hot rolling heating furnace or a cold rolling annealing furnace, a forge furnace, or the like.
<Set for Installing Heat Insulating Block>
A set for installing the heat insulating block 10 according to the present invention is a set of the heat insulating block 10 and the fixture 20 which is used in the above-described method of installing the heat insulating block 10 to a furnace shell. A preferred embodiment of this set is a set for installing a heat insulating block which comprises: the heat insulating block 10 comprising the inorganic fiber aggregate mat 12, which is folded up and which has at least two folds on a face thereof which is to be fixed to a furnace wall; and the fixture 20 having at least two beams 24, wherein the positions of the folds of the heat insulating block 10 and the positions of the beams 24 of the fixture 20 correspond to each other.
This set for installing the heat insulating block is a set including the heat insulating blocks 10 and the fixtures 20 in numbers necessary for a heat insulating wall to be formed. A constructor who is to form a heat insulating wall can purchase this set to form the heat insulating wall on a furnace shell in a short time through simple procedures.
The method of installing the heat insulating block 10 on a furnace shell according to the present invention enables the heat insulating block 10 to be firmly fixed to a furnace shell. Thus, this method is useful particularly when a heat insulating wall is formed on a ceiling inside a heat insulating furnace. This method is also useful in the work of repapering heat insulating walls of various new or existing heat insulating furnaces because workability at a site is well and because not much time or costs is required for making the heat insulating block.
Number | Date | Country | Kind |
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2021-009143 | Jan 2021 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2022/002030 | 1/20/2022 | WO |
Publishing Document | Publishing Date | Country | Kind |
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WO2022/158532 | 7/28/2022 | WO | A |
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20130019553 | Kohno et al. | Jan 2013 | A1 |
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57-37687 | Mar 1982 | JP |
59-049485 | Mar 1984 | JP |
62-299691 | Dec 1987 | JP |
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2020-125890 | Aug 2020 | JP |
Entry |
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International Search Report for PCT/JP2022/002030 dated Mar. 15, 2022 [PCT/ISA/210]. |
Number | Date | Country | |
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20230194172 A1 | Jun 2023 | US |