Patent Application
20190240926
This application is related to the field of acoustic, net-shape molded part formation for vehicles.
Current processes of producing fibrous ducts require sheet-forming of incoming feedstock, followed by fusing duct halves together, and trimming significant portions of the incoming stock off as un-recycled waste. Such techniques start with a certain thickness of incoming sheet-stock and effectively stretch the material into thinner sections during molding, which can severely limit both the shapes that can be formed and the uniformity of material distribution in the final part. Although surface profile corrugations can be formed into the parts for stiffening, it is generally not possible for these processes to incorporate ribs or thick sections since the forming process can only stretch and compress the material. Such parts tend to be very flexible in nature, to the point of being floppy, which can require the addition of reinforcements, mounting tabs, and end-fittings so the parts can be adequately assembled into a system. Thermoforming of this nature is generally regarded as a slow manufacturing process and is best suited for low-volume production.
The use of pulp-forming of cellulosic fiber packaging for consumer goods is well known. Thermoforming and matched-mold forming of either fibrous mat or extruded open-celled foam parts is common practice for use with consumer goods. Blow molding of foamed polymers is becoming more prevalent, but the known technologies cannot currently produce sufficiently open-celled structures that are necessary to produce a truly acoustically functional, net-shape molded part for use in an automobile. All known techniques suffer from sensitivity to stretch ratios, which makes wall thinning a challenge for deep draw areas.
Most applicable prior art is primarily defined by the potential for porosity and its importance for acoustic properties and, owing to the open structure of the material, increased thickness and improved thermal insulation. Such prior art primarily relates to matched-mold thermoforming of either partially or fully open-cell extruded foam sheets or nonwoven polymer fiber mat sheets. These techniques are limited in their capabilities in that a finite material must be stretched to match the contour of the mold wherein designs must be limited to restrict local stretch ratios and excessive thinning in deeply drawn areas. Another challenge with these techniques is that the material is generally utilized in rectangular blanks which, after forming, must be trimmed either before or after separate duct components are bonded together. In many cases, owing to the irregular nature of many part shapes, the inability to nest formed shapes into a mold layout limits part yield and results in a significant portion of the incoming material to be trimmed as scrap since the material is not directly recyclable back into the primary raw material stream and must be otherwise disposed of. Furthermore, the materials herein, being limited in thickness and stiffness, must frequently have expensive secondary applications of mounting tabs and boundary features for proper interfacing and assembly. All of the steps and waste inherent in the manufacture of such parts, although while providing useful performance benefits, are too costly for broad market acceptance, thus they remain limited primarily to select premium vehicles; forcing lower cost vehicles to suffer with inefficient technologies.
WO2016/004522 A1 discloses a porous automotive HVAC duct composed of expanded polypropylene beads (EPP) which is formed in halves in a steam-chest process. However, EPP is not generally suitable for thin sections, such as for ducts, due to several shortcomings with the manner in which the material is fused only at their surfaces. While structures constructed from EPP are excellent in compression and generally applied as thick energy absorbers, they typically exhibit poor tensile and flexural properties. This material may serve well in permanent non-contact situations such as those behind instrument panels, but is less suited for floor ducts that may be exposed to high concentrated forces due to stepping loads, without considerable thickening or reinforcements. Thin EPP wall sections tend to break under conditions of tube-crush and component assembly forces. Molded EPP mounting tabs tend to be prone to breakage, and frequently must be made much thicker than is feasible for packaging, or must be added as injection, or otherwise molded, tabs in a secondary operation, further increasing system costs. Very thin wall sections, which are a frequent necessity in many tightly packaged situations, are ill-advised for EPP. Finally, expanded bead products, such as EPP and EPE, are specialty materials that cannot easily incorporate bio-materials or even recycled polymers.
U.S. Patent Publication 2004/001489 in the name of Kimbara discloses a method of producing a fiber-molded hollow article by using a papermaking mold. Kimbara does not address the possibility of a preform with a non-uniform thickness. Without such a process it is not possible to adapt Kimbara teachings to any flow variations through a tool, which would happen during a normal process due to corrosion, deposits, etc. clogging up the flow passageways. Kimbara also does not disclose any process by which acoustic properties, density, porosity, etc., are specifically produced. Kimbara does not address any effort to melt or similarly bond fibers together, Kimbara only discloses a drying operation. Kimbara's mention of thermoplastic fibers is directed to pulped paper systems and fibrillated polymer fibers that impart certain properties to a paper part. Kimbara cannot provide a final thickness variation across a finished part, and cannot create highly compressed areas, such as mounting areas, or areas with tight clearances where porosity is undesirable.
What is lacking in the art is the use of fiber slurry technologies for the forming of net-shape molded automotive parts such as that are acoustically functional to produce quieter and more comfortable vehicles.
Disclosed is a method to form arbitrarily shaped, uniform, lightweight, bio-inhibiting, and acoustically absorptive and/or thermally insulating automotive parts with controllable density, thickness, porosity, and surface integrity. Henceforth, the term porosity will be used as a general term to refer to a broad range of more specific acoustically relevant properties, such as void content, open surface area, exposed fiber surface area, tortuosity, air permeability, etc. The terms acoustically and thermally can generally be interchanged, such as fibrous ducts that exhibit desirable acoustical properties also tend to exhibit desirable thermal insulation properties. Depending on the materials selected, this process can be used to produce an automotive part, such as a duct, wire trough, contoured panel, decorative coverstock laminated substrate, etc., with only desirable acoustical properties or only desirable thermal insulation properties. For the purposes of this disclosure, the term acoustic can refer to a part that is either both acoustically absorptive and thermally insulating, or either acoustically absorptive or thermally insulating. The method is an adaptation of pulp forming technologies based primarily on natural cellulosic fibers such as those found in cardboard and paper. In an effort to create the improved automobile HVAC and AIS (air induction system) ducting, or other single-sided or hollow components, that OEM customers desire, the concept of adapting pulp technologies to use a thermoplastic fiber and optional particle slurry to form fusible components was envisaged. The goal was to produce components that have the benefits of commercially available thermoformed fiber mat or open-cell extruded foam components, such as excellent acoustical properties, enhanced thermal insulation, and light weight without the inherent waste, manufacturing challenges, inefficiency, and high cost of such parts; which ultimately limits their large scale implementation.
An objective of the invention is to disclose a method of manufacturing that allows for arbitrary shapes with uniform walls that have no concern for draw or stretch ratios. The method allows for self-reinforced structures, such as with robust internal and external ribbing and tack-offs, an inherent capability, without wall thinning.
An objective of the invention is to disclose a net-shape part manufacturing method that significantly reduces or eliminates in-process scrap.
Another objective of the invention is to provide a method to produce components of extremely uniform areal mass and thickness distribution, generally irrespective of part shape.
Another objective of the invention is to disclose a method of manufacturing that allows locally variable areal mass and thickness potential for integrally formed, thick, acoustic and thermal padding.
Another objective of the invention is to create a deposited wall structure that offers density and porosity gradients, with the potential for internal gaps, for more ideal acoustic properties.
Yet still another objective of the invention is to disclose a method that permits the potential for integrally formed semi-continuous to continuous skin.
Another objective of the invention is to disclose a method for use in forming a tough and resilient structure so as to maintain shape and support mounting features.
Still another objective of the invention is to disclose a method of manufacturing that allows a part to be formed from multiple synthetic materials, including polyethylene, polypropylene, thermoplastic elastomers (TPE), polyester, polyester copolymers, aliphatic or semi-aromatic polyamides, polyether ether ketone, polyeterimide, polyacrylonitrile, melamine, glass, carbon, or aramid, and/or natural materials, including as hemp, jute, flax, cellulose, and the like, and material blends thereof.
Another objective of the invention is to disclose a method of manufacturing that can be functionalized and tuned with locally or globally applied polymer beads or foam particles, expandable microspheres, particle damping additives, and the like.
Another objective of the invention is to disclose a method of manufacturing that allows the addition of components by over-molding in the slurry stage, fusing in the molding stage, or trapping in the bonding stage.
Still another objective of the invention is to disclose a method of manufacturing that allows inherent ability to incorporate recycled materials and bio-fibers into the part, eventually even becoming 100% recycled or bio-based.
Still another objective of the invention is to incorporate absorbent cellulosic fibers or polymer particles or fibers, such as polyacrylamide gel, into the wall structure to temporarily absorb and then to release through evaporation, condensed water that could cause damaging or annoying drips in an automotive HVAC system.
Another objective of the invention is to disclose a method of manufacturing that allows pulp-forming systems to create pre-forms very rapidly, either in-house or through external and regionally dispersed areas, allowing for distributed manufacturing operations to complete the assembly for improved flexibility.
Another objective of the invention is to disclose the in-mold lamination of surface scrims, films, or decorative coatings to offer reinforcement, porosity regulation, coloration, appearance, or surface chemistry modification, among other properties.
Another objective of the invention is to teach a method by which microwave, infrared, or radio frequency heating could be employed to provide the required heat for any step of drying, fusing, or bonding the components and the means by which susceptors could be incorporated into the mat composition to improve such heating methods.
Another objective of the invention is to teach a method of depositing a mat onto a porous, perforated, or otherwise acceptable, pre-formed material to serve as a carrier, binder, or to otherwise modify the properties of the composite.
Another objective of the invention is to teach the method of applying a solution to the composite, either pre- or post-forming, to apply liquid binders, adhesive particles, hydrocarbon absorbers, biocides, expandable microspheres, surface energy modifiers, etc., for either global or selective property enhancement.
Another objective of the invention is to teach a process by which reprocessed material, either un-fused fibers removed from preforms prior to fusing, or fused fiber bundles and clusters having been derived from previously fused or bonded components, shredded into acceptable form, and reintroduced into the pulp at an acceptable level to minimize waste.
An advantage of the invention is that high-strength organic or inorganic fibers, such as carbon, glass, or metallic fibers, can be included in the method for improved strength, stiffness, electrical conductivity, or other beneficial properties.
Still another advantage of the invention is that the method of manufacturing allows activated carbon particles or fibers or similarly functional zeolytes or other materials to be incorporated to impart hydrocarbon adsorption/desorption properties for AIS systems or smell abatement or biocide properties for HVAC ducting.
Yet another advantage of this invention is that the technology could be applied to other non or semi-structural properties, such as load floors, under body shielding, substrates for interior trim, such as for door liners, and the like.
Other objectives and advantages of this invention will become apparent from the following description taken in conjunction with any accompanying drawings wherein are set forth, by way of illustration and example, and certain embodiments of this invention. Any drawings contained herein constitute a part of this specification and include exemplary embodiments of the present invention and illustrate various objects and features thereof.
A detailed description of the preferred embodiment of the instant invention is disclosed herein; however, it is to be understood that the disclosed embodiments are merely exemplary of the invention, which may be embodied in various forms. Therefore, specific functional and structural details disclosed herein are not to be interpreted as limiting, but merely as a basis for the claims and as a representative basis for teaching one skilled in the art to employ the present invention in virtually any appropriately detailed structure.
The method disclosed herein replaces much, or all, of the natural fibers with synthetic polymer fibers and particles, which, for the pursuit of greatest current interest, focuses mostly, but not exclusively, on thermoplastics. Natural fibers and particles may also be incorporated to attain certain levels of performance. In the preferred embodiment, the fibers are between 2-38 mm in length, though it is possible to use fibers of other lengths, and in the range of 1-45 denier, though it is possible to use fibers of other diameters.
The first step in the process is to prepare the slurry. In this step, the fibers must be sufficiently opened, or separated. This can be done by using a hydropulper, which is a high shear mixing device commonly used in the pulp and paper industry to prepare slurries by both opening fibers, mixing fibers, and blending any process aids, such as dispersants, thickeners, and/or surfactants, into the slurry. The prepared slurry is then transferred to a vessel that will permit the slurry to be exposed to the porous mold.
Next, the slurry is accumulated onto the surface of a porous mold exposed to the fluidized slurry while under the action of vacuum. In this embodiment, vacuum is used to draw the slurry to the surface of the porous mold, through which the water from the slurry will pass while the solids present in the slurry will accumulate on the surface of the porous mold, thus forming the net-shape mat. It is possible to form the mat by pouring the slurry onto the surface of the porous mold while the mold faces a direction parallel to but opposite of the direction in which gravity acts. It is also possible to pump the slurry through the porous mold. The necessary action is to use the porous mold to filter solids from the slurry. To do this, a pressure difference must be created across the porous mold, with the pressure highest at the outside surface of the mold and decreasing through the mold. The method used to create the pressure difference is not of critical importance.
The porous mold can be machined from a block of metal, preferably aluminum in order to minimize weight, with holes to allow air and water to pass through, and covered on the side of the mold that is exposed to the slurry with a screen having an opening size sufficiently small enough to prevent the fibers and particles from passing through the mold. The screen material would preferably be stainless steel. However, the details of the porous mold are not critical; any mold design or material that sufficiently separates the solids in the slurry from the carrying fluid as the carrying fluid passes through the mold, and permits the use of partitioned vacuum, if desired for a particular process, can be used. After a prescribed time, the particles and fibers will form a substantially random mat on the porous areas of the mold; forming a nearly net-shape pre-form. The deposited material can be extremely uniform, regardless of shape, such as typically limits thermoformed and blow-molded components that are sensitive to stretch or blow ratios. Upon removal of the mold from the slurry, most of the carrying fluid is extracted and recycled into the system. The loose mat, in the shape of the component formed, is transferred to another mold where it is compression molded with sufficient heat to fuse the fibers and particles together to create a final component with excellent structural properties and the desired thickness, density, porosity, and surface integrity.
The fusing can be carried out though many mechanisms. In one embodiment, The heating process can melt all of the fibers in the preform together to create the structure. Alternatively, bi-component fibers, which are fibers made of two different materials, typically a lower melting temperature material on the outside of the fiber that surrounds a higher melting temperature fiber, can be incorporated into the preform. To fuse the part, the material on the outside of the bi-component fiber can melt and either bond to other bi-component fibers or flow around and mechanically bond via encapsulation of the other fibers in the matrix. The choice of the appropriate mechanism depends on the desired properties of the duct part, raw material economics, etc.
The fusing of the part need not be carried out with a compression molding process. It is possible to fuse the part by applying heat and pressure using heated air that either flows through of past the surface of the preform. In such an embodiment, the transfer step in the process could be eliminated, and the fusing could be carried out on the porous mold by, for example, exposing the porous mold, with the preform still on the mold, to heated air, and then drawing the air through the porous mold, thereby drawing heated air through the preform and fusing the fibers of the duct. This type of fusing process would not be possible when using a purely cellulose slurry; the cellulose fibers do not permit air to flow through the preform with a sufficient volumetric flow rate to make this method of fusing economical in mass production.
The heated compression molding process may also enable thin inner and outer surface skins, such as films, woven, or nonwoven fabrics to be applied. Additionally, resin infusion or local application of fabric or solid reinforcements may also be applied. It is envisaged that, if the desired part is a hollow member, two halves of a final part would be produced with suitable joining features to enable the two halves to be welded, glued, or otherwise joined together. Because the components are produced in a substantially net-shape form, there is very little waste in the process.
The current invention improves upon the prior art above by enabling the ability to selectively form an open structured, porous component by depositing layers of fibers and, potentially, particles on the porous surface of a mold. This method can create a very uniform thickness of deposited material regardless of part shape, and, depending upon the duration and intensity of the vacuum draw in local areas of a mold, regions of dramatically increased thickness can be created to serve as thick acoustic absorbers, thermal padding, etc. The ability to deposit successive layers with different properties by exposing the porous mold to different slurries enables the formation of stratified structures for dramatic improvements in acoustics, structural integrity, and thermal insulation, and to help promote bonding of mating shells. The deposition process can also be used to selectively incorporate expandable polymer microspheres into the wall, which can be used to both increase the thickness and regulate the porosity and surface integrity of the material during the heating process. Prior to molding, or after, as desired, sprayed-on or dipped chemical treatments can be selectively added for mold prevention, hydrophobicity, flame retardency, coloration, hydrocarbon adsorption, etc. The fibers employed may be all of one type or material, or a blend of different structural, binder, and/or bi-component fibers or particles of varying sizes, shapes, and orientations.
The molding process, which fuses the fibers together at contact points, can be used to both consolidate and expand the structure to the desired wall thickness, density, and porosity. Incorporation of shaped cross section, hollow or fibrillated micro/nano fibers or other lightweight particles, such as intercalated graphite or organosilicate clays, into the slurry can provide tortuosity for both viscous and particle damping to further improve acoustic and thermal properties. The 3D network of bonded fibers throughout the structure, including fibers oriented, to some degree, in all directions, creates a very tough, resilient structure that can better sustain crushing forces with limited damage, rebounding to the original shape with relative ease. Built-in mounting tabs and mounting flanges will be similarly tough and resilient. Formed wall thicknesses can vary from less than 1 mm to over 20 mm, depending upon the degree of consolidation and expansion imposed in the molding process.
It is known in the industry that the application of an acoustical absorber, such as an adhesive backed open-cell foam pad, on the outside bend of the inner surface portion of a part is frequently beneficial for reducing-noise. Application of similar external pads is frequently used to improve thermal insulation or to provide a countermeasure to condensation accumulation and dripping, as well as to improve acoustical performance and reduce buzz, squeak, and rattle noises. In forming technologies such as blow molding, where access to deep interior bends may not be available, application of absorbent material may be difficult to accomplish. In open shell techniques, such as with injection molding, EPP molding, and thermoforming, access to bends in interiors of ducts is easily available, and application of adhesive-backed acoustic foam is possible before bonding the shells together to complete the duct. Such approaches add cost and are difficult to verify once a part is closed and bonded, making quality more of a challenge. The method of manufacture provides an ability to vary local thicknesses by either depositing a locally thicker layer of material or by selectively molding the area to be thicker and more porous. The capability to build-in sound-absorbing or thermal insulation features is also inherent using this method of manufacturing. This reduces the cost, complexity, and risk of using secondary operations for such features.
It is possible to further reduce assembly risk by over-molding components directly in the pulping system. Properly designed items, such as end fittings with suitable open-structured, perforated, or porous items, can be placed into the mold before exposure to the slurry. While accumulating the fiber deposit on the surface of the mold, fibers and particles can work their way into the pores and passages in the over-molded part, thus encapsulating it. During the molding/fusing step, the molded-in component can be fused into a permanent addition to the structure. This may be an ideal method to add naturally porous items such as foam seals, pads, and other items to the structure without the need for adhesives. Adding additional components during the fusing process is also an inherent and obvious possibility as well.
Heating the surfaces can impose a degree of surface melt that can create a locally formed, smooth, integral polymer film to further regulate local porosities for acoustic tuning, regulation of adhesive absorption, anti-drip, etc. Furthermore, the application of expandable microspheres with various expansion and degradation temperatures not only promotes expansion of the composite within the mold cavity and separation of fibers (lofting), it also presses fibers to the mold surface for proper surface integrity, increases the compressive and flexural properties of the structure, and, finally, can be used to further regulate porosity. Once the expandable microspheres expand to fill the cavity, they can be heated to their degradation temperature, wherein some of the microspheres will collapse, leaving a more open final structure. Polymer beads, expandable microspheres, and foam particles can be selected such that, at programmed temperatures, some will melt and collapse to leave behind voids and, upon solidification, may serve as a binder resin to further strengthen the composite. The formed shells can be produced with variable degrees of consolidation to promote effective bonding of adjacent shells or additional components.
Due to the nature of the method, since both inside and outside surfaces are molded in the primary embodiment, the inside surfaces are exceptionally smooth, thus promoting efficient air flow with both low pressure drops and reduced likelihood of flow-induced noise, which are both important performance criteria for components such as HVAC ducting. Smooth walled AIS ducting is beneficial due to the nature of high speed airflow causing undesirable pressure losses in the presence of rough surfaces. An alternative to the primary embodiment is the ability of slurry to be pumped within the inner cavity of a hollow, porous mold, and thus deposit a suitable layer of material to form a wall. This can create a hollow component in a single step, with no secondary bonding operation required. This option would be heated and fused in a closed mold, but would result in a more rough interior surface since that surface doesn't contact a mold during fusing. This option may be employed for complex shapes where air flow velocities are lower and less prone to experience frictional losses or flow induced noise. In some instances a flexible member, such as an inflatable membrane or tube, may be used to press against the inner surface to both consolidate and smooth the inner surface during the heated forming stage.
Referring to Figures, set forth is a method of producing a net-shaped acoustic duct from a fiber slurry of the instant invention.
Particles 0-5%; fibers 0.01-5%; adhesion promoters 0-2%; dispersion aids 0-1%; thickeners 0-1%; and surfactants 0-1%; with the balance of the slurry being comprised of a carrying fluid.
Particles are selected from the group of: Polymer particles, beads, and flakes, expandable microspheres, polymer foam particles, organosilicate clays, expandable or non-expandable graphite flakes, mica, metal flake, graphene, carbon fiber or nanotubes, and the like.
Fine fibers are selected from the group of: Fibrillated or nano-fibrillated polyolefins, polyesters, polyamides, polyacrylonitrile, or bio-fibers such as any cellulose bearing plant fiber, cotton, or the like.
Chopped fibers are selected from the group of: thermoplastics, including polyethylene, polypropylene, thermoplastic elastomers (TPE), polyester, polyester copolymers, aliphatic or semi-aromatic polyamides, polyether ether ketone, polyeterimide, polyacrylonitrile, and/or non-thermoplastics, such as melamine, glass, carbon, or aramid, and/or natural materials, including as hemp, jute, flax, cellulose, and the like. Such fibers may be multi-component to incorporate several distinct properties, as well as supplied in profile shapes ranging from round, polygonal, multi-lobed, flat, or hollow, and in potentially different diameters and lengths.
Carrying fluids are selected from the group of: Water and primarily aqueous solutions of water, metal salts, PH modifiers, and various additives listed herein.
Adhesion promoters are selected from the group of: Organofunctional silanes, maleated monomers or polymers or other similar compatibalizing modifiers.
Dispersion aids are selected from the group of: 1,2-propanediol, 1,3-propanediol, 1,4-butanediol, 1,2-butanediol and 1,3-butanediol, among others.
Thickeners are selected from the group of: polypropylene glycols or oxides having high molecular weights, or high molecular weight polyacrylamides.
Surfactants are selected from the group of: Primarily cationic surfactants, such as cetyl trimethyl ammonium bromide or stearyl dimethyl benzyl ammonium chloride.
The degree of dewatering needed will depend upon the composition and specific process needs and may not need to be complete. In some cases, substantial dewatering may not be desired nor needed at all.
Referring to
The overall method of manufacture produces lightweight, selectively porous components with the potential for programmable thickness and density in an essentially net-shape manner, thus providing engineering benefits that meet or exceed those of the competing prior art, but with very little in-process waste and improved overall cost. Recycled polymer fibers are quite suitable for this technology, improving sustainability and further decreasing system costs. Additionally, this method is adaptable for the incorporation of bio-based, renewable fibers to supplant some of the polymer fibers as needed.
All patents and publications mentioned in this specification are indicative of the levels of those skilled in the art to which the invention pertains. It is to be understood that while a certain form of the invention is illustrated, it is not to be limited to the specific form or arrangement herein described and shown. It will be apparent to those skilled in the art that various changes may be made without departing from the scope of the invention and the invention is not to be considered limited to what is shown and described in the specification and drawings/figures.
One skilled in the art will readily appreciate that the present invention is well adapted to carry out the objectives and obtain the ends and advantages mentioned, as well as those inherent therein. The embodiments, methods, procedures and techniques described herein are presently representative of the preferred embodiments, are intended to be exemplary and are not intended as limitations on the scope. Changes therein and other uses will occur to those skilled in the art which are encompassed within the spirit of the invention. Although the invention has been described in connection with specific preferred embodiments, it should be understood that the invention should not be unduly limited to such specific embodiments.
In accordance with 37 C.F.R. 1.76, a claim of priority is included in an Application Data Sheet filed concurrently herewith. Accordingly, the present invention claims priority as a continuation-in-part of U.S. patent application Ser. No. 15/492,848 entitled “Method Of Making An Acoustic Automotive HVAC and AIS Duct with a Particle Fiber Slurry,” filed on Apr. 20, 2017, which claims the benefit of priority to U.S. Provisional Patent Application No. 62/324,934, filed Apr. 20, 2016, entitled “Method Of Making An Acoustic Automotive HVAC and AIS Duct with a Particle Fiber Slurry”, the contents of which are incorporated herein by reference.
| Number | Date | Country | |
|---|---|---|---|
| 62324934 | Apr 2016 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 15492848 | Apr 2017 | US |
| Child | 16384976 | US |
