The inventors extend their appreciation to the Deputyship for Research and Innovation, Ministry of Education in Saudi Arabia for funding this research work through the project number 2020-069 and King Abdulaziz University, DSR, J eddah, Saudi Arabia.
The present disclosure is directed to a method of making a composite laminate, and, more particularly, a method of making a composite laminate using chicken feather fibers and Ceiba Pentandra bark fibers.
The “background” description provided herein is for the purpose of generally presenting the context of the disclosure. Work of the presently named inventors, to the extent it is described in this background section, as well as aspects of the description which may not otherwise qualify as prior art at the time of filing, are neither expressly nor impliedly admitted as prior art against the present invention.
Composite materials are of great importance for engineering applications due to their unique advantages of having high strength to weight ratio, non-corrosive property, and high fracture toughness. For example, a composite material can include reinforcing fiber fillers, carbon, glass, aramid, boron fiber, and a low-strength polymeric matrix. Although such materials provide good physical and mechanical properties, the composite material is non-renewable and non-recyclable, requires high energy consumption in the manufacturing process, poses a health risk, and is non-biodegradable. Meanwhile, environmental footprints of these fibers have become a great concern for several industries and society at large. This has led to the usage of natural fibers as reinforcement in composite materials.
Further, the vast amount of bird feathers produced by various poultry-based industries as waste is a significant solid agricultural disposal problem. The disposal of waste in an economically and environmentally acceptable manner is a critical problem faced by many modern industries. This is mainly due to the increased difficulties in locating disposal facilities and complying with stringent environmental quality requirements imposed by waste management and disposal legislation. Globally, the poultry-processing industry generates large quantities of feather by-products. There lies a great opportunity to effectively use bird feather fibers to manufacture composite materials.
BR102013003950B1 discloses a resin containing a duroplastica (e.g., an epoxy resin) and a fibrous material (e.g., carbon fibers, CPFs). However, a stabilizing agent (e.g., copolyester) is required to create the resin.
IN201941027362A discloses polymer nanocomposites reinforced by chicken nano keratin fiber, but the polymer includes Al—SiC nanoparticles and is fabricated using an ultrasonicator-assisted wet layup method.
Each of the aforementioned disclosures suffers from one or more drawbacks hindering adoption. Accordingly, it is one object of the present disclosure to provide a method of making a composite laminate in a cost-effective and efficient manner using the natural fibers without losing the physical and mechanical properties.
In an exemplary embodiment of the present disclosure, a method of preparing a composite laminate is disclosed. The method includes dequilling chicken feathers to form chicken feather fibers (CFFs). The CFFs and Ceiba Pentandra bark fibers (CPFs) are milled to form milled CFFs and milled CPFs so that the milled CFFs have a length of smaller than 200 microns and the milled CPFs have a length of smaller than 600 microns. In some embodiments, the CFFs and the CPFs may be co-milled to form a macroscopically homogeneous mixture of the milled CFFs and the milled CPFs. The CFFs are treated with an amine compatibilizer to esterify carboxy groups present on keratin in the CFFs. The method further includes solution casting a mixture of an epoxy resin, the milled CFFs, and the milled CPFs to form an epoxy composite. In some embodiments, the method includes mixing the epoxy resin, the milled CFFs, and the milled CPFs at an elevated temperature to form an epoxy mixture, casting the epoxy mixture onto a casting mold, and drying to form the epoxy composite. The epoxy composite may have a thickness of 2-4 millimeters.
The method further includes placing a first carbon fabric layer on a front side of the epoxy composite and a second carbon fabric layer on a backside of the epoxy composite to form an epoxy laminate precursor and compression molding the epoxy laminate precursor in a mold to cure the epoxy laminate precursor to form the composite laminate. Compression molding includes preheating a mold cavity to contain an object requiring a desired shape. The composite laminate may have a thickness of 2-4 millimeters. The method includes curing the composite laminate at an elevated temperature. In some embodiments, the method includes curing the composite laminate at 80° C. for 24 hours to form a cured composite laminate before cutting the cured composite laminate into required specimen dimensions.
In some embodiments, the compression molding of the epoxy laminate precursor includes distributing the first carbon fabric layer and the second carbon fabric layer by using brushes and hand lay-up. The compression molding further includes placing a first thin film below the epoxy laminate precursor to cover a bottom mold and placing a second thin film over the epoxy laminate precursor, wherein the second thin film is covered by a top mold.
In some embodiments, the method further includes extracting the CFFs from chicken feathers by washing the chicken feathers with an organic solvent that is soluble in water and milling the CFFs having a length of 10-30 mm to form the milled CFFs. In some embodiments, the milled CFFs may have a density of 0.35-0.40 gram per cubic centimeter. The method also includes extracting the CPFs from Ceiba Pentandra bark by immersing the Ceiba Pentandra bark in water, comminuting the Ceiba Pentandra bark to form comminuted CPFs, treating the comminuted CPFs with an aqueous solution of sodium hydroxide to form the CPFs, and milling the CPFs to form the milled CPFs. The milled CPFs may have a density of 0.55-0.60 grams per cubic centimeter.
In some embodiment, the method may include mixing the epoxy resin with a hardener. The hardener may include a mixture of isophorone diamine and benzyl alcohol and the epoxy resin and the hardener are mixed in a weight ratio of 1:0.5 to 1:0.2. The isophorone diamine may have a weight percentage of less than 60% in the hardener, and the benzyl alcohol may have a weight percentage of less than 40% in the hardener.
In some embodiments, the epoxy resin may have a weight fraction of 50%-75% in the composite laminate, the CFFs may have a weight fraction of 10%-30% in the composite laminate, the CPFs may have a weight fraction of 10%-30% in the composite laminate, and the first carbon fabric layer and the second carbon fabric layer may have a weight fraction of 5%-15% in the composite laminate. In some exemplary embodiments, more than 50% of the chemical composition of the epoxy resin is from plants. In some embodiments, the first carbon fabric layer and the second carbon fabric layer may include carbon fabrics in a plain woven form of 300-400 grams per square meter.
The foregoing general description of the illustrative embodiments and the following detailed description thereof are merely exemplary aspects of the teachings of this disclosure, and are not restrictive.
A more complete appreciation of this disclosure and many of the attendant advantages thereof will be readily obtained as the same becomes better understood by reference to the following detailed description when considered in connection with the accompanying drawings, wherein:
In the drawings, like reference numerals designate identical or corresponding parts throughout the several views. Further, as used herein, the words “a,” “an” and the like generally carry a meaning of “one or more,” unless stated otherwise.
Furthermore, the terms “approximately,” “approximate,” “about,” and similar terms generally refer to ranges that include the identified value within a margin of 20%, 10%, or preferably 5%, and any values therebetween.
Aspects of the present disclosure relate to a method of preparing a composite laminate. The composite laminate uses natural fibers such as chicken feather fiber and Ceiba Pentandra bark fiber as a reinforcement with carbon fabric layers for engineering applications.
In some embodiments, the chicken feathers may be collected from poultry farms and local chicken meat vendors where the chicken feathers are considered as a waste product and are discarded. In one embodiment, the organic solution may be ethanol. In another embodiment, the chicken feathers may be dried in an oven after washing the chicken feathers with the organic solvent. Further, CFFs having a length of 10-30 mm, preferably 15-25 mm, preferably 17-22 mm, preferably about 20 nm, are milled to form the milled CFFs. The chicken feathers having the length of 10-30 mm were separated from the quill using a separator. In some embodiments, the separators may use turbulent flow to separate the quills from the feathers. In one embodiment, the milled CFFs have a density of 0.35-0.40 grams per cubic centimeter.
In one embodiment, the method 100 includes extracting the CPFs from Ceiba Pentandra bark by immersing the Ceiba Pentandra bark in water. In some embodiment, the Ceiba Pentandra bark may be immersed in water for a period of 10-15 days to dissolve the unwanted substance surrounding the Ceiba Pentandra bark by the action of moisture or bacteria. The method 100 further includes comminuting the Ceiba Pentandra bark to form comminuted CPFs. The comminuting may be performed by processes such as, but not limited to, crushing, grinding, cutting, etc. The CFFs may be primary CFFs including contour, bristle, semi-plume, down or filo plume or a combination thereof. In some embodiments, the CPFs may be extracted from other parts of Ceiba Pendtandra including bark. Such parts may include fruit clusters, flowers, buds, twigs, roots, leaves of a combination thereof.
In one embodiment, the method 100 also includes treating the comminuted CPFs with an aqueous solution of sodium hydroxide to form the CPFs and treating the comminuted CPFs with a 1-10%, preferably 3-7% (w/v) aqueous solution of sodium hydroxide at an ambient temperature for 30 minutes. In one embodiment, the aqueous solution may have about 3% (w/v) of sodium hydroxide. In another embodiment, the aqueous solution may have about 5% (w/v) of sodium hydroxide. In yet another embodiment, the aqueous solution may have about 7% (w/v) of sodium hydroxide. The comminuted CPFs may further be neutralized, cleaned, and dried. The method 100 may further include milling the CPFs to form the milled CPFs. In an embodiment, the milled CPFs have a density of 0.55-0.60 grams per cubic centimeter. In an embodiment, the CFFs and the CPFs may be co-milled to form a macroscopically homogeneous mixture of the milled CFFs and the milled CPFs. In another embodiment, the milling may be performed by machines such as, but not limited to, Pulverisette19®, ball mill, hammer mill, and cutting mill.
In some embodiments, the CFFs include 70-95 wt. % of crude protein, for example 90 wt. % of keratin, while the CPFs include holocellulose as a majority component, e.g., preferably more than 60% wt, more than 70 wt %, more than 80 wt % based on the weight of the CPFs. Keratin has amide groups, carboxylic groups, and disulfide groups with hydrogen bonding and disulfide bridges connecting keratin molecules. Similarly, holocellulose has hydroxyl groups and thus also may also engage in hydrogen bonding. In one embodiment, a compatibilizer is added to a blend of the CFFs and the CPFs before being co-milled. The compatibilizer may form hydrogen bonding with both keratin and holocellulose in order to increase compatibility between the CFFs and the CPFs. The compatibilizer may act as a linking agent to bond CFFs and CPFs. The hydrogen bonding may also function as weak crosslinking points. The compatibilizer can include ethylene diamine, ethylenediaminetetraacetic acid (EDTA), tris(hydroxymethyl)aminomethane, or other chelating agents. The compatibilizer can also include a block or graft copolymer of keratin and cellulose, or the like. In another embodiment, the CFFs and the CPFs may be crosslinked before being co-milled. In one example, a cross-linking agent may be used to crosslink keratin and holocellulose. In another example, the CFFs and/or the CPFs may be chemically modified. For instance, the CPFs can be treated with NaIO4 to impart dialdehyde groups to holocellulose. The dialdehyde groups can react with the -NH groups of keratin so that holocellulose is linked to keratin via covalent bonding [ACS Sustainable Chem. Eng. 2017, 5, 7, 5669-5678, incorporated herein by reference in its entirety]. An amount of NaIO4 relative to the CPFs can be varied to adjust a linking density between keratin and holocellulose. Alternatively, a silane agent can readily react with hydroxyl groups of holocellulose and graft functional groups to holocellulose.
The chicken fibers are preferably dried prior to pre-treatment and/or compatibilization. In their normal natural state chicken fiber feathers may have a moisture content of around 10 wt. %. After milling, the milled CFFs are preferably dried by heating under reduced pressure. Heating is typically carried out at temperatures of 30-80° C., preferably 40-70° C. or from about 50 to about 60° C. Heating is carried out for a time and under pressure sufficient to reduce moisture content of the milled CFFs to less than 5% by weight, preferably less than 4%, less than 2% or about 1% by weight. Further drying of CFFs risks subjecting the keratin structure to denaturization. Milling and drying preferably do not cause denaturization in the form of breakage of the disulfide bonds in an amount more than 20% based on the total number of disulfide bonds in a given weight. Preferably no more than 15%, 10% and most preferably no more than 5% of disulfide bonds are broken during drying and milling. Prior to milling, chicken feathers are subject to dequilling such that the resultant milled CFFs do not contain more than 5 wt % weight of water.
During compatibilization it is likewise advantageous to maintain disulfide bonds to the greatest extent possible. In a preferred embodiment carboxyl groups of amino acid residues forming keratin are esterified with an alcohol under slightly acidic conditions. In order to improve compatibilization an epoxy matrix, CFFs are esterified with a long chain aliphatic alcohol such as a C5-C12 unbranched alcohol, or preferably C8-C10 a branched alcohol. In other aspects the long-chain alcohol includes at least six carbon atoms in a linear chain with 2-4 C1 or C2 branches.
At step 104, the method 100 includes solution casting a mixture of an epoxy resin, the milled CFFs, and the milled CPFs to form an epoxy composite. Solution casting is a method to produce substrates having a matrix and a fiber reinforcement, the matrix holds the fiber reinforcement together. In an embodiment, the epoxy resin may have more than 50% of the chemical composition from plants. In another embodiment, the epoxy resin may have more than 75% of the chemical composition from plants. In yet another embodiment, the epoxy resin may have more than 90% of the chemical composition from plants. In some embodiments, the epoxy resin may be selected from a group of bio epoxy resins such as, but not limited to, SR GreenPoxy 56®, furan-based epoxy resins.
The method 100 may include mixing the epoxy resin with a hardener in a weight ratio of 1:0.5 to 1:0.2, preferably 1:0.4 to 1:0.3, preferably 1:0.35. The hardener may include a mixture of isophorone diamine and benzyl alcohol.
In one embodiment, the isophorone diamine may have a weight percentage of less than 60%, preferably 30-60%, preferably 40-50%, preferably about 45%, in the hardener and the benzyl alcohol may have a weight percentage of less than 40%, preferably 10-40%, preferably 20-30%, preferably about 25% in the hardener. In another embodiment, the isophorone diamine may have a weight percentage of less than 40% in the hardener and the benzyl alcohol may have a weight percentage of less than 30% in the hardener. In yet another embodiment, the isophorone diamine may have a weight percentage of less than 20% in the hardener and the benzyl alcohol may have a weight percentage of less than 10% in the hardener. In some embodiments, the hardener may be SD Surf Clear®.
In one embodiment, the hardener may be mixed with the milled CFFs before being mixed with the epoxy resin. Consequently, the epoxy resin can harden around the milled CFFs and have better affinity to the milled CFFs. CFFs on which the hardener is adsorbed permit the epoxy resin to be formulated with hardener. This in turn leads to longer resin life and more flexibility with cure time and green time. Individual milled CFFs may also be confined by a crosslinked network of the epoxy resin after the hardening. Similarly, the hardener may be mixed with the milled CPFs, or the hardener may be mixed with both the milled CFFs and the mixed CPFs, before being mixed with the epoxy resin.
In one embodiment, the disulfide bridges in keratin are reduced to mercapto groups, which can react readily with epoxide groups in the resin. Therefore, the CFFs with mercapto groups may be used alone or with another hardener to harden the epoxy resin. In another embodiment, a hardening moiety (e.g. amine, imidazole, anhydride, thiol, etc.) may be grafted to keratin and/or holocellulose. The keratin and/or holocellulose having the hardening moiety may be used alone or with another hardener to harden the epoxy resin. The keratin and/or holocellulose is then covalently bonded to an epoxy matrix after the hardening.
In an embodiment, an epoxy mixture may be formed by mixing the epoxy resin, the milled CFFs, and the milled CPFs at an elevated temperature preferably 40-80° C., preferably 50-70° C., preferably 60° C. Further, the method 100 may include casting the epoxy mixture onto a casting mold and drying to form the epoxy composite. Casting is an act of pouring liquid into a cavity of a mold having a desired shape to form an object. The epoxy composite may have a thickness of 2-4 mm, preferably 2.5-3.5 mm. In one embodiment, the epoxy composite may have a thickness of about 2.8 millimeters.
At step 106, the method 100 includes placing a first carbon fabric layer on a front side of the epoxy composite and a second carbon fabric layer on a backside of the epoxy composite to form an epoxy laminate precursor. The addition of the first carbon fabric layer and the second carbon fabric layer improves the mechanical and thermal properties of the epoxy composite. In an embodiment, the first carbon fabric layer and the second carbon fabric layer may include carbon fabrics in a plain woven form of 300-400 grams, preferably 360 grams, per square meter. Further, the method 100 may include distributing the first carbon fabric layer and the second carbon fabric layer by using brushes and hand lay-up.
At step 108, the method 100 includes compression molding the epoxy laminate precursor in a mold to cure the epoxy laminate precursor and form the composite laminate. The composite laminate may have a thickness of 2-4 mm, preferably 2.5-3.5 mm, preferably 3.0 mm. In one embodiment, the composite laminate may have a thickness of about 2.6 millimeters. In another embodiment, the composite laminate may have a thickness of about 3.0 millimeters. In yet another embodiment, the composite laminate may have a thickness of about 3.4 millimeters. The mold may include a top mold and a bottom mold to contain the epoxy laminate precursor. In one embodiment, a first thin film may be placed below the epoxy laminate precursor to cover a bottom mold. In another embodiment, a second thin film may be placed over the epoxy laminate precursor and the second thin film is covered by the top mold. In some embodiments, the bottom and top molds are made of hydrophobic materials and provide support to the second thin film. In some examples, the molds are made up of hard materials such as Teflon, or copper to provide the support and protection to the film. In some embodiments, the molds are coated with nanostructure coatings to enhance the toughness and provide safety to the thin film.
The first thin film and the second thin film cover the epoxy laminate precursor to protect the epoxy laminate precursor from any damage caused during the compression molding process. Further, the first thin film and the second thin film may be hydrophobic and non-reactive with the epoxy laminate precursor to protect the epoxy laminate precursor from contamination. In some embodiments, the first laminate and the second laminate may be manufactured using polymers, for example, but not limited to, Chemfilm® Mr, polytetrafluoroethylene (PTFE), ethylene tetrafluoroethylene (ETFE), ethylene chlorotrifluoroethylene (ECTFE), or combinations thereof. The method 100 may further include curing the composite laminate at an elevated temperature, preferably 60-100° C., preferably 70-90° C. In one embodiment, the method 100 may include curing the composite laminate at 80° C. for 24 hours to form a cured composite laminate. The curing may be done by using ovens such as, but not limited to, Universal oven XU058®, composite curing ovens, industrial curing ovens. The composite laminate may further be cut into required specimen dimensions for engineering applications.
In an exemplary embodiment, the epoxy resin may have a weight fraction of 50%-75%, preferably 55-70%, preferably 60-65% in the composite laminate; the CFFs may have a weight fraction of 10%-30%, preferably 15-25%, preferably 17-23%, in the composite laminate; the CPFs may have a weight fraction of 10%-30%, preferably 15-25%, preferably 17-23%; in the composite laminate; and the first carbon fabric layer and the second carbon fabric layer may have a weight fraction of 5%-15%, preferably 7-13%, preferably about 10%, in the composite laminate. In some exemplary embodiments, more than 50%, preferably 60-90%, preferably 70-80%, preferably 75%, of the chemical composition of the epoxy resin is from plants. In some examples, the epoxy resin may be derived from plant-derived phenolic acid such as difunctional phenolic acids. In some embodiments, the plant-based epoxy resins are nontoxic and renewable with high modulus, high glass transition temperature and high elongation at break. In some embodiments, the first carbon fabric layer and the second carbon fabric layer may include carbon fabrics in a plain-woven form of 300-400 grams, preferably 360 grams, per square meter. Thus, the method 100 of preparing the composite laminate is low cost and eco-friendly method. The CPFs and CFFs serve as reinforcement for the composite laminate making it a low-cost and low-density bio composite further by increasing its recyclability and biodegradability.
The composite formed by the method 100 may have application in various fields such as, but not limited to, electric devices, aerospace industry, helmets, interiors of automobiles, etc.
Manufacturing of Composites and Preparation of Specimens
For manufacturing the composites of the present disclosure, two types of compositions were prepared, a first composition containing CPFs filler reinforced with carbon fabrics layers to form a bio epoxy composite, alternatively referred to as “CPCEFC” and a second composition containing a mixture of CPFs and CFFs as fillers reinforced with carbon fabric layers to form another bio epoxy composite, alternatively referred to as “CPCFCEFC”. For each test, five identical samples of the CPCEFC and the CPCFCEFC specimens were analyzed to obtain an average value.
The CFFs and the CPFs fillers are reinforced with the epoxy resins to form the composite laminate by solution-casting technique as per weight fraction presented in Table 1. The fillers were subsequently mixed with the epoxy resin under constant stirring on a magnetic stirrer-hotplate at 60° C. for 30 min. After proper stirring, the composite laminate was obtained by pouring the solution onto a casting mold as a casting surface and allowing the solution to evaporate at room temperature overnight. The composite laminate had an area of 200 mm×200 mm and a thickness of 2.8 mm.
CPCEFC: Ceiba pentandra bark fiber filler reinforced carbon fabrics layered bioepoxy composites. CPCFCEFC: Ceiba pentandra bark fiber/chicken feather fiber fillers reinforced carbon fabrics layered bioepoxy composites. CFF: Chicken feather fiber. CPF: Ceiba Pentandra bark fiber. C: Carbon fabric. m: Matrix.
After the casting technique, the composite laminate was prepared by the compression molding technique. In this process, the prepared composite laminate from the casting technique was placed on the bottom mold cleaned by wax, and covered with thin film. Then the epoxy resin was applied after placing carbon fabrics as skin layers (top and bottom layers) on the composite laminate, which was equally distributed by using brushes, followed by hand lay-up. Later, the thin films were placed over the composite laminate. After this, the laminate was covered by top mold, then cured at room temperature for 24 h. The composite laminate (Final Dimension: 200 mm×200 mm×3 mm) was then taken off the mold and post-cured in Universal Oven (Make & Model: FRANCE ETUVES, XU058) at 80° C. for 24 h before cutting into required specimen dimensions.
The prepared composite laminate was taken out from the Universal Oven and then specimens of suitable dimensions were prepared from composites for testing in accordance with ASTM standards by using a diamond-tipped saw cutter. Emery sheets were used to remove the rough edges of test specimens. Five identical test specimens were prepared for different tests.
Testing and Characterization
To determine voids in composites, ASTM D2734-94 method was used. The tensile test was carried out using a Universal testing machine (UTM) (Model: Comtech tensile testing machine M1 type) with a load cell of 1 kN. The dimension, gauge length, and cross-head speed were chosen according to the ASTM D3039. The test was carried out at a room temperature of 25° C and a loading rate of 2.5 mm/min. Flexural test was conducted according to the ASTM D790-07 on the same UTM using a flexural test fixture and a load cell of 1 KN. Impact strength of the composites was measured by the pendulum impact tester (Model: Zwick/Roell, 727676) as per ASTM D256-06 standard. Micro-hardness of the composite laminate specimens was measured by using a Shore hardness tester (Model: Rex durometer, OS-1) as per ASTM E384 standard. Thermogravimetric analysis (TGA) traces were recorded in the temperature range from 50 to 700° C. with a heating rate of 10° C./min by a TGA 2 (Model: Mettler Toledo TGA/DSC 3+HT/1600, Switzerland).
Results
It is useful to evaluate the thermal stability of composites at different temperatures to decide the temperature range for composites applications.
The results of the thermal analysis indicate that the CPCFCEFC has a much better thermal stability because the CFF reinforcements act as a thermal barrier in the composite materials. The TGA results confirmed that the CFFs and CPFs are suitable compositions for reinforcement in composite applications with working temperatures up to 310° C.
Obviously, numerous modifications and variations of the present disclosure are possible in light of the above teachings. It is therefore to be understood that within the scope of the appended claims, the invention may be practiced otherwise than as specifically described herein.
Number | Name | Date | Kind |
---|---|---|---|
2398347 | Anderson | Apr 1946 | A |
2814851 | Hervey | Dec 1957 | A |
5817303 | Stedronsky | Oct 1998 | A |
5897739 | Forster | Apr 1999 | A |
5958593 | Shomer | Sep 1999 | A |
20070077423 | Yan | Apr 2007 | A1 |
20080236716 | Bergman | Oct 2008 | A1 |
20100078287 | Gaffney | Apr 2010 | A1 |
20110271616 | Rasmussen | Nov 2011 | A1 |
20110272856 | Rasmussen et al. | Nov 2011 | A1 |
20110293876 | Rasmussen et al. | Dec 2011 | A1 |
20180334522 | Rabnawaz | Nov 2018 | A1 |
20200181845 | Dinzinger | Jun 2020 | A1 |
20210257228 | Sakai | Aug 2021 | A1 |
20210260793 | Iftime | Aug 2021 | A1 |
20210323253 | Lu | Oct 2021 | A1 |
Number | Date | Country |
---|---|---|
102013003950-0 | Sep 2020 | BR |
104233505 | Dec 2014 | CN |
201941027362 | Aug 2019 | IN |
Entry |
---|
Kumar et al., Physicochemical and Thermal Properties of Ceiba pentandra Bark Fiber, Oct. 3, 2017, Taylor & Francis (Year: 2017). |
Performance Composites, Carbon Fiber Composite Design Guide, Feb. 9, 2018, Performance Composites (Year: 2018). |
Dipen Kumar Rajak, et al., “Fiber-Reinforced Polymer Composites: Manufacturing, Properties, and Applications”, Polymers, vol. 11, Issue 10: 1667, Oct. 12, 2019, pp. 1-37. |
Akarsh Verma, et al., “Experimental Analysis on Carbon Residuum Transformed Epoxy Resin: Chicken Feather Fiber Hybrid Composite”, Polymer Composites, vol. 40, Issue 7, Oct. 12, 2018, pp. 2690-2699 (Abstract only). |
A. Verma, et al., “Physical and Thermal Characterization of Chicken Feather Fiber and Crumb Rubber Reformed Epoxy Resin Hybrid Composite”, Advances in Civil Engineering Materials, vol. 7, No. 1, 2018, pp. 2690-2699 (Abstract only). |