Patent Grant
7074247
This invention relates to a method of making a composite abrasive compact.
Abrasive compacts are used extensively in cutting, milling, grinding, drilling, boring and other abrasive operations. Abrasive compacts consist of a mass of diamond or cubic boron nitride particles bonded into a coherent, polycrystalline conglomerate. The abrasive particle content of abrasive compacts is high and there is generally an extensive amount of direct particle-to-particle bonding. Abrasive compacts are made under elevated temperature and pressure conditions at which the abrasive particle, be it diamond or cubic boron nitride, is crystallographically stable.
Diamond abrasive compacts are also known as polycrystalline diamond or PCD and cubic boron nitride abrasive compacts are also known as polycrystalline CBN or PCBN.
Abrasive compacts tend to be brittle and in use they are frequently supported by being bonded to a cemented carbide substrate or support. Such supported abrasive compacts are known in the art as composite abrasive compacts. Composite abrasive compacts may be used as such in a working surface of an abrasive tool.
In making abrasive compacts, particles of a single size or a mixture of particles of various sizes may be used. Examples of such compacts are disclosed in U.S. Pat. Nos. 4,604,106 and 5,011,514.
It is also known to produce an abrasive compact which has two zones differing in particle size. Examples of such compacts are described in U.S. Pat. Nos. 4,861,350 and 4,311,490.
European Patent No. 0 626 236 describes a method of making an abrasive compact which includes the step of subjecting a mass of ultra-hard abrasive particles to conditions of elevated temperature and pressure suitable for producing an abrasive compact, the mass being characterised by at least 25% by mass of ultra-hard abrasive particles having an average particles size in the range 10 to 100 microns and consisting of particles having at least three different particle sizes and at least 4% by mass of ultra-hard abrasive particles having an average particles size of less then 10 microns. The particle mix thus contains four different sizes of particles. The specification discloses the advantages of using such a mixture of particles in producing abrasive compacts in turning and shaper tests.
European Patent No. 0 626 237 discloses a method of making an abrasive compact which includes the step of subjecting a mass of ultra-hard abrasive particles to conditions of elevated temperature and pressure suitable for producing an abrasive compact, the mass being characterised by the ultra-hard abrasive particles having an average particle size of less than 20 microns and consisting of particles having three different average particle sizes.
Composite abrasive compacts of the type described above are used in a variety of applications. One such application is as an insert for drill bits. Such bits including percussion bits, rolling cone bits and drag bits. For drill bits, the diamond compact layer is generally fairly thick, e.g. having a thickness of up to 5 mm. In the manufacture of composite diamond compacts, stresses arise in the diamond compact layer. These stresses are caused, in part, by a difference in the thermal coefficient of expansion between the diamond layer and the substrate. Such stresses give rise to several problems. For example delamination of the diamond layer from the substrate can occur when the composite diamond compact is brazed to a working surface of a tool. Further, the stresses in the diamond layer can lead to spalling or chipping of the diamond layer, in use.
According to the present invention, a method of making a composite abrasive compact comprising an abrasive compact bonded to a substrate, generally a cemented carbide substrate, includes the steps of providing a mass of ultra-hard abrasive particles on a surface of a substrate to form an unbonded assembly and subjecting the unbonded assembly to conditions of elevated temperature and pressure suitable for producing an abrasive compact, the mass of ultra-hard abrasive particles being characterised by three regions:
The method of the invention utilises a mass of ultra-hard abrasive particles which has at least three regions, the inner and outer regions differing from each other in their particle size composition. The particles of the inner region will generally be coarser than the particles of the outer region.
The particles present in the inner region, which generally have a size up to 100 microns. The particles in the outer region will generally have a size of up to 25 microns.
The inner region contains particles having at least four different average particle sizes. It has been found particularly suitable for this region to comprise a mass containing six different average particle sizes.
The outer region contains particles having at least three different average particle sizes, the particles all generally being fine. This region thus provides the compact produced with a tough, wear-resistant and abrasive region.
The intermediate region may comprise more than one region or layer, each region or layer differing in particle size composition from the others.
The intermediate region will generally be in contact with both the outer region and the inner region.
The regions will generally be defined as layers.
The surface of the substrate on which the particulate mass is provided may be planar, curved, or profiled.
The ultra-hard abrasive particles may be diamond or cubic boron nitride, and are preferably diamond particles. The diamond may be natural or synthetic or a mixture thereof.
The ultra-hard abrasive particle mass will be subjected to known temperature and pressure conditions necessary to produce an abrasive compact. These conditions are typically those required to synthesise the abrasive particles themselves. Generally the pressures used will be in the range 4 to 7 GPa and the temperature used will be in the range 1300° C. to 1600° C. During production of the abrasive compact, bonding of the compact to the substrate occurs.
The abrasive compact which is produced by the method of the invention will generally and preferably have a binder present. The binder will preferably be a solvent/catalyst for the ultra-hard abrasive particle used. Solvents/catalysts for diamond and cubic boron nitride are well known in the art. In the case of diamond, the binder is preferably cobalt, iron, nickel or an alloy containing one or more of these metals.
When a binder is used, particularly in the case of diamond compacts, it may be caused to infiltrate the mass of abrasive particles during compact manufacture. A shim or layer of the binder may be used for this purpose. This shim or layer may be placed on a surface of the substrate and the mass of ultra-hard abrasive particles placed on the shim or layer. Alternatively, and preferably, the binder is in particulate form and is mixed with the mass of abrasive particles. The binder will typically be present in an amount of 2 to 25% by mass of the abrasive compact produced.
The substrate is preferably a cemented carbide substrate such as cemented tungsten carbide, cemented tantalum carbide, cemented titanium carbide, cemented molybdenum carbide or a mixture thereof. The binder metal for such carbide may be any known in the art such as nickel, cobalt, iron or an alloy containing one or more of these metals. Typically this binder will be present in an amount of 10 to 20% by mass, but the binder may be present in an amount as low as 6% by mass. Some of the binder metal may infiltrate the abrasive compact during compact formation.
The method of the invention is characterised by the use of three different regions of abrasive particles in the abrasive particle mass which is used to produce the compact. These regions, or at least the inner and outer regions, will be discernible in the sintered compact under magnification.
The inner and outer regions contain particles differing from each other in their composition of particles sizes. The intermediate region will also preferably contain such a mixture of particles. By the term “average particle size” is meant that a major amount of the particles will be close to the specified size although there will be some particles above and some particles below the specified size. The peak in the distribution of particles will have a specified size. Thus, for example, if the average particle size is 10 microns, there will be some particles which are larger and some particles which are smaller than 10 microns, but the major amount of the particles will be at approximately 10 microns in size and a peak in the distribution of particles will be 10 microns.
The inner region contains particles having at least four different average particle sizes. Preferably, in this region, (i) the majority of particles will have an average particle size in the range 10 to 100 microns and consist of at least three different average particle sizes and (ii) at least 4% by mass of particles will have an average particle size of less than 10 microns.
The particles (i) will preferably have the following composition:
An example of a particularly useful particle composition for the inner region is:
It has been found that a particle mix for the inner region containing at least four different particle sizes provides an excellent bonding region for the compact and the substrate. Strong bonding to the substrate is achieved and mis-match stresses which can build up are minimised. The thickness of this region, in the sintered abrasive compact, will typically be 0.5 to 3 mm.
The outer region is the region which provides the sintered abrasive compact with the cutting surface or edge. The abrasive particle mass for this region is characterised by containing at least three different particle sizes. Preferably the particles of this region will have an average particle size not exceeding 25 microns.
An example of a composition for the abrasive particles of this mix is:
Examples of specific compositions which are useful for the outer region are:
The outer region in the sintered abrasive compact will typically have a thickness of 0.5 to 3 mm.
The intermediate region will preferably contain a mixture of abrasive particles differing in average particle size. That mixture typically contains at least two different average particle sizes and preferably contains four different average particle sizes. An example of a suitable composition for the intermediate layer is:
The intermediate region may itself contain more than one region or layer. For example the intermediate region may comprise three layers each differing in average particle size.
The intermediate region, or each layer or region thereof, will generally be thin and have a thickness typically less than 0.3 mm in the sintered abrasive compact. The region may merge with the inner and outer regions during compact manufacture, or may remain, in the sintered compact, as a distinct layer.
When the intermediate region comprises more than one region or layer, the layer in contact with the inner region will typically have a composition as identified the second layer, on the first layer, will typically have a composition of:
The substrate surface on which the abrasive particle mass is placed may be planar, curved or otherwise profiled. The invention has particular application to producing composite abrasive compacts which have a profiled interface between the substrate and the abrasive compact of the type illustrated described in European Patent Publication No. 0 941 791.
Embodiments of the invention will now be described with reference to
The layer 10 comprises three regions—an inner region 16, an intermediate region 18 and an outer region 20. The regions differ in their particle size composition, as described above. The unbonded assembly is placed in the reaction zone of a conventional high temperature/high pressure apparatus and subjected to appropriate high temperature/high pressure sintering conditions. The product which is produced is a diamond compact layer 10 bonded to a substrate 12 along interface 14. The diamond compact layer will have the three regions or layers 16, 18 and 20. The peripheral edge 22 of the compact layer 10 as produced provides the cutting edge of the compact.
A second embodiment is illustrated by
The embodiment of
A further embodiment is illustrated by
In the embodiments described above, the cutting edges may be provided with a chamfer, radius or edge otherwise broken.
Yet another embodiment of the invention is illustrated by
The composite abrasive compact produced by the method of the invention has a wide range of applications such as drilling, cutting, milling, grinding, boring and other abrasive operations. More particularly, the composite abrasive compact has application as an insert for percussion drills, rolling cone bits and drag bits. In such applications it is desirable to have as thick a compact layer as possible. Using regions of different particle size compositions, as described above, in the manufacture of such compacts reduces significantly the tendency for such composite abrasive compacts to spall, delaminate or otherwise fail due to internal stresses created in the compact layer during manufacture. The intermediate region, whether one or more layers, and the use of multimodal material, i.e. different particle sizes in the various regions, minimises the residual stresses within the compact thus ensuring high toughness of the compact.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2000/5827 | Oct 2000 | ZA | national |
| 2000/6677 | Nov 2000 | ZA | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/IB01/01922 | 10/15/2001 | WO | 00 | 8/25/2003 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO02/34437 | 5/2/2002 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 4247304 | Morelock | Jan 1981 | A |
| 5468268 | Tank et al. | Nov 1995 | A |
| 5505748 | Tank et al. | Apr 1996 | A |
| 5766394 | Anderson et al. | Jun 1998 | A |
| 6132675 | Corrigan et al. | Oct 2000 | A |
| Number | Date | Country |
|---|---|---|
| 0 626 236 | Nov 1994 | EP |
| 00 38864 | Jul 2000 | WO |
| Number | Date | Country | |
|---|---|---|---|
| 20040037948 A1 | Feb 2004 | US |
